CN215026060U - Processing system for evaporation crystallization and secondary steam purification of fly ash water washing liquid - Google Patents
Processing system for evaporation crystallization and secondary steam purification of fly ash water washing liquid Download PDFInfo
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Abstract
The utility model discloses a flying dust washing liquid evaporative crystallization and secondary steam purification's processing system, including preheating unit, membrane evaporation and separation unit, forced circulation evaporative crystallization unit, secondary steam purification unit and vapor compression unit. The secondary steam purification device of the utility model can effectively remove impurities in the steam and ensure the stable operation of the system; the forced circulation heat exchanger is adopted in the evaporation concentration process, so that the scaling phenomenon of equipment in the evaporation concentration process is reduced, and the energy consumption of mass transfer and heat transfer is reduced; the non-crystallized mother liquor generated by the forced circulation evaporation crystallization unit and the cleaning solution generated by the secondary steam purification unit are purified and reused, so that the equipment load of the evaporation crystallization unit is reduced, and the consumption of the forced circulation evaporation equipment is reduced; the steam from the falling film separator and the evaporation crystallizer is compressed in two/three stages, so that the secondary steam is reused and the steam utilization rate is improved.
Description
Technical Field
The utility model relates to a flying dust dechlorination and recycle's processing system again especially relates to flying dust washing liquid evaporative crystallization and secondary vapor purification's processing system, belongs to flying dust washing liquid and recycles the field.
Background
The fly ash is a powdery substance which is collected in a flue gas pipeline, a flue gas purification device, a separator, a dust remover device and the like in the waste incineration process and has light volume weight and small particle size. The fly ash is listed as solid hazardous waste (code HW18) by the nation because the fly ash is rich in heavy metal inorganic harmful substances and high-concentration dioxin organic carcinogens. The fly ash can be treated in a harmless and resource way by adopting the technology of cooperatively treating the fly ash by the cement kiln. The water washing pretreatment of the fly ash can transfer soluble substances (potassium, sodium and chloride ions) in the fly ash into water washing liquid, the fly ash water washing liquid contains about 6 to 15 weight percent of potassium and sodium salts, potassium salt resources in China are relatively scarce, and potassium salt and sodium salt are prepared from the fly ash water washing liquid by an evaporation crystallization technology, so that the vacancy of potassium salt in China can be relieved.
Generally, in the evaporative crystallization process of high-salinity wastewater, scaling is easy to form in the heating pipe along with the increase of temperature and concentration. The heat conduction is seriously influenced after the pipe wall is scaled, the evaporation treatment capacity is influenced, and the stability of evaporation equipment is damaged. Meanwhile, in the evaporation process, steam usually discharged from the falling film separator and the crystallization separator needs to enter a compressor, and is returned to equipment for reuse after being compressed and heated. The steam contains a large amount of salt substances, which can seriously affect the stable operation of the system, easily cause the corrosion of the compressor, reduce the service life of the compressor, affect the process performance of the system and increase the cost.
The Chinese invention patent (CN108191135A) discloses a system and a method for preparing salt by evaporating waste incineration fly ash or kiln ash water washing liquid, which comprises a falling film evaporation unit, a forced circulation crystallization unit and an equal gradient cooling crystallization unit; each unit is internally provided with an independent condensed water collecting system, a noncondensable gas treatment system and a mechanical vapor recompression system; and a forced circulation crystallization unit is provided with a separation device, and potassium salt and sodium salt are separated. Although the method realizes the difficult scabbing of equipment, good product salt quality and stable system operation to a certain extent in the evaporation salt-making process aiming at the fly ash or kiln ash washing liquid with high salt content, the fly ash washing liquid has complex components and high salt concentration, the feed liquid is continuously and circularly evaporated in the evaporation process, salt crystal grains in the concentrated feed liquid can be attached to the surface of an evaporator, the heat transfer is uneven, the heat transfer efficiency is low, energy waste can be caused, the regular shutdown and cleaning are required, and the production efficiency is seriously influenced.
The Chinese invention patent (CN203959976U) discloses a strong brine mechanical steam recompression evaporation crystallization system, which comprises a calcium and magnesium removal reaction tank, a filter press and a feeding tank, wherein the filter press is connected with the calcium and magnesium removal reaction tank, and the feeding tank is connected with the filter press; the MVR evaporation crystallization device is connected with the feeding tank; and the thickener, the centrifuge and the mother liquor tank, wherein an inlet of the thickener is connected with the MVR evaporative crystallization device, an outlet of the thickener is connected with the centrifuge, and a liquid outlet of the centrifuge is connected with the MVR evaporative crystallization device through the mother liquor tank. The MVR evaporative crystallization device comprises a crystallization separator 8, a crystallization heater 12 and a compressor. The technology aims at treating mixed concentrated brine with TDS concentration of 100-300 g/L, can solve regional water resource shortage and reduce environmental pollution. However, in the evaporation process, the steam generated by the crystallization separator is directly compressed in two stages and then sent to the crystallization heater for practical use. The steam contains a large amount of salt substances, which can seriously affect the stable operation of the system, easily cause the corrosion of the compressor, reduce the service life of the compressor, affect the process performance of the system and increase the cost.
SUMMERY OF THE UTILITY MODEL
The utility model mainly aims at providing a flying dust washing liquid evaporation crystallization and secondary steam purification's processing system to solve the problem that prior art exists.
In order to achieve the above object, the present invention adopts the following technical solutions:
a treatment system for evaporation crystallization and secondary steam purification of fly ash water washing liquid comprises a preheating unit, a membrane evaporation and separation unit, a forced circulation evaporation and crystallization unit, a secondary steam purification unit and a steam compression unit;
the preheating unit comprises a raw material tank, a raw liquid pump, a condensed water plate type heat exchanger, a non-condensing heat exchanger, a raw steam plate type heat exchanger, a distilled water pump, a condensed water tank, a liquid accumulation pump and a liquid accumulation tank which are sequentially connected through pipelines;
the raw steam plate type heat exchanger is provided with a feed liquid inlet, a fresh steam inlet and a condensed water outlet, and the condensed water outlet of the raw steam plate type heat exchanger is communicated with the inlet of a condensed water tank;
the membrane evaporation and separation unit comprises a membrane evaporator, a circulating pump, a membrane separator and a material transfer pump 2-4; the membrane evaporator is provided with a feed liquid inlet, a gas phase inlet, a condensed water outlet, a first concentrated feed liquid outlet and a second concentrated feed liquid outlet; the feed liquid inlet of the membrane evaporator is arranged at the top, a first concentrated feed liquid outlet and a second concentrated feed liquid outlet of the membrane evaporator are both arranged at the bottom, the feed liquid inlet of the membrane evaporator is connected with the first concentrated feed liquid outlet through a circulating pump, the first concentrated feed liquid outlet is connected with the concentrated feed liquid inlet of the membrane separator, and the second feed liquid outlet of the membrane evaporator is connected with the feed liquid inlet of the evaporation crystallizer through a material transfer pump; a feed liquid inlet of the membrane evaporator is connected with a feed liquid outlet of the raw steam plate type heat exchanger and a condensed water outlet of the condensed water tank;
the membrane type separator is provided with a concentrated feed liquid feeding hole, a concentrated feed liquid discharging hole, a steam outlet and a condensed water outlet; the steam outlet is arranged at the top of the membrane separator, the concentrated feed liquid discharge port is arranged at the lower end of the membrane separator, the steam outlet of the membrane separator is connected with the inlet of the secondary steam purification unit through a pipeline, and the concentrated feed liquid outlet of the membrane separator is communicated with the feed liquid inlet of the membrane evaporator through a pipeline.
The forced circulation evaporative crystallization unit comprises an evaporative crystallizer, a forced circulation pump, a forced circulation heat exchanger, a crystal slurry pump and a crystal salt separator; the evaporation crystallizer is provided with a feed liquid inlet, a steam outlet, a strong brine outlet, a crystal slurry outlet and a steam outlet; the steam outlet of the evaporation crystallizer is arranged at the top of the evaporation crystallizer, the steam outlet is connected with the inlet of the secondary steam purification unit, and the strong brine outlet of the evaporation crystallizer is connected with the inlet of the forced circulation heat exchanger through a forced circulation pump.
The crystallized salt separator is provided with a crystal slurry inlet, a mother liquid outlet, a non-crystallized mother liquid outlet and a crystallized salt outlet; the crystal slurry outlet of the evaporative crystallizer is connected with the crystal slurry inlet of the crystallized salt separator through a crystal slurry pump, the mother liquor outlet of the crystallized salt separator is connected with the inlet of the forced circulation heat exchanger through a forced circulation pump, and the non-crystallized mother liquor outlet of the crystallized salt separator is connected with the inlet of the purification treatment device.
The secondary steam purification unit comprises a scrubber tower. The gas washing tower is provided with a gas phase inlet, a gas phase outlet and a condensed water recycling inlet; and a steam inlet of the gas washing tower is communicated with a steam outlet of the membrane separator and a steam outlet of the evaporative crystallizer, and a steam outlet of the gas washing tower is communicated with an inlet of the steam compression unit. The gas washing device is provided with a condensed water recycling inlet, namely, the gas washing liquid water is condensed water generated by the condensed water heat exchange device.
Wherein, the steam of the membrane separator is connected with the gas phase inlet of the gas washing tower through a pipeline, and the steam outlet of the evaporation crystallizer is connected with the gas phase inlet of the gas washing tower; the gas phase outlet of the scrubber tower 4 is in communication with the inlet of the vapor compression unit.
The vapor compression unit comprises a first compressor, a second compressor and a third compressor; the first compressor, the second compressor and the third compressor are respectively provided with a steam inlet, a steam outlet, a water outlet, a machine seal water inlet and a fresh steam inlet, wherein the second compressor is provided with a first steam outlet and a second steam outlet; a vapor inlet of the first compressor is communicated with a gas phase outlet of the scrubbing tower, a vapor outlet of the first compressor is communicated with a vapor inlet of the second compressor, and a first vapor outlet of the second compressor is communicated with a vapor inlet of the third compressor; a steam outlet of the third compressor is communicated with a heat source inlet of the forced circulation heat exchanger, and a steam outlet of the forced circulation heat exchanger is communicated with a steam inlet of the membrane evaporator; a second steam outlet of the second compressor is communicated with a heat source inlet of the membrane evaporator, and a steam outlet of the membrane evaporator is communicated with a steam inlet of the noncondensable gas plate type heat exchanger;
the water outlet of the first compressor, the water outlet of the second compressor and the water outlet of the third compressor are communicated with the water inlet of the condensed water collecting device; a water outlet of the raw steam plate type heat exchanger is communicated with a water inlet of the condensed water collecting device; the water outlet of the membrane evaporator and the water outlet of the forced circulation heat exchanger are communicated with the water inlet of the condensed water collecting device; the water outlet of the condensed water collecting device is communicated with the water inlet of the condensed water heat exchange device, and condensed water of the condensed water heat exchange device is discharged from the water outlet; the secondary steam purification is provided with a condensed water recycling inlet, and a water outlet of the secondary steam purification is communicated with a water inlet of the purification treatment device.
The water outlets of the first compressor, the second compressor and the third compressor are communicated with the water inlet of the effusion tank through pipelines; and a condensed water outlet of the falling film evaporator and a condensed water outlet of the forced circulation heat exchanger are communicated with a water inlet of a condensed water tank through pipelines.
In a more preferable embodiment of the utility model, the condensed water tank is connected with the effusion tank through the effusion pump; the condensate water tank is connected with the condensate water plate type heat exchanger through a distilled water pump and provides condensate water for heat exchange for the condensate water plate type heat exchanger; and a condensed water outlet of the condensed water plate type heat exchanger is used for discharging and recycling condensed water. The discharged condensed water can be reused as the gas washing liquid in the gas washing tower.
The utility model discloses well condensate water collection device delivery port communicates with each other with the comdenstion water heat transfer device water inlet, and the comdenstion water heat transfer device thermal current adopts the comdenstion water that each device produced to preheat promptly. The utility model discloses well condensate water collection device is equipped with four water inlets, and membrane evaporator comdenstion water, forced circulation heat exchanger comdenstion water, the steam heat transfer device comdenstion water of giving birth to, first compressor second compressor third compressor machine seal water promptly, and is preferred, and comdenstion water heat transfer device, noncondensable gas heat transfer device, give birth to steam heat transfer device are plate heat exchanger.
Preferably, the middle membrane evaporator of the present invention is preferably a falling film evaporator, and the membrane separator is preferably a falling film separator.
Compared with the prior art, the utility model, have following advantage and outstanding technological effect:
1. the secondary steam purification device is arranged, salt substances and other impurities in the steam can be effectively removed, and the stable operation of the system is ensured.
2. The forced circulation heat exchanger is adopted in the evaporation concentration process, so that the scaling phenomenon of equipment in the evaporation concentration process is reduced, and the energy consumption of mass transfer and heat transfer is reduced.
3. The non-crystallization mother liquor generated by the forced circulation evaporation crystallization unit (the non-crystallization mother liquor is the mother liquor required to be discharged in the evaporation crystallization treatment process) and the cleaning liquid generated by the secondary steam purification unit are reused after purification treatment, so that the equipment load of the evaporation crystallization unit is reduced, the consumption of the forced circulation evaporation equipment is reduced to a certain extent, and the yield of salt produced by the system is improved more efficiently.
4. The steam from the falling film separator and the evaporation crystallizer is compressed in two/three stages, so that the secondary steam is recycled, the steam utilization rate is improved, and the operation cost is reduced.
Drawings
Fig. 1 is a schematic diagram of the system of the present invention.
Description of reference numerals: 1-1 raw liquid tank, 1-2 raw liquid pump, 1-3 condensed water plate heat exchanger, 1-4 non-condensing heat exchanger, 1-5 steam plate heat exchanger, 1-6 distilled water pump, 1-7 condensed water tank, 1-8 liquid accumulation pump, 1-9 liquid accumulation tank, 2-1 falling film heat exchanger, 2-2 circulating pump, 2-3 falling film separator, 2-4 material transfer pump, 3-1 evaporation crystallizer, 3-2 forced circulating pump, 3-3 forced circulation heat exchanger, 3-4 crystal slurry pump, 3-5 crystal salt separator, 4-1 gas washing tower, 5-1 first compressor, 5-2 second compressor, 5-3 third compressor.
Detailed Description
The invention will be described with reference to specific embodiments and drawings, the advantages and features of which will become more apparent as the description proceeds. It is to be understood that these examples are illustrative only and are not to be construed as limiting the scope of the invention in any way. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention, and it is intended that all such changes and modifications fall within the scope of the invention.
In the description of the embodiments of the present application, it should be noted that the indication of orientation or positional relationship is based on the orientation or positional relationship shown in the drawings, or the orientation or positional relationship which is usually placed when the product of the application is used, or the orientation or positional relationship which is usually understood by those skilled in the art, or the orientation or positional relationship which is usually placed when the product of the application is used, and is only for the convenience of describing the application and simplifying the description, but does not indicate or imply that the indicated device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the application. In the description of the embodiments of the present application, it should also be noted that, unless otherwise explicitly stated or limited, the terms "disposed," "mounted," and "connected" are to be construed broadly, and may for example be fixedly connected, detachably connected, or integrally connected; may be directly connected or indirectly connected through an intermediate. The specific meaning of the above terms in the present application can be understood in a specific case by those of ordinary skill in the art.
In the description of embodiments of the present application, reference to the description of the term "one embodiment," "some embodiments," "an example," "a specific example," or "some examples," etc., means that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples and features of different embodiments or examples described in this specification can be combined and combined by one skilled in the art without contradiction.
A treatment method for evaporation crystallization and secondary steam purification of fly ash water washing liquid comprises the following steps: (1) carrying out heat exchange treatment on the purified fly ash water washing liquid in a preheating unit, and preheating the feed liquid to 80-100 ℃; (2) the preheated feed liquid is heated and vaporized by a heating medium in the falling film evaporator 2-1, and the generated steam and the feed liquid enter a falling film separator 2-3 to be separated into steam and feed liquid to respectively obtain steam and concentrated feed liquid; the steam enters a secondary steam purification unit for purification treatment, concentrated feed liquid flows back to a falling film evaporator 2-1, and enters an evaporation crystallizer 3-1 for concentration and crystallization when the solid-to-liquid ratio of the feed liquid reaches 20-25%, so as to obtain strong brine, crystal slurry and secondary steam respectively; pumping the concentrated salt solution into a forced circulation heat exchanger 3-3 under the action of a forced circulation pump 3-2 to carry out evaporation concentration treatment to obtain concentrated feed liquid, and then feeding the concentrated feed liquid into an evaporation crystallizer 3-1; the secondary steam enters a secondary steam purification unit for purification treatment; (3) pumping the crystal slurry generated in the step (2) into a crystallization salt separator 3-5 under the action of a crystal slurry pump 3-4 for purification and separation treatment to respectively obtain crystallization salt, non-crystallization mother liquor and mother liquor; the mother liquor returns to the forced circulation heat exchanger 3-3 for continuous evaporation and concentration treatment under the action of the forced circulation pump 3-2 through a pipeline; the non-crystallization mother liquor enters a purification treatment device through a pipeline for purification treatment; (4) and (3) compressing the steam subjected to the purification treatment in the step (2) by a steam compression unit.
As a preferred embodiment, the method for heat-exchanging the purified fly ash water scrubbing liquid in the preheating unit in the step (1) comprises the following steps: purified fly ash washing liquid stored in a raw liquid tank 1-1 sequentially enters a condensed water plate type heat exchanger 1-3, a non-condensing heat exchanger 1-4 and a raw steam plate type heat exchanger 1-5 under the action of a raw liquid pump 1-2, and is subjected to heat exchange treatment with condensed water in the condensed water plate type heat exchanger 1-3, non-condensing gas in the non-condensing gas plate type heat exchanger 1-4 and fresh steam in the raw steam plate type heat exchanger 1-5; the condensed water is condensed water in a condensed water tank 1-7, namely secondary steam condensed water obtained by heat exchange and evaporation, and the temperature of the condensed water is 80-100 ℃; the fresh steam is preferably saturated steam with the temperature of 110-130 ℃.
As a preferred specific embodiment, in the step (2), the preheated feed liquid enters the falling film evaporator 2-1 to enable the feed liquid to flow from top to bottom to complete heating vaporization, the generated steam and the concentrated feed liquid enter the falling film separator 2-3 through a pipeline to generate steam and concentrated feed liquid, the steam enters the secondary steam purification unit, the concentrated feed liquid returns to the falling film evaporator 2-1 again through a pipeline to complete heating, and then enters the evaporation crystallizer 3-1 through the action of the material transfer pump 2-4 to perform evaporation crystallization to respectively obtain concentrated salt liquid, crystal slurry and steam; pumping the strong brine into a forced circulation heat exchanger 3-3 through a forced circulation pump 3-2 to continue evaporation concentration treatment, introducing steam into a gas washing system for treatment, introducing the crystal slurry into a crystal salt separator 3-5 through a crystal slurry pump 3-4 to crystallize and stratify, and obtaining a mother liquor, a non-crystallized mother liquor and a crystallized salt; wherein, the mother liquor enters a forced circulation pump 3-2 through a pipeline to continue evaporation concentration treatment, and the mother liquor which is not crystallized enters a purification treatment device through a pipeline to be treated.
As a preferred embodiment, the gas washing system in the step (2) is a gas washing tower 4-1, and the steam entering the gas washing system is secondary steam with the temperature of 85-95 ℃.
As a preferred embodiment, in the step (2), the evaporation temperature is controlled to 90 to 100 ℃ when the evaporation treatment is carried out in the falling-film evaporator 2-1, and the heating medium in the falling-film evaporator 2-1 is derived from the steam of the second compressor 5-2 at a temperature of 110 to 130 ℃; after steam is condensed, the steam is discharged from a condensate water outlet of the falling film evaporator 2-1 and then enters a condensate water tank 1-7, the condensate water tank 1-7 is used for storing secondary steam condensate water obtained by heat exchange and evaporation, and the temperature of the condensate water is 80-100 ℃.
As a preferred embodiment, the step (2) controls the temperature of the forced circulation heat exchanger 3-3 at 100-120 ℃ when the evaporation concentration treatment is carried out in the forced circulation heat exchanger 3-3; in the step (4), the purified steam enters the first compressor 5-1 and the second compressor 5-2 in sequence for compression treatment to obtain steam with the temperature of 110-; or the purified steam enters the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 in sequence for compression treatment to obtain high-temperature steam with the temperature of 90-110 ℃, the high-temperature steam is recycled to the forced circulation heat exchanger 3-3 to heat the feed liquid, and the high-temperature steam is condensed into water flow to the condensate water tank 1-7 in the feed liquid heating process.
Referring to fig. 1, the treatment system for evaporation crystallization and secondary steam purification of fly ash washing liquid provided by the present invention comprises a preheating unit, a membrane evaporation and separation unit, a forced circulation evaporation and crystallization unit, a secondary steam purification unit and a steam compression unit;
the preheating unit comprises a raw material tank 1-1, a raw liquid pump 1-2, a condensed water plate heat exchanger 1-3, a non-condensing heat exchanger 1-4, a raw steam plate heat exchanger 1-5, a distilled water pump 1-6, a condensed water tank 1-7, a liquid accumulation pump 1-8 and a liquid accumulation tank 1-9 which are sequentially connected through pipelines; the raw steam plate type heat exchanger 1-5 is provided with a feed liquid inlet, a fresh steam inlet and a condensed water outlet, and the condensed water outlet of the raw steam plate type heat exchanger 1-5 is communicated with the inlet of a condensed water tank 1-7;
the membrane evaporation separation unit comprises a membrane evaporator 2-1, a circulating pump 2-2, a membrane separator 2-3 and a material transfer pump 2-4; wherein, the membrane evaporator 2-1 is provided with a feed liquid inlet, a gas phase inlet, a condensed water outlet, a first concentrated feed liquid outlet and a second concentrated feed liquid outlet; the feed liquid inlet is arranged at the top, the first concentrated feed liquid outlet and the second concentrated feed liquid outlet are arranged at the bottom, the feed liquid inlet is connected with the first concentrated feed liquid outlet through a circulating pump 2-2, the first concentrated feed liquid outlet is connected with the concentrated feed liquid inlet of the membrane type separator 2-3, and the second feed liquid outlet of the membrane type evaporator 2-1 is connected with the feed liquid inlet of the evaporative crystallizer 3-1 through a material transfer pump 2-4; the feed liquid inlet of the membrane evaporator 2-1 is connected with the feed liquid outlet of the raw steam plate type heat exchanger 1-5 and the condensed water outlet of the condensed water tank.
The membrane type separator 2-3 is provided with a concentrated feed liquid feeding hole, a concentrated feed liquid discharging hole, a steam outlet and a condensed water outlet; wherein, the steam outlet is arranged at the top of the membrane separator 2-3, the concentrated feed liquid discharge port is arranged at the lower end, the steam outlet of the membrane separator 2-3 enters and is connected with the secondary steam purification unit through a pipeline, and the concentrated feed liquid outlet of the membrane separator 2-3 is communicated with the feed liquid inlet of the membrane evaporator 2-1 through a pipeline.
The forced circulation evaporation crystallization unit comprises an evaporation crystallizer 3-1, a forced circulation pump 3-2, a forced circulation heat exchanger 3-3, a crystal slurry pump 3-4 and a crystallized salt separator 3-5; wherein, the evaporation crystallizer 3-1 is provided with a feed liquid inlet, a steam outlet, a strong brine outlet, a crystal slurry outlet and a steam outlet; the steam outlet is arranged at the top of the evaporation crystallizer, the steam outlet is connected with the inlet of the secondary steam purification unit, and the concentrated brine outlet is connected with the inlet of the forced circulation heat exchanger 3-3 through a forced circulation pump 3-2.
The crystallized salt separator 3-5 is provided with a crystal slurry inlet, a mother liquor outlet, a non-crystallized mother liquor outlet and a crystallized salt outlet; wherein, the crystal slurry outlet of the evaporation crystallizer 3-1 is connected with the crystal slurry inlet of the crystallization salt separator 3-5 through a crystal slurry pump 3-4, the mother liquor outlet is connected with the inlet of the forced circulation heat exchanger 3-3 through a forced circulation pump 3-2, and the non-crystallization mother liquor outlet is connected with the inlet of the purification treatment device.
The secondary steam purification unit comprises a gas washing tower 4-1 (the utility model discloses a waste incineration fly ash or kiln dust water washing liquid evaporation salt production system CN 208414108U); the gas washing tower 4-1 is provided with a steam inlet, a steam outlet and a condensed water recycling inlet, the steam inlet is communicated with the steam outlet of the membrane separator 2-3 and the steam outlet of the evaporative crystallizer 3-1, the steam outlet is communicated with the steam compression unit, the gas washing device is provided with the condensed water recycling inlet, namely, the water used by the gas washing liquid is condensed water generated by the condensed water heat exchange device.
The steam of the membrane separator 2-3 is connected with the gas phase inlet of the scrubber 4-1 through a pipeline. A steam outlet of the evaporative crystallizer 3-2 is connected with a gas phase inlet of the gas washing tower 4-1; the gas phase outlet of the scrubber 4-1 is communicated with the inlet of the vapor compression unit.
The vapor compression unit comprises a first compressor 5-1, a second compressor 5-2 and a third compressor 5-3; the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 are all provided with a steam inlet, a steam outlet, a water outlet, a machine seal water inlet and a fresh steam inlet, wherein the second compressor 5-2 is provided with a first steam outlet and a second steam outlet; a steam inlet of the first compressor 5-1 is communicated with a steam outlet of the scrubber 4-1, a steam outlet of the first compressor 5-1 is communicated with a steam inlet of the second compressor 5-2, and a first steam outlet of the second compressor 5-2 is communicated with a steam inlet of the third compressor 5-3; a steam outlet of the third compressor 5-3 is communicated with a heat source inlet of the forced circulation heat exchanger 3-3, and a steam outlet of the forced circulation heat exchanger 3-3 is communicated with a steam inlet of the membrane evaporator 2-1; a second steam outlet of the second compressor 5-2 is communicated with a heat source inlet of the membrane evaporator 2-1, and a steam outlet of the membrane evaporator 2-1 is communicated with a steam inlet of the non-condensable gas plate type heat exchanger 1-4.
The water outlet of the first compressor 5-1, the water outlet of the second compressor 5-2 and the water outlet of the third compressor 5-3 are communicated with the water inlet of the condensed water collecting device; the water outlet of the raw steam plate type heat exchanger 1-5 is communicated with the water inlet of the condensed water collecting device; the water outlet of the membrane evaporator 2-1 and the water outlet of the forced circulation heat exchanger 3-3 are communicated with the water inlet of a condensed water collecting device; the water outlet of the condensed water collecting device is communicated with the water inlet of the condensed water heat exchange device, and condensed water of the condensed water heat exchange device is discharged from the water outlet; the secondary steam purification is provided with a condensed water recycling inlet, and a water outlet of the secondary steam purification is communicated with a water inlet of the purification treatment device.
The water outlets of the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 are all communicated with the water inlet of the liquid accumulation tank 1-9 through pipelines.
The condensed water outlet of the falling-film evaporator 2-1 and the condensed water outlet of the forced circulation heat exchanger 3-3 are both communicated with the water inlet of the condensed water tank 1-7 through pipelines.
In a more preferable embodiment of the utility model, the condensed water tank 1-7 is connected with the liquid accumulation tank 1-9 through a liquid accumulation pump; the condensate water tank 1-7 is connected with the condensate water plate type heat exchanger 1-3 through a distilled water pump 1-6, and the condensate water tank 1-7 provides condensate water for heat exchange for the condensate water plate type heat exchanger 1-3; and a condensed water outlet of the condensed water plate type heat exchanger 1-3 is used for discharging and recycling condensed water, and the discharged condensed water can be recycled to the gas washing tower 4-1 to be used for gas washing liquid.
The utility model discloses well condensate water collection device delivery port communicates with each other with the comdenstion water heat transfer device water inlet, and the comdenstion water heat transfer device thermal current adopts the comdenstion water that each device produced to preheat promptly. The utility model discloses well condensate water collection device is equipped with four water inlets, and membrane evaporator comdenstion water, forced circulation heat exchanger comdenstion water, the steam heat transfer device comdenstion water of giving birth to, first compressor second compressor third compressor machine seal water promptly, and is preferred, and comdenstion water heat transfer device, noncondensable gas heat transfer device, give birth to steam heat transfer device are plate heat exchanger.
In the utility model, the membrane evaporator is preferably a falling film evaporator, and the membrane separator is preferably a falling film separator.
The system of the present invention will be further described with reference to specific embodiments.
EXAMPLE 1 fly ash Water scrubbing liquid evaporative crystallization and Secondary steam purification treatment method
Preheating water washing liquid: and (3) introducing the purified fly ash washing liquid into a raw liquid tank 1-1, pumping the material liquid through a raw liquid pump 1-2, sequentially exchanging heat with a condensed water plate type heat exchanger 1-3, a non-condensable gas plate type heat exchanger 1-4 and a raw steam plate type heat exchanger 1, and heating to an evaporation temperature.
Specifically, the feed liquid exchanges heat with condensed water, non-condensable gas and fresh steam in each preheater in sequence to reach the evaporation temperature of 90-110 ℃ of the feed liquid, the condensed water is condensed water in a condensed water tank 1-7, namely secondary steam condensed water obtained by heat exchange and evaporation, and the temperature of the condensed water is 80-100 ℃; the fresh steam is saturated steam with the pressure of 0.1MpaG and the temperature of 120 ℃.
Step (2) falling film evaporation: the preheated feed liquid enters a falling film evaporator 2-1, the feed liquid is heated and vaporized by a heating medium in the falling film evaporator 2-1, the generated steam and the feed liquid enter a falling film separator 2-3, gas and liquid are fully separated in the falling film separator 2-3, the steam enters a gas washing system, and the concentrated feed liquid flows back to the falling film evaporator 2-1; when the solid-liquid ratio of the feed liquid reaches 20-25%, carrying out the operation of the step (3);
specifically, the evaporation temperature in the falling-film evaporator 2-1 is controlled at 90-100 ℃; the heating medium in the falling-film evaporator 2-1 comes from the second compressor 5-2 and is steam with the pressure of 0.1MpaG and the temperature of 120 ℃; after being condensed, the steam is discharged from a condensate water outlet of the falling film evaporator 2-1 and then enters a condensate water tank 1-7; the gas washing system is a gas washing tower 4-1, and the steam entering the gas washing system is secondary steam with the pressure of 0.1MpaG and the temperature of 90 ℃.
And (3) evaporation and crystallization: feeding the feed liquid treated in the step (2) into an evaporation crystallizer 3-1 for concentration and crystallization to obtain strong brine, crystal slurry and secondary steam; pumping the concentrated salt solution into a forced circulation heat exchanger 3-3 under the action of a forced circulation pump 3-2 for evaporation and concentration treatment to obtain concentrated feed liquid, and feeding the concentrated feed liquid into an evaporation crystallizer 3-1; and the secondary steam enters a gas washing system.
Specifically, the temperature of the forced circulation heat exchanger 3-3 is controlled at 100-120 ℃; the secondary steam is discharged from the top of the evaporative crystallizer 3-1, the pressure is 0.1MpaG, and the temperature is 85 ℃.
Step (4), crystallization and separation: pumping crystal slurry generated in the evaporation crystallization process into a crystallization salt separator 3-5 under the action of a crystal slurry pump 3-4, and purifying and separating crystallization salt and feed liquid to obtain crystallization salt with the water content not more than 6 wt%, non-crystallization mother liquid and mother liquid; the separated mother liquor returns to the forced circulation heat exchanger 3-3 through a pipeline under the action of the forced circulation pump 3-2 to continue to be subjected to evaporation concentration treatment; the non-crystallization mother liquor enters a purification treatment device through a pipeline for treatment.
And (5) secondary steam compression: and the steam purified by the gas washing tower 4-1 is compressed by a steam compression unit, and returns to the forced circulation evaporation crystallization unit after being heated and pressurized.
Specifically, purified steam enters a first compressor 5-1 and a second compressor 5-2 in sequence, the steam with the temperature of 105 ℃ and the pressure of 120.8Kpa is obtained after compression, the steam is recycled to a falling film evaporator 2-1 to heat feed liquid, and the steam is condensed into water flowing to a condensate water tank 1-7 in the process of heating the feed liquid; the purified steam enters a first compressor 5-1, a second compressor 5-2 and a third compressor 5-3 in sequence, high-temperature steam with the temperature of 90-110 ℃ is obtained after compression, the high-temperature steam is recycled to a forced circulation heat exchanger 3-3 to heat feed liquid, and the high-temperature steam is condensed into water flow to a condensate water tank 1-7 in the feed liquid heating process.
Specifically, the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 are all provided with fresh steam inlets, and the fresh steam is saturated steam with the pressure of 0.1MpaG and the temperature of 120 ℃.
Specifically, the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 are provided with machine seal water inlets, and water outlets of the first compressor 5-1, the second compressor 5-2 and the third compressor 5-3 are connected with the liquid accumulation tank 1-9 through pipelines and are sent into the condensed water tank 1-7 through the liquid accumulation pump 1-8.
Claims (10)
1. A fly ash washing liquid evaporation crystallization and secondary steam purification's processing system which characterized in that includes: the system comprises a preheating unit, a membrane evaporation and separation unit, a forced circulation evaporation and crystallization unit, a secondary steam purification unit and a steam compression unit.
2. The treatment system according to claim 1, wherein the preheating unit comprises a raw material tank (1-1), a raw material pump (1-2), a condensed water plate heat exchanger (1-3), a non-condensing heat exchanger (1-4), a raw steam plate heat exchanger (1-5), a distilled water pump (1-6), a condensed water tank (1-7), a liquid collecting pump (1-8) and a liquid collecting tank (1-9) which are connected in sequence through pipelines; the raw steam plate type heat exchanger (1-5) is provided with a feed liquid inlet, a fresh steam inlet and a condensed water outlet, and the condensed water outlet of the raw steam plate type heat exchanger (1-5) is communicated with the inlet of a condensed water tank 1-7;
the membrane evaporation separation unit comprises a membrane evaporator (2-1), a circulating pump (2-2), a membrane separator (2-3) and a material transfer pump (2-4); wherein the membrane evaporator (2-1) is provided with a feed liquid inlet, a gas phase inlet, a condensed water outlet, a first concentrated feed liquid outlet and a second concentrated feed liquid outlet; the feed liquid inlet of the membrane evaporator (2-1) is arranged at the top, the first concentrated feed liquid outlet and the second concentrated feed liquid outlet of the membrane evaporator (2-1) are both arranged at the bottom, the feed liquid inlet of the membrane evaporator (2-1) is connected with the first concentrated feed liquid outlet through a circulating pump (2-2), the first concentrated feed liquid outlet is connected with the concentrated feed liquid inlet of the membrane separator (2-3), and the second feed liquid outlet of the membrane evaporator (2-1) is connected with the feed liquid inlet of the evaporation crystallizer (3-1) through a material transfer pump (2-4); a feed liquid inlet of the membrane evaporator (2-1) is connected with a feed liquid outlet of the raw steam plate type heat exchanger (1-5) and a condensed water outlet of the condensed water tank;
the membrane separator (2-3) is provided with a concentrated feed liquid feeding hole, a concentrated feed liquid discharging hole, a steam outlet and a condensed water outlet; wherein, the steam outlet is arranged at the top of the membrane separator (2-3), the concentrated feed liquid discharge port is arranged at the lower end of the membrane separator (2-3), the steam outlet of the membrane separator (2-3) is connected with the inlet of the secondary steam purification unit through a pipeline, and the concentrated feed liquid outlet of the membrane separator (2-3) is communicated with the feed liquid inlet of the membrane evaporator (2-1) through a pipeline;
the forced circulation evaporative crystallization unit comprises an evaporative crystallizer (3-1), a forced circulation pump (3-2), a forced circulation heat exchanger (3-3), a crystal slurry pump (3-4) and a crystallized salt separator (3-5); the evaporation crystallizer (3-1) is provided with a feed liquid inlet, a steam outlet, a strong brine outlet, a crystal slurry outlet and a steam outlet; wherein, a steam outlet of the evaporative crystallizer (3-1) is arranged at the top of the evaporative crystallizer (3-1), the steam outlet is connected with an inlet of the secondary steam purification unit, and a strong brine outlet of the evaporative crystallizer (3-1) is connected with an inlet of the forced circulation heat exchanger (3-3) through a forced circulation pump (3-2);
the crystallized salt separator (3-5) is provided with a crystal slurry inlet, a mother liquid outlet, a non-crystallized mother liquid outlet and a crystallized salt outlet; wherein, a crystal slurry outlet of the evaporative crystallizer (3-1) is connected with a crystal slurry inlet of a crystallized salt separator (3-5) through a crystal slurry pump (3-4), a mother liquor outlet of the crystallized salt separator (3-5) is connected with an inlet of a forced circulation heat exchanger (3-3) through a forced circulation pump (3-2), and a non-crystallized mother liquor outlet of the crystallized salt separator (3-5) is connected with an inlet of a purification treatment device;
the secondary steam purification unit comprises a scrubbing tower (4-1); the gas washing tower (4-1) is provided with a gas phase inlet, a gas phase outlet and a condensed water recycling inlet; a steam inlet of the scrubbing tower (4-1) is communicated with a steam outlet of the membrane separator (2-3) and a steam outlet of the evaporative crystallizer (3-1), and a steam outlet of the scrubbing tower (4-1) is communicated with an inlet of the steam compression unit; the gas washing device is provided with a condensed water recycling inlet; wherein, the steam of the membrane separator (2-3) is connected with the gas phase inlet of the scrubbing tower (4-1) through a pipeline, and the steam outlet of the evaporative crystallizer (3-1) is connected with the gas phase inlet of the scrubbing tower (4-1); the gas phase outlet of the gas washing tower (4-1) is communicated with the inlet of the vapor compression unit;
the vapor compression unit comprises a first compressor (5-1), a second compressor (5-2) and a third compressor (5-3); the first compressor (5-1), the second compressor (5-2) and the third compressor (5-3) are respectively provided with a steam inlet, a steam outlet and a water outlet, a machine seal water inlet and a fresh steam inlet, and the second compressor (5-2) is provided with a first steam outlet and a second steam outlet; wherein, a steam inlet of the first compressor (5-1) is communicated with a gas phase outlet of the scrubber tower (4-1), a steam outlet of the first compressor (5-1) is communicated with a steam inlet of the second compressor (5-2), and a first steam outlet of the second compressor (5-2) is communicated with a steam inlet of the third compressor (5-3); a steam outlet of the third compressor (5-3) is communicated with a heat source inlet of the forced circulation heat exchanger (3-3), and a steam outlet of the forced circulation heat exchanger (3-3) is communicated with a steam inlet of the membrane evaporator (2-1); a second steam outlet of the second compressor (5-2) is communicated with a heat source inlet of the membrane evaporator (2-1), and a steam outlet of the membrane evaporator (2-1) is communicated with a steam inlet of the non-condensing heat exchanger (1-4).
3. The system according to claim 2, characterized in that the water outlet of the first compressor (5-1), the water outlet of the second compressor (5-2) and the water outlet of the third compressor (5-3) are all in communication with the water inlet of the condensate-collecting device.
4. The system according to claim 2, characterized in that the water outlet of the raw steam plate heat exchanger (1-5) is in communication with the water inlet of a condensate collecting device; the water outlet of the membrane evaporator (2-1) and the water outlet of the forced circulation heat exchanger (3-3) are communicated with the water inlet of a condensed water collecting device; the water outlet of the condensed water collecting device is communicated with the water inlet of the condensed water heat exchange device, and the condensed water of the condensed water heat exchange device is discharged from the water outlet.
5. The system of claim 2, wherein the secondary steam purification unit is provided with a condensate water recycling inlet, and a water outlet of the secondary steam purification unit is communicated with a water inlet of the purification treatment device.
6. The system according to claim 2, characterized in that the water outlets of the first compressor (5-1), the second compressor (5-2) and the third compressor (5-3) are communicated with the water inlet of the liquid accumulation tank (1-9) through pipelines; the condensed water outlet of the membrane evaporator (2-1) and the condensed water outlet of the forced circulation heat exchanger (3-3) are communicated with the water inlet of the condensed water tank (1-7) through pipelines.
7. A system according to claim 2, characterized in that the condensate tank (1-7) is connected to the liquid trap tank (1-9) by means of a liquid trap pump (1-8); the condensed water tank (1-7) is connected with the condensed water plate type heat exchanger (1-3) through a distilled water pump (1-6).
8. The system of claim 2, wherein the condensate collection device outlet communicates with the condensate heat exchange device inlet, and wherein the condensate collection device has four inlets, namely, the membrane evaporator condensate inlet, the forced circulation heat exchanger condensate inlet, the raw steam heat exchange device condensate inlet, and the first/second/third compressor seal water inlets.
9. The system of claim 2, wherein the condensed water heat exchange device, the non-condensed gas heat exchange device, or the raw steam heat exchange device is a plate heat exchanger.
10. The system of claim 2, wherein the membrane evaporator is a falling film evaporator and the membrane separator is a falling film separator.
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