CN212640159U

CN212640159U - Antimony oxide processing is with waste liquid treatment device

Info

Publication number: CN212640159U
Application number: CN202021163952.2U
Authority: CN
Inventors: 龚文; 蒋贵亚
Original assignee: Guizhou Huaxing Metallurgy Co ltd
Current assignee: Guizhou Huaxing Metallurgy Co ltd
Priority date: 2020-06-22
Filing date: 2020-06-22
Publication date: 2021-03-02
Anticipated expiration: 2030-06-22

Abstract

The utility model discloses a waste liquid treatment device is used in antimony oxide processing, including handling the case, one side of handling the case is equipped with the feed liquor pipe, and the opposite side of handling the case is equipped with the fluid-discharge tube, the inner wall fixedly connected with feed liquor channel of feed liquor pipe, top outer wall one side of handling the case is equipped with the support, and the top outer wall fixedly connected with pneumatic cylinder of support, and the bottom outer wall connection of pneumatic cylinder has the connecting rod, the bottom outer wall connection of connecting rod has electrode subassembly, it is close to one side outer wall fixedly connected with scraper blade ware of support to handle the case, and is connected between the output of scraper blade ware and the electrode subassembly. The utility model is used for combine the equipment that electrochemistry method and coagulation method handled antimony-containing waste water, at first get rid of the antimony in some waste water through the electrochemistry method, then further remove antimony through the coagulation method, it is effectual to remove antimony, and the processing time is short, and the cost is lower, and equipment area is little, can handle antimony-containing waste water in a large number.

Description

Antimony oxide processing is with waste liquid treatment device

Technical Field

The utility model relates to an antimony oxide processing technology field especially relates to a waste liquid treatment device is used in antimony oxide processing.

Background

Antimony oxide is a chemical component, and comprises antimony trioxide Sb2O3 and antimony pentoxide Sb2O 5. Antimony trioxide is a white cubic crystal, is soluble in hydrochloric acid and tartaric acid, and is insoluble in water and acetic acid. Antimony pentoxide is a pale yellow powder, insoluble in water and slightly soluble in alkali, and can produce antimonate.

In the current antimony oxide production and processing process, antimony content is high in the waste liquid that produces, and antimony content is higher can produce heavy metal pollution, influences the environment, and current waste liquid is handled through chemical agent, and equipment takes up an area of greatly, and is not enough in the recovery of antimony in the waste liquid, the wasting of resources.

SUMMERY OF THE UTILITY MODEL

The utility model aims at solving the defects existing in the prior art and providing a waste liquid treatment device for processing antimony oxide.

In order to achieve the above purpose, the utility model adopts the following technical scheme:

a waste liquid treatment device for antimony oxide processing comprises a treatment box, wherein a liquid inlet pipe is arranged on one side of the treatment box, a liquid discharge pipe is arranged on the other side of the treatment box, a liquid inlet channel is fixedly connected to the inner wall of the liquid inlet pipe, a support is arranged on one side of the outer wall of the top of the treatment box, a hydraulic cylinder is fixedly connected to the outer wall of the top of the support, a connecting rod is connected to the outer wall of the bottom of the hydraulic cylinder, an electrode assembly is connected to the outer wall of the bottom of the connecting rod, a scraper blade is fixedly connected to the outer wall of one side, close to the support, of the treatment box, the output end of the scraper blade is connected with the electrode assembly, a dispenser is fixedly connected to the outer wall of one side, far away from the liquid inlet pipe, a cavity is arranged on the inner wall of the, the outer wall of the top end of the stainless steel plate is fixedly connected to the outer wall of the upper electrode fixing plate, the outer wall of the bottom end of the titanium-based coating electrode is fixedly connected to the outer wall of the lower electrode fixing plate, and the stainless steel plate and the titanium-based coating electrode are distributed in a staggered mode.

As a further proposal of the utility model, the outer wall of the upper electrode fixing plate is fixed with a controller through bolts, and the controller is connected with the stainless steel plate and the titanium-based coating electrode through wires.

As a further proposal, the stirring unit comprises a stirring motor and a stirring impeller, and the inner wall middle part of the stirring impeller is sleeved on the outer wall of the output shaft of the stirring motor.

As a further aspect of the present invention, the dispenser includes a storage and an air pump, a dispensing tube, and the bottom outer wall of the dispensing tube is fixedly connected to the outer wall of the storage, the output end of the air pump is connected to the bottom outer wall of the storage.

As a further aspect of the present invention, the scraper comprises a vibration motor and a scraper grid, and the scraper grid is slidably connected to the outer wall of the stainless steel plate, the output end of the vibration motor is connected to the outer wall of the scraper grid.

As a further scheme of the utility model, pneumatic cylinder, air pump and agitator motor all are connected with the switch, and the switch is connected with the PLC controller through the wire.

As a further scheme of the utility model, still include the side direction pneumatic cylinder, the outer wall of side direction pneumatic cylinder is crisscross to be fixed on the both sides outer wall of handling the case, and the output of side direction pneumatic cylinder is connected with the side of last electrode fixing plate, bottom electrode fixing plate.

The utility model has the advantages that:

1. the antimony oxide processing waste liquid treatment device is used for equipment for treating antimony-containing waste water by combining an electrochemical method and a coagulation method, firstly, antimony in a part of waste water is removed by the electrochemical method, and then, antimony is further removed by the coagulation method, so that the antimony removal effect is good, the treatment time is short, the cost is lower, the equipment floor area is small, and a large amount of antimony-containing waste water can be treated;

2. the electrochemical method in the antimony oxide processing waste liquid treatment device adopts a direct current power supply, adopts a titanium-based coating electrode as an anode and stainless steel as a cathode, and forms a plurality of electrode structures in a treatment box by staggered distribution and fixation between the two electrodes, so that the treatment efficiency can be improved, and the control efficiency is controlled by utilizing the positive facing area of the electrodes to achieve the control effect;

3. the reagent used by the coagulation method in the antimony oxide processing waste liquid treatment device is ferric chloride and anionic polyacrylamide, the ferric chloride and the anionic polyacrylamide are put in through the lateral dispenser in a controlled amount, and are combined on a stainless steel plate after being clarified, flocs combined on the plate body can be conveniently removed by utilizing a scraper, and the subsequent collection and reutilization are realized.

Drawings

FIG. 1 is a schematic perspective view of an embodiment 1 of a waste liquid treatment apparatus for antimony oxide processing according to the present invention;

FIG. 2 is a schematic top view of the antimony oxide processing waste liquid treatment apparatus of example 1;

FIG. 3 is a schematic structural view of an electrode assembly of example 1 of a waste liquid treatment apparatus for antimony oxide processing according to the present invention;

fig. 4 is a schematic structural view of an electrode assembly of embodiment 2 of the waste liquid treatment device for processing antimony oxide of the present invention.

In the figure: the device comprises a base 1, a treatment box 2, a liquid discharge pipe 3, an electrode assembly 4, a scraper 5, a controller 6, a support 7, a hydraulic cylinder 8, a dispenser 9, a liquid inlet pipe 10, a stirring unit 11, a liquid inlet channel 12, a connecting rod 13, an upper electrode fixing plate 14, a stainless steel plate 15, a titanium-based coating electrode 16, a lower electrode fixing plate 17 and a lateral hydraulic cylinder 18.

Detailed Description

The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments.

Example 1

Referring to fig. 1-3, a waste liquid treatment device for antimony oxide processing, comprises a treatment box 2, a liquid inlet pipe 10 is arranged on one side of the treatment box 2, a liquid discharge pipe 3 is arranged on the other side of the treatment box 2, a liquid inlet channel 12 is fixedly connected to the inner wall of the liquid inlet pipe 10, a support 7 is arranged on one side of the outer wall of the top of the treatment box 2, a hydraulic cylinder 8 is fixedly connected to the outer wall of the top of the support 7, a connecting rod 13 is connected to the outer wall of the bottom of the hydraulic cylinder 8, an electrode assembly 4 is connected to the outer wall of the bottom of the connecting rod 13, a scraper 5 is fixedly connected to the outer wall of one side of the treatment box 2 close to the support 7, the output end of the scraper 5 is connected with the electrode assembly 4, a dispenser 9 is fixedly connected to the outer wall of one side of the treatment box 2 far away, The device comprises a lower electrode fixing plate 17, a stainless steel plate 15 and a titanium-based coating electrode 16, wherein the outer wall of the top end of the stainless steel plate 15 is fixedly connected to the outer wall of an upper electrode fixing plate 14, the outer wall of the bottom end of the titanium-based coating electrode 16 is fixedly connected to the outer wall of the lower electrode fixing plate 17, the stainless steel plate 15 and the titanium-based coating electrode 16 are distributed in a staggered mode, a controller 6 is fixed to the outer wall of the upper electrode fixing plate 14 through bolts, the controller 6 is connected with the stainless steel plate 15 and the titanium-based coating electrode 16 through wires, a stirring unit 11 comprises a stirring motor and a stirring impeller, the middle part of the inner wall of the stirring impeller is sleeved on the outer wall of an output shaft of the stirring motor, a dispenser 9 comprises a storage device, an air pump and a dispensing pipe, the outer wall of the bottom end of the dispensing pipe is fixedly, and scraper blade grid sliding connection is on corrosion resistant plate 15's outer wall, and vibrating motor's output is connected on scraper blade grid's outer wall, and pneumatic cylinder 8, air pump and agitator motor all are connected with the switch, and the switch is connected with the PLC controller through the wire.

The working principle of the embodiment is as follows: this waste liquid treatment device is used in antimony oxide processing when using, let in the waste liquid through feed liquor pipe 10, put in the chlorinated high-iron in proper order through dispenser 9, anion type polyacrylamide, utilize clarification after the stirring of stirring unit 11, carry out the electrolysis to internal solution, electrode fixing plate 14 is transferred on 8 controls through pneumatic cylinder, it is opposite mutually parallel between corrosion resistant plate 15 and the titanium base coating electrode 16, utilize controller 6 control electric quantity, guarantee its treatment rate, then utilize scraper blade 5 to combine impurity and flocculation thing on corrosion resistant plate 15 to clear up, be convenient for follow-up reuse.

Example 2

Referring to fig. 4, the present embodiment is different from embodiment 1 in that the present embodiment further includes lateral hydraulic cylinders 18, outer walls of the lateral hydraulic cylinders 18 are fixed to outer walls of two sides of the treatment tank 2 in a staggered manner, and output ends of the lateral hydraulic cylinders 18 are connected to side edges of the upper electrode fixing plate 14 and the lower electrode fixing plate 17.

The working principle of the embodiment is as follows: based on the working principle of the embodiment 1, the electrode assembly 4 which moves up and down is changed into the electrode assembly which is pulled left and right, and the lateral hydraulic cylinder 18 is used for replacing the hydraulic cylinder 8, so that the internal electrode assembly is prevented from being disconnected during control effect, the electrode is exposed in the air, subsequent electrolysis operation is influenced, and impurity treatment in wastewater is not facilitated.

In the description of the present invention, it is to be understood that the terms "coaxial", "bottom", "one end", "top", "middle", "other end", "upper", "one side", "top", "inner", "front", "center", "both ends", "first", "second", etc. indicate the orientation or positional relationship based on the orientation or positional relationship shown in the drawings, and are only for convenience of description and simplicity of description, and do not indicate or imply that the device or element referred to must have a particular orientation, be constructed and operated in a particular orientation, and therefore should not be construed as limiting the present invention.

In the description of this patent, it is noted that unless otherwise specifically stated or limited, the terms "mounted," "connected," and "disposed" are to be construed broadly and can include, for example, fixedly connected, disposed, detachably connected, disposed, or integrally connected and disposed. The specific meaning of the above terms in this patent may be understood by those of ordinary skill in the art as appropriate.

The above, only be the concrete implementation of the preferred embodiment of the present invention, but the protection scope of the present invention is not limited thereto, and any person skilled in the art is in the technical scope of the present invention, according to the technical solution of the present invention and the utility model, the concept of which is equivalent to replace or change, should be covered within the protection scope of the present invention.

Claims

1. The utility model provides a waste liquid treatment device is used in antimony oxide processing, includes handles case (2), its characterized in that, one side of handling case (2) is equipped with feed liquor pipe (10), and the opposite side of handling case (2) is equipped with fluid-discharge tube (3), the inner wall fixedly connected with feed liquor channel (12) of feed liquor pipe (10), top outer wall one side of handling case (2) is equipped with support (7), and the top outer wall fixedly connected with pneumatic cylinder (8) of support (7), and the bottom outer wall of pneumatic cylinder (8) is connected with connecting rod (13), the bottom outer wall of connecting rod (13) is connected with electrode subassembly (4), one side outer wall fixedly connected with scraper blade (5) that handle case (2) is close to support (7), and be connected between the output of scraper blade (5) and electrode subassembly (4), one side outer wall fixedly connected with dispenser (9) that handle case (2) kept away from feed liquor pipe (10), the bottom inner wall of processing case (2) is equipped with the cavity, and the inner wall of cavity is equipped with stirring unit (11), electrode subassembly (4) are including last electrode fixing plate (14), bottom electrode fixing plate (17), corrosion resistant plate (15) and titanium base coating electrode (16), the top outer wall fixed connection of corrosion resistant plate (15) is on the outer wall of last electrode fixing plate (14), and the bottom outer wall fixed connection of titanium base coating electrode (16) is on the outer wall of bottom electrode fixing plate (17), crisscross distribution between corrosion resistant plate (15) and the titanium base coating electrode (16).

2. The antimony oxide processing waste liquid treatment device as claimed in claim 1, wherein a controller (6) is fixed on the outer wall of the upper electrode fixing plate (14) through bolts, and the controller (6) is connected with the stainless steel plate (15) and the titanium-based coating electrode (16) through wires.

3. The antimony oxide processing waste liquid treatment device as claimed in claim 1, wherein the stirrer set (11) comprises a stirring motor and a stirring impeller, and the middle part of the inner wall of the stirring impeller is sleeved on the outer wall of the output shaft of the stirring motor.

4. The antimony oxide processing waste liquid treatment device according to claim 1, wherein the dispenser (9) comprises a storage, an air pump and a dispensing pipe, the outer wall of the bottom end of the dispensing pipe is fixedly connected to the outer wall of the storage, and the output end of the air pump is connected to the outer wall of the bottom end of the storage.

5. The antimony oxide processing waste liquid treatment device as claimed in claim 1, wherein the scraper (5) comprises a vibration motor and a scraper grid, the scraper grid is slidably connected to the outer wall of the stainless steel plate (15), and the output end of the vibration motor is connected to the outer wall of the scraper grid.

6. The antimony oxide processing waste liquid treatment device as claimed in claim 1, wherein the hydraulic cylinder (8), the air pump and the stirring motor are all connected with a switch, and the switch is connected with a PLC controller through a lead.

7. The antimony oxide processing waste liquid treatment device as claimed in claim 1, further comprising lateral hydraulic cylinders (18), wherein the outer walls of the lateral hydraulic cylinders (18) are fixed on the outer walls of two sides of the treatment box (2) in a staggered manner, and the output ends of the lateral hydraulic cylinders (18) are connected with the side edges of the upper electrode fixing plate (14) and the lower electrode fixing plate (17).