CN213302469U

CN213302469U - Electric pile test platform and system with online internal resistance detection function

Info

Publication number: CN213302469U
Application number: CN202021420657.0U
Authority: CN
Inventors: 王昕�; 齐志刚
Original assignee: Beijing Xinyan Chuangneng Technology Co ltd
Current assignee: Beijing Xinyan Chuangneng Technology Co ltd
Priority date: 2020-07-17
Filing date: 2020-07-17
Publication date: 2021-05-28
Anticipated expiration: 2030-07-17

Abstract

The embodiment of the utility model provides a pile test platform and system that possess online internal resistance and detect function relates to the fuel cell field. On the basis of a conventional galvanic pile test platform, the test platform is additionally provided with an online internal resistance detection unit which comprises a direct-current power supply, a first pipeline, a second pipeline, a third pipeline, a fourth pipeline, a fifth pipeline, valves, flow regulators and the like, wherein the valves, the flow regulators and the like are arranged on the pipelines. When hydrogen and air are respectively introduced into the anode side and the cathode side of the galvanic pile, the test platform can carry out conventional detection on the power generation performance of the galvanic pile; when hydrogen is introduced into the anode side and the cathode side of the electric pile, the testing platform can carry out rapid online detection on the internal resistance of the electric pile to obtain the internal resistance of the electric pile and each single cell in the electric pile, and the testing platform is simple to operate, low in cost and high in efficiency.

Description

Electric pile test platform and system with online internal resistance detection function

Technical Field

The utility model relates to a fuel cell field particularly, relates to a galvanic pile test platform and system that possess online internal resistance and detect function.

Background

The voltage of the fuel cell stack (short for electric stack) is less than the theoretical voltage and is caused by three overpotentials. One is the activation of overpotentials, which is caused by the resistance to the reaction kinetics that needs to be overcome during the reaction. The second is ohmic overpotential, which is a voltage drop caused by ohmic resistance, including material bulk resistance (such as proton exchange membrane, catalyst layer, gas diffusion layer, bipolar plate) and various contact resistances (such as proton exchange membrane/catalyst layer, catalyst layer/gas diffusion layer, gas diffusion layer/bipolar plate). And thirdly, mass transfer overpotential is voltage drop caused by resistance in the reactant transfer process.

The characteristic curve expressing the relation between current density and voltage is called polarization curve, and the overpotential of each point on the polarization curve is the sum of the three overpotentials. In the low current density region (e.g. current density less than 0.2A/cm)²) The activation overpotential dominates. In a large current density interval (e.g. the current density is more than 2A/cm)²) Mass transfer overvoltage dominates. At a current density of 0.2-2A/cm²In between, the ohmic overpotential is dominant, and this interval is also the interval where the current density of the pile is mainly located in the power generation process. For this reason, measuring the magnitude of the stack ohmic resistance is a critical requirement.

The ohmic resistance test method mainly comprises a current interruption method and an alternating current impedance method. The current interruption method is simple to operate and simple in equipment, but the test result is often higher than an actual value, the accuracy is poor, and each single cell in the cell stack cannot be tested simultaneously. The alternating current impedance method is the most commonly adopted method at present, but the equipment is very expensive, the testing time is long, and the popularization and the use are difficult.

SUMMERY OF THE UTILITY MODEL

An object of the utility model is to provide a possess on-line internal resistance and detect electric pile test platform and system of function, it can improve the above-mentioned technical problem who mentions effectively.

The embodiment of the utility model is realized like this:

in a first aspect, an embodiment of the utility model provides a possess galvanic pile test platform of online internal resistance detection function, this galvanic pile test platform includes:

a) all components of a conventional stack test platform;

b) the online internal resistance detection unit comprises a direct-current power supply, a pipeline, a valve, a flowmeter and a flow regulator;

c) when hydrogen and air are respectively introduced into the anode side and the cathode side of the electric pile, the electric pile test platform can carry out conventional detection on the electric pile and the power generation performance of each single cell in the electric pile;

d) when hydrogen is introduced into both the anode side and the cathode side of the electric pile, the test platform can carry out rapid online detection on the internal resistance of the electric pile to obtain the internal resistance of the electric pile and each single cell in the electric pile.

In an alternative embodiment, the internal resistance detection unit includes a first pipeline, a second pipeline, a third pipeline, a fourth pipeline, and a fifth pipeline;

a) one end of the first pipeline is used for being communicated with the hydrogen cavity of the galvanic pile, and the other end of the first pipeline is used for being selectively communicated with a hydrogen source or a nitrogen source;

b) one end of the second pipeline is used for being communicated with the air cavity of the electric pile, and the other end of the second pipeline is used for being selectively communicated with an air source or a nitrogen source;

c) two ends of the third pipeline are respectively communicated with the first pipeline and the second pipeline;

d) one end of the fourth pipeline is communicated with the first pipeline, and the other end of the fourth pipeline is communicated with a nitrogen source;

e) one end of the fifth pipeline is communicated with the second pipeline, and the other end of the fifth pipeline is communicated with a nitrogen source.

In an alternative embodiment, a) a flow regulator is connected to the first conduit for regulating the flow of gas through the first conduit;

b) the third pipeline is connected with a third one-way valve, a flowmeter and a proportional valve; a third one-way valve for blocking fluid flow from the second line to the first line through the third line; the flow meter is used for measuring the flow of the gas flowing through the third pipeline; a proportional valve for controlling the flow of gas through the third conduit;

c) the fourth pipeline is connected with a first one-way valve and a first valve; the first one-way valve is for blocking gas of the hydrogen source from flowing through the fourth conduit; the first valve is used for controlling the on-off of the fourth pipeline;

d) a second valve and a second one-way valve are connected to the fifth pipeline; the second valve is used for controlling the on-off of the fifth pipeline, and the second one-way valve is used for blocking the air source gas from flowing through the fifth pipeline.

In a second aspect, an embodiment of the present invention provides a galvanic pile testing system with online internal resistance detection function, including any one of the foregoing embodiments.

In a third aspect, an embodiment of the present invention provides an online method, including:

a) starting a hydrogen source, introducing hydrogen into a hydrogen cavity of the galvanic pile through a first pipeline, and introducing hydrogen into an air cavity through a third pipeline and a second pipeline;

b) starting a direct current power supply connected with the positive end and the negative end of the electric pile, and gradually adjusting the output current of the direct current power supply from small to large; detecting the voltage of each single battery in the electric pile through a polling instrument connected with each single battery in the electric pile;

c) and dividing the output current of the direct current power supply by the active area of the single cell in the galvanic pile to obtain the current density, drawing a characteristic curve of the current density and the corresponding voltage for each single cell in the galvanic pile, wherein the slope of the characteristic curve is the ohmic resistance of the single cell.

In an alternative embodiment, the hydrogen gas is sufficiently pre-humidified before being passed into the hydrogen gas chamber and the air chamber of the stack.

In an optional embodiment, before introducing hydrogen into a hydrogen chamber and an air chamber of a galvanic pile, introducing gas in a nitrogen source into the hydrogen chamber through a fourth pipeline and a first pipeline, and introducing gas in the nitrogen source into the air chamber through a fifth pipeline and a second pipeline to exhaust original gas in the hydrogen chamber and the air chamber.

In an alternative embodiment, the flow of hydrogen into the hydrogen chamber and the air chamber of the stack is controlled by a flow regulator and a proportional valve together.

The utility model discloses beneficial effect includes, for example:

the embodiment of the utility model provides a pile test platform who possesses online internal resistance and detect function, this test platform increase online internal resistance detecting element on conventional pile test platform's basis, including DC power supply, first pipeline, second pipeline, third pipeline, fourth pipeline, fifth pipeline and flowmeter, proportional valve, check valve etc.. The direct current power supply is electrically connected with the electric pile, the patrol instrument is electrically connected with each single battery in the electric pile, and the voltage value corresponding to each single battery when different currents pass through the single battery can be detected. The current density is obtained by dividing the current by the active area of the single cell, and a characteristic curve between the current density and the voltage of each single cell can be obtained according to the voltage values corresponding to different current densities, wherein the characteristic curve is a straight line, and the gas slope is the ohmic resistance of each single cell, so that the ohmic resistances of a plurality of single cells can be obtained simultaneously. Compared with the existing internal resistance detection method, the platform detects the internal resistance of each single cell of the pile, can effectively evaluate the power generation performance of the pile, is simple to operate and low in cost, and has great advantages.

The embodiment of the utility model provides a pile test system who possesses online internal resistance and detect function, this test system include the above-mentioned test platform to possess this test platform's whole functions, this test system can carry out the detection that pile internal resistance detected and pile electricity generation performance effectively, improves efficiency of software testing.

The embodiment of the utility model provides a still provide a pile test method who possesses online internal resistance detection function, this internal resistance test method implements through foretell test platform, when this internal resistance test method carries out the internal resistance test, can be according to the voltage value that the current density of difference corresponds, obtain the current density of every monocell and the characteristic curve between the voltage, the slope of every characteristic curve is the ohmic resistance of every monocell promptly, thereby can obtain the ohmic resistance of a plurality of monocells simultaneously, compare with current internal resistance test instrument, this platform can detect the internal resistance of each monocell in the pile simultaneously, and can effectively assess the power generation performance of pile, and is easy to operate, and is with low costs.

Drawings

In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings that are required to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention, and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.

Fig. 1 is a schematic structural diagram of a galvanic pile testing system with an online internal resistance detection function according to an embodiment of the present invention;

fig. 2 is a schematic flow chart of a method for testing a stack with an online internal resistance detection function according to an embodiment of the present invention.

Icon: 1-testing the system; 11-electric pile; 111-single cells; 112-a hydrogen chamber; 113-an air chamber; 12-an online internal resistance detection unit; 13-a test platform; 121-a direct current power supply; 122-patrol instrument; 123-a first conduit; 124-a second conduit; 125-a third pipeline; 140-a fourth conduit; 141-fifth pipeline; 126-a proportional valve; 127-a flow meter; 128-a third one-way valve; 129-a first valve; 130-a second valve; 131-a first one-way valve; 132-a second one-way valve; 133-a circuit breaker; 134-a flow regulator; a 2-nitrogen source; 31-a source of hydrogen gas; 32-air source.

Detailed Description

In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are some, but not all, embodiments of the present invention. The components of embodiments of the present invention, as generally described and illustrated in the figures herein, may be arranged and designed in a wide variety of different configurations.

Thus, the following detailed description of the embodiments of the present invention, presented in the accompanying drawings, is not intended to limit the scope of the invention, as claimed, but is merely representative of selected embodiments of the invention. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.

It should be noted that: like reference numbers and letters refer to like items in the following figures, and thus, once an item is defined in one figure, it need not be further defined and explained in subsequent figures.

In the description of the present invention, it should be noted that the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", and the like indicate the position or positional relationship based on the position or positional relationship shown in the drawings, or the position or positional relationship which is usually placed when the product of the present invention is used, and are only for convenience of description and simplification of the description, but do not indicate or imply that the device or element referred to must have a specific position, be constructed and operated in a specific orientation, and thus, should not be construed as limiting the present invention. Furthermore, the terms "first," "second," "third," and the like are used solely to distinguish one from another and are not to be construed as indicating or implying relative importance.

Furthermore, the terms "horizontal", "vertical" and the like do not imply that the components are required to be absolutely horizontal or pendant, but rather may be slightly inclined. For example, "horizontal" merely means that the direction is more horizontal than "vertical" and does not mean that the structure must be perfectly horizontal, but may be slightly inclined.

In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly, e.g., as meaning either a fixed connection, a removable connection, or an integral connection; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meaning of the above terms in the present invention can be understood in specific cases to those skilled in the art.

Referring to fig. 1, the present embodiment provides a system 1 for testing a stack, where the system 1 includes a testing platform 13, the testing platform 13 is added with an online internal resistance detecting unit 12 on the basis of a conventional testing platform, a tested stack 11 includes a plurality of cells 111 connected in series, and the testing platform 13 can obtain ohmic resistances of one or more cells 111 simultaneously when performing an internal resistance test.

Specifically, the on-line internal resistance detection unit 12 in the test platform 13 includes a dc power supply 121 and a polling device 122, the dc power supply 121 is connected to the cell stack 11, and it can be understood that after the dc power supply 121 supplies power to the cell stack 11, since the plurality of cells 111 are connected in series, the current passing through each cell 111 is the same.

In the present embodiment, the direct current power supply 121 can output different currents, so that the currents passing through the plurality of single cells 111 can be changed.

In the present embodiment, the polling device 122 is electrically connected to one or more cells 111 at the same time. The polling device 122 can detect a voltage value corresponding to each of the cells 111 when a different current is passed therethrough.

The current density is obtained by dividing the current by the active area of the single cell, and according to the voltage values corresponding to different current densities, a characteristic curve between the current density and the voltage of each single cell 111 can be obtained, and the slope of each characteristic curve is the ohmic resistance of each single cell 111, so that the ohmic resistances of a plurality of single cells 111 can be obtained simultaneously, and the method is simple to operate and low in cost.

It should be noted that the stack 11 further includes a hydrogen chamber 112 and an air chamber 113, and the hydrogen chamber 112 is a chamber into which hydrogen enters the stack 11 during normal discharge. Similarly, air chamber 113 is the chamber into which air enters during normal discharge of stack 11. However, in the present embodiment, hydrogen gas is introduced into both the hydrogen chamber 112 and the air chamber 113 during the internal resistance test.

In general, when the internal resistance test is performed, the current output from the dc power supply 121 corresponds to the current density of the active area of the single cellThe degree variation range is 0-1A/cm²。

Referring to fig. 1, in the present embodiment, the testing platform 13 further includes a circuit breaker 133, and the circuit breaker 133 can enable the dc power supply 121 to power on or off the stack 11.

Referring to fig. 1, in the embodiment, the testing system 1 further includes a nitrogen source 2, a hydrogen source 31, an air source 32, and the online internal resistance detecting unit 12 further includes a first pipeline 123 and a second pipeline 124, one end of the first pipeline 123 is communicated with the hydrogen chamber 112, the other end of the first pipeline 123 is selectively communicated with the nitrogen source 2 or the hydrogen source 31, one end of the second pipeline 124 is communicated with the air chamber 113, and the other end of the second pipeline 124 is selectively communicated with the nitrogen source 2 or the air source 32.

It is understood that, in the present embodiment, the gas output from the nitrogen gas source 2 or the hydrogen gas source 31 may enter the hydrogen chamber 112 through the first piping 123. Similarly, gas output from nitrogen source 2 or air source 32 may enter air chamber 113 through second conduit 124. Similarly, gas output from hydrogen source 31 may enter air cavity 113 through first and

third conduits

123 and 125.

It should be noted that, during the normal power generation performance test of the stack, hydrogen gas is output from the hydrogen source 31 through the first pipe 123 into the hydrogen chamber 112, while air is output from the air source 32 through the second pipe 124 into the air chamber 113.

Referring to fig. 1, in the present embodiment, the online internal resistance detecting unit 12 further includes a third pipeline 125, and two ends of the third pipeline 125 are respectively communicated with the first pipeline 123 and the second pipeline 124.

During the internal resistance test, gas such as nitrogen can be output from the nitrogen source 2 as required, and simultaneously, the gas passes through the fourth pipeline 140 and the fifth pipeline 141, and then enters the pile hydrogen air chamber 112 and the air chamber 113 through the first pipeline and the second pipeline respectively, so as to purge and discharge residual gas such as air in the pile 11. The hydrogen output from the hydrogen source 31 then enters the stack hydrogen chamber 112 and the air chamber 113 through the first pipeline 123 and the third pipeline 125, respectively, for internal resistance detection.

In the present embodiment, the online internal resistance detection unit 12 further includes a proportional valve 126, the proportional valve 126 is disposed on the third pipeline 125, and the proportional valve 126 can regulate the flow rate of the gas passing through the third pipeline 125. In this way, the proportional valve 126 is able to regulate the flow of hydrogen from the first line 123 through the third line 125 into the second line 124, and thus to regulate the flow of hydrogen into the hydrogen chamber 112 and to regulate the flow of hydrogen into the air chamber 113.

When a direct current is applied to the stack by the direct current power supply, the amount of hydrogen introduced into the stack chamber connected to the positive electrode of the direct current power supply is at least equal to the amount of hydrogen consumed by the direct current in the chamber, and when the two are equal, the standard flow rate can be called.

Generally, when the internal resistance test is performed, if the positive electrode and the negative electrode of the dc power supply 121 are connected to the raw air side and the hydrogen side of the stack, respectively, the flow rate of hydrogen entering the hydrogen chamber 112 may be 0.3 times of the standard flow rate of hydrogen, and the flow rate of hydrogen entering the air chamber 113 may be 1.2 times of the standard flow rate of hydrogen.

It should be noted that, in this embodiment, the testing platform 13 further includes a flow regulator 134, and the flow regulator 134 can regulate the flow in the first pipeline 123, so that the total flow of the hydrogen gas before entering the third pipeline 125 is 1.5 times of the standard flow of the hydrogen gas.

Referring to fig. 1, in the present embodiment, the testing platform 13 further includes a flow meter 127, the flow meter 127 is disposed on the third pipeline 125, and the flow meter 127 can detect a flow rate in the third pipeline 125. In this way, the operator can determine from the data displayed by the flow meter 127 whether the hydrogen flow through the third line 125 meets the hydrogen demand into the air chamber 113.

Referring to fig. 1, in the present embodiment, the testing platform 13 further includes a third check valve 128, the third check valve 128 is disposed on the third pipeline 125, and the third check valve 128 can prevent the gas from flowing back from the second pipeline 124 to the first pipeline 123 through the third pipeline 125.

Referring to fig. 1, the testing platform 13 further includes a first valve 129 and a second valve 130, the first valve 129 is disposed on the fourth pipeline 140, the second valve 130 is disposed on the fifth pipeline 141, the first valve 129 can control on/off of the fourth pipeline 140, and the second valve 130 can control on/off of the fifth pipeline 141.

Generally, prior to introducing hydrogen gas into hydrogen chamber 112 and air chamber 113, nitrogen gas may be introduced into hydrogen chamber 112 and air chamber 113, such that the gas, such as air, that is present inside hydrogen chamber 112 and air chamber 113 is removed.

It should be noted that, when introducing nitrogen gas into hydrogen gas chamber 112 and air chamber 113, first valve 129 and second valve 130 may be opened simultaneously to allow nitrogen gas to enter hydrogen gas chamber 112 and air chamber 113 more quickly, and to remove air in hydrogen gas chamber 112 and air chamber 113 more quickly.

Referring to fig. 1, in the present embodiment, the testing platform 13 further includes a first check valve 131 and a second check valve 132, the first check valve 131 is disposed on the fourth pipeline 140, and the second check valve 132 is disposed on the fifth pipeline 141.

It will be appreciated that the first check valve 131 can prevent the gas from the hydrogen source 31 from flowing through the fourth pipeline to the fifth pipeline, and the second check valve 132 can prevent the gas from the air source 32 from flowing through the fifth pipeline to the fourth pipeline, so as to improve the safety performance of the entire testing platform 13.

Referring to fig. 2, the present embodiment further provides an internal resistance testing method, including:

s32: a certain flow of hydrogen is introduced into the hydrogen chamber 112 and the air chamber 113 of the stack 11.

S33: the dc power supply 121 is activated to regulate the current output by the dc power supply 121.

S34: the voltage value of each cell 111 detected by the patrol instrument 122 when different currents are passed through the cell is recorded.

The current density is obtained by dividing the current by the active area of the single cell, and according to the voltage values corresponding to different current densities, a characteristic curve between the current density and the voltage of each single cell 111 can be obtained, and the slope of each characteristic curve is the ohmic resistance of each single cell 111, so that the ohmic resistances of a plurality of single cells 111 can be obtained simultaneously, the test cost is reduced, and the test efficiency is improved.

In this embodiment, the internal resistance test method can be implemented by the internal resistance test system 1 described above.

Referring to fig. 2, in the present embodiment, before step S32, the internal resistance testing method further includes:

s31: the hydrogen gas is humidified.

Therefore, the humidified hydrogen can improve the proton conductivity of the proton exchange membrane so as to accurately test the internal resistance of the galvanic pile.

Referring to fig. 2, in the present embodiment, before step S31, the internal resistance testing method further includes:

s30: nitrogen gas is introduced into the hydrogen chamber 112 and the air chamber 113 to discharge the air in the hydrogen chamber 112 and the air chamber 113.

Thus, nitrogen gas can remove the original air inside hydrogen chamber 112 and air chamber 113.

In summary, the principle of the internal resistance testing system 1 provided in this embodiment is as follows:

the nitrogen source 2 is opened, the first valve 129 and the second valve 130 are opened, nitrogen gas is introduced into the hydrogen chamber 112 and the air chamber 113, and after a certain period of time, the first valve 129 and the second valve 130 are closed, and the nitrogen source 2 is closed.

The hydrogen source 31 is opened, the proportional valve 126 is opened, the humidified hydrogen is introduced into the first pipeline 123 and the third pipeline 125, so that a certain flow of hydrogen is introduced into the pile hydrogen chamber 112 and the air chamber 113 at the same time, the circuit breaker 133 is closed, and the direct current power supply 121 applies current to the pile.

The current of the DC power supply 121 is adjusted to make the current density of the single cell be 0-1A/cm²Gradually increases, and the voltage value corresponding to each single cell 111 at different current densities is recorded by the polling instrument 122.

Then, characteristic curves of each single cell 111 with respect to current density and voltage are obtained, and the slope of each characteristic curve is the ohmic resistance of each single cell 111.

The above description is only exemplary of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims

1. The galvanic pile test platform with the online internal resistance detection function is characterized by comprising an internal resistance detection unit (12), wherein the internal resistance detection unit (12) comprises a first pipeline (123), a second pipeline (124), a third pipeline (125), a fourth pipeline (140) and a fifth pipeline (141);

one end of the first pipeline (123) is used for being communicated with a hydrogen chamber (112) of the galvanic pile (11), and the other end of the first pipeline (123) is used for being selectively communicated with a hydrogen source (31) or a nitrogen source (2);

one end of the second pipeline (124) is used for being communicated with an air cavity (113) of the galvanic pile (11), and the other end of the second pipeline (124) is used for being selectively communicated with an air source (32) or a nitrogen source (2);

both ends of the third pipeline (125) are respectively communicated with the first pipeline (123) and the second pipeline (124);

one end of the fourth pipeline (140) is communicated with the first pipeline (123), and the other end of the fourth pipeline is communicated with the nitrogen source (2);

one end of the fifth pipeline (141) is communicated with the second pipeline (124), and the other end of the fifth pipeline is communicated with the nitrogen source (2).

2. The electric pile test platform with the function of on-line internal resistance detection according to claim 1,

a flow regulator (134) is connected to the first pipeline (123) and is used for regulating the flow of the gas flowing through the first pipeline (123);

a third one-way valve (128), a flow meter (127) and a proportional valve (126) are connected to the third pipeline (125); -a third non return valve (128) for blocking fluid flow from the second line (124) to the first line (123) through the third line (125); a flow meter (127) for measuring the flow of gas through the third conduit (125); a proportional valve (126) for controlling the flow of gas through the third conduit (125);

a first check valve (131) and a first valve (129) are connected to the fourth pipeline (140); the first one-way valve (131) is used for obstructing the gas of the hydrogen source (31) from flowing through the fourth pipeline (140); the first valve (129) is used for controlling the on-off of the fourth pipeline (140);

a second valve (130) and a second one-way valve (132) are connected to the fifth pipeline (141); the second valve (130) is used for controlling the on-off of the fifth pipeline (141), and the second one-way valve (132) is used for blocking the air source (32) from flowing through the fifth pipeline (141).

3. A galvanic pile test system with on-line internal resistance detection function, which is characterized by comprising the galvanic pile test platform with on-line internal resistance detection function of claim 1 or 2.