CN214654556U - Production system for continuous chlorination of trichlorotoluene - Google Patents
Production system for continuous chlorination of trichlorotoluene Download PDFInfo
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- CN214654556U CN214654556U CN202120712614.8U CN202120712614U CN214654556U CN 214654556 U CN214654556 U CN 214654556U CN 202120712614 U CN202120712614 U CN 202120712614U CN 214654556 U CN214654556 U CN 214654556U
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- chlorination
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- cauldron
- toluene
- absorption
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- 238000005660 chlorination reaction Methods 0.000 title claims abstract description 177
- XEMRAKSQROQPBR-UHFFFAOYSA-N (trichloromethyl)benzene Chemical compound ClC(Cl)(Cl)C1=CC=CC=C1 XEMRAKSQROQPBR-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 146
- 239000000463 material Substances 0.000 claims abstract description 46
- 238000010521 absorption reaction Methods 0.000 claims abstract description 43
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 35
- 239000007789 gas Substances 0.000 claims description 27
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 21
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 21
- 229910000041 hydrogen chloride Inorganic materials 0.000 claims description 21
- 238000007710 freezing Methods 0.000 claims description 20
- 230000008014 freezing Effects 0.000 claims description 20
- 239000007788 liquid Substances 0.000 claims description 13
- 239000012043 crude product Substances 0.000 claims description 6
- 239000000460 chlorine Substances 0.000 abstract description 27
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 26
- 229910052801 chlorine Inorganic materials 0.000 abstract description 26
- 238000006243 chemical reaction Methods 0.000 description 18
- 238000001816 cooling Methods 0.000 description 10
- 239000012071 phase Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 4
- 239000007791 liquid phase Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 3
- 239000000498 cooling water Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000005416 organic matter Substances 0.000 description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000010517 secondary reaction Methods 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- CAHQGWAXKLQREW-UHFFFAOYSA-N Benzal chloride Chemical compound ClC(Cl)C1=CC=CC=C1 CAHQGWAXKLQREW-UHFFFAOYSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000001000 anthraquinone dye Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 125000003963 dichloro group Chemical group Cl* 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000012450 pharmaceutical intermediate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000013547 stew Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The utility model relates to a production system of trichlorotoluene continuous chlorination, toluene metering tank top is located to the toluene inlet pipe, toluene metering tank adopts first pipeline to communicate with chlorination absorption cauldron, chlorination absorption cauldron passes through pipeline and first chlorination cauldron intercommunication through first force pump, material passes through overflow pipe and second chlorination cauldron in the first chlorination cauldron, the third chlorination cauldron, fourth chlorination cauldron and fifth chlorination cauldron communicate in proper order, first chlorination cauldron, the second chlorination cauldron, the third chlorination cauldron, fourth chlorination cauldron and fifth chlorination cauldron bottom are equipped with chlorine respectively and let in house steward intercommunication through entry and chlorine, first chlorination cauldron, the second chlorination cauldron, the third chlorination cauldron, fourth chlorination cauldron and fifth chlorination cauldron top are equipped with gas discharge port respectively and communicate with chlorine discharge tube respectively, chlorine discharge tube communicates in proper order with condenser and refrigerated condenser. The utility model discloses continuous feeding, the ejection of compact in succession, continuous chlorination, the yield of chlorination product is more than 98%, and crude purity is more than 99%.
Description
Technical Field
The utility model relates to a chemical industry technology field, concretely relates to production system of trichlorotoluene continuous chlorination.
Background
Trichlorotoluene, CAS No.: 98-07-7, formula: c7H5Cl3Molecular weight: 195.474, useful as a basic raw material for dyes, pharmaceutical intermediates and ultraviolet absorbers UV-9, UV-531, and organic synthesis intermediates for the production of benzoic acid, benzoyl chloride, triphenylmethane dyes, anthraquinone dyes, quinoline dyes, etc. The traditional synthesis process comprises the steps of putting toluene into a chlorination kettle, heating to 90-120 ℃, introducing chlorine, stopping chlorination reaction until the content of dichlorotoluene is lower than 0.1%, and transferring the materials into a rectifying kettle for rectification to obtain a trichlorotoluene product. The intermittent reaction is adopted, the operation is complex, the working procedures are multiple, the energy consumption is high, and the productivity is low. There are mainly the following problems: firstly, the reaction initial stage, it is low to lead to the chlorine flow, and the material need heat up, and it is big to lead to the chlorine flow in the reaction middle stage, and the reaction exotherm is big, needs the cooling, and the operation is complicated, and improper control by temperature change leads to the secondary reaction many, and the big product quality of impurity is poor.
Disclosure of Invention
In order to solve the technical problem, the utility model provides a production system for trichlorotoluene continuous chlorination.
The utility model provides an adopted technical scheme is:
a production system for continuous chlorination of trichlorotoluene comprises a toluene feeding pipe, wherein the toluene feeding pipe is arranged above a toluene metering tank, the toluene metering tank is communicated with a chlorination absorption kettle through a first pipeline, the chlorination absorption kettle is communicated with a first chlorination kettle through a first pressure pump through a pipeline, materials in the first chlorination kettle are communicated with a second chlorination kettle, a third chlorination kettle, a fourth chlorination kettle and a fifth chlorination kettle in sequence through overflow pipes, chlorine gas inlet openings are respectively arranged at the bottoms of the first chlorination kettle, the second chlorination kettle, the third chlorination kettle, the fourth chlorination kettle and the fifth chlorination kettle and communicated with a chlorine gas inlet main pipe, gas outlet openings are respectively arranged at the tops of the first chlorination kettle, the second chlorination kettle, the third chlorination kettle, the fourth chlorination kettle and the fifth chlorination kettle and communicated with a chlorine gas outlet pipeline, the chlorine gas outlet pipeline is communicated with a condenser and a freezing condenser in sequence, a material outlet opening at the bottom of the condenser is communicated with the first chlorination kettle, the discharge port at the bottom of the freezing condenser is communicated with the chlorination absorption kettle, the exhaust port at the top of the chlorination absorption kettle is communicated with the cryogenic condenser, and a hydrogen chloride gas pipeline arranged on the cryogenic condenser is input into a hydrogen chloride absorption system for absorption to prepare hydrochloric acid.
Preferably, a crude product discharge pipeline is arranged at the upper part of the pentachlorinated kettle.
Preferably, there are three condensers in series.
Preferably, a feeding valve is arranged on the toluene feeding pipe and is interlocked with the liquid level of the toluene storage tank.
Preferably, the toluene metering tank is arranged above the chlorination absorption kettle.
The production process for carrying out continuous chlorination on trichlorotoluene by adopting the production system is characterized in that in the process, the chlorination absorption kettle is heated to 70-80 ℃ through steam, the temperature of materials in the chlorination absorption kettle is controlled, so that residual chlorine can be reacted completely, and the reaction temperature of the materials in the chlorination kettle can be ensured.
Preferably, the temperature of the first chlorination kettle is controlled to be 90-95 ℃, and the chlorine flow of the first chlorination kettle is not more than 110m3And h, controlling the chlorine overflowing amount.
Preferably, the temperature of the second chlorination kettle material is controlled to be 95-100 ℃, the temperature of the third chlorination kettle material is controlled to be 110-3/h，170-190m3/h，230-250m3The chlorination reaction degree is enabled to reach 95 percent.
Preferably, the temperature of the fifth chlorination kettle is controlled at 115 ℃ and 120 ℃, and the chlorine flow is controlled at 70-90m3And h, ensuring that the materials in the kettle react completely, and controlling the dichloro content to be 0.Less than 05 percent.
Preferably, the gas phase condensed by the condenser is condensed again by a freezing condenser, the condenser is cooled by cooling water, the condensed material and residual chlorine gas enter the chlorination absorption kettle through a pipeline for reaction, all hydrogen chloride gas and the material are condensed again by the freezing condenser, the freezing condenser is cooled by freezing water, and the deep cooling condenser is condensed by deep cooling brine. The gas-phase liquid-phase mixed material cooled by the freezing condenser enters the absorption kettle for secondary reaction, the gas-phase material generated in the reaction process of the absorption kettle is condensed by a cryogenic condenser by cryogenic brine at the temperature of-20 ℃, the organic matter components are completely condensed to be liquid-phase and flow back to the absorption kettle, the hydrogen chloride gas which is not condensed is absorbed by water through a hydrogen chloride gas pipeline to prepare hydrochloric acid, and the organic matter content in the hydrogen chloride is controlled at the lowest amount.
Preferably, the first chlorination kettle, the second chlorination kettle, the third chlorination kettle, the fourth chlorination kettle and the fifth chlorination kettle are sequentially kept at a position difference of 95-105mm from high to low, so that the materials are ensured to overflow smoothly.
The utility model discloses beneficial effect:
1. the utility model discloses continuous feeding, the ejection of compact in succession, chlorination in succession, the feeding carries out feed control according to getting rid of the material liquid level, and the yield of chlorination product is more than 98%, and crude product purity is more than 99%. The utility model discloses a continuous feed, the ejection of compact in succession, chlorination in succession, the feeding carries out the automatic replenishment according to the discharge material liquid level, and continuous feed and chlorination make every chlorination reation kettle temperature effectively control, and the reaction is stable. After the reaction is finished, the reaction product is directly transferred to a rectifying still for rectification, so that the manual material transferring operation is omitted, and the labor is saved.
2. 5 set chlorination cauldron react in succession, communicate the gaseous phase and carry out the condensation together and retrieve the material, reduced condenser quantity to adopt multistage condensation, make the material retrieve more completely, reduced the equipment input.
3. Every chlorine of going on alone of chlorination reaction kettle leads to chlorine, and every chlorination reaction kettle sets up and leads to chlorine flow according to the technological parameter control of setting for alone to lead to the chlorine valve, and according to reaction stage difference, each cauldron leads to chlorine simultaneously and improves whole reaction rate, improves production efficiency, and the reaction is more stable controllable, and control chlorine leads to chlorine flow, makes the reaction more stable, and the control of being convenient for, and the chlorine reaction is more complete. The impurities generated by the reaction are few, and the product quality is high.
4. The chlorine flow of each chlorination kettle for continuous chlorination of trichlorotoluene can be stably controlled, the flow is not required to be adjusted, the reaction is stable, the operation is simple and convenient, and the safety is higher.
Drawings
FIG. 1: the utility model has a schematic structure;
in the figure: toluene inlet pipe 1, toluene metering tank 2, chlorination absorption kettle 3, first pipeline 4, first force pump 5, first chlorination kettle 6, overflow pipe 7, second chlorination kettle 8, third chlorination kettle 9, fourth chlorination kettle 10, fifth chlorination kettle 11, chlorine gas inlet manifold 12, chlorine gas discharge pipeline 13, condenser 14, freezing condenser 15, deep cooling condenser 16, hydrogen chloride gas pipeline 17, crude product discharge pipeline 18.
Detailed Description
Example 1
As shown in figure 1, a production system for continuous chlorination of trichlorotoluene comprises a toluene feeding pipe 1, wherein the toluene feeding pipe 1 is arranged above a toluene metering tank 2, the toluene metering tank 2 is communicated with a chlorination reactor 3 by a first pipeline 4, the chlorination reactor 3 is communicated with a first chlorination reactor 6 by a first pressure pump 5 through a pipeline, materials in the first chlorination reactor 6 are sequentially communicated with a second chlorination reactor 8, a third chlorination reactor 9, a fourth chlorination reactor 10 and a fifth chlorination reactor 11 through an overflow pipe 7, the bottoms of the first chlorination reactor 6, the second chlorination reactor 8, the third chlorination reactor 9, the fourth chlorination reactor 10 and the fifth chlorination reactor 11 are respectively provided with a chlorine gas inlet and a chlorine gas inlet header pipe 12, the tops of the first chlorination reactor 6, the second chlorination reactor 8, the third chlorination reactor 9, the fourth chlorination reactor 10 and the fifth chlorination reactor 11 are respectively provided with a gas outlet and are respectively communicated with a chlorine gas outlet pipe 13, the chlorine gas discharge pipeline 13 is sequentially communicated with the condenser 14 and the freezing condenser 15, a material discharge port at the bottom of the condenser 14 is communicated with the first chlorination kettle 6, a discharge port at the bottom of the freezing condenser 15 is communicated with the chlorination absorption kettle 3, a gas exhaust port at the top of the chlorination absorption kettle 3 is communicated with the cryogenic condenser 16, and a hydrogen chloride gas pipeline 17 arranged on the cryogenic condenser 16 is input into a hydrogen chloride absorption system for absorption to prepare hydrochloric acid.
Preferably, a crude product discharge pipeline 18 is arranged at the upper part of the pentachlorinated kettle 11.
Preferably, three condensers 14 are provided in series.
Preferably, a feeding valve is arranged on the toluene feeding pipe 1 and is interlocked with the liquid level of the toluene storage tank. The automatic feeding is carried out according to the liquid level, guarantees material liquid level and toluene quiescent time in toluene metering tank 2 in the toluene, can deposit the storage tank bottom completely with moisture and the impurity in the toluene, regularly divides. And a feeding valve is arranged on the toluene feeding pipe 1 and is interlocked with a toluene storage tank discharging valve and the liquid level of the toluene metering tank 2. The feeding is automatically carried out according to the liquid level. The toluene storage tank is equipped with the water diversion device, and the toluene that gets into in the storage tank stews more than 2h, guarantees that moisture and impurity in the toluene can deposit the storage tank bottom completely, regularly divides out, makes the toluene moisture content of getting into toluene metering tank 2 no longer than 800 ppm.
Preferably, the toluene metering tank 2 is arranged above the chlorination absorption kettle 3.
Preferably, the toluene metering tank 2 is arranged above the chlorination absorption kettle 3. The material is automatically fed by potential difference, the material is automatically fed in a liquid level linkage mode of a feeding valve of the first pipeline 4 and the chlorination absorption kettle 3, the material is fed from the middle lower part, the material is discharged from the upper part, and the retention time of the material is ensured.
The production process for carrying out continuous chlorination on trichlorotoluene by adopting the production system comprises the following steps:
1. hydrogen chloride gas generated in the chlorination process, residual chlorine gas and carried-out materials enter a condenser 14 through a gas phase pipe, the materials are cooled and enter a first chlorination kettle 6 through a recovery pipe, uncondensed materials, unreacted chlorine gas and hydrogen chloride gas enter a freezing condenser 15 for cooling again and enter a chlorination absorption kettle 3 through a pipeline, the materials are recovered and reacted again, the unreacted chlorine gas is completely reacted in the chlorination absorption kettle 3, the gas phase materials in the chlorination absorption kettle 3 are cooled and refluxed again through a cryogenic condenser 16, the hydrogen chloride gas enters hydrochloric acid through a hydrogen chloride gas pipeline 17An absorbent system. The temperature of the first chlorination reactor 6 is controlled between 90 ℃ and 95 ℃, and the chlorine flow of the first chlorination reactor 6 is not more than 110m3And h, controlling the chlorine overflowing amount.
2. Chlorine gas enters each chlorination kettle through a chlorine gas inlet main pipe 12 and a regulating valve.
Preferably, the toluene storage tank is higher than the chlorination absorption kettle 3 through the installation position of the toluene feeding pipe 1, the toluene automatically enters in a mode of liquid level linkage of the first pipeline 4 feeding valve and the chlorination absorption kettle 3, and the toluene flows into the chlorination absorption kettle 3 through the position difference.
Preferably, the discharge port of the toluene metering tank 2 is arranged on the side surface of the storage tank, so that the moisture in the toluene is precipitated to the bottom of the storage tank, and the moisture is periodically distributed.
Preferably, the toluene inlet of the chlorination absorption kettle 3 is arranged at the lower part of the chlorination absorption kettle 3, the toluene feeding amount is controlled by interlocking the liquid level of the chlorination absorption kettle 3 with the regulating valve, and the temperature of the chlorination absorption kettle 3 is controlled, so that the entering chlorine can completely react with the toluene.
Preferably, the feeding of the first chlorination reactor 6 enters through a pipeline 14, the first pressure pump 5 is used for switching in, the feeding control valve and the liquid level of the first chlorination reactor 6 are used for interlocking control adjustment, the material enters from the lower part of the first chlorination reactor 6, and the upper part overflows to the next chlorination reactor.
Preferably, the first chlorination kettle 6, the second chlorination kettle 8, the third chlorination kettle 9, the fourth chlorination kettle 10 and the fifth chlorination kettle 11 are communicated with each other through an overflow pipe 7, and all adopt upper-outlet feeding and lower-inlet feeding, and the materials after chlorination are directly discharged into the next working procedure through a crude product discharge pipeline 18.
Preferably, the chlorine feeding holes of the first chlorination kettle 6, the second chlorination kettle 8, the third chlorination kettle 9, the fourth chlorination kettle 10 and the fifth chlorination kettle 11 are all arranged at the lower part, so that the chlorine is in long-time contact with the materials more fully, and the reaction speed is improved.
Preferably, the gas phase materials of the first chlorination kettle 6, the second chlorination kettle 8, the third chlorination kettle 9, the fourth chlorination kettle 10 and the fifth chlorination kettle 11 are communicated through a chlorine gas inlet main pipe 12, circulating water cooling is carried out by adopting a three-stage condenser 14, then freezing water cooling is carried out by adopting a freezing condenser 15, deep cooling water is carried out on tail gas by adopting a deep cooling condenser 16 again, and the organic materials are completely condensed and recovered.
Preferably, the material temperature of the second chlorination kettle 8 is controlled to be 95-100 ℃, the material temperature of the third chlorination kettle 9 is controlled to be 110 ℃ C., the material temperature of the fourth chlorination kettle 10 is controlled to be 115 ℃ C., the chlorine introduction flow rates of the second chlorination kettle 8, the third chlorination kettle 9 and the fourth chlorination kettle 10 are respectively 150m3/h、180m3/h、240m3/h。
Preferably, the gas phase condensed by the condenser 14 is condensed again by the freezing condenser 15, the condenser 14 is cooled by cooling water, the gas phase and liquid phase mixed material cooled by the freezing condenser 15 enters the absorption kettle 3 for reaction again, all hydrogen chloride gas and materials are condensed again by the freezing condenser 15, the freezing condenser 15 is cooled by freezing water, the gas phase materials generated in the reaction process of the absorption kettle 3 are condensed by a deep cooling condenser 16 by deep cooling saline water with the temperature of-20 ℃, organic matter components are completely condensed to be liquid phase and flow back to the absorption kettle 3, and the hydrogen chloride gas which is not condensed is absorbed by water by a hydrogen chloride gas pipeline 17 to prepare hydrochloric acid. The content of organic matters in the hydrogen chloride is controlled to be the minimum, and the hydrogen chloride gas is absorbed by water through a hydrogen chloride gas pipeline 17 to prepare the hydrochloric acid.
Preferably, the first chlorination kettle 6, the second chlorination kettle 8, the third chlorination kettle 9, the fourth chlorination kettle 10 and the fifth chlorination kettle 11 are sequentially arranged from high to low, and the position difference of 100mm is kept, so that smooth overflow of materials is ensured.
Claims (5)
1. A production system for trichlorotoluene continuous chlorination comprises a toluene feeding pipe (1), and is characterized in that: the toluene feeding pipe (1) is arranged above the toluene metering tank (2), the toluene metering tank (2) is communicated with the chlorination absorption kettle (3) by a first pipeline (4), the chlorination absorption kettle (3) is communicated with the first chlorination kettle (6) by a first pressure pump (5) through a pipeline, materials in the first chlorination kettle (6) are sequentially communicated with the second chlorination kettle (8), the third chlorination kettle (9), the fourth chlorination kettle (10) and the fifth chlorination kettle (11) through an overflow pipe (7), the first chlorination kettle (6), the second chlorination kettle (8), the third chlorination kettle (9), the fourth chlorination kettle (10) and the fifth chlorination kettle (11) are respectively provided with a chlorine gas inlet which is communicated with a chlorine gas inlet main pipe (12), the tops of the first chlorination kettle (6), the second chlorination kettle (8), the third chlorination kettle (9), the fourth chlorination kettle (10) and the fifth chlorination kettle (11) are respectively communicated with a chlorine gas outlet pipeline (13), the chlorine gas discharge pipeline (13) is sequentially communicated with the condenser (14) and the freezing condenser (15), a material discharge port at the bottom of the condenser (14) is communicated with the first chlorination kettle (6), a discharge port at the bottom of the freezing condenser (15) is communicated with the chlorination absorption kettle (3), an exhaust port at the top of the chlorination absorption kettle (3) is communicated with the cryogenic condenser (16), and a hydrogen chloride gas pipeline (17) arranged on the cryogenic condenser (16) is input into a hydrogen chloride absorption system for absorption to prepare hydrochloric acid.
2. The system for continuously chlorinating trichlorotoluene according to claim 1, wherein: a crude product discharge pipeline (18) is arranged at the upper part of the pentachlorinated kettle (11).
3. The system for continuously chlorinating trichlorotoluene according to claim 1, wherein: the number of the condensers (14) is three.
4. The system for continuously chlorinating trichlorotoluene according to claim 1, wherein: and a feeding valve is arranged on the toluene feeding pipe (1) and is interlocked with the liquid level of the toluene storage tank.
5. The system for continuously chlorinating trichlorotoluene according to claim 1, wherein: and the toluene metering tank (2) is arranged above the chlorination absorption kettle (3).
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113173831A (en) * | 2021-04-08 | 2021-07-27 | 宜都市友源实业有限公司 | Production system and process for continuous chlorination of trichlorotoluene |
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| CN113173831A (en) * | 2021-04-08 | 2021-07-27 | 宜都市友源实业有限公司 | Production system and process for continuous chlorination of trichlorotoluene |
| CN113173831B (en) * | 2021-04-08 | 2024-01-19 | 宜都市友源实业有限公司 | Production system and process for continuous chlorination of trichlorotoluene |
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