CN213716938U - Hydrogen production and storage system - Google Patents

Hydrogen production and storage system Download PDF

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Publication number
CN213716938U
CN213716938U CN202022520203.7U CN202022520203U CN213716938U CN 213716938 U CN213716938 U CN 213716938U CN 202022520203 U CN202022520203 U CN 202022520203U CN 213716938 U CN213716938 U CN 213716938U
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module
hydrogen
water
electromagnetic valve
hydrogen production
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CN202022520203.7U
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顾志伟
宋珊菲
徐拥华
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Quzhou Guangming Electric Power Investment Group Co ltd Futeng Technology Branch
Quzhou Power Supply Co of State Grid Zhejiang Electric Power Co Ltd
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Quzhou Guangming Electric Power Investment Group Co ltd Futeng Technology Branch
Quzhou Power Supply Co of State Grid Zhejiang Electric Power Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The invention discloses a hydrogen production and storage system, which comprises a water electrolysis hydrogen production machine, wherein the output end of the water electrolysis hydrogen production machine is connected with a hydrogen discharge module and a water-vapor separation module through electromagnetic valves, the output end of the water-vapor separation module is connected with a dryer, the electromagnetic valve, a PIC module, a FI module, an M module, the hydrogen discharge module, the electromagnetic valve and a PI module are sequentially connected behind the output end of the dryer, and the PI module is connected with three metal oxide gas storage bottles through three parallel three-way valves; the three metal oxide gas storage bottle output ends are sequentially connected with a three-way valve, a PI module, an electromagnetic valve, a PIC module, an FI module, a hydrogen discharge module and an M module; the front of the input end of the water-vapor separation module is sequentially connected with an electromagnetic valve, an M module, an FI module, an FIC module, a PI module, a water pump, a PI module, an electromagnetic valve and a water replenishing tank. The invention automatically adjusts the output flow and the hydrogen supply flow of the hydrogen through the detection of various parameters, and has high control precision, good reliability and good hydrogen production and storage effects.

Description

Hydrogen production and storage system
Technical Field
The invention relates to the technical field of energy conservation and environmental protection, in particular to a hydrogen production and storage system.
Background
The 21 st century is the century of energy and environmental protection. With the rapid development of the century economy, the consumption of fossil energy is increasing year by year, while the storage is decreasing year by year, and due to the low efficiency of fossil energy, a series of environmental pollution problems are caused, and the normal life of human beings is seriously threatened. Therefore, saving energy, developing new energy, increasing energy utilization rate and reducing pollution caused by energy use become important problems to be solved urgently. The fuel cell is in the sight of people under the background, and the fuel cell uses the novel energy of hydrogen energy as fuel, does not pass through a low-pollution and high-efficiency power generation device in a combustion process, and is known as a fourth major power generation mode after thermal power generation, hydraulic power generation and atomic power generation. However, the hydrogen production and storage link of the hydrogen storage fuel cell power generation technology in the prior art has poor control precision, poor reliability and poor hydrogen production and storage effect, and is difficult to meet the production and living requirements.
Disclosure of Invention
In view of the above-mentioned drawbacks of the prior art, the technical problem to be solved by the present invention is to provide a hydrogen production and storage system to solve the deficiencies of the prior art.
In order to achieve the above object, the present invention provides a hydrogen production and storage system, which is characterized in that: the device comprises a water electrolysis hydrogen production machine, wherein the output end of the water electrolysis hydrogen production machine is connected with a hydrogen discharge module and a water-vapor separation module through electromagnetic valves, the output end of the water-vapor separation module is connected with a dryer, the rear end of the dryer is sequentially connected with an electromagnetic valve, a PIC module, an FI module, an M module, a hydrogen discharge module, an electromagnetic valve and a PI module, and the PI module is connected with three metal oxide gas storage bottles through three parallel three-way valves; the three metal oxide gas storage bottle output ends are sequentially connected with a three-way valve, a PI module, an electromagnetic valve, a PIC module, an FI module, a hydrogen discharge module and an M module; the water-vapor separation module is characterized in that an electromagnetic valve, an M module, an FI module, an FIC module, a PI module, a water pump, a PI module, an electromagnetic valve and a water replenishing tank are sequentially connected in front of the input end of the water-vapor separation module.
The hydrogen production and storage system is characterized in that: the water replenishing tank is also connected with the TI module and the LC module.
The hydrogen production and storage system is characterized in that: the dryer is also connected to a HI module.
The invention has the beneficial effects that:
the hydrogen production and storage system comprises a water electrolysis hydrogen production machine and a metal oxide gas storage cylinder, and mainly comprises a hydrogen production machine outlet hydrogen pressure detection part, a flow detection part, an electrolyzed water pump front/pump rear pressure detection part, a water replenishing tank liquid level detection/control part, a hydrogen storage tank temperature detection/control part, a hydrogen charging/releasing pressure detection/control part, a hydrogen charging/releasing flow detection part, a cooling water inlet/outlet temperature detection part, a cooling water flow detection/control part, a hydrogen storage tank residual quantity detection part and the like. The water electrolysis hydrogen production machine can automatically adjust the output flow of hydrogen according to the change of input power; the metal oxide gas storage cylinder automatically adjusts the hydrogen supply flow according to the change of the load. High control precision, good reliability and good hydrogen production and storage effects.
The conception, the specific structure and the technical effects of the present invention will be further described with reference to the accompanying drawings to fully understand the objects, the features and the effects of the present invention.
Drawings
Fig. 1 is a schematic view of the overall structure of the present invention.
Detailed Description
As shown in fig. 1, a hydrogen production and storage system is characterized in that: the device comprises a water electrolysis hydrogen production machine, wherein the output end of the water electrolysis hydrogen production machine is connected with a hydrogen discharge module and a water-vapor separation module through electromagnetic valves, the output end of the water-vapor separation module is connected with a dryer, the rear end of the dryer is sequentially connected with an electromagnetic valve, a PIC module, an FI module, an M module, a hydrogen discharge module, an electromagnetic valve and a PI module, and the PI module is connected with three metal oxide gas storage bottles through three parallel three-way valves; the three metal oxide gas storage bottle output ends are sequentially connected with a three-way valve, a PI module, an electromagnetic valve, a PIC module, an FI module, a hydrogen discharge module and an M module; the water-vapor separation module is characterized in that an electromagnetic valve, an M module, an FI module, an FIC module, a PI module, a water pump, a PI module, an electromagnetic valve and a water replenishing tank are sequentially connected in front of the input end of the water-vapor separation module.
In this embodiment, the water replenishing tank is further connected with the TI module and the LC module.
In this embodiment, the dryer is further connected to a HI module.
Wherein, the definitions of the electric modules are as follows:
the PI module represents a pressure indicating instrument;
the PIC module represents a pressure indication control instrument;
the TI module represents a temperature indicating instrument;
the HI module represents a humidity indicator;
the LC module represents a liquid level control instrument;
the FI module represents a flow indicating instrument;
the TC module represents a temperature control instrument;
the LI module represents a liquid level display instrument;
the FIC module represents a flow indicating control instrument.
The hydrogen production and storage system mainly comprises a hydrogen production machine outlet hydrogen pressure detection part, a flow detection part, an electrolytic water pump front/pump rear pressure detection part, a water replenishing tank liquid level detection/control part, a hydrogen storage tank temperature detection/control part, a hydrogen charging/releasing pressure detection/control part, a hydrogen charging/releasing flow detection part, a cooling water inlet/outlet temperature detection part, a cooling water flow detection/control part, a hydrogen storage tank residual quantity detection part and the like. The method comprises the following specific steps:
firstly, detecting the pressure of hydrogen at the outlet of the hydrogen production machine:
considering that the output pressure of the hydrogen production machine is adjustable, and the maximum pressure can reach 2MPa, the pressure range of an instrument selected for detecting the outlet pressure of the hydrogen production machine is satisfied as follows: 0-2MPa, and the use temperature range meets the requirements of the hydrogen production machine during normal operation: -20 to 80 ℃.
Hydrogen flow detection at the outlet of the hydrogen production machine:
the outlet flow of hydrogen of the hydrogen production machine can change along with the difference of input power, when the hydrogen production machine works at the maximum input power, the output flow of hydrogen can reach 1000NL/h, and the measuring range of a flow sensor is selected as follows: 0-1000 NL/h.
Thirdly, detecting the pressure before/after the hydrogen production and electrolysis water pump:
because the estimated water tank size is 1 x 1m, the pressure before the electrolysis water pump is very small, the maximum pressure of the water before the pump is calculated to be 1kPa, the pressure after the pump is improved according to the selected small water pump, and the maximum pressure after the pump is 15kPa according to 15 times calculation. The pressure range of the pre-pump meter is therefore chosen: 0-1.5kPa, gauge pressure range installed after pump: 0 to 15 kPa.
Fourthly, detecting/controlling the liquid level of the water replenishing tank:
the size design of moisturizing case is 1 x 1 m's water tank, can see that the change of liquid level is between 0-1m, but requires its minimum liquid level to detect 0.05 m's precision, accurate detection when just so can realizing the low water level, timely moisturizing, so the level sensor's of chooseing for use scope: 0-1m, and the precision requirement reaches 1%.
Detecting the temperature of the hydrogen storage tank:
the hydrogen release speed of the metal hydride hydrogen storage tank is influenced by temperature, and researches show that the temperature of the hydrogen storage tank corresponding to the maximum hydrogen release speed is about 60 ℃, and the working temperature of the hydrogen storage tank is generally in the range of-20-75 ℃, so that a sensor with the measuring range of-20-80 ℃ and the accuracy of 0.5 percent needs to be selected.
Sixthly, detecting the hydrogen filling/releasing pressure:
the maximum hydrogen charging pressure of the hydrogen storage tank can reach 2MPa, so the range of a pressure gauge on the hydrogen charging pressure side is 0-2MPa, and the precision requirement is 5%. The maximum hydrogen release pressure is 0.3MPa, the regulation can be realized, the range of the selected pressure gauge is 0-0.3MPa, and the precision requirement is 3%.
Seventhly, detecting the flow of charged hydrogen/released hydrogen:
the design requirement of the hydrogen release flow of the hydrogen storage tank reaches 30NL/min, the range of the selected flowmeter is 0-50NL/min, and the precision is 1%. The maximum hydrogen production flow of the hydrogen production machine is 1000NL/h, can be converted into 16.7NL/min, and the selected range is 0-18 NL/min.
Detecting the temperature of the cooling water inlet/outlet:
the metal hydride hydrogen storage tank needs to realize temperature control, so the temperature of the inlet and the outlet of the cooling water needs to be detected, the temperature range of the hydrogen storage tank is-20-80 ℃ when the hydrogen storage tank works, the range of the selected instrument is 0-80 ℃, and the instrument can display the temperature in real time with the precision of 1%.
Ninthly, cooling water flow detection/control:
the size of the cooling water flow is the key for controlling the temperature of the hydrogen storage tank, the working of the hydrogen storage tank is the temperature change range, the change range of the cooling water flow is not too large, the selection range is 0-0.04L/min, and the precision is 2%.
Detecting the residual quantity of the hydrogen storage tank at the red (R):
because there is the minimum redundant quantity in the metal hydride hydrogen storage tank, so should carry out real-time detection to the hydrogen surplus in the hydrogen storage tank, the volume scope of detection table is 0 ~ 100% to adapt to high pressure high temperature operational environment.
The system provides reference for system control through detection of various control parameters, and reasonably controls the water electrolysis hydrogen production machine and the metal oxide gas storage cylinder, the water electrolysis hydrogen production machine can automatically adjust the output flow of hydrogen according to the change of input power, and the metal oxide gas storage cylinder automatically adjusts the hydrogen supply flow according to the change of load. High control precision, good reliability and good hydrogen production and storage effects.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.

Claims (3)

1. A hydrogen production and storage system, comprising: the device comprises a water electrolysis hydrogen production machine, wherein the output end of the water electrolysis hydrogen production machine is connected with a hydrogen discharge module and a water-vapor separation module through electromagnetic valves, the output end of the water-vapor separation module is connected with a dryer, the rear end of the dryer is sequentially connected with an electromagnetic valve, a PIC module, an FI module, an M module, a hydrogen discharge module, an electromagnetic valve and a PI module, and the PI module is connected with three metal oxide gas storage bottles through three parallel three-way valves; the three metal oxide gas storage bottle output ends are sequentially connected with a three-way valve, a PI module, an electromagnetic valve, a PIC module, an FI module, a hydrogen discharge module and an M module; the water-vapor separation module is characterized in that an electromagnetic valve, an M module, an FI module, an FIC module, a PI module, a water pump, a PI module, an electromagnetic valve and a water replenishing tank are sequentially connected in front of the input end of the water-vapor separation module.
2. A system for producing hydrogen and storing hydrogen as claimed in claim 1, wherein: the water replenishing tank is also connected with the TI module and the LC module.
3. A system for producing hydrogen and storing hydrogen as claimed in claim 1, wherein: the dryer is also connected to a HI module.
CN202022520203.7U 2020-11-04 2020-11-04 Hydrogen production and storage system Active CN213716938U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114779863A (en) * 2022-06-14 2022-07-22 山东智奇环境技术有限公司 Automatic change hydrogen manufacturing intelligence control system

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114779863A (en) * 2022-06-14 2022-07-22 山东智奇环境技术有限公司 Automatic change hydrogen manufacturing intelligence control system
CN114779863B (en) * 2022-06-14 2022-09-13 山东智奇环境技术有限公司 Automatic hydrogen production intelligent control system

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