CN213434354U - Reformer of alcohol-water reforming hydrogen production equipment - Google Patents

Reformer of alcohol-water reforming hydrogen production equipment Download PDF

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Publication number
CN213434354U
CN213434354U CN202021534937.4U CN202021534937U CN213434354U CN 213434354 U CN213434354 U CN 213434354U CN 202021534937 U CN202021534937 U CN 202021534937U CN 213434354 U CN213434354 U CN 213434354U
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China
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pipeline
heat
alcohol
reformer
reforming
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Expired - Fee Related
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CN202021534937.4U
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Chinese (zh)
Inventor
王建明
卢进
孙营
王琛
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Pubei Gaomai New Energy Technology Co ltd
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Pubei Gaomai New Energy Technology Co ltd
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Abstract

The utility model provides a reformer of mellow wine water reforming hydrogen manufacturing equipment, include: a reforming reaction assembly including an inner housing, a catalyst, and a heat transfer member between the inner housing and the catalyst; the inner shell is provided with a reaction channel, the reaction channel comprises an input end and an output end, and the catalyst is arranged in the reaction channel; the palladium membrane assembly is communicated with the output end and is used for purifying hydrogen from hydrogen-rich gas; the reforming reaction assembly and the palladium membrane assembly are contained in the reforming cavity; the heat conduction member has a thermal conductivity greater than that of the inner case. Compared with the prior art, the reformer of the alcohol-water reforming hydrogen production equipment of the utility model is made by the heat-conducting piece, and the temperature in the reaction channel is distributed evenly.

Description

Reformer of alcohol-water reforming hydrogen production equipment
Technical Field
The utility model relates to an alcohol-water reforming hydrogen production technical field especially relates to a reformer of alcohol-water reforming hydrogen production equipment.
Background
Hydrogen energy is the most promising clean energy source. When coal, petroleum and hydrogen gas of the same weight are combusted, the energy generated by the hydrogen gas is the largest. In addition, the product of hydrogen combustion is water, and no pollutant such as ash, waste gas and the like is generated, so that the hydrogen combustion system is an environment-friendly energy source. The products generated by burning coal and petroleum mainly comprise carbon dioxide and sulfur dioxide, which can respectively generate greenhouse effect and acid rain, and pollute the environment. Secondly, the reserves of coal and oil are limited and belong to non-renewable resources. The global distribution of hydrogen is relatively extensive, and the majority of hydrogen is in the form of compound water. 70% of the earth's surface is covered by water, and the water storage capacity is large, so hydrogen is an inexhaustible energy source. Hydrogen would also be a relatively inexpensive source of energy if it could be produced by a suitable process.
At present, most of hydrogen is prepared from petroleum, coal and natural gas, and the technical scheme needs to consume a large amount of scarce fossil fuels. The method of electrolyzing water to prepare hydrogen needs to consume a large amount of electric power, and has low benefit. In order to solve this problem, the skilled person has developed a technology for producing hydrogen by reforming methanol-water, that is: the hydrogen and carbon dioxide are prepared by reforming methanol and steam, and then are separated by a palladium membrane. The temperature in a reaction cavity for the alcohol-water reforming reaction in the existing alcohol-water reforming hydrogen production equipment is not uniformly distributed, so that the exertion of the catalyst effect is influenced, and the catalytic effect is reduced.
In view of the above problems, there is a need to provide a reformer of an alcohol-water reforming hydrogen production apparatus to solve the above problems.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a reformer of mellow wine water reforming hydrogen manufacturing equipment, this reformer of mellow wine water reforming hydrogen manufacturing equipment make the temperature distribution in the reaction channel even through the heat-conducting piece that the heat conductivity is high, the heat transfer rate is fast.
In order to achieve the above object, the present invention provides a reformer of an alcohol-water reforming hydrogen production apparatus, comprising: a reforming reaction assembly including an inner shell and a catalyst; the inner shell is provided with a reaction channel, and the reaction channel comprises an input end for inputting alcohol water and an output end for outputting hydrogen-rich gas; the catalyst is arranged in the reaction channel and is positioned between the input end and the output end; the palladium membrane assembly is communicated with the output end and is used for purifying hydrogen from the hydrogen-rich gas; the reforming reaction assembly and the palladium membrane assembly are contained in the reforming cavity; the reforming reaction assembly further includes a heat transfer member disposed between the inner housing and the catalyst, and a thermal conductivity of the heat transfer member is greater than a thermal conductivity of the inner housing.
As a further improvement of the present invention, the heat-conducting member coats the catalyst so that the catalyst is out of contact with the inner wall of the reaction channel.
As a further improvement of the present invention, the inner housing includes a first pipe and a second pipe sleeved outside the first pipe; the reaction channel is formed by the first pipeline and the second pipeline together.
As a further improvement of the present invention, the heat conducting member includes a first heat conducting pipe and a second heat conducting pipe sleeved outside the first heat conducting pipe, and the first heat conducting pipe and the second heat conducting pipe are located between the first pipe and the second pipe; the inner wall of the first heat conduction pipeline is closely attached to the outer wall of the first pipeline, and the outer wall of the second heat conduction pipeline is closely attached to the inner wall of the second pipeline.
As a further improvement of the present invention, the first pipe and the second pipe are made of stainless steel, and the first heat conducting pipe and the second heat conducting pipe are made of copper.
As a further improvement of the utility model, the thickness of the pipe wall of the first pipeline and the second pipeline is between 2.5mm and 3 mm; the thickness of the pipe wall of the first heat-conducting pipeline and the second heat-conducting pipeline is not less than 5 mm.
As a further improvement of the utility model, the cross section of the reaction channel is annular, and the annular width is between 12mm and 16 mm.
As a further improvement of the present invention, the reaction channel comprises a preheating channel close to the input end and a catalytic channel close to the output end.
As a further improvement of the utility model, a heat preservation layer is further arranged on the inner wall of the reforming cavity to prevent heat loss in the reforming cavity.
As a further improvement of the present invention, the palladium membrane module is disposed in the first pipe.
The utility model has the advantages that: the reformer of the alcohol-water reforming hydrogen production equipment of the utility model makes the temperature distribution in the reaction channel even through the heat conducting piece with high heat conductivity and high heat transfer speed.
Drawings
FIG. 1 is a schematic cross-sectional view of a reformer of an apparatus for producing hydrogen by reforming alcohol and water according to the present invention.
Fig. 2 is a sectional view of a reforming reaction assembly.
Fig. 3 is a sectional view of the inner case and the heat conductive member.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention clearer, the present invention will be described in detail with reference to the accompanying drawings and specific embodiments.
Referring to fig. 1, the present invention discloses a reformer 100 of an alcohol-water reforming hydrogen production apparatus, which includes a reforming reaction assembly 10 for reacting alcohol-water, a palladium membrane assembly 20 communicated with the reforming reaction assembly 10, an outer shell 30 for accommodating the reforming reaction assembly 10 and the palladium membrane assembly 20, a feeding pipe 40 communicated with the reforming reaction assembly 10, an air outlet pipe 50 communicated with the palladium membrane assembly 20, and a burner 60 communicated with the outer shell 30. The alcohol water may be methanol water, ethanol water, etc.
Referring to fig. 1, 2 and 3, the reforming reaction assembly 10 includes an inner housing 11, a heat conducting member 12 closely attached to the inner housing 11, and a catalyst 13 disposed in the inner housing 11. The inner shell 11 is provided with a reaction channel 110 penetrating through the inner shell 11, and the reaction channel 110 comprises an input end 111 for inputting alcohol water and an output end 112 for outputting hydrogen-rich gas generated after the alcohol water reforming reaction. The heat transfer member 12 is closely attached to the inner wall of the reaction channel 110 and is positioned between the inner housing 11 and the catalyst 13. With this arrangement, the heat-conducting member 12 can sufficiently and efficiently absorb the heat transferred from the inner housing 11. The heat conductive member 12 has a thermal conductivity greater than that of the inner case 11. Since the heat-conducting member 12 has high thermal conductivity and high heat transfer speed, the temperature distribution in the reaction channel 110 is uniform. The catalyst 13 is disposed in the reaction channel 110 and between the input end 111 and the output end 112, so as to increase the reaction rate of alcohol and water. The outer surface of the catalyst 13 is at least partially closely attached to the heat conduction member 12, so that the catalyst 13 is efficiently heated by the heat conduction member 12. Preferably, the heat-conductive member 12 wraps the catalyst 13 such that the catalyst 13 is out of contact with the inner wall of the reaction channel 110. So arranged, the catalyst 13 is heated most efficiently.
Referring to fig. 2 and fig. 3, the inner housing 11 includes a first pipe 113 and a second pipe 114 sleeved outside the first pipe 113, and the first pipe 113 and the second pipe 114 together form the reaction channel 110. The thickness of the pipe wall of the first pipeline 113 and the second pipeline 114 is between 2.5mm and 3 mm. The cross section of the reaction channel 110 is annular, and the annular width is between 12mm and 16 mm. In the present embodiment, the inner housing 11 is made of stainless steel, so that the inner housing 11 has high strength and good corrosion resistance. The heat conducting member 12 includes a first heat conducting pipe 121 and a second heat conducting pipe 122 sleeved outside the first heat conducting pipe 121, and the pipe wall thicknesses of the first heat conducting pipe 121 and the second heat conducting pipe 122 are not less than 5 mm. The first and second heat-conducting pipes 121 and 122 are located between the first and second pipes 113 and 114. The inner wall of the first heat conduction pipe 121 is closely attached to the outer wall of the first pipe 113, and the outer wall of the second heat conduction pipe 122 is closely attached to the inner wall of the second pipe 114. With this arrangement, the first and second heat transfer pipes 121 and 122 can efficiently extract heat from the first and second pipes 113 and 114. In the present embodiment, the heat conducting member 12 is made of copper, but in other embodiments, the heat conducting member 12 may also be made of silver, aluminum, graphite, or other materials. Since the thermal conductivity of the copper, silver, aluminum, graphite, etc. is higher than that of the stainless steel, the catalyst 13 can be heated efficiently by the copper, silver, aluminum, graphite, etc.
Preferably, the reaction channel 110 may further include a preheating channel 115 near the input end 111 and a catalytic channel 116 near the output end 112. The preheating passage 115 is used for preheating the alcohol water. The catalytic channel 116 is used to fill the catalyst 13.
Referring to fig. 1, the palladium membrane module 20 is disposed in the first pipeline 113 for purifying hydrogen from the hydrogen-rich gas, and includes an air inlet 21 communicated with the output end 112, an air outlet 22 for outputting the purified hydrogen, and a tail gas outlet 23 for discharging tail gas. The tail gas refers to the non-hydrogen-rich gas left after the hydrogen-rich gas is purified. The outer shell 30 is provided with a reforming cavity 31 and an insulating layer 32 attached to the inner wall of the reforming cavity 31. The reforming reaction assembly 10 and the palladium membrane assembly 20 are accommodated in the reforming chamber 31. The insulating layer 32 is used to prevent heat loss in the reforming chamber. A heating channel 33 is disposed between the reforming reaction assembly 10 and the outer shell 30 or between the reforming reaction assembly 10 and the palladium membrane assembly 20, and is used for heating the reforming reaction assembly 10, the palladium membrane assembly 20, and the outer shell 30. The feeding pipe 40 is communicated with the input end 111 for inputting alcohol water into the reforming reaction assembly 10. The gas outlet pipeline 50 is communicated with the gas outlet 22 and is used for outputting purified hydrogen. The gas outlet pipe 50 is at least partially sleeved in the feeding pipe 40 so as to preheat the alcohol water through the purified hydrogen, and the purified hydrogen is cooled by the alcohol water. By the arrangement, the heat in the reforming cavity 31 can be fully utilized, and heat loss is effectively avoided.
Referring to fig. 1, the burner 60 includes an ignition assembly 61, a feed pipe 62 for supplying alcohol to the ignition assembly 61, and an exhaust passage 63 for supplying high-temperature gas to the heating passage 33. The alcohol may be methanol, ethanol, or the like. The ignition assembly 61 includes an atomizer 611, a silicon carbon heater rod 612, a blower 613, a ceramic alumina layer 614, and a catalytic oxidation layer (not shown) coated on the ceramic alumina layer 614. The atomizer 611 is used for atomizing and spraying the alcohol. The silicon carbon heating rod 612 ignites the alcohol mist after being electrified. The blower 613 is used to send outside air into the burner 60 so that the alcohol mist is sufficiently burned. The ceramic alumina layer 614 is used for stabilizing flame to ensure the continuous combustion of the alcohol mist. The catalytic oxidation layer is used for eliminating carbon monoxide generated after alcohol combustion so as to avoid carbon monoxide from polluting the environment.
When the reformer 100 of the alcohol-water reforming hydrogen production equipment of the present invention is used, firstly, the atomizer 611 is used to atomize the alcohol fed through the feeding pipe 62, then the silicon-carbon heating rod 612 is used to ignite the alcohol mist, the high temperature gas generated after the alcohol mist is combusted passes through the exhaust channel 63 to enter the heating channel 33, and flows along the heating channel 33, so as to heat the reforming cavity 31, the heat preservation layer 32, the reforming reaction component 10 and the palladium membrane component 20. The direction of flow of the hot gas is shown by the arrows in fig. 1. When the reforming cavity 31, the insulating layer 32, the reforming reaction assembly 10 and the palladium membrane assembly 20 reach a preset temperature, the alcohol-water mixed solution enters the reforming reaction assembly 10 through the feeding pipeline 40, and carries out a reforming reaction in the reforming reaction assembly 10 to generate a hydrogen-rich gas. The palladium membrane module 20 purifies the hydrogen-rich gas, outputs hydrogen from the gas outlet pipeline 50, and discharges non-hydrogen-rich gas from the tail gas port 23.
Compared with the prior art, the reformer 100 of the alcohol-water reforming hydrogen production equipment of the utility model makes the temperature distribution in the reaction channel 110 uniform through the heat conducting piece 12 with high heat conductivity and high heat transfer speed.
The above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, and although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that the technical solutions of the present invention can be modified or replaced equivalently without departing from the spirit and scope of the technical solutions of the present invention.

Claims (10)

1. A reformer of an alcohol-water reforming hydrogen production device comprises:
a reforming reaction assembly including an inner shell and a catalyst; the inner shell is provided with a reaction channel, and the reaction channel comprises an input end for inputting alcohol water and an output end for outputting hydrogen-rich gas; the catalyst is arranged in the reaction channel and is positioned between the input end and the output end;
the palladium membrane assembly is communicated with the output end and is used for purifying hydrogen from the hydrogen-rich gas; and
the reforming reaction component and the palladium membrane component are contained in the reforming cavity; the method is characterized in that:
the reforming reaction assembly further includes a heat transfer member disposed between the inner housing and the catalyst, and a thermal conductivity of the heat transfer member is greater than a thermal conductivity of the inner housing.
2. A reformer for an alcohol-water reforming hydrogen production apparatus according to claim 1, characterized in that: the heat-conducting member wraps the catalyst so that the catalyst is out of contact with the inner wall of the reaction channel.
3. A reformer for an alcohol-water reforming hydrogen production apparatus according to claim 1, characterized in that: the inner shell comprises a first pipeline and a second pipeline sleeved outside the first pipeline; the reaction channel is formed by the first pipeline and the second pipeline together.
4. A reformer for an alcohol-water reforming hydrogen production apparatus according to claim 3, characterized in that: the heat conducting piece comprises a first heat conducting pipeline and a second heat conducting pipeline sleeved outside the first heat conducting pipeline, and the first heat conducting pipeline and the second heat conducting pipeline are positioned between the first pipeline and the second pipeline; the inner wall of the first heat conduction pipeline is closely attached to the outer wall of the first pipeline, and the outer wall of the second heat conduction pipeline is closely attached to the inner wall of the second pipeline.
5. The reformer of an alcohol-water reforming hydrogen production apparatus according to claim 4, characterized in that: the first pipeline and the second pipeline are made of stainless steel, and the first heat-conducting pipeline and the second heat-conducting pipeline are made of copper.
6. The reformer of an alcohol-water reforming hydrogen production apparatus according to claim 5, characterized in that: the pipe wall thicknesses of the first pipeline and the second pipeline are between 2.5mm and 3 mm; the thickness of the pipe wall of the first heat-conducting pipeline and the second heat-conducting pipeline is not less than 5 mm.
7. The reformer of an alcohol-water reforming hydrogen production apparatus according to claim 4, characterized in that: the cross section of the reaction channel is annular, and the annular width of the reaction channel is between 12mm and 16 mm.
8. The reformer of an alcohol-water reforming hydrogen production apparatus according to claim 4, characterized in that: the reaction channels include a preheat channel adjacent the input end and a catalytic channel adjacent the output end.
9. A reformer for an alcohol-water reforming hydrogen production apparatus according to claim 1, characterized in that: and the inner wall of the reforming cavity is also provided with a heat-insulating layer to prevent heat in the reforming cavity from losing.
10. A reformer for an alcohol-water reforming hydrogen production apparatus according to claim 3, characterized in that: the palladium membrane assembly is disposed in the first pipe.
CN202021534937.4U 2020-07-29 2020-07-29 Reformer of alcohol-water reforming hydrogen production equipment Expired - Fee Related CN213434354U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202021534937.4U CN213434354U (en) 2020-07-29 2020-07-29 Reformer of alcohol-water reforming hydrogen production equipment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202021534937.4U CN213434354U (en) 2020-07-29 2020-07-29 Reformer of alcohol-water reforming hydrogen production equipment

Publications (1)

Publication Number Publication Date
CN213434354U true CN213434354U (en) 2021-06-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115784153A (en) * 2022-12-02 2023-03-14 武汉氢能与燃料电池产业技术研究院有限公司 Self-heating type alcohol reforming hydrogen production reactor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115784153A (en) * 2022-12-02 2023-03-14 武汉氢能与燃料电池产业技术研究院有限公司 Self-heating type alcohol reforming hydrogen production reactor

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20210615

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