CN213771720U - High-efficient deep purification system of compact water - Google Patents
High-efficient deep purification system of compact water Download PDFInfo
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- CN213771720U CN213771720U CN202021433801.4U CN202021433801U CN213771720U CN 213771720 U CN213771720 U CN 213771720U CN 202021433801 U CN202021433801 U CN 202021433801U CN 213771720 U CN213771720 U CN 213771720U
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Abstract
The utility model discloses a high-efficient deep purification system of compact water, include: a pretreatment device, a coagulation device, an electrolytic denitrification device, an aeration biological filter, an adsorption dephosphorization device and a sludge treatment device. The utility model can remove 80-95% of COD in the polluted water body after the polluted water body is treated by a pretreatment device, a coagulation device, an electrolytic denitrification device, an aeration biological filter and an adsorption dephosphorization device in sequence, so that the COD of the discharged water is less than or equal to 20 mg/L; removing 95-99% of BOD, and enabling the BOD of effluent to be less than or equal to 4 mg/L; removing 60-98% of total phosphorus, so that the total phosphorus in the effluent is less than or equal to 0.1 mg/L; 95-99.99% of ammonia nitrogen is removed, the ammonia nitrogen content of the effluent is less than or equal to 1.0mg/L, the total nitrogen content of the effluent is 95-99.00%, the total nitrogen content of the effluent is less than or equal to 2mg/L, the chromaticity is removed by 80-95%, the dissolved oxygen in the water body is increased to more than 7mg/L, the purified water body reaches the III or IV class water quality standard of the environmental quality Standard of surface Water (GB3838-2002), and the sewage and the wastewater are changed into water resources.
Description
Technical Field
The utility model relates to a water purifies technical field, concretely relates to collect high-efficient deep purification system of compact water that devices such as coagulating sedimentation dephosphorization, electrolytic denitrification, bological aerated filter and degree of depth dephosphorization in an organic whole.
Background
At present, the serious consequence of annual outbreak of algae caused by water eutrophication is an important problem at home and abroad in the treatment of water eutrophication. The eutrophication of water body mainly means that the nitrogen and phosphorus content in the water body accumulates day by day, accumulates continuously and seriously exceeds the standard, one of the main reasons of the result is the sewage discharge of urban sewage treatment plants, and a large amount of nitrogen and phosphorus are discharged into the water body along with the sewage discharge. The urban domestic sewage is a polluted water body generated in the living process of people, and the general physical and chemical indexes are that COD is less than or equal to 800mg/L, BOD and less than or equal to 350mg/L, SS and less than or equal to 400mg/L, ammonia nitrogen is less than or equal to 50mg/L, total nitrogen is less than or equal to 70mg/L, and total phosphorus is less than or equal to 10mg/L, pH 7-9. At present, pollution treatment at home and abroad is divided into primary treatment, secondary treatment and advanced treatment. The main treatment process of the primary treatment comprises sewage collection, coarse grid filtration and fine grid filtration to an aeration sand settling tank and a primary settling tank. The main application processes of the secondary treatment include three major types, namely an activated sludge treatment process, a biofilm process and a Membrane Bioreactor (MBR). The activated sludge treatment process applied to the urban sewage plant mainly comprises three series: (1) oxidation ditch series; (2) A/A/O series; (3) sequencing Batch Reactor (SBR) series. The biofilm process applied to the urban sewage treatment plant mainly comprises a Biological Aerated Filter (BAF) process and a Moving Bed Biofilm (MBBR) process. Membrane Bioreactors (MBR) are new sewage treatment processes that have been developed recently, and can be classified into tubular membranes, curtain membranes, plate membranes, and the like according to the processing mode of membrane modules, and also into built-in or external MBRs according to the installation positions of the membrane modules and the bioreactors. At present, the advanced treatment process mainly applied at home and abroad is a coagulation dephosphorization and denitrification process. When the process is adopted to treat sewage in a sewage treatment plant, the process has the advantages of large investment, high operating cost, large occupied area, more structures and long construction time, the effluent quality is mostly quasi IV (mainly the total nitrogen can only reach 10mg/L) of pollutant discharge standard of urban sewage treatment plant (GB 18918-. In addition, from the analysis of the adopted standard, the pollutant discharge standard of urban sewage treatment plants (GB 18918-2002) is implemented in domestic urban sewage treatment plants at present, and compared with the main physicochemical indexes of the environmental quality standard of surface water (GB3838-2002), the main physicochemical indexes are that the total nitrogen, the total phosphorus and the dissolved oxygen can not meet the index requirements of the environmental quality standard of surface water (GB 3838-2002). Although the classical sewage treatment processes are applied for more than a hundred years, the quality of the effluent water hardly meets the index requirements of the environmental quality standard of surface water (GB3838-2002) after the classical sewage treatment processes are almost not changed for more than a hundred years, so that a novel sewage treatment process which has the advantages of high effluent water quality (meeting the requirement of water resource utilization), less investment, lower operating cost, small floor area, less structures and greatly shortened construction time is urgently needed. The poor V-class water body and the black and odorous water body are blackened and smelled due to the fact that the water body excessively receives dirt and exceeds the water environment capacity of the water body, and are generally lower than the V-class water quality standard of surface water environment quality standard (GB3838-2002), and the main characteristic indexes of the poor V-class water body and the black and odorous water body are that dissolved oxygen is less than 2.0mg/L, ammonia nitrogen is more than 2.0mg/L or total phosphorus is more than 0.4mg/L, the poor V-class water body and the black and odorous water body are located in areas with dense population, high pollution load intensity and incomplete infrastructure, and mainly comprise water bodies in urban built-up areas, urban and rural junctions, county cities, central towns and other areas. Therefore, the treatment of water pollution is an urgent task.
Disclosure of Invention
The utility model provides a process flow is short, the running cost is low, to the strong adaptability of quality of water, last effectual sewage and the high-efficient deep purification system of polluted water, its aim at overcomes the defect that the play water quality that current sewage treatment plant treatment process or water purification technique exist is poor, the investment is big, the purification cycle is long, take up an area of big, make sewage treatment plant go out water and reach "surface water environment quality standard" (GB3838-2002) IV class or even III water quality standard, make water quality of water improve, aquatic ecosystem resumes, realize the reconstruction and the healthy sustainable development of river, lake ecosystem.
The utility model discloses a following technical scheme realizes:
the utility model discloses an aspect provides a high-efficient deep purification system of compact water, include:
the pretreatment device (100) comprises a coarse grating, a fine and coarse grating, an aeration grit chamber and a lift pump which are sequentially communicated; the water inlet of the coarse grating is communicated with a water inlet pipeline of a polluted water body to be treated, the water outlet of the coarse grating is communicated with the water inlet of the fine and coarse grating, the water outlet of the fine and coarse grating is communicated with the water inlet of the aeration grit chamber, and the water outlet of the aeration grit chamber is communicated with the water inlet of the lift pump;
(II) a coagulating sedimentation device (200) which comprises a coagulating basin, a coagulation aiding basin, a sedimentation basin, an intermediate water basin and a sludge collecting basin which are sequentially communicated; the coagulation tank and the coagulation aiding tank are respectively provided with a water inlet, a water outlet and a medicine adding port; the sedimentation tank is provided with a water outlet and a sludge outlet; the water inlet of the coagulation tank is communicated with the water outlet of a lift pump of the pretreatment device (100), the water outlet of the coagulation tank is communicated with the water inlet of the coagulation aiding tank, and the water outlet of the coagulation aiding tank is communicated with the water inlet of the sedimentation tank; the water outlet of the sedimentation tank is communicated with the water inlet of the intermediate water tank, the water outlet of the intermediate water tank is communicated with the water inlet of an electrolytic denitrification main machine (310) of the electrolytic denitrification device (300), and a lift pump (311) is further arranged in a connecting pipeline between the water outlet and the electrolytic denitrification main machine (310); the inlet of the coagulation aiding tank and the inlet of the sludge collecting tank are communicated with the sludge outlet of the sedimentation tank through a sludge pump and a three-way valve, and the outlet of the sludge collecting tank is communicated with the inlet of the sludge treatment device (500);
(III) the electrolytic denitrification device (300) comprises an electrolytic denitrification host (310), a direct-current power supply (320) and a denitrification reaction tank (330), wherein a water inlet of the electrolytic denitrification host (310) is used for allowing clear water after coagulating sedimentation to enter, and a water outlet of the electrolytic denitrification host (310) is respectively communicated with a water inlet (331) of the denitrification reaction tank and a water inlet of the coagulation tank through a tee joint (315);
(IV) the aeration biological filter (400) consists of a biological filter body, an aeration pipe, a bracket, a filter material supporting layer, a filter material, a water collecting tank, an aeration fan, a backwashing water pipe, a sewage outlet, a sludge outlet and a disinfection tank; the water inlet of the biological aerated filter (400) is communicated with the water outlet of a denitrification reaction tank (330) of the electrolytic denitrification device (300) system, and the sewage outlet of the biological aerated filter (400) is communicated with the water inlet of the disinfection tank;
(V) a sludge treatment device (500) which comprises a sludge pump, a gravity concentration tank, a physical and chemical conditioning tank and a dehydrator, wherein the inlet of the sludge pump is communicated with the sludge outlet of the coagulation sedimentation tank and the sludge outlet of the biological filter tank body; the outlet of the physical and chemical conditioning pool is communicated with the sludge inlet of the dehydrator, the sludge blocks of the dehydrator are collected in the sludge collecting terrace, and the sewage of the dehydrator is communicated with the water inlet of the biological filter pool body.
The coagulating sedimentation device (200) is one of a high-efficiency sedimentation device, a magnetic coagulation device and a supermagnetic coagulating sedimentation device.
Specifically, the coagulation tank of the coagulation sedimentation device (200) further comprises a coagulant dosing device and a stirrer.
Furthermore, ferrous sulfate with the mass ratio of 5-10% or polyaluminium chloride solution with the mass ratio of 10-15% is stored in the coagulant dosing device.
Specifically, the coagulant aid tank also comprises a coagulant aid dosing device and a stirrer.
Furthermore, a PAM solution with the mass ratio of 1-2 per mill is stored in the coagulant aid dosing device.
Specifically, the electrolytic denitrification device also comprises an electrolyte adding device which is composed of an electrolyte solution preparation tank (341), an electrolyte solution storage tank (342), an electrolyte solution delivery pump (343) and an electrolyte solution flowmeter (344), wherein the electrolyte solution is delivered to the electrolyte solution storage tank (342) through the pump to be stored after the electrolyte solution preparation tank (341) is prepared, and when the electrolytic denitrification device works, the electrolyte solution delivery pump (343) is started and is input into the polluted water body through the electrolyte solution flowmeter (344), and then the polluted water body is electrolyzed in a main machine of the electrolytic denitrification system;
more specifically, the electrolyte adding device is used for adding 3-12% of sodium hypochlorite solution or 2-6% of sodium chloride solution into the electrolytic denitrification device; the electrolyte solution preparation tank (341) is used for preparing 4-12% sodium hypochlorite solution or 2-6% sodium chloride solution;
preferably, when ammonia nitrogen and total nitrogen are removed, an electrolyte adding device is adopted to add 3-12% of sodium hypochlorite solution into the electrolytic denitrification device according to the concentration of ammonia nitrogen in the water body;
more preferably, when ammonia nitrogen and total nitrogen are removed, an electrolyte adding device is adopted to add 3-5% of sodium hypochlorite solution into the electrolytic denitrification device according to the concentration of ammonia nitrogen in the water body;
specifically, the electrolytic denitrification device also comprises an electrolytic main engine pickling system which consists of a pickling solution preparation tank and a pickling solution delivery pump. The acid washing solution adopts 2-3% hydrochloric acid solution or 3-5% citric acid solution. When the electrode of the electrolytic denitrification device is polluted and the electrolytic efficiency is reduced, the electrolytic denitrification device stops working, and the acid cleaning system is started to remove the scale deposited on the surface of the electrode.
Furthermore, the waste water of the pickling system enters a coagulating sedimentation purification treatment.
Specifically, a micro-electrolysis device can be arranged in front of the biological aerated filter, and the micro-electrolysis device consists of a filter body (610), a support frame (620), a support layer (630), an iron-carbon layer (640) and a filter material layer (650); the micro-electrolysis device is mainly used for consuming excessive sodium hypochlorite during electrolysis and denitrification and ensuring the normal growth of microbial flora in the biological aerated filter.
Specifically, an adsorption dephosphorization device can be arranged behind the secondary sedimentation tank.
Furthermore, the adsorption dephosphorization device at least comprises an adsorption tower (710), a desorption regeneration system and a phosphorus precipitation recovery system; the adsorption tower (710) is composed of a water inlet (711), a water inlet four-way (712), a water inlet valve (713), an eluent inlet valve (714), an adsorption filler (716) of a lower support plate (715), an upper support plate (717), a water outlet (718) and a water outlet four-way (719); the desorption regeneration system is composed of a desorption regeneration liquid storage tank (721), a regeneration liquid delivery pump (722), a regeneration liquid inlet valve (723), an adsorption tower (710), a clear water tank (724), a clear water pump (725), a clear water valve (726), an eluent water outlet valve (727) and an eluent storage tank (728); a desorption regeneration liquid storage tank (721) is connected to the adsorption tower (710) through a regeneration liquid transfer pump (722) and a water inlet valve (713) and a water inlet cross joint (712); the clean water tank (724) is connected with the water outlet four-way joint (719) and the adsorption tower (710) through a clean water pump (725) and a clean water valve (726); the eluent storage tank (728) is connected with the adsorption tower (710) through an eluent outlet valve (727) and an outlet four-way valve (719); the phosphorus precipitation recovery system consists of a desorption liquid delivery pump (731), a desorption liquid inlet valve (732), a precipitation reaction tank (733), a stirrer (734), a precipitant storage tank (735), a metering pump (736), a phosphorus precipitation recovery tank (737), a concentration tank (739) and a recovery pump (738); the inlet of the desorption liquid delivery pump (731) is connected with the water outlet of the eluent storage tank (728), the water outlet of the desorption liquid delivery pump (731) is connected with the inlet of a desorption liquid inlet valve (732), and the outlet of the desorption liquid inlet valve (732) is connected with a phosphorus precipitation reaction tank (733); the sedimentation reaction tank (733) is also provided with a stirrer (734) and a precipitant storage tank (735), the water outlet of the sedimentation reaction tank (733) is connected with a phosphorus sedimentation recovery tank (737), the water outlet of the phosphorus sedimentation recovery tank (737) is connected with the inlet of a concentration tank (739), and the outlet of the phosphorus sedimentation recovery tank (737) is connected with a desorption regeneration liquid storage tank (721) through a recovery pump (738); the precipitant storage tank (735) stores saturated solution of calcium hydroxide.
Specifically, the inlet of a sludge pump is respectively communicated with the sludge outlets of the coagulating sedimentation device (200) and the biological aerated filter (400), the outlet of the sludge pump is communicated with the inlet of the gravity concentration tank, the gravity concentration tank comprises an upper layer region, a middle layer region and a lower layer region from top to bottom, the water outlet of the upper layer region is used for being communicated with the water inlet of the biological filter tank body, the outlet of the lower layer region is communicated with the inlet of the dehydrator, and the middle layer region, the physicochemical conditioning tank and the dehydrator are sequentially communicated in sequence; and a stirrer is also arranged in the gravity concentration tank.
Specifically, the water body deep purification system can be one of an underground type, a semi-underground type or an overground type.
A compact water body high-efficiency deep purification method utilizes the water body deep purification system to carry out deep purification of water body, and comprises the following steps:
(1) pretreatment: filtering the polluted water collected by the pipeline through a coarse grating and a fine grating to remove large-particle solid matters, and precipitating the polluted water through an aeration grit chamber to remove impurities such as silt and the like in the water;
(2) coagulating sedimentation: the method comprises the following steps:
firstly, the pretreated water body is lifted by a lift pump to enter a coagulation tank, and 10-120 g/m of the pretreated water body is added by a coagulation agent adding device3Ferrous sulfate solution or 15-150 g/m3The polyaluminium chloride solution and electrolytic water with the total amount of 3-5% of the inlet water are mixed and continuously stirred, the stirring speed is 50-300 r/min, and the coagulation reaction time is 3-15 min;
secondly, coagulation aiding: the water body after coagulation reaction in the step (1) enters a coagulation aiding pool, PAM is added through a coagulation aiding and dosing device, and the relation between the weight of the added PAM and the volume of sewage is 0.1-1 g/m3Stirring and reacting for 1-5 min at a stirring speed of 10-80 r/min;
precipitation: enabling the sewage subjected to the coagulation aiding reaction in the step (2) to enter a sedimentation tank for solid-liquid separation, wherein the solid-liquid separation time is 3-10 min, and forming a supernatant liquid zone on the upper layer of the sedimentation tank, a sludge concentration zone at the bottom of the sedimentation tank and a solid-liquid separation zone in the middle of the sedimentation tank through the solid-liquid separation for 3-10 min; and (3) when the precipitation amount formed in the coagulation aid tank in the step (2) is insufficient, starting a sludge pump, and returning partial sludge from the precipitation tank into the coagulation aid tank to promote the generation of precipitates.
In the coagulation, coagulation aiding and precipitation processes, phosphate radicals and hydrogen phosphate radicals in the water body react with ferric ions to generate ferric phosphate precipitates, so that total phosphorus in the water body is removed.
3Fe3++2PO4 3-＝Fe3(PO4)2↓
In addition, the generated large amount of floc precipitates have huge specific surface area and charge, can adsorb organic matters in the water body, and can simultaneously remove chroma and COD in the water body
After coagulating sedimentation treatment, removing 80-95% of SS in the water body to ensure that the SS in the water body is less than or equal to 50mg/L, removing 40-90% of total phosphorus in the water body to ensure that the total phosphorus in the water body is less than or equal to 1mg/L, and removing 40-75% of COD in the water body together to ensure that the COD in the water body is less than or equal to 150 mg/L;
(3) the electrolytic denitrification comprises the following steps:
electrolysis: conveying the polluted water body subjected to coagulating sedimentation to an electrolytic denitrification host (310) through an intermediate water tank and a lifting pump (311) for electrolysis for 10-150 s; during electrolysis, 3-12% of sodium hypochlorite solution or 2-6% of sodium chloride solution is added through an electrolyte adding system;
② denitrification reaction: feeding the electrolyzed effluent of the electrolytic denitrification host machine into a denitrification reaction tank (330) and uniformly distributing the electrolyzed effluent at the bottom of the denitrification reaction tank (330) through a water inlet (331) to enable the water body to flow from bottom to top, wherein the retention time is 30-150 min, and the sodium hypochlorite and the oxygen and hydrogen generated by electrolysis react with the ammonia nitrogen and the nitrate nitrogen in the polluted water body respectively in a denitrification reaction tank (330) for 10-150 min to generate nitrogen and water, so that the ammonia nitrogen and the nitrate nitrogen in the water body are removed; the working voltage of the electrolytic denitrification host (310) is 35-90V, and the current density is 3-50 mA/cm2(ii) a Through electrolytic denitrification, 50mg/L of ammonia nitrogen in the water body is reduced to be less than or equal to 1mg/L, and the total nitrogen in the water body is reduced to be less than or equal to 5mg/L from 10-70 mg/L; and removing 5-15% of COD and 5-10% of total phosphorus in the water body through an electrolytic denitrification reaction, and simultaneously increasing the dissolved oxygen in the water body to be more than 7 mg/L.
The principle of electrolysis of sodium hypochlorite solution to remove ammonia nitrogen is that hypochlorous acid reacts with ammonia to finally generate nitrogen.
NaOCl+H2O→HOCl+NaOH
NH3+HOCl→NH2Cl+H2O (monochloramine)
NH2Cl+HOCl→NHCl2+H2O (dichloramine)
2NHCl2+HOCl→N2↑+3HCl+H2O (denitrogenation main reaction one)
The main reaction formula is as follows:
2NH3+3NaOCl→N2↑+3NaCl+3H2O
principle of deammoniation (side reaction)
At the same time, the radical O.produced by electrolysis reacts with ammonia to produce nitrate radical.
2NH4 ++5O2→2NO3 -+4H2O
In addition, hydrogen generated by electrolysis reacts with nitrate and nitrite in the water body under the action of the catalyst to generate nitrogen, so that nitrate nitrogen in the water body is removed.
NO3 -+H2—→NO2 -+H2O
2NO2 -+2H2—→N2↑+2H2O (total nitrogen removal reaction)
(4) Micro-electricity to remove sodium hypochlorite: enabling the water body after electrolytic denitrification to flow into an iron-carbon microelectrochemical sodium hypochlorite removal device, and staying in the device for 10-30 min, wherein excessive sodium hypochlorite reacts with iron carbon during electrolytic denitrification, so that the interference of the sodium hypochlorite on the operation of a subsequent aeration biological filter is eliminated, and the sodium hypochlorite content of microelectrolytic effluent is less than or equal to 0.1 mg/L;
(5) and (3) biological aerated filter purification: conveying the water subjected to micro-electricity sodium hypochlorite removal to an aeration biological filter for biochemical treatment, wherein the retention time of the polluted water in the filter is 120-180 min, so as to fully remove COD, BOD and total nitrogen in the water;
(6) and (3) disinfection: and (2) feeding the water body treated by the biological aerated filter into a contact disinfection tank for disinfection, wherein the water body after treatment reaches the III or IV class water quality standard of surface water environmental quality standard (GB3838-2002), and the bottom sludge is fed into a sludge treatment device (500) through a sludge pump for sludge dehydration treatment.
(7) Sludge treatment: conveying sludge in the sedimentation tank and sludge in the secondary sedimentation tank into a gravity concentration tank through a sludge pump, stirring, performing gravity sedimentation separation by using density difference of water, organic matters and inorganic matters to form a supernatant layer, a middle-layer organic matter enrichment layer and a lower-layer inorganic layer, and conveying liquid in the supernatant layer into a biological aerated filter (400) for purification; adding a physicochemical conditioner into the lower inorganic layer in the physicochemical conditioning pool, then conveying the lower inorganic layer into a dehydrator for dehydration to form organic mud blocks and water, and conveying the effluent of the dehydrator into a biological aerated filter (400) for purification; and dehydrating and drying the organic matter enrichment layer in the middle layer to obtain the carbon fertilizer.
After the treatment by the method, the effect of removing main sewage in each step of water body purification is shown in table 1:
TABLE 1 Water purification Effect of removing Main waste Water
The residence time of each step after the above treatment is shown in Table 2
Table 2 residence time units for the procedure: min
| Pretreatment of | Coagulating sedimentation | Electrolytic denitrification | Micro-electrolysis | Aeration biological filter | Deep phosphorus removal | Total up to |
| 10～15 | 25～30 | 30～120 | 10～30 | 120～180 | 10～15 | 205～390 |
After the water body purification system is adopted and treated by the steps, the COD in the water body can be removed by 80-95%, so that the COD of the effluent water is less than or equal to 20 mg/L; removing 95-99% of BOD, and enabling the BOD of the effluent to be less than or equal to 4 mg/L; removing 90-95% of total phosphorus, so that the total phosphorus of effluent is less than or equal to 0.1 mg/L; the ammonia nitrogen of the effluent is less than or equal to 1.0mg/L, the ammonia nitrogen is removed by 95-99.99%, the total nitrogen of the effluent is less than or equal to 1mg/L, and the total nitrogen is removed by 80-95%; the chroma is removed by 80-95%, and the dissolved oxygen is increased to more than 7 mg/L. Is particularly suitable for the purification treatment of water bodies with poor V-class water quality or black and odorous water bodies, so that the water bodies reach the III-class or IV-class water quality standard of surface water environmental quality standard (GB 3838-2002). The main indexes of inlet and outlet water for deep purification of sewage or water are shown in table 3.
Table 3 main indices of inlet and outlet water for deep purification of sewage or water.
The utility model discloses a water body treatment system and method has following outstanding effect:
1. high water quality and changing sewage into water resource
Adopt the utility model discloses a water degree of depth system and method including total nitrogen main index after to the water purification all reaches "surface water environmental quality standard" (GB3838-2002) III class or IV water quality standard, and the dissolved oxygen content is high and is greater than 7mg/L, has changed sewage into the water resource, discharges into natural water, can effectively improve the dissolved oxygen of water, effectively restraines the growth of alga, improves quality of water comprehensively, can regard as industrial and agricultural production and commercial water simultaneously.
2. Eliminate nitrogen and phosphorus pollution from source
At present, nitrogen and phosphorus in water body seriously exceed the standard, and eutrophication of water bodies such as rivers and lakes is caused, so that blue algae in main lakes in China explode year after year. In order to radically treat blue algae, China invests a large amount of manpower and material resources, but the effect is not high. The discharge standard of the sewage is that the total nitrogen is less than or equal to 15mg/L and the total phosphorus is less than or equal to 0.5mg/L, and a large amount of nitrogen and phosphorus enter a water body along with the discharge water of the sewage treatment plant, so that the nitrogen and phosphorus in the water body are greatly enriched, and therefore, the discharge water of the sewage treatment plant is one of the main sources of the nitrogen and phosphorus in the water body. After the sewage deep purification system and the method thereof are adopted to treat sewage, the total nitrogen of the water body is less than or equal to 2mg/L, the total phosphorus is less than or equal to 0.1mg/L, the water quality standards of III types or IV types in the surface water environmental quality standard (GB3838-2002) are all reached, and the nitrogen and phosphorus pollution of the water body is thoroughly eradicated from the source.
3. Simple process flow
Adopt the utility model discloses only handle main processes such as coagulation, electrolytic denitrification and biofiltration to sewage, the production technology flow is simpler than current sewage treatment production technology flow, and building structures still less.
4. Investment saving
At present, the investment for construction of the fixed assets of ten thousand tons per day sewage treatment plants of the mainstream urban sewage treatment process at home and abroad is about 3500-5000 ten thousand yuan, and the investment for construction of the fixed assets of ten thousand tons per day sewage treatment plants of the deep water purification system of the utility model is about 3000-4000 ten thousand yuan, which saves about 20% of the investment compared with the prior art.
5. Low running cost
Adopt the utility model discloses a water deep purification system carries out deep purification treatment's running cost than current sewage town sewage treatment plant's running cost low 15 ~ 20% to sewage.
6. Saving a lot of land
At present, when sewage treatment plants constructed by an activated sludge method are adopted at home and abroad to treat sewage, most of the sewage stays for 13-18 hours, some sewage stays for more than 20 hours, the land occupation of each ten thousand tons of sewage treatment facilities is 0.6-1 hectare, and the land occupation is large. Adopt the utility model discloses a when water degree of depth clean system handled the water, the dwell time of water only has 5 ~ 7 hours, and device area is the third of traditional device only, and area is little, can save land resource in a large number, is particularly suitable for the nervous city of land resource.
7. Short construction period
The utility model discloses a water deep purification system's essential element coagulating sedimentation device, electrolytic denitrification device, absorption phosphorus removal device etc. all are the modular system, and the essential system all is in the factory production, when adopting these equipment construction sewage treatment plant, as long as assemble these modular system at sewage treatment plant, need not a large amount of construction structures, so, the construction period of sewage treatment plant's construction period than traditional sewage plant will shorten more than half, and construction period is short.
Drawings
In order to more clearly illustrate the technical solution of the present invention, the drawings needed for the description of the embodiments or the prior art will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and it is obvious for those skilled in the art that other drawings can be obtained according to the drawings without creative efforts.
FIG. 1 is a process flow diagram of the present invention;
FIG. 2 is a schematic view of the installation of the present invention;
FIG. 3 is a schematic view of an electrolytic denitrification apparatus according to the present invention;
FIG. 4 is a schematic diagram of a microelectrolysis sodium hypochlorite residue removing device of the utility model;
FIG. 5 is a schematic view of the adsorption phosphorus removal device of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by a person of ordinary skill in the art without creative efforts belong to the protection scope of the present invention.
Referring to the attached drawings 1-5 of the specification, a compact water body deep purification treatment system comprises:
the pretreatment device (100) comprises a coarse grating, a fine and coarse grating, an aeration grit chamber and a lift pump which are sequentially communicated; the water inlet of the coarse grating is communicated with a water inlet pipeline of a polluted water body to be treated, the water outlet of the coarse grating is communicated with the water inlet of the fine and coarse grating, the water outlet of the fine and coarse grating is communicated with the water inlet of the aeration grit chamber, and the water outlet of the aeration grit chamber is communicated with the water inlet of the lift pump;
the coagulation device (200) comprises a coagulation tank, a coagulation aiding tank, a sedimentation tank, an intermediate water tank and a sludge collection tank which are sequentially communicated; the coagulation tank and the coagulation aiding tank are respectively provided with a water inlet, a water outlet and a medicine adding port; the sedimentation tank is provided with a water outlet and a sludge outlet; the water inlet of the coagulation tank is communicated with the water outlet of a lift pump of the pretreatment device (100), the water outlet of the coagulation tank is communicated with the water inlet of the coagulation aiding tank, and the water outlet of the coagulation aiding tank is communicated with the water inlet of the sedimentation tank; the water outlet of the sedimentation tank is communicated with the water inlet of the intermediate water tank, the water outlet of the intermediate water tank is communicated with the water inlet of an electrolytic denitrification main machine (310) of the electrolytic denitrification device (300), and a lift pump (311) is further arranged in a connecting pipeline between the water outlet and the electrolytic denitrification main machine (310); the inlet of the coagulation aiding tank and the inlet of the sludge collecting tank are communicated with the sludge outlet of the sedimentation tank through a sludge pump and a three-way valve, and the outlet of the sludge collecting tank is communicated with the inlet of the sludge treatment device (500);
(III) the electrolytic denitrification device (300) comprises an electrolytic denitrification host (310), a direct-current power supply (320) and a denitrification reaction tank (330), wherein a water inlet of the electrolytic denitrification host (310) is used for allowing clear water after coagulating sedimentation to enter, and a water outlet of the electrolytic denitrification host (310) is respectively communicated with a water inlet (331) of the denitrification reaction tank (330) and a water inlet of a coagulation tank through a tee joint (315);
(IV) the aeration biological filter (400) consists of a biological filter body, an aeration pipe, a bracket, a filter material supporting layer, a filter material, a water collecting tank, an aeration fan, a backwashing water pipe, a sewage outlet, a sludge outlet and a disinfection tank; the water inlet of the biological aerated filter (400) is communicated with the water outlet of a denitrification reaction tank (330) of the electrolytic denitrification device (300) system, and the sewage outlet of the biological aerated filter (400) is communicated with the water inlet of the disinfection tank;
(V) a sludge treatment device (500) which comprises a sludge pump, a gravity concentration tank, a physical and chemical conditioning tank and a dehydrator, wherein the inlet of the sludge pump is communicated with the sludge outlet of the coagulation sedimentation tank and the sludge outlet of the biological filter tank body; the outlet of the physical and chemical conditioning pool is communicated with the sludge inlet of the dehydrator, the sludge blocks of the dehydrator are collected in the sludge collecting terrace, and the sewage of the dehydrator is communicated with the water inlet of the biological filter pool body.
The coagulating sedimentation device (200) is one of a high-efficiency sedimentation device, a magnetic coagulation device and a supermagnetic coagulating sedimentation device.
Specifically, the coagulation tank of the coagulation sedimentation device (200) further comprises a coagulant dosing device and a stirrer.
Furthermore, ferrous sulfate with the mass ratio of 5-10% or polyaluminium chloride solution with the mass ratio of 10-15% is stored in the coagulant dosing device.
Specifically, the coagulant aid tank also comprises a coagulant aid dosing device and a stirrer.
Furthermore, a PAM solution with the mass ratio of 1-2 per mill is stored in the coagulant aid dosing device.
Specifically, the electrolytic denitrification device also comprises an electrolyte adding device which is composed of an electrolyte solution preparation tank (341), an electrolyte solution storage tank (342), an electrolyte solution delivery pump (343) and an electrolyte solution flowmeter (344), wherein the electrolyte solution is delivered to the electrolyte solution storage tank (342) through the pump to be stored after the electrolyte solution preparation tank (341) is prepared, and when the electrolytic denitrification device works, the electrolyte solution delivery pump (343) is started and is input into the polluted water body through the electrolyte solution flowmeter (344), and then the polluted water body is electrolyzed in a main machine of the electrolytic denitrification system;
more specifically, the electrolyte adding device is used for adding 3-12% of sodium hypochlorite solution or 2-6% of sodium chloride solution into the electrolytic denitrification device; the electrolyte solution preparation tank (341) is used for preparing 4-12% sodium hypochlorite solution or 2-6% sodium chloride solution;
preferably, when ammonia nitrogen and total nitrogen are removed, an electrolyte adding device is adopted to add 3-12% of sodium hypochlorite solution into the electrolytic denitrification device according to the concentration of ammonia nitrogen in the water body;
more preferably, when ammonia nitrogen and total nitrogen are removed, an electrolyte adding device is adopted to add 3-5% of sodium hypochlorite solution into the electrolytic denitrification device according to the concentration of ammonia nitrogen in the water body;
specifically, the electrolytic denitrification device also comprises an electrolytic main engine pickling system which consists of a pickling solution preparation tank and a pickling solution delivery pump. The acid washing solution adopts 2-3% hydrochloric acid solution or 3-5% citric acid solution. When the electrode of the electrolytic denitrification device is polluted and the electrolytic efficiency is reduced, the electrolytic denitrification device stops working, and the acid cleaning system is started to remove the scale deposited on the surface of the electrode.
Furthermore, the waste water of the pickling system enters a coagulating sedimentation purification treatment.
Specifically, a micro-electrolysis device can be arranged in front of the biological aerated filter, and the micro-electrolysis device consists of a filter body (610), a support frame (620), a support layer (630), an iron-carbon layer (640) and a filter material layer (650); the micro-electrolysis device is mainly used for consuming excessive sodium hypochlorite during electrolysis and denitrification and ensuring the normal growth of bacteria in the biological aerated filter.
Specifically, a deep phosphorus removal device can be arranged behind the biological aerated filter, and the deep phosphorus removal device is an adsorption phosphorus removal device.
Furthermore, the adsorption dephosphorization device at least comprises an adsorption tower (710), a desorption regeneration system and a phosphorus precipitation recovery system; the adsorption tower (710) is composed of a water inlet (711), a water inlet four-way (712), a water inlet valve (713), an eluent inlet valve (714), an adsorption filler (716) of a lower support plate (715), an upper support plate (717), a water outlet (718) and a water outlet four-way (719); the desorption regeneration system is composed of a desorption regeneration liquid storage tank (721), a regeneration liquid delivery pump (722), a regeneration liquid inlet valve (723), an adsorption tower (710), a clear water tank (724), a clear water pump (725), a clear water valve (726), an eluent water outlet valve (727) and an eluent storage tank (728); a desorption regeneration liquid storage tank (721) is connected to the adsorption tower (710) through a regeneration liquid transfer pump (722) and a water inlet valve (713) and a water inlet cross joint (712); the clean water tank (724) is connected with the water outlet four-way joint (719) and the adsorption tower (710) through a clean water pump (725) and a clean water valve (726); the eluent storage tank (728) is connected with the adsorption tower (710) through an eluent outlet valve (727) and an outlet four-way valve (719); the phosphorus precipitation recovery system consists of a desorption liquid delivery pump (731), a desorption liquid inlet valve (732), a precipitation reaction tank (733), a stirrer (734), a precipitant storage tank (735), a metering pump (736), a phosphorus precipitation recovery tank (737), a concentration tank (739) and a recovery pump (738); the inlet of the desorption liquid delivery pump (731) is connected with the water outlet of the eluent storage tank (728), the water outlet of the desorption liquid delivery pump (731) is connected with the inlet of a desorption liquid inlet valve (732), and the outlet of the desorption liquid inlet valve (732) is connected with a phosphorus precipitation reaction tank (733); the sedimentation reaction tank (733) is also provided with a stirrer (734) and a precipitant storage tank (735), the water outlet of the sedimentation reaction tank (733) is connected with a phosphorus sedimentation recovery tank (737), the water outlet of the phosphorus sedimentation recovery tank (737) is connected with the inlet of a concentration tank (739), and the outlet of the concentration tank (739) is connected with a desorption regeneration liquid storage tank (721) through a recovery pump (738); the precipitant storage tank (735) stores saturated solution of calcium hydroxide.
Specifically, the inlet of a sludge pump is respectively communicated with the sludge outlets of the coagulating sedimentation device (200) and the biological aerated filter (400), the outlet of the sludge pump is communicated with the inlet of the gravity concentration tank, the gravity concentration tank comprises an upper layer region, a middle layer region and a lower layer region from top to bottom, the water outlet of the upper layer region is used for being communicated with the water inlet of the biological filter tank body, the outlet of the lower layer region is communicated with the inlet of the dehydrator, and the middle layer region, the physicochemical conditioning tank and the dehydrator are sequentially communicated in sequence; and a stirrer is also arranged in the gravity concentration tank.
A water body deep purification method which utilizes the compact water body deep purification system to carry out water body deep purification comprises the following steps:
(1) pretreatment: filtering the polluted water collected by the pipeline through a coarse grating and a fine grating to remove large-particle solid matters, and precipitating the polluted water through an aeration grit chamber to remove impurities such as silt and the like in the water;
(2) coagulating sedimentation: the method comprises the following steps:
firstly, the pretreated water body is lifted by a lift pump to enter a coagulation tank, and 10-120 g/m of the pretreated water body is added by a coagulation agent adding device3Ferrous sulfate solution or 15-150 g/m3The polyaluminium chloride solution and electrolytic water with the total amount of 3-5% of the inlet water are mixed and continuously stirred, the stirring speed is 50-300 r/min, and the coagulation reaction time is 3-15 min;
secondly, coagulation aiding: the water body after coagulation reaction in the step (1) enters a coagulation aiding pool, PAM is added through a coagulation aiding and dosing device, and the relation between the weight of the added PAM and the volume of sewage is 0.1-1 g/m3Stirring and reacting for 1-5 min at a stirring speed of 10-80 r/min;
precipitation: enabling the sewage subjected to the coagulation aiding reaction in the step (2) to enter a sedimentation tank for solid-liquid separation, wherein the solid-liquid separation time is 3-10 min, and forming a supernatant liquid zone on the upper layer of the sedimentation tank, a sludge concentration zone at the bottom of the sedimentation tank and a solid-liquid separation zone in the middle of the sedimentation tank through the solid-liquid separation for 3-10 min; and (3) when the precipitation amount formed in the coagulation aid tank in the step (2) is insufficient, starting a sludge pump, and returning partial sludge from the precipitation tank into the coagulation aid tank to promote the generation of precipitates.
In the coagulation, coagulation aiding and precipitation processes, phosphate radicals and hydrogen phosphate radicals in the water body react with ferric ions to generate ferric phosphate precipitates, so that total phosphorus in the water body is removed.
3Fe3++2PO4 3-＝Fe3(PO4)2↓
In addition, the generated large amount of floc precipitates have huge specific surface area and charge, can adsorb organic matters in the water body, and can simultaneously remove chroma and COD in the water body
After coagulating sedimentation treatment, removing 80-95% of SS in the water body to ensure that the SS in the water body is less than or equal to 50mg/L, removing 40-90% of total phosphorus in the water body to ensure that the total phosphorus in the water body is less than or equal to 1mg/L, and removing 40-75% of COD in the water body together to ensure that the COD in the water body is less than or equal to 150 mg/L;
(3) the electrolytic denitrification comprises the following steps:
electrolysis: conveying the polluted water body subjected to coagulating sedimentation to an electrolytic denitrification host (310) through an intermediate water tank and a lifting pump (311) for electrolysis for 10-150 s; during electrolysis, 3-12% of sodium hypochlorite solution or 2-6% of sodium chloride solution is added through an electrolyte adding system;
② denitrification reaction: feeding the electrolyzed effluent of the electrolytic denitrification host machine into a denitrification reaction tank (330) and uniformly distributing the electrolyzed effluent at the bottom of the denitrification reaction tank (330) through a water inlet (331) to enable the water body to flow from bottom to top, wherein the retention time is 30-150 min, and the sodium hypochlorite and the oxygen and hydrogen generated by electrolysis react with the ammonia nitrogen and the nitrate nitrogen in the polluted water body respectively in a denitrification reaction tank (330) for 10-150 min to generate nitrogen and water, so that the ammonia nitrogen and the nitrate nitrogen in the water body are removed; the working voltage of the electrolytic denitrification host (310) is 35-90V, and the current density is 3-50 mA/cm2(ii) a Through electrolytic denitrification, 50mg/L of ammonia nitrogen in the water body is reduced to be less than or equal to 1mg/L, and the total nitrogen in the water body is reduced to be less than or equal to 5mg/L from 10-70 mg/L; and removing 5-15% of COD and 5-10% of total phosphorus in the water body through an electrolytic denitrification reaction, and simultaneously increasing the dissolved oxygen in the water body to be more than 7 mg/L.
The principle of electrolysis of sodium hypochlorite solution to remove ammonia nitrogen is that hypochlorous acid reacts with ammonia to finally generate nitrogen.
NaOCl+H2O→HOCl+NaOH
NH3+HOCl→NH2Cl+H2O (monochloramine)
NH2Cl+HOCl→NHCl2+H2O (dichloramine)
2NHCl2+HOCl→N2↑+3HCl+H2O (denitrogenation main reaction one)
The main reaction formula is as follows:
2NH3+3NaOCl→N2↑+3NaCl+3H2O
principle of deammoniation (side reaction)
At the same time, the radical O.produced by electrolysis reacts with ammonia to produce nitrate radical.
2NH4 ++5O2→2NO3 -+4H2O
In addition, hydrogen generated by electrolysis reacts with nitrate and nitrite in the water body under the action of the catalyst to generate nitrogen, so that nitrate nitrogen in the water body is removed.
NO3 -+H2—→NO2 -+H2O
2NO2 -+2H2—→N2↑+2H2O (total nitrogen removal reaction)
(4) Micro-electricity to remove sodium hypochlorite: enabling the water body after electrolytic denitrification to flow into an iron-carbon microelectrochemical sodium hypochlorite removal device, and staying in the device for 10-30 min, wherein excessive sodium hypochlorite reacts with iron carbon during electrolytic denitrification, so that the interference of the sodium hypochlorite on a subsequent biological aerated filter section is eliminated, and the sodium hypochlorite content of microelectrolytic effluent is less than or equal to 0.1 mg/L;
(5) and (3) aerating the biological filter: conveying the water subjected to micro-electricity sodium hypochlorite removal to an aeration biological filter for biochemical treatment, wherein the retention time of the polluted water in the aeration biological filter is 120-180 min, so as to fully remove residual COD, BOD and total nitrogen (mainly nitrate and nitrite) in the water;
(6) and (3) disinfection: and (2) feeding the water body treated by the biological aerated filter into a contact disinfection tank for disinfection, wherein the water body after treatment reaches the III or IV class water quality standard of surface water environmental quality standard (GB3838-2002), and the bottom sludge is fed into a sludge treatment device (500) through a sludge pump for sludge dehydration treatment.
(7) Sludge treatment: conveying sludge in the sedimentation tank and sludge in the secondary sedimentation tank into a gravity concentration tank through a sludge pump, stirring, performing gravity sedimentation separation by using density difference of water, organic matters and inorganic matters to form a supernatant layer, a middle-layer organic matter enrichment layer and a lower-layer inorganic layer, and conveying liquid in the supernatant layer into a biological aerated filter (400) for purification; adding a physicochemical conditioner into the lower inorganic layer in the physicochemical conditioning pool, then conveying the lower inorganic layer into a dehydrator for dehydration to form organic mud blocks and water, and conveying the effluent of the dehydrator into a biological aerated filter (400) for purification; and dehydrating and drying the organic matter enrichment layer in the middle layer to obtain the carbon fertilizer.
Example 1
A certain municipal sewage treatment plant adopts the production process of the utility model, which mainly comprises pretreatment (coarse grid, fine grid, aeration sand settling tank), coagulating sedimentation, electrolytic denitrification, micro electrolysis, aeration biological filter, adsorption dephosphorization and disinfection.
TABLE 1 Water quality index of influent water from certain Sewage treatment plant
And the urban domestic sewage enters the water body deep purification system of the sewage treatment plant. The water body purification system comprises pretreatment (100), coagulating sedimentation device treatment (200), an electrolytic denitrification device (300) and an aeration biological filter (400). The purification system of the sewage treatment plant also comprises a sludge treatment device (500).
The sewage enters a pretreatment device (100), a coagulating sedimentation device (200), an electrolytic denitrification device (300) and an aeration biological filter (400) in sequence.
Adding a ferrous sulfate coagulant into the coagulating sedimentation device, wherein the adding amount is 45mg/L, adding 1mg/L of coagulant aid PAM after coagulation reaction under the condition of 100 revolutions, reacting under the condition of 20 revolutions, and then feeding the mixture into a sedimentation tank for separation, wherein the water quality of the coagulating sedimentation effluent is shown in Table 2.
TABLE 2 Water quality index after coagulating sedimentation treatment of certain municipal sewage
| Serial number | Basic control items | Sewage plant influent (mg/L) | Coagulation water (mg/L) | Removal Rate (%) |
| 1 | COD | 521 | 182.05 | 65.06 |
| 2 | BOD | 236 | 86.51 | 63.34 |
| 3 | |
200 | 35 | 82.50 |
| 4 | Animal and vegetable oil | - | 0.5 | |
| 5 | Petroleum products | - | 0.3 | |
| 6 | Total nitrogen (in N) | 47.2 | 45.31 | 4.00 |
| 7 | Ammonia nitrogen (in N) | 42.7 | 40.09 | 6.11 |
| 8 | Total phosphorus (in terms of P) | 8 | 0.95 | 88.13 |
| 9 | Dissolved oxygen | - | 2.5 | - |
| 10 | Chroma (dilution multiple) | 80 | 20 | 75.00 |
| 11 | pH | 6～9 | 6-9 | - |
The water body after coagulating sedimentation enters an electrolytic denitrification device (300) for treatment, the treated water body enters a denitrification reaction tank (330) for denitrification reaction, and the effluent indexes are shown in table 3. The working voltage of the electrolytic denitrification host (310) is 36.5V, and the current density is 11mA/cm2。
TABLE 3 Water quality index of a certain sewage after coagulating sedimentation and electrolytic denitrification
The effluent treated by the electrolytic denitrification device (300) is biochemically treated by the biological aerated filter (400), and the quality of the purified effluent is shown in Table 4.
TABLE 4 Water quality index of a certain sewage after being treated by the electrolytic denitrification and biological aerated filter system
| Serial number | Basic control items | Denitrification effluent (mg/L) | Filter outlet (mg/L) | Removal Rate (%) |
| 1 | COD | 101.35 | 16.35 | 83.82 |
| 2 | BOD | 2 | - | |
| 3 | SS | 19 | 7 | 63.16 |
| 4 | Animal and vegetable oil | 0.4 | 0.2 | - |
| 5 | Petroleum products | 0.2 | 0.1 | - |
| 6 | Total nitrogen (in N) | 1.93 | 0.94 | 51.03 |
| 7 | Ammonia nitrogen (in N) | 1.12 | 0.81 | 27.68 |
| 8 | Total phosphorus (in terms of P) | 0.41 | 0.33 | 19.51 |
| 9 | Dissolved oxygen | 8.91 | 8.02 | - |
| 10 | Chroma (dilution multiple) | 5 | 1 | 80 |
| 11 | pH | 7～9 | 7～9 | - |
As can be seen from Table 4, the effluent index of a certain sewage treated by the sewage treatment process of the utility model completely meets the III-class water quality standard of the Water environmental quality Standard of Earth's surface (GB 3838-2002).
Example 2
TABLE 5 Water quality index of certain Sewage plant
| Serial number | Basic control items | Measured value (mg/L) |
| 1 | COD | 282.43 |
| 2 | BOD | 125.08 |
| 3 | SS | 155 |
| 4 | Total nitrogen (in N) | 42.22 |
| 5 | Ammonia nitrogen (in N) | 39.66 |
| 6 | Total phosphorus (in terms of P) | 8.1 |
| 7 | Chroma (dilution multiple) | 120 |
| 8 | pH | 7～9 |
| 9 | Dissolved oxygen | 2.3 |
And the water body enters the water body deep purification system. The water body deep purification system comprises pretreatment (100), coagulating sedimentation device treatment (200), an electrolytic denitrification device (300), an aeration biological filter and adsorption dephosphorization. The water body purification system also comprises a sludge treatment device.
The water body sequentially enters a pretreatment device (100), a coagulating sedimentation device (200), an electrolytic denitrification device (300), an aeration biological filter (400) and an adsorption dephosphorization device.
Adding 15% PAC solution into the coagulating sedimentation device (200), wherein the adding amount is 200mg/L, after coagulating reaction under the condition that the rotating speed is 100 revolutions, adding coagulant aid PAM according to 1mg/L, reacting under the condition that the rotating speed is 20 revolutions, and then entering a sedimentation tank for separation, wherein the water quality of coagulating sedimentation effluent is shown in Table 6.
TABLE 6 Water quality index of a certain wastewater after coagulating sedimentation treatment
The water body after coagulating sedimentation enters an electrolytic denitrification device (300) for treatment, the treated water body enters a denitrification reaction tank (330) for denitrification reaction, and the effluent indexes are shown in table 7. The working voltage of the electrolytic denitrification host (310) is 90V, and the current density is 3mA/cm2。
TABLE 7 Water quality index of a certain wastewater after coagulating sedimentation and electrolytic denitrification device treatment
| Serial number | Basic control items | Coagulation water (mg/L) | Denitrification effluent (mg/L) | Removal Rate (%) |
| 1 | COD | 93.11 | 66.21 | 7.62 |
| 2 | BOD | 71.55 | - | - |
| 3 | SS | 16 | 13 | 18.75 |
| 4 | Animal and vegetable oil | 0.5 | 0.1 | 80.00 |
| 5 | Petroleum products | 0.7 | 0.2 | 71.43 |
| 6 | Total nitrogen (in N) | 37.51 | 3.72 | 90.08 |
| 7 | Ammonia nitrogen (in N) | 37.09 | 0.57 | 98.46 |
| 8 | Total phosphorus (in terms of P) | 0.91 | 0.82 | 9.89 |
| 9 | Dissolved oxygen | 2.5 | 8.1 | - |
| 10 | Chroma (dilution multiple) | 30 | 20 | - |
| 11 | pH | 7～9 | 7.3 | - |
The effluent treated by the electrolytic denitrification device (300) is subjected to micro-electrolysis to remove residual sodium hypochlorite and then is subjected to aerobic treatment by the biological aerated filter (400); the quality of the effluent water after the effluent water treated by the electrolytic denitrification device (300) is treated by the biological aerated filter (400) and is adsorbed by the dephosphorization device is shown in Table 8.
TABLE 8 Water quality index of a certain wastewater after electrolytic denitrification, biological aerated filter and phosphorus removal by adsorption
As can be seen from Table 8, the effluent indexes of the sewage after pretreatment, coagulating sedimentation, electrolytic denitrification, micro-electrolysis, biological aerated filter and adsorption dephosphorization completely meet the III-class water quality standard of surface water environmental quality Standard (GB 3838-2002).
Example 3
TABLE 9 Water quality index of certain black and odorous Water body
| Serial number | Basic control items | Measured value (mg/L) |
| 1 | COD | 449.47 |
| 2 | BOD | 219.84 |
| 3 | SS | 360.21 |
| 4 | Total nitrogen (in N) | 43.61 |
| 5 | Ammonia nitrogen (in N) | 27.96 |
| 6 | Total phosphorus (in terms of P) | 8.43 |
| 7 | Color intensity(dilution factor) | 29.59 |
| 8 | pH | 7.5 |
| 9 | Dissolved oxygen | 1.2 |
And the black and odorous water enters the water deep purification system. The water body purification system comprises a pretreatment device (100), a coagulating sedimentation device treatment (200), an electrolytic denitrification device (300), a micro-electrolysis device and a biological aerated filter (400). The water body purification system also comprises a sludge treatment device (500).
The water body enters a pretreatment device (100), a coagulating sedimentation device (200), an electrolytic denitrification device (300), a micro-electrolysis device and an aeration biological filter (400) in sequence.
Adding a ferrous sulfate coagulant into the coagulating sedimentation device, wherein the adding amount is 50mg/L, after the coagulating reaction is carried out under the condition that the rotating speed is 100 revolutions, adding a coagulant aid PAM according to 1mg/L, reacting under the condition that the rotating speed is 20 revolutions, and then feeding the mixture into a sedimentation tank for separation, wherein the water quality of the coagulating sedimentation effluent is shown in the table 10.
TABLE 10 Water quality index after coagulating sedimentation treatment of certain black and odorous water
| Serial number | Basic control items | Certain river channel water intake (mg/L) | Coagulation water (mg/L) | Removal Rate (%) |
| 1 | COD | 449.47 | 195.84 | 56.43 |
| 2 | BOD | 219.84 | 144.44 | 34.30 |
| 3 | SS | 360.21 | 18 | 95.00 |
| 4 | Animal and vegetable oil | 5 | 0.3 | 94.00 |
| 5 | Petroleum products | 2.3 | 0.2 | 91.30 |
| 6 | Total nitrogen (in N) | 43.61 | 29.42 | 32.52 |
| 7 | Ammonia nitrogen (in N) | 27.96 | 25.12 | 10.14 |
| 8 | Total phosphorus (in terms of P) | 8.43 | 0.18 | 97.86 |
| 9 | Dissolved oxygen | 1.20 | 2.1 | - |
| 10 | Chroma (dilution multiple) | 29.59 | 4.46 | 84.92 |
| 11 | pH | 7.5 | 7.6 | - |
The water body after coagulating sedimentation enters an electrolytic denitrification purification device(300) And (3) treating, wherein the treated water body enters a denitrification reaction tank (330) for denitrification reaction, and the effluent indexes are shown in the table 11. The working voltage of the electrolytic denitrification host (310) is 39V, and the current density is 10mA/cm2. When the electrolytic denitrification host works, 4% sodium hypochlorite solution is mixed into the water body, and the adding amount is seven to ten per thousand (volume ratio).
TABLE 11 Water quality index after coagulating sedimentation and electrolytic denitrification of black and odorous water
The effluent treated by the plasma denitrification device (300) flows through the micro-electrolysis and biological aerated filter (400) for deep purification. The quality of the effluent water after the effluent water treated by the electrolytic denitrification device (300) is subjected to micro-electrolysis and advanced purification treatment is shown in a table 12.
TABLE 12 Water quality index after plasma denitrification and biological aerated filter treatment of a black and odorous water body
| Serial number | Basic control items | Denitrification effluent (mg/L) | Filter outlet (mg/L) | Removal Rate (%) |
| 1 | COD | 176.21 | 17.64 | 89.99 |
| 2 | BOD | Not detected out | 2 | - |
| 3 | SS | 13 | 7 | 46.15 |
| 4 | Animal and vegetable oil | 0.1 | Not detected out | - |
| 5 | Petroleum products | 0.2 | Not detected out | - |
| 6 | Total nitrogen (in N) | 3.72 | 0.93 | 75.00 |
| 7 | Ammonia nitrogen (in N) | 0.39 | 0.35 | 10.26 |
| 8 | Total phosphorus (in terms of P) | 0.69 | 0.09 | 87.00 |
| 9 | Dissolved oxygen | 8.1 | 7.9 | -2.47 |
| 10 | Chroma (dilution multiple) | 20 | 1 | 95.00 |
| 11 | pH | 7.3 | 7.4 | - |
As can be seen from Table 12, the effluent indexes of the slightly polluted riverway water body after treatment completely meet the III-class water quality standard of the quality standard of surface water environment (GB 3838-2002).
Example 4
TABLE 13 Water quality index after secondary sedimentation tank sedimentation in certain sewage treatment plant
The sewage treatment plant goes into coagulating sedimentation device (200) coagulation processing back that the water purified system is got into to sewage treatment plant, goes out the water and carries out denitrification through electrolysis denitrogenation host computer (310), and the play water after the electrolysis denitrogenation host computer is handled gets into denitrification reaction pond (330) and carries out the denitrification reaction, and denitrification reaction pond (330) play water is little electrolysis of flowing through water again and is carried out deep purification processing.
When the mixed solution enters a coagulating sedimentation device (200) for coagulation treatment, as the total phosphorus in the water body is only 1mg/L and the concentration is low, a polyaluminum chloride (usually called PAC) solution is added according to 5mg/L, a 5% sodium hydroxide solution is added to adjust the pH to 7-8 (as the pH is 6-7), the mixed solution enters a coagulation tank after coagulation reaction at the rotation speed of 200 revolutions, a coagulant aid PAM is added according to 1mg/L, the mixed solution enters a sedimentation tank for solid-liquid separation after coagulation at the rotation speed of 60 revolutions, and the effluent quality is as shown in Table 14.
TABLE 14 Water quality index of water precipitated in secondary sedimentation tank of certain sewage treatment plant after coagulating sedimentation
| Serial number | Basic control items | Sewage plant influent (mg/L) | Coagulation water (mg/L) | Removal Rate (%) |
| 1 | COD | 57 | 34.2 | 40.00 |
| 2 | BOD | 19 | 13.00 | 31.58 |
| 3 | SS | 23 | 9 | 60.87 |
| 4 | Animal and vegetable oil | 3 | 0.5 | 83.33 |
| 5 | Petroleum products | 1.5 | 0.2 | 86.67 |
| 6 | Total nitrogen (in N) | 23 | 22.07 | 4.04 |
| 7 | Ammonia nitrogen (in N) | 12 | 11.51 | 4.08 |
| 8 | Total phosphorus (in terms of P) | 1.0 | 0.41 | 59.00 |
| 9 | Dissolved oxygen | 4.6 | 4.8 | - |
| 10 | Chroma (dilution multiple) | 40 | 20 | 50 |
| 11 | pH | 7 | 7.2 | - |
The effluent treated by the coagulating sedimentation (200) enters an electrolytic denitrification host (310), the working voltage of the electrolytic denitrification host (310) is 56V, and the current density is 10mA/cm2. The effluent after the electrolytic denitrification (310) enters a denitrification reaction tank (330) for denitrification reaction, and the water quality of the effluent after the denitrification treatment is shown in the table 15.
TABLE 15 Water quality index after treatment of coagulation sedimentation and denitrification device for effluent of certain sewage plant
| Serial number | Basic control items | Coagulation water (mg/L) | Denitrification effluent (mg/L) | Removal Rate (%) |
| 1 | COD | 34.2 | 32.31 | 5.56 |
| 2 | BOD | 15.00 | Not detected out | 100 |
| 3 | SS | 9 | 7 | 22.22 |
| 4 | Animal and vegetable oil | 0.5 | 0 | 100 |
| 5 | Petroleum products | 0.2 | 0 | 100 |
| 6 | Total nitrogen (in N) | 22.07 | 9 | 59.22 |
| 7 | Ammonia nitrogen (in N) | 11.51 | 1.32 | 88.53 |
| 8 | Total phosphorus (in terms of P) | 0.41 | 0.35 | 14.63 |
| 9 | Dissolved oxygen | 4.8 | 7.93 | - |
| 10 | Chroma (dilution multiple) | 20 | 20 | 0 |
| 11 | pH | 7.2 | 7.1 | - |
The effluent treated by the electrolytic denitrification device (300) is subjected to micro-electrolysis for deep purification.
The quality of the effluent water after the effluent water treated by the electrolytic denitrification device (300) is subjected to micro-electrolysis and advanced purification treatment is shown in a table 16.
TABLE 16 Water quality index of effluent from certain sewage plant after electrolytic denitrification and micro-electrolysis treatment
As can be seen from Table 16, the effluent indexes of the treated effluent of the sewage treatment plant completely meet the IV-class water quality standard of the quality Standard of Water surface Environment (GB 3838-2002).
Example 5
TABLE 17 Water quality index of a slightly polluted Water body
| Serial number | Basic control items | Measurement (mg +)L) |
| 1 | COD | 89.56 |
| 2 | BOD | 29.88 |
| 3 | SS | 69.67 |
| 4 | Total nitrogen (in N) | 43.61 |
| 5 | Ammonia nitrogen (in N) | 27.96 |
| 6 | Total phosphorus (in terms of P) | 5.44 |
| 7 | Chroma (dilution multiple) | 29.59 |
| 8 | pH | 7.5 |
| 9 | Dissolved oxygen | 1.2 |
And the micro-polluted water enters the water deep purification system. The water body purification system comprises a pretreatment device (100), a coagulating sedimentation device treatment device (200), an electrolytic denitrification device (300) and a micro-electrolysis device. The water body purification system also comprises a sludge treatment device (500).
The water body enters a pretreatment device (100), a coagulating sedimentation device for treatment (200), an electrolytic denitrification device (300) and a micro-electrolysis device in sequence.
Adding 10% of polyaluminium solution into the coagulating sedimentation device, wherein the adding amount is 40mg/L, after coagulating reaction at the rotating speed of 100 revolutions, adding 1mg/L of PAM (Polyacrylamide) as a coagulant aid, reacting at the rotating speed of 20 revolutions, and then separating in a sedimentation tank, wherein the water quality of coagulating sedimentation effluent is shown in Table 18.
TABLE 18 Water quality index after coagulating sedimentation treatment of certain black and odorous water
The water body after coagulating sedimentation enters an electrolytic denitrification purification device (300) for treatment, the treated water body enters a denitrification reaction tank (330) for denitrification reaction, and the effluent indexes are shown in the table 19. The working voltage of the electrolytic denitrification host (310) is 39V, and the current density is 10mA/cm2. When the electrolytic denitrification host works, 4% sodium hypochlorite solution is mixed into the water body, and the adding amount is seven to ten per thousand (volume ratio).
TABLE 19 Water quality index after coagulating sedimentation and electrolytic denitrogenation of black and odorous water
| Serial number | Basic control items | Coagulation water (mg/L) | Denitrification effluent (mg/L) | Removal Rate (%) |
| 1 | COD | 25.81 | 16.21 | 37.19 |
| 2 | BOD | 14.45 | Not detected out | |
| 3 | SS | 13 | 11 | 15.38 |
| 4 | Animal and vegetable oil | 0.5 | 0.1 | 80.00 |
| 5 | Petroleum products | 0.5 | 0.2 | 60.00 |
| 6 | Total nitrogen (in N) | 29.37 | 3.72 | 87.33 |
| 7 | Ammonia nitrogen (in N) | 21.09 | 0.39 | 98.15 |
| 8 | Total phosphorus (in terms of P) | 0.81 | 0.69 | 14.81 |
| 9 | Dissolved oxygen | 2.5 | 8.1 | - |
| 10 | Chroma (dilution multiple) | 20 | 20 | - |
| 11 | pH | 7.6 | 7.3 | - |
The effluent treated by the plasma denitrification device (300) is subjected to micro-electrolysis for deep purification. The quality of the effluent water after the effluent water treated by the electrolytic denitrification device (300) is subjected to micro-electrolysis and advanced purification treatment is shown in a table 20.
TABLE 20 Water quality index after plasma denitrification and micro-electrolysis treatment of certain black and odorous water body
As can be seen from Table 20, the effluent indexes of the slightly polluted riverway water body after treatment completely meet the III-class water quality standard of the quality standard of surface water environment (GB 3838-2002).
While the foregoing description shows and describes the preferred embodiments of the present invention, it is to be understood that the invention is not limited to the forms disclosed herein, but is not intended to be exhaustive or to exclude other embodiments and may be used in various other combinations, modifications, and environments and is capable of changes within the scope of the inventive concept as expressed herein, commensurate with the above teachings, or the skill or knowledge of the relevant art. But that modifications and variations may be effected by those skilled in the art without departing from the spirit and scope of the invention, which is to be limited only by the claims appended hereto.
Claims (10)
1. A high-efficient deep purification system of compact water body which characterized in that includes:
(1) the pretreatment device (100) comprises a coarse grating, a fine and coarse grating, an aeration grit chamber and a lift pump which are sequentially communicated; the water inlet of the coarse grating is communicated with a water inlet pipeline of a polluted water body to be treated, the water outlet of the coarse grating is communicated with the water inlet of the fine and coarse grating, the water outlet of the fine and coarse grating is communicated with the water inlet of the aeration grit chamber, and the water outlet of the aeration grit chamber is communicated with the water inlet of the lift pump;
(2) the coagulating sedimentation device (200) comprises a coagulating basin, a coagulation aiding basin, a sedimentation basin, an intermediate water basin and a sludge collecting basin which are sequentially communicated; the coagulation tank and the coagulation aiding tank are respectively provided with a water inlet, a water outlet and a medicine adding port; the sedimentation tank is provided with a water outlet and a sludge outlet; the water inlet of the coagulation tank is communicated with the water outlet of a lift pump of the pretreatment device (100), the water outlet of the coagulation tank is communicated with the water inlet of the coagulation aiding tank, and the water outlet of the coagulation aiding tank is communicated with the water inlet of the sedimentation tank; the water outlet of the sedimentation tank is communicated with the water inlet of the intermediate water tank, the water outlet of the intermediate water tank is communicated with the water inlet of an electrolytic denitrification main machine (310) of the electrolytic denitrification device (300), and a lift pump (311) is further arranged in a connecting pipeline between the water outlet and the electrolytic denitrification main machine (310); the inlet of the coagulation aiding tank and the inlet of the sludge collecting tank are communicated with the sludge outlet of the sedimentation tank through a sludge pump and a three-way valve, and the outlet of the sludge collecting tank is communicated with the inlet of the sludge treatment device (500);
(3) the electrolytic denitrification device (300) comprises an electrolytic denitrification host (310), a direct-current power supply (320) and a denitrification reaction tank (330), wherein a water inlet of the electrolytic denitrification host (310) is used for allowing clear water after coagulating sedimentation to enter, and a water outlet of the electrolytic denitrification host (310) is respectively communicated with a water inlet (331) of the denitrification reaction tank and a water inlet of the coagulation tank through a tee joint (315);
(4) the biological aerated filter (400) consists of a biological filter body, an aeration pipe, a bracket, a filter material supporting layer, a filter material, a water collecting tank, an aeration fan, a backwashing water pipe, a sewage outlet, a sludge outlet and a disinfection tank; the water inlet of the biological aerated filter (400) is communicated with the water outlet of a denitrification reaction tank (330) of the electrolytic denitrification device (300) system, and the sewage outlet of the biological aerated filter (400) is communicated with the water inlet of the disinfection tank;
(5) the sludge treatment device (500) comprises a sludge pump, a gravity concentration tank, a physicochemical conditioning tank and a dehydrator, wherein the inlet of the sludge pump is communicated with the sludge outlet of the coagulation sedimentation tank and the sludge outlet of the biological filter tank body; the outlet of the physical and chemical conditioning pool is communicated with the sludge inlet of the dehydrator, the sludge blocks of the dehydrator are collected in the sludge collecting terrace, and the sewage of the dehydrator is communicated with the water inlet of the biological filter pool body.
2. The compact water body high-efficiency deep purification system as claimed in claim 1, wherein the coagulating sedimentation device (200) is one of a high-efficiency sedimentation device, a magnetic coagulation device and a supermagnetic coagulating sedimentation device.
3. The compact water body efficient deep purification system according to claim 1, wherein the coagulation tank of the coagulation sedimentation device (200) further comprises a coagulant dosing device and a stirrer, and the coagulant dosing device stores 5-10% of ferrous sulfate or 10-15% of polyaluminium chloride solution by mass; the coagulant aid tank further comprises a coagulant aid dosing device and a stirrer, and a PAM solution with the mass ratio of 1-2 per mill is stored in the coagulant aid dosing device.
4. The compact type efficient deep water purification system of claim 1, wherein the electrolytic denitrification device further comprises an electrolyte adding device, the electrolyte adding device is composed of an electrolyte solution preparation tank (341), an electrolyte solution storage tank (342), an electrolyte solution delivery pump (343) and an electrolyte solution flowmeter (344), and the electrolyte adding device is used for adding 3-12% of sodium hypochlorite solution or 2-6% of sodium chloride solution into the electrolytic denitrification device.
5. The compact water body high-efficiency deep purification system as claimed in claim 1, wherein the electrolytic denitrification device further comprises a main pickling system which is composed of a pickling solution preparation tank and a pickling solution delivery pump.
6. The compact water body efficient deep purification system according to claim 1, wherein a micro-electrolysis device is further arranged in front of the biological aerated filter, and the micro-electrolysis device is composed of a tank body (610), a support frame (620), a support layer (630), an iron-carbon layer (640) and a filter material layer (650).
7. The compact water body efficient deep purification system according to claim 1, wherein a deep phosphorus removal device is further arranged behind the biological aerated filter, and the deep phosphorus removal device is one of an adsorption phosphorus removal device and a chemical precipitation phosphorus removal device.
8. The compact water body high-efficiency deep purification system as claimed in claim 7, wherein the adsorption phosphorus removal device comprises at least one adsorption tower (710), a desorption regeneration system and a phosphorus precipitation recovery system; the adsorption tower (710) is composed of a water inlet (711), a water inlet four-way (712), a water inlet valve (713), an eluent inlet valve (714), an adsorption filler (716) of a lower support plate (715), an upper support plate (717), a water outlet (718) and a water outlet four-way (719); the desorption regeneration system is composed of a desorption regeneration liquid storage tank (721), a regeneration liquid delivery pump (722), a regeneration liquid inlet valve (723), an adsorption tower (710), a clear water tank (724), a clear water pump (725), a clear water valve (726), an eluent water outlet valve (727) and an eluent storage tank (728); a desorption regeneration liquid storage tank (721) is connected to the adsorption tower (710) through a regeneration liquid transfer pump (722) and a water inlet valve (713) and a water inlet cross joint (712); the clean water tank (724) is connected with the water outlet four-way joint (719) and the adsorption tower (710) through a clean water pump (725) and a clean water valve (726); the eluent storage tank (728) is connected with the adsorption tower (710) through an eluent outlet valve (727) and an outlet four-way valve (719); the phosphorus precipitation recovery system consists of a desorption liquid delivery pump (731), a desorption liquid inlet valve (732), a precipitation reaction tank (733), a stirrer (734), a precipitant storage tank (735), a metering pump (736), a phosphorus precipitation recovery tank (737), a concentration tank (739) and a recovery pump (738); the inlet of the desorption liquid delivery pump (731) is connected with the water outlet of the eluent storage tank (728), the water outlet of the desorption liquid delivery pump (731) is connected with the inlet of a desorption liquid inlet valve (732), and the outlet of the desorption liquid inlet valve (732) is connected with a phosphorus precipitation reaction tank (733); the sedimentation reaction tank (733) is also provided with a stirrer (734), a precipitator storage tank (735) and a metering pump (736), the water outlet of the sedimentation reaction tank (733) is connected with a phosphorus sedimentation recovery tank (737), the water outlet of the phosphorus sedimentation recovery tank (737) is connected with the inlet of a concentration tank (739), and the outlet of the phosphorus sedimentation recovery tank (737) is connected with a desorption regeneration liquid storage tank (721) through a recovery pump (738) and the concentration tank (739); the precipitant storage tank (735) stores saturated solution of calcium hydroxide.
9. The compact water body efficient deep purification system according to claim 1, wherein the inlet of the sludge pump is respectively communicated with the sludge outlets of the coagulating sedimentation device (200) and the biological aerated filter (400), the outlet of the sludge pump is communicated with the inlet of the gravity concentration tank, the gravity concentration tank comprises an upper layer, a middle layer and a lower layer from top to bottom, the water outlet of the upper layer is used for being communicated with the water inlet of the aerobic tank, the outlet of the lower layer is communicated with the inlet of the dehydrator, and the middle layer, the physical and chemical conditioning tank and the dehydrator are sequentially communicated in sequence; and a stirrer is also arranged in the gravity concentration tank.
10. The compact water body efficient deep purification system of claim 1, wherein the compact water body efficient deep purification system is one of underground type, semi-underground type or overground type.
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