CN213253732U - Recoverable hydrogen pressure swing adsorption device for organic amine waste gas - Google Patents

Recoverable hydrogen pressure swing adsorption device for organic amine waste gas Download PDF

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Publication number
CN213253732U
CN213253732U CN202021649072.6U CN202021649072U CN213253732U CN 213253732 U CN213253732 U CN 213253732U CN 202021649072 U CN202021649072 U CN 202021649072U CN 213253732 U CN213253732 U CN 213253732U
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waste gas
pressure swing
swing adsorption
hydrogen
compressor
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苏逖
陈立
王根
傅露星
施平平
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Zhejiang Biliantian Environmental Technology Co ltd
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Zhejiang Biliantian Environmental Technology Co ltd
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Abstract

The utility model discloses a recoverable hydrogen pressure swing adsorption equipment for organic amine waste gas, including the pressure swing adsorption jar, its characterized in that: the waste gas compressor is connected to the air inlet of pressure swing adsorption jar, and waste gas compressor connects water and gas separator, and gas holder is connected to the water and gas separator, pressure swing adsorption jar's exhaust outlet connection exhaust gas purification device, exhaust gas purification device connects the chimney, pressure swing adsorption tank deck portion is equipped with the hydrogen export, hydrogen compressor is connected to hydrogen export connection buffer tank, and hydrogen compressor connects the hydrogen storage tank, the utility model discloses easy operation, maintenance convenience, safe and reliable, equipment area are little, and the running cost is low, and purification efficiency is high, no secondary pollution, hydrogen recycle, energy saving.

Description

Recoverable hydrogen pressure swing adsorption device for organic amine waste gas
Technical Field
The utility model relates to an exhaust-gas treatment's technical field, concretely relates to recoverable hydrogen pressure swing adsorption equipment for organic amine waste gas.
Background
The organic amine generally refers to an organic substance generated by a chemical reaction between the organic substance and ammonia. At the end of the 90 s of the 20 th century, the global organic amine production capacity reaches 32 ten thousand tons, and the annual average growth rate reaches 10%. The speed has slowed somewhat by the time this century entered, but has progressed at 5%. Asia, and in particular china, rapidly develops at an average annual rate of 20% to 30%. By the end of 2007, global organic amine production capacity has reached 50 million tons. The tail gas generated by the organic amine production line not only pollutes the environment, but also directly affects the physical health of staff. The organic waste gas treatment means that the organic waste gas pollution is eliminated by reducing the use amount of an organic solvent or purifying exhaust gas through different ways by using various technical measures. The organic waste gas pollution source is widely distributed, in order to prevent pollution, besides reducing the use amount of organic solvent to reduce the generation and emission of organic waste gas, exhaust purification is a feasible treatment way at present, and common methods include an adsorption method, an absorption method, a combustion method, a condensation method, a biological method and the like, wherein the adsorption method, the absorption method and the condensation method have the risk of secondary pollution, the biological method has higher cost, although the combustion method has good effect, the content of hydrogen in the waste gas is high (generally 55% -75%), the waste gas is secondarily alkane (methane, ethane, propane and the like) (generally 15% -35%), and the rest is respectively organic amine, ammonia and a small amount of impurities, and because the content of hydrogen in the waste gas is high, the combustion method has the risk of explosion.
SUMMERY OF THE UTILITY MODEL
The utility model provides a not enough to prior art, the utility model provides a recoverable hydrogen pressure swing adsorption equipment for organic amine waste gas has solved the problem that proposes in the above-mentioned background art.
In order to achieve the above purpose, the utility model discloses a following technical scheme realizes: the utility model provides a recoverable hydrogen pressure swing adsorption equipment for organic amine waste gas, includes the pressure swing adsorption jar, the waste gas compressor is connected to the air inlet of pressure swing adsorption jar, and the waste gas compressor connects water and gas separator, and the gas holder is connected to the water and gas separator, the exhaust gas outlet connection exhaust gas purification device of pressure swing adsorption jar, exhaust gas purification device connects the chimney, pressure swing adsorption tank deck portion is equipped with the hydrogen export, hydrogen exit linkage buffer tank, hydrogen compressor are connected to the buffer tank, and the hydrogen storage tank is connected to the hydrogen compressor.
Preferably, the gas holder is connected with an exhaust emission device.
Preferably, the pressure swing adsorption tanks are in a plurality of groups, and each group of pressure swing adsorption tanks is provided with an air inlet, an exhaust gas outlet and a hydrogen outlet.
Preferably, the air inlet of each pressure swing adsorption tank is connected with a waste gas compressor, the waste gas outlet is connected with a waste gas purification device, and the hydrogen outlet is connected with a buffer tank.
Preferably, the exhaust gas purification device is a device for treating organic exhaust gas. The utility model provides a recoverable hydrogen pressure swing adsorption equipment for organic amine waste gas possesses following beneficial effect:
(1) thereby recycling the hydrogen. The pressure swing adsorption technology can be used for recovering high-purity hydrogen, and the purity of the hydrogen can reach 99.99 percent;
(2) high purifying efficiency, stable operation and no secondary pollution. The organic waste gas is oxidized and decomposed by a thermal method combustion mode, sufficient combustion oxygen and certain residence time are provided at a proper temperature, so that the removal efficiency can be achieved, and the purification effect is good;
(3) the operation is simple, the maintenance is convenient, the safety and the reliability are realized, the coal-fired boiler is fed for combustion, a combustor is not required to be added, and the equipment investment and the maintenance cost are reduced;
(4) the occupied area is small, the operation cost is low, the combustion heat value can be increased, the real operation cost is reduced, and the effects of energy conservation and emission reduction are achieved.
Drawings
Fig. 1 is a schematic structural diagram of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments.
As shown in figure 1, a recoverable hydrogen pressure swing adsorption device for organic amine waste gas comprises a pressure swing adsorption tank 4, wherein an air inlet of the pressure swing adsorption tank 4 is connected with a waste gas compressor 3, the waste gas compressor 3 is connected with a water-gas separator 2, the water-gas separator 2 is connected with an air cabinet 1, a waste gas outlet of the pressure swing adsorption tank 4 is connected with a waste gas purification device 8, the waste gas purification device 8 is connected with a chimney 9, a hydrogen outlet is arranged at the top of the pressure swing adsorption tank 4, the hydrogen outlet is connected with a buffer tank 5, the buffer tank 5 is connected with a hydrogen compressor 6, the hydrogen compressor 6 is connected with a hydrogen storage tank 7, the air cabinet 1 is connected with a waste gas discharge device, the pressure swing adsorption tank 4 is provided with a plurality of groups, each pressure swing adsorption tank 4 is provided with an air inlet, a waste gas outlet and a hydrogen outlet, the air inlet of each pressure swing, the hydrogen outlets are connected with a buffer tank 5, and the waste gas purification device 8 is a device for treating organic waste gas.
During the in-service use, at first waste gas is discharged and is kept in the gas holder 1 temporarily, then detach moisture wherein through water vapor separator 2, the rethread exhaust gas compressor compresses back and gets into pressure swing adsorption device 4, hydrogen separation wherein through pressure swing adsorption device 4, hydrogen gets into buffer tank 5 from the hydrogen export at pressure swing adsorption device 4 top and keeps temporarily, rethread hydrogen compressor 6 compresses back and gets into hydrogen storage tank 7 and store, thereby recycle, remaining waste gas in pressure swing adsorption tank 4 gets into exhaust gas purification device 8 through the exhaust gas export, reach emission standard after exhaust gas purification device 8 handles and get into chimney 9 and discharge.
The above, only be the concrete implementation of the preferred embodiment of the present invention, but the protection scope of the present invention is not limited thereto, and any person skilled in the art is in the technical scope of the present invention, according to the technical solution of the present invention and the utility model, the concept of which is equivalent to replace or change, should be covered within the protection scope of the present invention.

Claims (5)

1. A recoverable hydrogen pressure swing adsorption device for organic amine waste gas, includes the pressure swing adsorption jar, its characterized in that: the gas inlet of the pressure swing adsorption tank is connected with a waste gas compressor, the waste gas compressor is connected with a water-gas separator, the water-gas separator is connected with a gas holder, the waste gas outlet of the pressure swing adsorption tank is connected with a waste gas purification device, the waste gas purification device is connected with a chimney, the top of the pressure swing adsorption tank is provided with a hydrogen outlet, the hydrogen outlet is connected with a buffer tank, the buffer tank is connected with a hydrogen compressor, and the hydrogen compressor is connected with a hydrogen storage tank.
2. The recoverable hydrogen pressure swing adsorption unit for organic amine waste gas of claim 1, characterized in that: the gas holder is connected with a waste gas discharge device.
3. The recoverable hydrogen pressure swing adsorption unit for organic amine waste gas of claim 1, characterized in that: the pressure swing adsorption tanks are in a plurality of groups, and each group of pressure swing adsorption tanks is provided with an air inlet, a waste gas outlet and a hydrogen outlet.
4. The recoverable hydrogen pressure swing adsorption unit for organic amine waste gas of claim 3, characterized in that: the air inlet of each pressure swing adsorption tank is connected with a waste gas compressor, the waste gas outlet is connected with a waste gas purification device, and the hydrogen outlet is connected with a buffer tank.
5. The recoverable hydrogen pressure swing adsorption unit for organic amine waste gas of claim 4, characterized in that: the waste gas purification device is used for treating organic waste gas.
CN202021649072.6U 2020-08-11 2020-08-11 Recoverable hydrogen pressure swing adsorption device for organic amine waste gas Active CN213253732U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202021649072.6U CN213253732U (en) 2020-08-11 2020-08-11 Recoverable hydrogen pressure swing adsorption device for organic amine waste gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202021649072.6U CN213253732U (en) 2020-08-11 2020-08-11 Recoverable hydrogen pressure swing adsorption device for organic amine waste gas

Publications (1)

Publication Number Publication Date
CN213253732U true CN213253732U (en) 2021-05-25

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CN202021649072.6U Active CN213253732U (en) 2020-08-11 2020-08-11 Recoverable hydrogen pressure swing adsorption device for organic amine waste gas

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CN (1) CN213253732U (en)

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