Background
The waterproof material is widely used in construction, water conservancy and other projects, and the waterproof material in China is mainly divided into five categories of asphalt coiled materials, high polymer sheets, sealing materials, waterproof coatings and special waterproof materials with special purposes at present.
The composite waterproof coiled material occupies an important position in a building material product, and the quality of the composite waterproof coiled material directly influences the quality of the whole building engineering. The common composite waterproof coiled material mainly comprises petroleum, asphalt, paper tire and asphalt felt, which account for about 70% of the total amount of the market recently, the macromolecule composite waterproof coiled material only accounts for about 10%, and the others are waterproof paint and other composite waterproof coiled materials, but the material has the defect that the material is difficult to overcome. Such as: a large amount of waste gas generated during the preparation of asphalt seriously pollutes the environment, and easily causes the problems of scalding, fire accidents and the like. In particular, the common waterproof coiled material has the defects of low tensile strength, low tear strength, poor conformability, small elongation at break, poor heat resistance, poor low-temperature flexibility, corrosion resistance, easy aging and the like, and the physical properties of some waterproof coiled materials are slightly better but the flame retardant effect is sacrificed.
The high-molecular sheet material, also called synthetic high-molecular waterproof coiled material, is a curlable sheet-like waterproof material made up by using synthetic rubber, synthetic resin or their mixture as base material, adding proper quantity of chemical adjuvant and filling agent, and adopting the processes of banburying, extruding or calendering, etc. to make rubber or plastics. In the prior art, two sides or one side of a polymer coiled material are both provided with thermal composite smooth non-woven fabrics, and in order to further improve the mechanical property of the polymer waterproof coiled material, various reinforcing layers such as metal grids, carcass fabrics and other materials are generally compounded in the polymer waterproof coiled material. And the lapping areas which are respectively empty and 100mm at the two sides of the coiled material along the length direction are not provided with polyester fabric, and the lapping welding construction is carried out by adopting a hot melting welding machine while the empty edges are remained.
Patent publication No. CN105500847A discloses a polyethylene double-sided composite waterproof roll, which comprises a polymer sheet, and a reinforced nonwoven fabric is compounded on both sides of the polymer sheet. The inner layer is made of polypropylene filament non-woven fabric, the outer layer is made of polyester filament non-woven fabric, the middle layer is made of polyethylene resin, and the middle layer is compounded between the inner layer and the outer layer. The middle layer is a sheet made of polyethylene resin, and the thickness of the middle layer is larger than that of the inner layer and the outer layer. The prominent defects are as follows: the double-sided composite waterproof coiled material is a novel double-sided composite waterproof coiled material with convenient construction and is suitable for a wet paving method. The polyethylenes are classified into different bai types: low density polyethylene (duLDPE), Medium Density Polyethylene (MDPE), high density zhi degree polyethylene dao alkene (HDPE), Linear Low Density Polyethylene (LLDPE), its Shore hardness respectively for LDPE 45-55, MDPE 50-60, HDPE 62-72. According to the national standard, in the field of construction, the thickness of the high-molecular waterproof coiled material is not less than 1.2 mm. The document does not disclose technical parameters of the product, but the polyethylene material does not have very strong tensile strength, elongation, low-temperature flexibility, good heat resistance and radiation resistance compared with other high polymer materials, and the thickness can be judged to be far more than 1.2mm to achieve the effects of high tensile strength, high elongation, good low-temperature flexibility, good heat resistance, chemical corrosion resistance and strong radiation resistance. The sheet material made of the main body polyethylene resin of the polyethylene double-sided composite waterproof coiled material has larger thickness and is harder, and the construction must be carried out by adopting a wet paving method. The upper and lower layers are made of non-woven fabrics, and the top surface of the non-woven fabrics needs cement plastering. The product adopting the structure is not easy to bend and construct at the special-shaped parts such as corners and the like of the parts of the building needing water proofing, so that the phenomenon of loose combination and hollowing is easy to generate between the coiled material and the special-shaped parts such as the corners and the like of the parts of the building needing water proofing, and the weak points exist in the water proofing construction.
The patent with publication number CN1182157A discloses a modified polyethylene composite non-woven waterproof roll and a production method thereof, and provides a modified polyethylene composite non-woven waterproof roll which has good surface roughness and excellent ultraviolet resistance and can be directly bonded with cement materials in the curing process, and a production method thereof. This waterproofing membrane main waterproof layer uses polyethylene, EVA resin as the main part material, and the compound polyester filament non-woven fabrics of main waterproof layer upper surface improves waterproofing material's ultraviolet resistance ability, and lower surface complex polypropylene fibre non-woven fabrics is done the reinforcing skeleton, improves the roughness on material surface, improves the bonding and lays the performance, increases mechanical strength, improves the resistant destructiveness of coiled material, increases elasticity and elasticity, reduces the damage of external factor to main waterproof layer. The addition amount (percentage of the total weight) of the polyethylene in the main waterproof layer is 65-75%, and the addition amount of the EVA resin is 25-35%. In order to prevent the product from being illuminated and slowly oxidized and degraded at normal temperature in the production, transportation, storage and construction processes, a light shielding agent, a heat stabilizer and an antioxidant are added into the main waterproof layer, the light shielding agent and the heat stabilizer are pigment carbon black, and the main component of the light shielding agent and the heat stabilizer is carbon, so that the light shielding agent and the heat stabilizer mainly play a role in high polymers: first coloring, second oxidation inhibition, and third ultraviolet screening. Thereby effectively stabilizing the polymer. DLTP is used as antioxidant and has obvious synergistic effect with carbon black. In order to improve the dispersibility of the carbon black in the main waterproof layer and achieve the light shielding effect, white oil is also required to be added. Various additives are added into the main waterproof layer, and the percentages of the additives in the total weight of the polyethylene and the EVA resin are respectively: 1-1.5% of pigment carbon black, 1.5% of antioxidant DLTP1 and 0.2-0.5% of white oil. The polyester filament non-woven fabric is compounded on the upper surface of the main waterproof layer, so that the ultraviolet resistance of the waterproof material is improved; the lower surface is compounded with polypropylene non-woven fabric to be used as a reinforcing framework, so that the roughness of the surface of the material is improved, and the bonding laying performance is improved. The disadvantages are two: firstly, in order to ensure the composite effect, the composite temperature of each layer is set to be 120-150 ℃, and the melting point of the polyester filament non-woven fabric is not reached, but in the actual production, the inventor finds that at the temperature, the polypropylene non-woven fabric is compounded at the temperature, and can deform and damage the porous structure of the polypropylene non-woven fabric; although the combination of the polyester filament non-woven fabric and the main waterproof layer can be well realized, the composite polypropylene fiber non-woven fabric plays a role in making a reinforcing framework, the roughness of the surface of the material is improved, the function of bonding laying performance is improved, the mechanical strength is increased, and the damage resistance of the coiled material is improved, the manufacturing process is realized on the basis of sacrificing the porous structural characteristics of the polypropylene fiber non-woven fabric. Secondly, the whole hardness is high, the main waterproof layer adopts polyethylene and EVA resin, and in the resin plasticizing extrusion process, the auxiliary agents are mixed together and uniformly plasticized and dispersed. The auxiliary agent has the functions of reducing the surface tension of the resin in a molten state and enhancing the composite contact effect, and the condition of ensuring the composite effect and the effective dispersion of the auxiliary agent is sufficient plasticization. The plasticizing extrusion temperature is too high to lead to the composite temperature to rise, can make the non-woven fabrics damage when compounding, influences product quality, and when the temperature was crossed lowly, the plasticizing was unfavorable, and extrusion pressure increases, and the carbon black dispersion is uneven, and stiff piece, fisheye form appear in the main waterproof layer, appear the cavity when serious. The addition of polyethylene and EVA resin, as well as the adjuvants, results in a material that is relatively "hard". In addition, in order to improve the ultraviolet resistance of the waterproof material, the polyester filament non-woven fabric is compounded on the upper surface of the main waterproof layer; in order to improve the roughness of the surface of the material, the polypropylene fiber non-woven fabric is compounded on the lower surface to be used as a reinforcing framework, and the whole coiled material is not easy to bend.
In conclusion, the polymer waterproof coiled material in the prior art has the outstanding defects that the surface is smooth and low in roughness, the coiled material and the cement cannot be directly bonded in the cement solidification process, and the waterproof engineering quality cannot be constructed or is seriously influenced when the water content of a base surface exceeds 8%; the special-shaped parts such as corners and the like of the parts of the building needing water proofing are not easy to be bent for construction, the phenomenon that the coiled material is combined with the special-shaped parts such as the corners and the like of the parts of the building needing water proofing and is easy to generate hollowing is easy to generate, and the weak points exist in the water proofing construction,
the waterproof paint comprises a spray polyurea waterproof material and a polyurethane waterproof material. Polyurea is an A, B bi-component, solvent-free and fast-curing green and environment-friendly elastic waterproof material, is divided into high-elasticity spraying (pure) polyurea waterproof paint (JNC) and high-elasticity spraying polyurethane (urea) (commonly known as semi-polyurea) elastic waterproof paint (JNJ) according to different film forming reaction groups, and is divided into I type and II type according to physical properties. A. The component B is mixed and sprayed out in a spray gun of special spraying equipment, and the elastic waterproof membrane is generated through rapid reaction and solidification. The component A of the high-elastic spray (pure) polyurea waterproof coating is a semi-prepolymer prepared by the reaction of a hydroxyl-terminated compound and isocyanate; the component B is a mixture consisting of an amino-terminated resin and an amino-terminated chain extender, and does not contain any hydroxyl component and catalyst, but allows a small amount of pigment and dispersing aid. The component A of the high-elasticity spray polyurethane (urea) (commonly known as semi-polyurea) elastic waterproof coating is a semi-prepolymer prepared by the reaction of a hydroxyl-terminated compound and isocyanate; the component B is a mixture of hydroxyl-terminated resin or amino-terminated resin and an amino-terminated chain extender, and a catalyst for improving the reaction activity can be contained in the component B, so that a small amount of pigment and dispersing auxiliary agents are allowed to be contained. When the product is formed into a film, special professional construction machinery is required to be adopted for spray forming, the excellent physical and chemical performance index, the convenient construction process, the integrity of a waterproof and anticorrosion system and the environmental protection performance of the product are beyond the reach of any other traditional protective material and technology, and the product is widely applied to waterproof, anticorrosion and wear-resistant 'two-prevention one-resistance' engineering of urban subways, high-speed railways, tunnel bridges, hydraulic and electromechanical engineering, ocean chemical engineering and dual-purpose projects of military and civil use. The polyurethane waterproof paint bai is one kind of single component waterproof polyurethane paint prepared with isocyanate group containing prepolymerized dao body of isocyanate, du polyether, etc. and through addition polymerization to form zhi, mixing with catalyst, anhydrous assistant, anhydrous stuffing, solvent, etc. The paint is a reaction curing type (moisture curing) paint and has the characteristics of high strength, high elongation, good water resistance and the like. In the prior art, the polyurea waterproof material and the polyurea waterproof material have the following defects in the construction process: during construction of polyurea and polyurethane, certain requirements are imposed on temperature, and the combination effect is influenced when the temperature is too high or too low; the requirement on construction conditions is high, sundries such as dry, uneven and sand, dust and the like do not exist in a construction area, and the bonding force with a part of a building needing water prevention is not strong. But the reality is that: in rainy days, the construction area is difficult to be ensured to be dry and meet the spraying condition; the construction period of the building engineering is generally tighter, and the concrete needs to be sprayed when not completely dried; when the weather is heavy, or the construction surface is not flat, the construction area is difficult to clean. These difficulties have plagued those skilled in the art.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a spraying auxiliary coiled material, its preparation method and adopt the waterproof construction of this coiled material to prior art not enough, solve the construction region humidity or have debris such as dust grit or worker's face not the not good problem of condition spraying polyurea or polyurethane effect of planishing face.
The utility model adopts the technical proposal as follows.
The spraying auxiliary coiled material comprises a 0.5-0.9 mm polyvinyl chloride soft layer, a polypropylene non-woven fabric with a mesh structure and compounded on the top surface of the polyvinyl chloride soft layer in a hot-pressing mode, and a polyester fabric with a wool surface and compounded on the bottom surface of the polyvinyl chloride soft layer in a hot-pressing mode.
As the preferred technical scheme, a lower overlapping area without polyester fabric is reserved on one side edge of the bottom surface of the polyvinyl chloride soft layer, and an upper overlapping area without polypropylene non-woven fabric is reserved on the side edge of the top surface of the base layer, which is far away from the lower overlapping area.
According to a preferable technical scheme, the polypropylene non-woven fabric is 40-70 g/m2 polypropylene spun-bonded non-woven fabric.
According to a preferable technical scheme, the polyester fabric is polyester filament hot-rolled non-woven fabric.
As a preferred technical scheme, the terylene cloth is 70-90 g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
As a preferred technical scheme, the polyvinyl chloride soft layer raw material comprises the following components in parts by weight: 100 parts of polyvinyl chloride resin, 30-35 parts of diisononyl phthalate, 2-5 parts of DOTP softening plasticizer, 2-3 parts of OPE lubricant, 11-15 parts of dioctyl oxalate, 2-5 parts of epoxidized soybean oil, 1.5-2.0 parts of antimony trioxide, 0.10-0.15 part of sodium pentachlorophenate, 0.05-0.06 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 1-2 parts of liquid barium-zinc composite stabilizer and 5-10 parts of chlorinated polyethylene.
The chlorinated polyethylene is a saturated high polymer material, is white powder in appearance, is nontoxic and tasteless, has excellent weather resistance, ozone resistance, chemical medicine resistance and aging resistance, and has good oil resistance, flame retardance and coloring performance. Good toughness (flexibility at minus 30 ℃), good compatibility with other high polymer materials and higher decomposition temperature. The liquid barium-zinc composite stabilizer has different properties due to different compositions. But is generally light yellow to yellow clear liquid, the specific gravity is 0.95-1.02 at normal temperature, the viscosity is less than 100 centipoise, and the freezing point is about-15 ℃.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring materials for manufacturing the polyvinyl chloride soft layer in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth into a calender for hot-pressing compounding, and enabling the terylene cloth to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135-140 ℃; obtaining a terylene cloth and polyvinyl chloride coiled material blank combination;
and 4, step 4: triple heat-melting direct pressure
And (3) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric into a pair of drafting rollers while closely adhering to the top surface of the combination of the polyester fabric and the polyvinyl chloride coiled material blank, extruding through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric on the top surface of the polyvinyl chloride soft layer to obtain the spraying auxiliary coiled material.
The cooling measure is that a blower blows cold air to the top surface of the combination of the polyester fabric and the polyvinyl chloride coiled material body to realize cooling.
The polypropylene non-woven fabric is polypropylene spun-bonded non-woven fabric.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer into a mixer for stirring, stirring for 16-20 minutes at the temperature of 110-;
cooling the slurry in a cooler at-20-10 deg.c for 10-20 min;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The waterproof structure comprises a spraying auxiliary layer formed by adjacent lap joint of any one spraying auxiliary coiled material; the overlapping areas of the two adjacent overlapped spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer is sprayed with a polyurea layer or a polyurethane layer; the bottom surface of the spray auxiliary layer is bonded with the area to be constructed through a bonding layer made of cement-based adhesive or cement paste.
As a preferred technical scheme, the adhesive is formed by mixing cement, rubber powder and water according to the weight ratio of 50:0.5-1.0: 10-20.
As a preferred technical scheme, the thickness of the polyurea layer or the polyurethane layer is 1.0-2.0 mm.
As a preferred technical scheme, the top surface of the polyurea layer is coated with a finish paint protective layer.
As a preferred technical scheme, the finish coat protective layer is one of fluorocarbon paint, water-based acrylic paint, acrylic resin modified polyurethane paint, aliphatic polyurethane paint and aliphatic polyaspartic ester paint.
The beneficial effects of the utility model are as follows.
1. Set up a spraying auxiliary coiled material, the combination of spraying auxiliary coiled material forms the spraying auxiliary layer, has solved the condition that the construction area is moist or has debris such as dust grit or worker's face is not the level surface among the prior art, and the spraying polyurea or the poor problem of polyurethane effect.
2. The spraying auxiliary coiled material has small thickness and is a non-standard structure, and the spraying auxiliary coiled material has the advantages of light and soft property, can be pasted by cement paste or cement-based adhesive in a construction area according to construction requirements during construction, solves the problems that in the prior art, the construction is easy to bend at special-shaped parts such as corners and the like of the parts of a building needing water proofing, the combination between the coiled material and the special-shaped parts such as the corners and the like of the parts of the building needing water proofing is not firm, and the phenomenon of hollowing is easy to generate; the operation of cutting and pasting the material during construction is reduced, and the generation of pasting surfaces is reduced, so that the weak points of waterproof construction are reduced.
3. The hot-pressing compounding of the polyester hot-rolled non-woven fabric on the bottom surface of the high-molecular soft layer mainly utilizes the characteristic of high-temperature resistance of the polyester hot-pressing compounding, and after the hot-pressing compounding is completed, the polyester filament hot-rolled non-woven fabric still can keep filament fuzz with a certain length on the bottom surface, so that when the polyester filament hot-rolled non-woven fabric is combined with cement-based adhesive or cement paste, the adhesive effect is improved while the hydrophilic wetting of the cement mortar on the polyester filament hot-.
4. The polypropylene non-woven fabric layer and the polyester non-woven fabric layer with porous structures are respectively compounded on the top surface and the bottom surface of the polymer soft layer by adopting a three-time hot pressing method, particularly, the non-woven fabric layers of the polypropylene non-woven fabric layer are in accordance at the low temperature of 95-100 ℃, the porous moisture absorption performance of the polypropylene non-woven fabric is ensured, the compounding temperature of the polyester fabric is optimized, the polyester filament hot-rolled non-woven fabric can still keep filament fluff with a certain length on the bottom surface, the affinity with a construction area is improved, and the bonding effect is improved.
5. The overlapping areas of two adjacent spraying auxiliary coiled materials are bonded by the adhesive bonding agent, so that open fire is not needed in construction, and the construction is safe.
6. The spraying auxiliary coiled material and the waterproof structure are thin in thickness and light in weight, and the quantity of organic materials consumed by waterproof engineering can be reduced.
7. The spraying auxiliary coiled material has reinforced structure of polypropylene fabric and polyester fabric on its top and bottom, high breaking strength, high product flexibility, easy bending, no breaking, high tensile strength and high perforation resistance. Therefore, the product is more suitable for the waterproof engineering of special parts.
8. In the waterproof construction structure, the polypropylene fiber non-woven fabric layer with the porous structure is compounded at the low temperature of the top surface of the polymer soft layer of 0.6-0.9mm, polyurea is sprayed on the polypropylene fiber non-woven fabric or polyurethane is coated on the polypropylene fiber non-woven fabric, the porous moisture absorption performance of the polypropylene fiber non-woven fabric is fully utilized, the problem that polyurethane or polyurea is not tightly combined with polymer materials directly in the prior art is solved, meanwhile, ribs are added between the polyurethane or polyurea and the polymer layer, and the deformation resistance of the waterproof structure is remarkably improved.
9. The polyurea layer is protected by the finish paint protective layer, and the anti-aging property of the polyvinyl chloride is strong, so that the service life of the waterproof engineering can be the same as that of the building engineering.
Detailed Description
The present invention will be further explained with reference to the drawings and examples.
Example 1. As shown in fig. 1, the spray coating auxiliary roll comprises a 0.5mm polyvinyl chloride soft layer 2, a polypropylene non-woven fabric 1 having a mesh structure and hot-pressed and compounded on the top surface of the polyvinyl chloride soft layer 2, and a polyester fabric 3 having a rough bottom surface and hot-pressed and compounded on the bottom surface of the polyvinyl chloride soft layer 2.
The polypropylene non-woven fabric 1 is 40g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene cloth 3 is 70g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The raw material of the polyvinyl chloride soft layer 2 is polyvinyl chloride particles.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 16 minutes at the temperature of 110 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 10 minutes at 10 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The cooling measure is that a blower blows cold air to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coil blank body to realize cooling.
The polypropylene non-woven fabric 1 is a polypropylene spun-bonded non-woven fabric.
As shown in fig. 3-4, a waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of spraying auxiliary coiled materials in an adjacent overlapping manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurea layer 5; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.5: 10.
The thickness of the polyurea layer 5 is 1.0 mm.
Example 2. This embodiment is different from embodiment 1 in that: the polypropylene nonwoven fabric 1 is a polypropylene spunbond nonwoven fabric of 40g/m 2. The thickness of the polyvinyl chloride soft layer 2 is 0.9 mm.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene cloth 3 is 70g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 30 parts of diisononyl phthalate, 2 parts of DOTP softening plasticizer, 2 parts of OPE lubricant, 11 parts of dioctyl oxalate, 2 parts of epoxidized soybean oil, 1.5 parts of antimony trioxide, 0.10 part of sodium pentachlorophenate, 0.05 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 1-2 parts of liquid barium-zinc composite stabilizer and 5 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 140 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 16 minutes at the temperature of 110 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 10 minutes at 10 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The cooling measure is that a blower blows cold air to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coil blank body to realize cooling.
The polypropylene non-woven fabric 1 is a polypropylene spun-bonded non-woven fabric.
As shown in fig. 5 to 6, a waterproof structure includes a spraying auxiliary layer 4 formed by adjacent lap-joint of a plurality of the above spraying auxiliary rolls; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurethane layer 6; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.5: 10.
The thickness of the polyurethane layer 6 is 1.0 mm.
Example 3. This embodiment is different from embodiment 2 in that: as shown in fig. 2, the left side of the bottom surface of the polyvinyl chloride soft layer 2 is provided with a lower overlapping region 21 where the polyester fabric 3 is not provided, and the right side of the top surface of the base layer is provided with an upper overlapping region 22 where the polypropylene nonwoven fabric 1 is not provided. The spraying auxiliary coiled material comprises a 0.8mm polyvinyl chloride soft layer 2, a polypropylene non-woven fabric 1 which is hot-pressed and compounded on the top surface of the polyvinyl chloride soft layer 2 and has a mesh structure, and a polyester fabric 3 which is hot-pressed and compounded on the bottom surface of the polyvinyl chloride soft layer 2 and has a rough surface.
The polypropylene non-woven fabric 1 is 50g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene fabric 3 is 90g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 35 parts of diisononyl phthalate, 5 parts of DOTP softening plasticizer, 2 parts of OPE lubricant, 11 parts of dioctyl oxalate, 2 parts of epoxidized soybean oil, 1.5 parts of antimony trioxide, 0.15 part of sodium pentachlorophenate, 0.06 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 1 part of liquid barium-zinc composite stabilizer and 5 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 140 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 20 minutes at the temperature of 120 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 20 minutes at-20 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The cooling measure is that a blower blows cold air to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coil blank body to realize cooling.
The polypropylene non-woven fabric 1 is a polypropylene spun-bonded non-woven fabric.
As shown in fig. 7-8, a waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of the spraying auxiliary coiled materials in an adjacent overlapping manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurethane layer 6; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:1.0: 120.
The thickness of the polyurethane layer 6 is 1.0 mm.
Example 4. This embodiment is different from embodiment 2 in that: the left side of the bottom surface of the polyvinyl chloride soft layer 2 is provided with a lower overlapping area 21 without the polyester fabric 3, and the right side of the top surface of the base layer is provided with an upper overlapping area 22 without the polypropylene non-woven fabric 1.
The polypropylene non-woven fabric 1 is 65g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene cloth 3 is 85g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 35 parts of diisononyl phthalate, 5 parts of DOTP softening plasticizer, 3 parts of OPE lubricant, 15 parts of dioctyl oxalate, 5 parts of epoxidized soybean oil, 2.0 parts of antimony trioxide, 0.10 part of sodium pentachlorophenate, 0.06 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 2 parts of liquid barium-zinc composite stabilizer and 5 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (3) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the material for preparing the polyvinyl chloride soft layer 2 into a mixer for stirring, stirring for 16-20 minutes at the temperature of 110-;
cooling the slurry in a cooling machine for 20 minutes at-20 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The cooling measure is that a blower blows cold air to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coil blank body to realize cooling.
The polypropylene non-woven fabric 1 is a polypropylene spun-bonded non-woven fabric.
As shown in fig. 7-8, a waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of the spraying auxiliary coiled materials in an adjacent overlapping manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurethane layer 6; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.8: 10.
The thickness of the polyurethane layer 6 is 2.0 mm.
Example 5. This embodiment is different from embodiment 3 in that: the polypropylene non-woven fabric 1 is 70g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene fabric 3 is 90g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 35 parts of diisononyl phthalate, 2 parts of DOTP softening plasticizer, 2 parts of OPE lubricant, 115 parts of dioctyl oxalate, 2 parts of epoxidized soybean oil, 1.5 parts of antimony trioxide, 0.10 part of sodium pentachlorophenate, 0.05 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 1 part of liquid barium-zinc composite stabilizer and 5 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the material for preparing the polyvinyl chloride soft layer 2 into a mixer for stirring, stirring for 16-20 minutes at the temperature of 110-;
cooling the slurry in a cooling machine for 20 minutes at-20 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
As shown in fig. 9-10, a waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of the spraying auxiliary coiled materials in an adjacent overlapping manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurea layer 5; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.5: 10.
The thickness of the polyurea layer 5 is 1.2 mm.
The top surface of the polyurea layer 5 is coated with a finish protective layer 7.
The finish paint protective layer 7 is fluorocarbon paint.
Example 6. This embodiment is different from embodiment 4 in that: the polypropylene non-woven fabric 1 is 70g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene fabric 3 is 90g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 35 parts of diisononyl phthalate, 2 parts of DOTP softening plasticizer, 2 parts of OPE lubricant, 11 parts of dioctyl oxalate, 2 parts of epoxidized soybean oil, 1.5 parts of antimony trioxide, 0.10 part of sodium pentachlorophenate, 0.06 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 2 parts of liquid barium-zinc composite stabilizer and 10 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 140 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 16-20 minutes at the temperature of 130 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 15 minutes at 10 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.5: 10.
The thickness of the polyurea layer 5 is 1.2 mm.
The top surface of the polyurea layer 5 is coated with a finish protective layer 7.
The finishing coat protective layer 7 is acrylic paint.
Example 7. This embodiment is different from embodiment 4 in that: the polypropylene non-woven fabric 1 is 45g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene cloth 3 is 85g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 35 parts of diisononyl phthalate, 5 parts of DOTP softening plasticizer, 3 parts of OPE lubricant, 15 parts of dioctyl oxalate, 5 parts of epoxidized soybean oil, 2.0 parts of antimony trioxide, 0.15 part of sodium pentachlorophenate, 0.06 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 2 parts of liquid barium-zinc composite stabilizer and 10 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 16-20 minutes at the temperature of 130 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 20 minutes at-20 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
A waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of spraying auxiliary coiled materials in an adjacent lap joint manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurea layer 5; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:1.0: 20.
The thickness of the polyurea layer 5 is 2.0 mm.
The top surface of the polyurea layer 5 is coated with a finish protective layer 7.
The finish paint protective layer 7 is acrylic resin modified polyurethane paint.
Example 8. This embodiment is different from embodiment 4 in that: the polypropylene non-woven fabric 1 is 70g/m2The polypropylene spun-bonded nonwoven fabric.
The terylene cloth 3 is terylene filament hot-rolled non-woven fabric.
The terylene fabric 3 is 90g/m terylene filament hot-rolled non-woven fabric2The polyester filament hot-rolled non-woven fabric.
The polyvinyl chloride soft layer 2 comprises the following raw materials in parts by weight: 100 parts of polyvinyl chloride resin, 30 parts of diisononyl phthalate, 5 parts of DOTP softening plasticizer, 2 parts of OPE lubricant, 12 parts of dioctyl oxalate, 5 parts of epoxidized soybean oil, 2.0 parts of antimony trioxide, 0.10 part of sodium pentachlorophenate, 0.05 part of beta-dodecyl thiopropionic acid pentaerythritol ester, 1 part of liquid barium-zinc composite stabilizer and 5 parts of chlorinated polyethylene.
The preparation method of the spraying auxiliary coiled material comprises the following steps:
step 1: material preparation
Uniformly stirring the materials for preparing the polyvinyl chloride soft layer 2 in a container;
granulating the uniformly stirred materials;
putting the granulated material into an electric heating oven, and fully plasticizing the material in a temperature zone from 180 ℃ to 210 ℃ to 180 ℃;
step 2: one-time hot melting and direct pressing
Conveying the granulated material to a calender to extrude the granulated material into a polyvinyl chloride coiled material green body;
and step 3: secondary hot melt direct pressing
Tightly attaching the terylene cloth 3 to the bottom of the polyvinyl chloride coiled material blank, putting the terylene cloth 3 into a calender for hot-pressing compounding, and enabling the terylene cloth 3 to be hot-pressed and compounded on the bottom surface of the polyvinyl chloride coiled material blank, wherein the hot-pressing temperature is controlled at 135 ℃; obtaining the combination of the terylene cloth 3 and a polyvinyl chloride coiled material blank;
and 4, step 4: triple heat-melting direct pressure
And (2) adopting a cooling measure to reduce the temperature of the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank to 95-100 ℃, leading the polypropylene non-woven fabric 1 to be tightly attached to the top surface of the combination of the polyester fabric 3 and the polyvinyl chloride coiled material blank and into a pair of drafting rollers, extruding the polypropylene non-woven fabric 1 through the rollers, and performing hot-pressing compounding on the polypropylene non-woven fabric 1 on the top surface of the polyvinyl chloride soft layer 2 to obtain the spraying auxiliary coiled material.
The step 1 comprises the following steps:
putting the materials for preparing the polyvinyl chloride soft layer 2 into a mixer, stirring for 16-20 minutes at the temperature of 110 ℃, and cooling the obtained materials to obtain pasty slurry;
cooling the slurry in a cooling machine for 10 minutes at-20 ℃;
cutting the obtained cooling material into particles, and screening the cut material through a sieve with the diameter of meshes of 8-10 mm;
storing the screened particles in a pattern spreader, starting a Teflon mesh belt of an electric heating oven, starting the pattern spreader to uniformly spread the particles on the Teflon mesh belt, and feeding the particles into the electric heating oven to fully heat and soften the materials.
A waterproof structure comprises a spraying auxiliary layer 4 formed by connecting a plurality of spraying auxiliary coiled materials in an adjacent lap joint manner; the overlapping areas of two adjacent spraying auxiliary coiled materials are bonded through an adhesive bonding agent; the top surface of the spraying auxiliary layer 4 is sprayed with a polyurea layer 5; the bottom surface of the spray auxiliary layer is bonded to the area to be constructed 8 by a bonding layer 9 made of a cement-based adhesive or cement paste.
The adhesive is prepared by mixing cement, rubber powder and water according to the weight ratio of 50:0.5: 15.
The thickness of the polyurea layer 5 is 1.5 mm.
The top surface of the polyurea layer 5 is coated with a finish protective layer 7.
The finish paint protective layer 7 is aliphatic polyaspartic acid ester paint.
The parameters of the spray auxiliary coil were as follows.
In light of the foregoing, it will be apparent to those skilled in the art from this disclosure that various changes and modifications can be made without departing from the spirit and scope of the invention. The technical scope of the present invention is not limited to the content of the specification, and must be determined according to the scope of the claims.