CN214004101U - Salt separating treatment system for salt-containing wastewater - Google Patents

Abstract

The utility model relates to a contain branch salt processing system of salt waste water. In the salt separation treatment system, a heater carries out primary evaporation treatment on the salt-containing wastewater to ensure that ammonium sulfate in the salt-containing wastewater reaches an oversaturated state, then the salt-containing wastewater enters a crystallization separator, primary crystallization treatment is carried out in the crystallization separator, and the supersaturated ammonium sulfate crystals can be crystallized and separated out from the ammonium sulfate reaching the oversaturated state in the salt-containing wastewater; then the ammonium sulfate enters a second evaporation crystallization device, the concentrated mother liquor is heated and evaporated through a heating reaction kettle, ammonium sulfate is crystallized and separated out firstly in the secondary evaporation crystallization process, ammonium nitrate is always kept in an unsaturated state so as to ensure that the ammonium nitrate is not crystallized and separated out in the secondary evaporation process, and finally solid-liquid separation is carried out through a first solid-liquid separator, so that high-purity ammonium sulfate crystals are further obtained. The salt separation treatment system can separate dominant ammonium sulfate from waste water containing ammonium sulfate and ammonium nitrate, and the separated ammonium sulfate has high purity and low impurity content.

Description

Salt separating treatment system for salt-containing wastewater

Technical Field

The utility model relates to a waste water treatment technical field especially relates to a divide salt processing system who contains salt waste water.

Background

In many chemical processes, a large amount of waste water containing ammonium sulfate and ammonium nitrate is produced. For example, in the denitration technique, wastewater containing ammonium sulfate and ammonium nitrate as main components is generated. The discharge of waste water containing ammonium sulfate and ammonium nitrate into natural water body can cause the content of nitrogen in the water body to seriously exceed the standard, cause water body eutrophication and further destroy the ecological balance of the water body; therefore, the wastewater is treated to be discharged.

In the traditional salt separation treatment process of wastewater containing ammonium sulfate and ammonium nitrate, different ions in the wastewater containing ammonium sulfate and ammonium nitrate are separated through membrane permeation treatment, or the ions in the wastewater are recovered through chemical precipitation, but the cost of the membrane permeation treatment is high, the industrial production is not facilitated, new ions are introduced in the chemical precipitation treatment, secondary pollution is easily caused, secondary industrial wastewater is formed, and the purification efficiency is not high.

Accordingly, the prior art is yet to be improved and developed.

SUMMERY OF THE UTILITY MODEL

Based on the above, there is a need for a salt separation treatment system for salt-containing wastewater, which can perform salt separation with high efficiency, and the salt separation treatment system can perform salt separation treatment on wastewater containing ammonium sulfate and ammonium nitrate with high efficiency.

The utility model provides a contain branch salt processing system of salt waste water, include:

the first evaporative crystallization device comprises a heat exchanger, an exhaust condenser, a crystallization separator and a heater; a first liquid outlet of the heat exchanger is connected with a liquid inlet of the exhaust condenser; the first liquid outlet of the exhaust condenser is connected with the liquid inlet of the crystallization separator; a first liquid outlet of the crystallization separator is connected with a liquid inlet of the heater so as to carry out primary crystallization treatment on the salt-containing wastewater; a first liquid outlet of the heater is connected with a liquid inlet of the crystallization separator, and an exhaust port of the heater is connected with an air inlet of the exhaust condenser so as to carry out primary evaporation treatment on the salt-containing wastewater;

the second evaporative crystallization device comprises a heating reaction kettle and a first solid-liquid separator; the inlet of heating reation kettle with the second liquid outlet of crystallization separator is connected, the liquid outlet of heating reation kettle with the inlet of first solid-liquid separator is connected, heating reation kettle is used for right the first concentrated mother liquor that the primary crystallization was obtained carries out the second grade evaporation crystallization, first solid-liquid separator is used for carrying out solid-liquid separation to the warp the product after the second grade evaporation crystallization.

In some embodiments, the liquid outlet of the first solid-liquid separator is connected with the liquid inlet of the heating reaction kettle.

In some embodiments, the first evaporative crystallization device further comprises a concentrate pump, a thickener, a second solid-liquid separator, a first mother liquor tank and a mother liquor pump; a second liquid outlet of the crystallization separator is connected with a liquid inlet of the thickener, a first liquid outlet of the thickener is connected with a liquid inlet of the second solid-liquid separator, a liquid outlet of the second solid-liquid separator is connected with a liquid outlet of the first mother liquor tank, and a liquid outlet of the first mother liquor tank is connected with a liquid inlet of the crystallization separator, so that the first concentrated mother liquor obtained through the first-stage crystallization is circularly subjected to the first-stage evaporation treatment;

the concentrated liquid pump is arranged on a connecting pipeline between the liquid outlet of the crystallization separator and the liquid inlet of the thickener; the mother liquor pump is arranged on a connecting pipeline between the liquid outlet of the first mother liquor tank and the liquid inlet of the crystallization separator, and the liquid outlet of the mother liquor pump is connected with the liquid inlet of the first solid-liquid separator.

In some embodiments, the second liquid outlet of the thickener is connected with the liquid inlet of the crystallization separator.

In some of these embodiments, the second evaporative crystallization device further comprises a second mother liquor tank, a second transfer pump, a spray drying tower, a fan, and a condenser; a liquid inlet of the second mother liquor tank is connected with a liquid outlet of the first solid-liquid separator, a liquid outlet of the second mother liquor tank is connected with a liquid inlet of the spray drying tower, and a gas outlet of the spray drying tower is connected with a gas inlet of the fan; the second delivery pump is positioned on a connecting pipeline between a liquid outlet of the second mother liquor tank and a liquid inlet of the spray drying tower, and an air inlet of the condenser is connected with an air outlet of the heating reaction kettle.

In some of these embodiments, the first evaporative crystallization device further comprises a forced circulation pump; and the forced circulation pump is positioned on a pipeline connected between the first liquid outlet of the crystallization separator and the liquid inlet of the heater.

In some embodiments, the first evaporative crystallization device further comprises a scrubber and a vapor compressor; the gas inlet of the gas washing tower is connected with the gas outlet of the crystallization separator, the gas outlet of the gas washing tower is connected with the gas inlet of the steam compressor so as to carry out gas washing treatment on the first steam obtained by the primary crystallization treatment, and the gas outlet of the steam compressor is connected with the gas inlet of the heater so as to lead the first steam after the gas washing treatment to return to the heater to be used as a heat source; and the liquid outlet of the gas washing tower is connected with the liquid inlet of the crystallization separator.

In some embodiments, an acid washing section and a base washing section are arranged in the scrubber tower to perform acid washing and base washing on the first steam.

In some of these embodiments, the first evaporative crystallization device further comprises a distilled water tank; and a second liquid outlet of the heater is connected with a liquid inlet of the distilled water tank, and a liquid outlet of the distilled water tank is connected with a first liquid inlet of the heat exchanger.

In some of these embodiments, the vapor inlet of the crystallization separator is connected to the outlet of the distillation water tank.

Advantageous effects

The salt separation treatment system for the salt-containing wastewater of the utility model can be used for the salt-containing wastewater containing ammonium sulfate and ammonium nitrate and the ammonium sulfate has dominant content; the heat exchanger preheats the saline wastewater to be treated, the preheated saline wastewater enters the exhaust condenser, steam carried by the preheated saline wastewater is condensed in the exhaust condenser, heat generated by condensation further heats the saline wastewater, condensed water is recovered, and the heat efficiency is improved; the method comprises the following steps that (1) the salt-containing wastewater after temperature raising enters a crystallization separator to be subjected to flash evaporation, so that the salt-containing wastewater is concentrated and steam is released, then the salt-containing wastewater enters a heater, the heater performs primary evaporation treatment on the salt-containing wastewater, so that ammonium sulfate in the salt-containing wastewater reaches an oversaturated state, then the salt-containing wastewater enters the crystallization separator, primary crystallization treatment is performed in the crystallization separator, the ammonium sulfate which reaches the oversaturated state in the salt-containing wastewater is crystallized to separate out oversaturated ammonium sulfate crystals, and the obtained concentrated mother liquor is kept at a saturated state; and then the concentrated mother liquor enters a second evaporation and crystallization device, the concentrated mother liquor is heated and evaporated through a heating reaction kettle, ammonium sulfate is crystallized and separated out firstly in the secondary evaporation and crystallization process, and ammonium nitrate is always kept in an unsaturated state so as to ensure that the ammonium nitrate is not crystallized and separated out until the content of the ammonium nitrate in the first concentrated mother liquor reaches a set end point, and finally solid-liquid separation is carried out through a first solid-liquid separator. Therefore, the dominant ammonium sulfate can be separated from the wastewater containing ammonium sulfate and ammonium nitrate, and the separated ammonium sulfate has high purity and low impurity content. Meanwhile, an exhaust port of the heater is connected with an air inlet of the exhaust condenser, the non-condensed steam generated by the salt-containing wastewater in the evaporative crystallization process can return to the exhaust condenser and continuously serve as a heat source of the exhaust condenser to exchange heat with the salt-containing wastewater, and atomized steam carried in the non-condensed steam is condensed into distilled water while the liquid inlet temperature is increased, so that the steam and heat are recovered, and the heat efficiency of the salt separation treatment system is further increased.

Drawings

FIG. 1 is a schematic view of a system for treating salt-containing wastewater according to example 1.

Detailed Description

In order to facilitate understanding of the present invention, the present invention will be described more fully hereinafter with reference to the accompanying drawings. The preferred embodiments of the present invention are shown in the drawings. The invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete.

It will be understood that when an element is referred to as being "secured to" another element, it can be directly on the other element or intervening elements may also be present. When an element is referred to as being "connected" to another element, it can be directly connected to the other element or intervening elements may also be present.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. The terminology used in the description of the invention herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the term "and/or" includes any and all combinations of one or more of the associated listed items.

In the chemical production process, a large amount of wastewater containing ammonium sulfate and ammonium nitrate is often generated, for example, the main components of the wastewater generated in the denitration technology are ammonium sulfate and ammonium nitrate. In the traditional salt separation treatment process of wastewater containing ammonium sulfate and ammonium nitrate, different ions in the wastewater containing ammonium sulfate and ammonium nitrate are usually separated through membrane permeation treatment, or the ions in the wastewater are recovered through chemical precipitation, but the cost of the membrane permeation treatment is high, the industrial production is not facilitated, new ions are introduced in the chemical precipitation treatment, secondary pollution is easily caused, secondary industrial wastewater is formed, and the purification efficiency is not high.

The skilled person tries to separate out sulfuric acid or ammonium nitrate by direct heating and freeze crystallization method by utilizing the characteristic of solubility difference between two salts, but because the solubility difference of the two salts in water is not large and their solubility trends in water are similar, the separation efficiency is not high, only a small part is often separated out, and the purity of the separated salt is not high.

The technical personnel of the utility model are based on self experience of many years at waste water treatment field practitioner accumulation to through a large amount of experiments, creatively provide the utility model discloses can carry out the technical scheme that the efficient divides the salt to handle to the waste water that contains ammonium sulfate and ammonium nitrate.

Referring to fig. 1, one embodiment of the present invention provides a salt separation treatment system 10 for salt-containing wastewater, which includes a first evaporative crystallization apparatus 100 and a second evaporative crystallization apparatus 200.

A first evaporative crystallization apparatus 100 including a heat exchanger 101, an exhaust condenser 102, a crystallization separator 103, and a heater 104; a first liquid outlet of the heat exchanger 101 is connected with a liquid inlet of the exhaust condenser 102; a first liquid outlet of the exhaust condenser 102 is connected with a liquid inlet of a crystallization separator 103 so as to carry out primary crystallization treatment on the salt-containing wastewater; a first liquid outlet of the crystallization separator 103 is connected with a liquid inlet of a heater 104; a first liquid outlet of the heater 104 is connected with a liquid inlet of the crystallization separator 103, and an exhaust port of the heater 104 is connected with an air inlet of the exhaust condenser 103 so as to carry out primary evaporation treatment on the salt-containing wastewater.

The salt separation treatment system 10 for salt-containing wastewater can be used for the salt-containing wastewater containing ammonium sulfate and ammonium nitrate, wherein the ammonium sulfate has a dominant content. The heat exchanger 101 preheats the saline wastewater to be treated, the preheated saline wastewater enters the exhaust condenser 102, steam carried by the preheated saline wastewater is condensed in the exhaust condenser 102, heat generated by condensation further raises the temperature of the saline wastewater, condensed water is recycled, and the heat efficiency of the salt separation treatment system is improved; the heated salt-containing wastewater enters a crystallization separator 103 to be subjected to flash evaporation, so that the salt-containing wastewater is concentrated and steam is released, and then the salt-containing wastewater enters a heater 104, and the heater 104 is used for performing primary evaporation treatment on the salt-containing wastewater so that ammonium sulfate in the salt-containing wastewater reaches a supersaturated state; then the wastewater enters a crystallization separator 103, primary crystallization treatment is carried out in the crystallization separator 103, the supersaturated ammonium sulfate in the saline wastewater reaches a supersaturated state, supersaturated ammonium sulfate crystals are crystallized and separated out, and the first concentrated mother liquor is obtained, wherein the ammonium sulfate is kept in a saturated state. Meanwhile, the air outlet of the heater 104 is connected with the air inlet of the exhaust condenser 102, the non-condensed steam generated in the salt-containing wastewater in the evaporative crystallization process can return to the exhaust condenser 102 and continue to be used as the heat source of the exhaust condenser 102 to exchange heat with the salt-containing wastewater to be treated entering the exhaust condenser 102, and atomized steam carried in the non-condensed steam is condensed into distilled water while the temperature of the salt-containing wastewater is increased, so that steam and heat are recovered, and the thermal efficiency of the treatment system is further increased.

A second evaporative crystallization device 200 comprising a heating reaction kettle 201 and a first solid-liquid separator 202; a liquid inlet of the heating reaction kettle 201 is connected with a second liquid outlet of the crystallization separator 103, and a liquid outlet of the heating reaction kettle 201 is connected with a liquid inlet of the first solid-liquid separator 202; the heating reaction kettle 201 is used for carrying out secondary evaporation crystallization on the first concentrated mother liquor obtained by the primary crystallization treatment, and the first solid-liquid separator 202 is used for carrying out solid-liquid separation on a product subjected to the secondary evaporation crystallization.

The first concentrated mother liquor enters a heating reaction kettle 201 in the second evaporative crystallization device 200 from a second liquid outlet of the crystallization separator 103, the heating reaction kettle 201 heats and evaporates the concentrated mother liquor, in the evaporation process, the concentrated mother liquor is further concentrated, ammonium sulfate is crystallized and separated out firstly, and ammonium nitrate is kept in an unsaturated state all the time, so that the ammonium nitrate is not crystallized and separated out until the content of the ammonium nitrate in the first concentrated mother liquor reaches a set end point, and finally, solid-liquid separation is carried out through a first solid-liquid separator, so that waste liquid and ammonium sulfate crystals are obtained. Therefore, the dominant ammonium sulfate can be separated from the wastewater containing ammonium sulfate and ammonium nitrate, and the separated ammonium sulfate has high purity and low impurity content.

It can be understood that the salt separation treatment system 10 for salt-containing wastewater of the present invention can be used for salt separation treatment of salt-containing wastewater containing 20 wt% -45 wt% ammonium sulfate and 1 wt% -10 wt% ammonium nitrate.

Further, an exhaust port is arranged on the exhaust condenser 102; the treated non-condensed steam is discharged from an exhaust port.

In some embodiments, the liquid outlet of the first solid-liquid separator 202 is connected to the liquid inlet of the heating reactor 201. When the mass content of ammonium nitrate in the waste liquid separated from the first solid-liquid separator does not reach the end point, the waste liquid can further heat the reaction kettle 201, and evaporation and crystallization are continuously carried out to recover ammonium sulfate, so that the recovery rate of the ammonium sulfate is improved.

In some embodiments, the first evaporative crystallization device 100 further comprises a concentrate pump 110, a thickener 111, a second solid-liquid separator 112, a first mother liquor tank 113 and a mother liquor pump 114; the second liquid outlet of the crystallization separator 103 is connected with the liquid inlet of the thickener 111, the first liquid outlet of the thickener 111 is connected with the liquid inlet of the second solid-liquid separator 112, the liquid outlet of the second solid-liquid separator 112 is connected with the liquid outlet of the first mother liquor tank 113, and the liquid outlet of the first mother liquor tank 113 is connected with the liquid inlet of the crystallization separator 13, so that the first concentrated mother liquor obtained by the above-mentioned first-stage crystallization enters the crystallization separator 103 and then continues to circulate for first-stage evaporation treatment.

The concentrate pump 110 is arranged on a connecting pipeline between the liquid outlet of the crystal separator 103 and the liquid inlet of the thickener 111 to provide power for the first concentrate in the crystal separator 103 to enter the thickener 111; the mother liquor pump 114 is disposed on a connecting pipeline between the liquid outlet of the first mother liquor tank 113 and the liquid inlet of the crystallization separator 103, and the liquid outlet of the mother liquor pump 114 is connected with the liquid inlet of the first solid-liquid separator 202.

During operation, the first evaporative crystallization device is concentrated and crystallized to salt-containing wastewater, after primary crystallization occurs in the crystallization separator 103, the obtained mother liquor enters the thickener 111 for pre-separation, the first concentrated mother liquor and ammonium sulfate crystals are separated by the second solid-liquid separator 112, and the ammonium sulfate crystals are discharged from the solid outlet D on the second solid-liquid separator 112. If the content of ammonium nitrate in the first concentrated mother liquor reaches the set working condition, the mother liquor pump 114 conveys the first concentrated mother liquor to the first solid-liquid separator 202 for the next second evaporation crystallization treatment; if the content of ammonium nitrate in the first concentrated mother liquor does not reach the set working condition, the mother liquor pump 114 conveys the first concentrated mother liquor to the separation crystallizer 103, mixes the first concentrated mother liquor with the saline wastewater to be treated and enters the separation crystallizer again, and circulates to perform primary evaporation treatment operation as new saline wastewater until the content of ammonium nitrate in the first concentrated mother liquor reaches 15 wt% -20 wt%. Thus, high-purity ammonium sulfate crystals can be further separated.

Further, a second liquid outlet of the thickener 111 is connected with a liquid inlet of the crystallization separator 103, after salt-containing wastewater is subjected to primary crystallization treatment by the crystallization separator, the obtained concentrated solution enters the thickener 111, crystals in the concentrated solution further grow to perform primary separation of solid and liquid, the upper layer liquid flows back into the crystallization separator 103 through the second liquid outlet of the thickener 111 to continuously participate in primary evaporation crystallization, and the lower layer concentrated solution enters the second solid-liquid separator 112 to separate out first concentrated mother liquor and ammonium sulfate crystals.

In some of these embodiments, the second evaporative crystallization device 200 further comprises a second mother liquor tank 203, a second transfer pump 204, a spray drying tower 205, a fan 206, and a condenser 207; a liquid inlet of the second mother liquor tank 203 is connected with a liquid outlet of the first solid-liquid separator 202, a liquid outlet of the mother liquor tank 203 is connected with a liquid inlet of the spray drying tower 205, and a liquid outlet of the spray drying tower 205 is connected with a liquid inlet of the fan 206; the second delivery pump 204 is positioned on a connecting pipeline between the liquid outlet of the mother liquor tank 203 and the liquid inlet of the spray drying tower 205 to provide power for the waste liquor to enter the spray drying tower 205 from the mother liquor tank 203; an air inlet of the condenser 207 is connected with an air outlet of the heating reaction kettle 201, and steam generated in the heating reaction kettle 201 enters the condenser 207, is condensed to obtain distilled water, and is discharged.

When the concentrated mother liquor in the heating reaction kettle 201 reaches the set working condition, solid-liquid separation is carried out through the first solid-liquid separator 202 to obtain ammonium sulfate crystals and waste liquor, the waste liquor is stored in the second mother liquor tank 203, enters the spray drying tower 205 through the second conveying pump 204, is dried into solid in a very short time, the solid waste is continuously output from the bottom of the spray drying tower 205 and the cyclone separator, and the waste gas is emptied by the fan 206.

The condenser 207 is provided with a vacuum removal system H.

In some embodiments, the fan 206 is provided with a cooling water outlet F, a cooling water inlet G, and an exhaust port through which the exhaust gas is exhausted.

In some embodiments, the first evaporative crystallization apparatus 100 further comprises a forced circulation pump 105; the forced circulation pump 105 is located on a pipeline connected between the first liquid outlet of the crystallization separator 103 and the liquid inlet of the heater 104. To provide power for the salt-containing wastewater of the crystal separator 103 to enter the heater 104.

Under the action of the forced circulation pump 105, the salt-containing wastewater is continuously heated, evaporated and crystallized in the heater 104 and the crystallization separator 103, the heated circulating liquid flows out from the heater 104 to the low-pressure crystallization separator 103, and the circulating liquid is flashed at the low-pressure crystallization separator 103 because of the sudden reduction of the pressure, so that the circulating liquid is concentrated and simultaneously generates steam.

In a specific example, the forced circulation pump 105 is controlled by VFD (variable frequency drive), the system is initially started to operate, and the frequency is automatically adjusted in a range of 0-50 Hz according to automatic detection of specific gravity and outlet pressure so as to meet the circulation flow demand; the salt-containing wastewater is shunted to each heat exchange pipe of the heater 104 by the forced circulation pump 105, the flow velocity is controlled to be 1.5 m/s-3.5 m/s, and the scaling probability is reduced so as to avoid influencing the heat exchange efficiency. When the circulating liquid flows at a high speed from the tubes, the circulating liquid is heated by heat generated by condensation of steam outside the heat exchange tubes, and the pressure in each heat exchange tube of the heater 104 is controlled to be lower than the saturated steam pressure of the salt-containing wastewater at a specific temperature, so that the salt-containing wastewater cannot be boiled and evaporated in the heat exchange tube of the heater 104, and the ammonium sulfate in the salt-containing wastewater reaches a supersaturated state.

In some of the embodiments, the first evaporative crystallization apparatus 100 further comprises a scrubber 106 and a vapor compressor 107; the air inlet of the scrubber tower 106 is connected with the air outlet of the crystallization separator 103, and the first steam generated in the crystallization separator 103 enters the scrubber tower 106 for scrubbing.

The gas outlet of the gas washing tower 106 is connected with the gas inlet of the vapor compressor 107, the gas outlet of the vapor compressor 107 is connected with the gas inlet of the heater 104, and the liquid outlet of the gas washing tower 107 is connected with the liquid inlet of the crystallization separator 103; the first steam obtained from the first-stage crystallization treatment is subjected to a gas washing treatment by the gas washing tower 106, and then returned to the heater 104 by the steam compressor 107 as a heat source, so that part of the heat required when the heater 104 heats the salt-containing wastewater can be provided.

Meanwhile, the liquid outlet of the gas washing tower 106 is connected with the liquid inlet of the crystallization separator 103, so that the waste liquid generated in the gas washing tower 106 can return to the crystallization separator 103 to participate in the evaporation crystallization process, and no additional waste water is generated in the gas washing process.

In some embodiments, the first evaporative crystallization apparatus 100 further comprises a first transfer pump 108, and the first transfer pump 108 is located on a pipeline connected between the liquid outlet of the gas washing tower 106 and the liquid inlet of the crystallization separator 103, so as to provide power for circulating the waste liquid of the gas washing tower 104 to the crystallization separator 103.

In some embodiments, a spraying device is disposed at the top of the gas washing tower 106, and the liquid outlet of the first transfer pump 108 is connected to the spraying device in the gas washing tower 106; the washing liquid enters the spraying device in the gas washing tower 106 under the action of the first transfer pump 108.

Waste liquid generated after steam is subjected to gas washing enters the crystallization separator 103 through the first conveying pump 108 to continuously participate in crystallization and evaporation, solid is separated out, and distilled water is recycled, so that additional waste water is not generated.

In some embodiments, an acid washing section and a base washing section are disposed in the scrubber 106 to perform acid washing and base washing on the first steam.

The alkali substances such as ammonia gas and the like in the steam can be neutralized by acid washing, and the organic substances or reducing substances in the steam can be removed by alkali washing, so that the COD value of the steam is reduced, and further, the distilled water recovered by condensing the first steam can reach the discharge standard.

Further, the first evaporative crystallization apparatus 100 further comprises a washing liquid delivery apparatus 109. The washing liquid conveying device 109 comprises a washing liquid pump 1091 and a washing liquid tank 1092, a liquid outlet of the washing liquid tank 1092 is connected with a liquid inlet of the gas washing tower 106, and the washing liquid tank 1092 is used for storing the washing liquid and conveying the washing liquid to the gas washing tower 106 for use. Further, the washing liquid conveying device 109 further comprises a washing liquid pump 1091, and the washing liquid pump 1091 is disposed on a connecting pipeline between a liquid outlet of the washing liquid tank 1092 and a liquid inlet of the gas washing tower 106. The washing liquid stored in the washing liquid tank 1092 is pumped into the washing gas tower 104 by the washing liquid pump 1091, and the washing liquid enters the spray device in the washing gas tower 106 through the first transfer pump 108.

In some embodiments, the scrubber tower 106 employs a gas-liquid reverse absorption method, the scrubber solution is sprayed downward in a mist (or small droplets) by a spraying device at the top of the scrubber tower 106, and the vapor flows upward from the bottom of the scrubber tower 106 in a counter-current manner, so as to achieve sufficient contact between the gas and the liquid.

Further, the top of the scrubber tower 106 is also provided with a demisting system, and the steam after scrubbing passes through the demisting system to remove entrained mist water droplets.

It is understood that the demister system of the scrubber tower 106 is disposed above the spray system.

In some of these embodiments, the crystallization separator 103 described above employs a salt leg crystallizer. The top of the salt leg crystallizer is provided with an integrated baffle plate and wire mesh demister. Adopt the baffling board of integral type to add the silk screen defroster, the defogging is efficient.

In some of these embodiments, the first evaporative crystallization device 100 further comprises a distilled water tank 115 and a distilled water pump 116.

A second liquid outlet of the heater 104 is connected with a liquid inlet of the distilled water tank 115, a liquid outlet of the distilled water tank 115 is connected with a liquid inlet of the distilled water pump 116, and a liquid outlet of the distilled water pump 116 is connected with a first liquid inlet of the heat exchanger 101. Further, the heat exchanger 101 is provided with a second liquid outlet B.

The first steam generated by the salt-containing wastewater treated by the first evaporative crystallization device 100 returns to the heater 104 to be used as a partial evaporation heat source of the heater 104, and partial heat required by the primary evaporation treatment is provided; after carrying out the heat exchange with the circulation waste liquid in the heat exchange tube that gets into heater 104, the circulation waste liquid is by the evaporation of heating, and first steam condensation obtains the distilled water, and the distilled water storage is in distilled water jar 115, is carried to heat exchanger 101 as the heat source by distilled water pump 116, and after the salt-containing waste water that gets into in the heat exchanger 101 carries out the heat transfer, second liquid outlet C discharge system on the heat exchanger 101, the outer heat of discharging of distilled water can be retrieved in a large number like this, the thermal efficiency is improved, and the distilled water of retrieving reaches emission standard: COD 100 mg/L.

Specifically, an electric valve is provided on the heater 104 to control the pressure in the heater 104; the electric valve is connected to the atmosphere, and when the pressure is too low/too high, the electric valve is opened to control the pressure in the heater 104.

In some of these embodiments, the second outlet of the vent condenser 102 is connected to an inlet of the distilled water tank 115. The distilled water produced in the exhaust condenser 102 is stored in a distilled water tank 115 to further recover the distilled water.

Further, the distilled water tank 115 is further provided with an air outlet, and the air outlet is connected with the saturated steam inlet of the crystallization separator 103. In this way, the saturated steam generated from the condensed water flowing into the distilled water tank 115 is returned to the crystal separator 103 to be forcibly circulated, thereby further improving the thermal efficiency of the apparatus, further ensuring the thermal balance of the entire apparatus, and maintaining the stability of the operation conditions.

Further, the crystallization separator 103 is also provided with a saturated steam inlet E. According to the practical application, a small amount of additional saturated steam is introduced through the saturated steam inlet E of the crystallization separator 103 to maintain the heat balance of the whole device and ensure the stability of the operation condition.

In some embodiments, the first evaporative crystallization apparatus 100 further comprises a feed liquid tank 117 and a feed liquid delivery pump 118, and a liquid outlet of the feed liquid delivery pump 118 is connected to the second liquid inlet of the heat exchanger 101.

Further, the feed liquid tank 117 is provided with a feed liquid inlet a and a tap water inlet C. The salt-containing wastewater enters the feed liquid tank 117 through the feed liquid inlet A.

Further, the first evaporative crystallization device 100 further comprises a cleaning device 119, the cleaning device 119 comprises a chemical agent tank 1192, and a liquid outlet of the chemical agent tank 1192 is connected with a liquid inlet of the crystallization separator 103. The chemical tank 1192 is used to store chemicals and deliver them to the crystal separator 103 to clean the crystal separator 103. Further, the cleaning device 118 further includes a chemical agent pump 1191, and the chemical agent pump 1191 is disposed on a connection pipeline between the liquid outlet of the chemical agent tank 1182 and the liquid inlet of the crystallization separator 103.

The chemical agent stored in the chemical agent tank 1192 is pumped into the crystallization separator 103 through the chemical agent pump 1191, and a PLC automatic control device is arranged to control the cleaning device 119 to clean the crystallization separator 103 regularly, so that the stability of the water volume treated for a long time and the quality of the discharged water can be ensured.

DETAILED DESCRIPTION OF EMBODIMENT (S) OF INVENTION

Here, the salt separation treatment system for salt-containing wastewater according to the present invention is exemplified, but the present invention is not limited to the following embodiments.

Example 1

In this example 1, the salt separation treatment system shown in fig. 1 is adopted to perform salt separation treatment on the salt-containing wastewater, and the water quality of the salt-containing wastewater is: ammonium sulfate: 40 wt% and 8 wt% of ammonium nitrate.

1) With continued reference to fig. 1, in the specific example of the present embodiment, the saline wastewater is treated as follows:

during operation, salt-containing wastewater to be treated enters a material liquid tank 117 through a material liquid inlet A, the salt-containing wastewater is conveyed into a heat exchanger 101 through a material liquid conveying pump 118, the salt-containing wastewater is preheated in the heat exchanger 101, the preheated salt-containing wastewater enters an exhaust condenser 102, steam carried by the preheated salt-containing wastewater is condensed in the exhaust condenser 102, heat generated by condensation further raises the temperature of the salt-containing wastewater, the raised salt-containing wastewater enters a crystallization separator 103 through a circulating pump 105 to be subjected to flash evaporation, and then enters a heater 104, the heater 104 performs primary evaporation treatment on the salt-containing wastewater, so that the temperature of the salt-containing wastewater reaches 108.2 ℃, the pressure in a heat exchange tube in the heater 104 is controlled to be 0.1mPa, and ammonium sulfate reaches a supersaturated state; then the wastewater enters a crystallization separator 103, primary crystallization treatment is carried out in the crystallization separator 103, the ammonium sulfate reaching a supersaturated state in the salt-containing wastewater can crystallize and separate out supersaturated ammonium sulfate crystals, the obtained concentrated solution enters a thickener 111 through a concentrated solution pump 110 for pre-separation, a first concentrated mother solution and ammonium sulfate crystals are separated out through a second solid-liquid separator 112, and the ammonium sulfate crystals are discharged from a solid outlet D on the second solid-liquid separator 112. If the content of ammonium nitrate in the first concentrated mother liquor reaches 16 wt%, the mother liquor pump 114 conveys the first concentrated mother liquor to the first solid-liquid separator 202 for the next secondary evaporation crystallization treatment; if the content of ammonium nitrate in the first concentrated mother liquor does not reach 16 wt%, the mother liquor pump 114 conveys the first concentrated mother liquor into the separation crystallizer 103, mixes the first concentrated mother liquor with the saline wastewater to be treated, and reenters the separation crystallizer 104 to be used as new saline wastewater to circularly perform primary evaporation treatment operation until the content of ammonium nitrate in the first concentrated mother liquor reaches 16 wt%.

After the content of ammonium nitrate reaches 16 wt% in the first concentrated mother liquor, get into heating reation kettle 201, heating reation kettle 201 carries out the second grade evaporation crystallization to first concentrated mother liquor and handles, in the second grade evaporation crystallization process, first concentrated mother liquor is further concentrated, the temperature rises, the increase of the solubility of ammonium nitrate along with the temperature rise is far greater than the increase of the solubility of ammonium sulfate, the ammonium sulfate is crystallized earlier and is appeared, through controlling the content terminal point of ammonium nitrate in the first concentrated mother liquor, make the ammonium nitrate remain unsaturated state throughout, with the assurance ammonium nitrate does not crystallize and appear in the second grade evaporation knot in-process, thereby further obtain high-purity ammonium sulfate crystal. And when the first concentrated mother liquor reaches the end point of the mass content of ammonium nitrate of 25 wt%, the first concentrated mother liquor enters a first solid-liquid separator for solid-liquid separation to obtain waste liquor and ammonium sulfate crystals. When the mass content of ammonium nitrate in the waste liquid separated from the first solid-liquid separator does not reach the end point, the waste liquid can further heat the reaction kettle 201, and evaporation crystallization is continuously carried out to recover sulfuric acid.

When the mass content of ammonium nitrate in the waste liquid reaches the end point, the waste liquid is stored in the second mother liquid tank 203, enters the spray drying tower 205 through the second conveying pump 204, is dried into solid in a very short time, the solid waste is continuously output from the bottom of the spray drying tower 205 and the cyclone separator, and the waste gas is exhausted by the fan 206.

Meanwhile, the salt-containing wastewater is treated by the first evaporative crystallization device 100, the first steam generated in the crystallization separator 103 enters the gas washing tower 106, and is subjected to acid washing and alkali washing by an acid washing area and an alkali washing area arranged in the gas washing tower 106, the steam after gas washing returns to the heater 104 through the vapor compressor 107 to be used as a heat source, and is subjected to heat exchange with the circulating waste liquid entering the heat exchange tube of the heater 104, and then is condensed to obtain distilled water. Distilled water is stored in the distilled water tank 115, is conveyed to the heat exchanger 101 by the distilled water pump 116 as a heat source, exchanges heat with the salt-containing wastewater entering the heat exchanger 101, and passes through the second liquid outlet C discharge system on the heat exchanger 101, so that the heat discharged by the distilled water can be greatly recovered, the heat efficiency is improved, and the recovered distilled water reaches the discharge standard: COD 100 mg/L. Meanwhile, the waste liquid generated in the gas washing tower 106 can return to the crystallization separator 103 to participate in the evaporative crystallization process, so that no additional waste water is generated in the gas washing process.

And the non-condensed steam generated in the primary crystallization treatment of the salt-containing wastewater can return to the exhaust condenser 102 and continuously serve as a heat source of the exhaust condenser 102 to exchange heat with the salt-containing wastewater to be treated entering the exhaust condenser 102, atomized steam carried in the non-condensed steam is condensed into distilled water while the temperature of the salt-containing wastewater is increased, the distilled water generated in the exhaust condenser 102 is stored in the distilled water tank 115 to further recover the distilled water, and thus the thermal efficiency of the treatment system is further increased.

The solid-liquid separation is carried out by the first solid-liquid separator 202 to obtain ammonium sulfate crystals and waste liquid, the waste liquid is stored in the second mother liquid tank 203, enters the spray drying tower 205 through the second conveying pump 204, is dried into solid in a very short time, the solid waste is continuously output from the bottom of the spray drying tower 205 and the cyclone separator, and the waste gas is emptied by the fan 206.

2) Drying the ammonium sulfate separated in the step 1), and testing the purity of the dried ammonium sulfate crystal by adopting High Performance Liquid Chromatography (HPLC), wherein the purity of the ammonium sulfate crystal is 98%.

The technical features of the embodiments described above may be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the embodiments described above are not described, but should be considered as being within the scope of the present specification as long as there is no contradiction between the combinations of the technical features.

The above-mentioned embodiments only represent some embodiments of the present invention, and the description thereof is specific and detailed, but not to be construed as limiting the scope of the present invention. It should be noted that, for those skilled in the art, without departing from the spirit of the present invention, several variations and modifications can be made, which are within the scope of the present invention. Therefore, the protection scope of the present invention should be subject to the appended claims.

Claims (10)

1. A salt separation treatment system for salt-containing wastewater, comprising:

the first evaporative crystallization device comprises a heat exchanger, an exhaust condenser, a crystallization separator and a heater; a first liquid outlet of the heat exchanger is connected with a liquid inlet of the exhaust condenser; the first liquid outlet of the exhaust condenser is connected with the liquid inlet of the crystallization separator; a first liquid outlet of the crystallization separator is connected with a liquid inlet of the heater so as to carry out primary crystallization treatment on the salt-containing wastewater; a first liquid outlet of the heater is connected with a liquid inlet of the crystallization separator, and an exhaust port of the heater is connected with an air inlet of the exhaust condenser so as to carry out primary evaporation treatment on the salt-containing wastewater;

the second evaporative crystallization device comprises a heating reaction kettle and a first solid-liquid separator; the inlet of heating reation kettle with the second liquid outlet of crystallization separator is connected, the liquid outlet of heating reation kettle with the inlet of first solid-liquid separator is connected, heating reation kettle is used for right the first concentrated mother liquor that the primary crystallization was obtained carries out the second grade evaporation crystallization, first solid-liquid separator is used for carrying out solid-liquid separation to the warp the product after the second grade evaporation crystallization.

2. The salt separating treatment system as claimed in claim 1, wherein the liquid outlet of the first solid-liquid separator is connected to the liquid inlet of the heating reaction kettle.

3. The salt separating treatment system as claimed in claim 1, wherein the first evaporative crystallization apparatus further comprises a concentrate pump, a thickener, a second solid-liquid separator, a first mother liquor tank and a mother liquor pump; a second liquid outlet of the crystallization separator is connected with a liquid inlet of the thickener, a first liquid outlet of the thickener is connected with a liquid inlet of the second solid-liquid separator, a liquid outlet of the second solid-liquid separator is connected with a liquid outlet of the first mother liquor tank, and a liquid outlet of the first mother liquor tank is connected with a liquid inlet of the crystallization separator, so that the first concentrated mother liquor obtained through the first-stage crystallization is circularly subjected to the first-stage evaporation treatment;

the concentrated liquid pump is arranged on a connecting pipeline between the liquid outlet of the crystallization separator and the liquid inlet of the thickener; the mother liquor pump is arranged on a connecting pipeline between the liquid outlet of the first mother liquor tank and the liquid inlet of the crystallization separator, and the liquid outlet of the mother liquor pump is connected with the liquid inlet of the first solid-liquid separator.

4. The salt dividing treatment system as claimed in claim 3, wherein the second outlet of the thickener is connected to the inlet of the crystal separator.

5. The salt separating treatment system as claimed in claim 1, wherein the second evaporative crystallization apparatus further comprises a second mother liquor tank, a second transfer pump, a spray drying tower, a fan and a condenser; a liquid inlet of the second mother liquor tank is connected with a liquid outlet of the first solid-liquid separator, a liquid outlet of the second mother liquor tank is connected with a liquid inlet of the spray drying tower, and a gas outlet of the spray drying tower is connected with a gas inlet of the fan; the second delivery pump is positioned on a connecting pipeline between a liquid outlet of the second mother liquor tank and a liquid inlet of the spray drying tower, and an air inlet of the condenser is connected with an air outlet of the heating reaction kettle.

6. The salt separating and treating system according to any one of claims 1 to 5, wherein the first evaporative crystallization apparatus further comprises a forced circulation pump; and the forced circulation pump is positioned on a pipeline connected between the first liquid outlet of the crystallization separator and the liquid inlet of the heater.

7. The salt separating treatment system as claimed in any one of claims 1 to 5, wherein the first evaporative crystallization apparatus further comprises a scrubber and a vapor compressor; the gas inlet of the gas washing tower is connected with the gas outlet of the crystallization separator, the gas outlet of the gas washing tower is connected with the gas inlet of the steam compressor so as to carry out gas washing treatment on the first steam obtained by the primary crystallization treatment, and the gas outlet of the steam compressor is connected with the gas inlet of the heater so as to lead the first steam after the gas washing treatment to return to the heater to be used as a heat source; and the liquid outlet of the gas washing tower is connected with the liquid inlet of the crystallization separator.

8. The system of claim 7, wherein an acid wash zone and a base wash zone are provided in the scrubber tower to acid wash and base wash the first steam.

9. The salt separating treatment system according to any one of claims 1 to 5, wherein the first evaporative crystallization apparatus further comprises a distilled water tank; and a second liquid outlet of the heater is connected with a liquid inlet of the distilled water tank, and a liquid outlet of the distilled water tank is connected with a first liquid inlet of the heat exchanger.

10. The salt separating treatment system as claimed in claim 9, wherein the vapor inlet of the crystallization separator is connected to the outlet port of the distilled water tank.

Images