Novel super capacitor
Technical Field
The utility model relates to a super capacitor makes technical field, has especially related to a novel super capacitor.
Background
The super capacitor is used as an energy storage component and is widely applied to the fields of intelligent three-meter, power carrier, starting, wind energy and solar energy and the like. The super capacitor has the advantages of high power, long service life and no maintenance, is often used in harsh environments such as high altitude, underground, mountainous areas, low temperature and the like, and has strict requirements on the safety and durability of the super capacitor in order to reduce the maintenance or replacement frequency. However, some electrolyte applied to the super capacitor has extremely high requirement on the sealing performance of external packaging due to low viscosity and strong permeability, and the super capacitor often has some inherent defects during packaging, so that certain hidden trouble is left for the permeation of the electrolyte, the electrolyte is easy to permeate from a sealing part, and the electrical performance and the service life of the super capacitor are seriously influenced by leakage. The problem of leakage of the super capacitor is an industrial problem.
In the prior art, the conventional method for improving the sealing performance is a mechanical sealing mode, namely, gaps are reduced by designing the size in a tight fit mode, the sealing effect is enhanced, for example, tight contact is kept between an aluminum shell and a rubber cover and between the rubber cover and a guide pin as far as possible, but the mechanical sealing mode can generate small gaps due to small deviation or impurities in the sealing process, electrolyte with high permeability can still seep out, and the problem of liquid leakage of a product cannot be thoroughly solved.
The other method is to coat glue solution at the sealing part to avoid the seepage of trace electrolyte, usually glue solution water is adopted for dispensing at the sealing interface, and after leveling, UV curing is carried out. The glue is sealed in a dispensing mode, the place covered by the glue can prevent seepage, but the full coverage of the glue on the sealing interface is difficult to control. The surface of a rubber cover and a sealing edge of a super capacitor body are usually uneven, the sealing position is shallow, and the super capacitor is easy to overflow due to too much glue dripping; too little glue may not cover glue at some points during leveling. Furthermore, UV curing is usually a few seconds, the glue is too thin to cure; the gum was too thick and cured too quickly to level. Therefore, the dispensing process is required to be accurate and stable, and the full coverage of the sealing edge by the glue surface can be realized, so that the dispensing mode still has the risk of liquid leakage.
The other method is to adopt a plastic shell glue filling mode, namely, the super capacitor body is placed in the plastic shell firstly, then epoxy resin is filled in the glue filling mode, and then the whole super capacitor body is packaged in the plastic shell after curing, so that the electrolyte cannot seep out. At present, a plastic shell glue-pouring product is mainly used for a module with two series-connected supercapacitors and is used in a high-humidity environment. The plastic shell glue filling mode is adopted, the requirement on process accuracy is lower than that of a glue dispensing mode, the sealing effect can be better guaranteed than that of the glue dispensing mode, however, the plastic is easy to age, the adhesiveness between the aged plastic shell and the epoxy glue is poor, the plastic shell has the risk of falling off, and the plastic shell cannot play a role in protection after being aged and cracked. Moreover, the glue solution can flow to body bottom cover explosion-proof valve and influence its normal opening when the plastic casing encapsulating, because be difficult to ensure the bottom roughness when preparation plastic casing drawing of patterns, also can be in the plastic casing printing explosion-proof line sometimes, also can have the difference in height between two monomers in the module of encapsulation, has the gap between product and the plastic casing bottom for the glue solution can flow ultracapacitor system body bottom cover explosion-proof valve. If the super capacitor body is abnormal and the internal air pressure is too high, the explosion-proof valve cannot be normally opened, but is opened from the head or exploded from the middle, peripheral devices can be affected.
Therefore, the existing glue pouring method for the liquid leakage prevention plastic shell of the super capacitor has the following defects: (1) the problem that glue flows to the bottom of the super capacitor body to cover the explosion-proof valve cannot be solved, and great potential safety hazard and instability exist;
(2) when a super capacitor product needs to be subjected to a high-temperature high-humidity load life test, when the test life reaches 1500 hours, the plastic shell is aged and becomes brittle, so that a defective product or a good product without obvious aging and embrittlement also has a large potential safety hazard in actual use;
(3) in the glue solution curing process, the outer surface is cured faster, the inner glue is cured slower, if air exists in the glue solution, the glue solution is difficult to discharge, and air holes are formed and left in the curing glue. Generally, the visible curing glue (i.e. the curing glue on the outer surface) on the end face of the supercapacitor body can ensure that no air holes are generated, but the air holes are probably formed in the internal curing glue between the plastic shell and the supercapacitor body. If the glue and the plastic shell can be tightly adhered in the service cycle, even if air holes are formed in the glue and the plastic shell, the electrolyte cannot leak out. However, the plastic shell has the defect of easy aging and embrittlement, so that the plastic shell is easy to degum, namely, the super capacitor body loses the protection of the plastic shell, the leakage risk is increased, and at the moment, the leakage can overflow through the conducted air hole, so that a circuit board or other devices connected with the leakage are influenced, and a relatively large potential safety hazard is caused to a terminal product. If the internal curing adhesive covers the explosion-proof valve, the risk potential can be further increased, and the electrolyte is discharged from the head (one side of the end face of the super capacitor body) through the air hole and directly impacts a connected circuit board or other devices because the super capacitor is abnormal and the explosion-proof valve cannot be opened due to overlarge internal pressure, so that the core devices of the terminal product are easily influenced and cannot be used.
SUMMERY OF THE UTILITY MODEL
In order to solve the problem of the above-mentioned prior art, the utility model provides a supercapacitor and encapsulating method, application thereof, the utility model discloses the encapsulating method adopts metal casing and bandage to combine together, and both synergism are in order to thoroughly solve supercapacitor product weeping problem and glue solution cover explosion-proof valve problem, the utility model discloses supercapacitor can not come unstuck because of the ageing embrittlement of shell causes the weeping problem to and explosion-proof valve can't normally be opened and cause the direct impact to continuous circuit board or other devices to lead to easy damage the core device of terminal product from the head and send its unable problem of using promptly, even supercapacitor appears unusually in the life cycle also can normally open explosion-proof valve and do not influence other circuit boards or devices, guarantees the durability of supercapacitor product, stability and security.
The utility model discloses the technical problem that will solve realizes through following technical scheme:
the utility model provides a novel supercapacitor, its includes open-mouth type metal casing and supercapacitor body, the supercapacitor body is arranged in metal casing's the intracavity that holds, the terminal surface of supercapacitor body with metal casing's open-end encapsulating forms the sealing layer, the cover in the supercapacitor body outside is equipped with the bandage to glue solution flow is stopped up to the bottom when avoiding the encapsulating the explosion-proof valve of supercapacitor body.
As the utility model provides an implementation improvement mode of ultracapacitor system, the bandage is located the upside in restraint waist groove of ultracapacitor system body.
As the utility model provides an implementation improvement mode of ultracapacitor system, the bandage is located the downside in restraint waist groove of ultracapacitor system body.
As the utility model provides an implementation improvement mode of ultracapacitor system, the bandage is the sticky tape.
As the utility model provides a supercapacitor's an implementation improvement mode, the bandage is the bubble cotton.
As the utility model provides an implementation improvement mode of ultracapacitor system, the ultracapacitor system body is monomer ultracapacitor system, binary ultracapacitor system or multibody ultracapacitor system.
As an implementation improvement mode of the supercapacitor provided in the present invention, the metal casing is made of any one of aluminum and its alloy, stainless steel, copper and its alloy.
The utility model discloses in, the glue solution can be epoxy glue, acrylic acid glue, organosilicon glue, UV glue etc..
The utility model discloses following beneficial effect has:
(1) the utility model discloses the encapsulating method adopts metal casing and bandage to combine together, and both synergism are in order to thoroughly solve ultracapacitor system product weeping problem and glue solution cover explosion-proof valve problem, the utility model discloses ultracapacitor system can not come unstuck because of the ageing embrittlement of shell causes the weeping problem to and do not have the explosion-proof valve and normally open and cause to let out the core device that directly strikes continuous circuit board or other devices damage the terminal product promptly from the head and send its unable problem of using, even ultracapacitor system appears unusually also can normally open the explosion-proof valve and do not influence other circuit boards or devices in the life cycle, guarantee the durability of ultracapacitor system product, stability and security.
(2) The adhesive property of the metal shell and the glue solution is better, the metal shell and the glue solution are not degummed basically, the long-term sealing property is ensured, moreover, the binding bands are additionally arranged, the sealing layer after glue pouring and curing can be only arranged at the sealing head part, the glue consumption is less, the glue cannot flow to the bottom of the super capacitor body to seal the explosion-proof valve, namely the normal opening of the explosion-proof valve is not influenced, the shock resistance and the impact resistance of the head part of a super capacitor product can be enhanced, the internal pressure is prevented from being leaked from the head part to impact a connected circuit board or other devices as far as possible, and the air.
(3) The utility model discloses the ultracapacitor system product mainly is used in the higher or higher occasion of requirement to the prevention of liquid leakage of humidity, for example terminal products such as intelligent three meters such as intelligent water gauge, ammeter, gas meter, vehicle event data recorder, energy recuperation system, starting power supply, backup power. Adopted the utility model discloses a terminal product of ultracapacitor system product can eliminate plastic casing's potential safety hazard, not only promotes terminal product's reliability, ensures moreover that data transmission does not break.
Drawings
Fig. 1 is a schematic structural diagram of a supercapacitor product according to embodiment 1 of the present invention, wherein a metal casing is in a cross-sectional view;
fig. 2 is a schematic flow chart of a glue filling method for a supercapacitor product according to embodiment 1 of the present invention, wherein the metal casing is in a cross-sectional view;
fig. 3 is a schematic structural diagram of a supercapacitor product according to embodiment 2 of the present invention, wherein the metal shell is in a cross-sectional view;
fig. 4 is a schematic structural diagram of a supercapacitor product according to embodiment 3 of the present invention, wherein the metal casing is in a cross-sectional view.
Detailed Description
The present invention will be described in detail with reference to the following examples, which are only preferred embodiments of the present invention and are not intended to limit the present invention.
Example 1
As shown in fig. 1 and 2, the present embodiment provides a novel supercapacitor 100, which includes:
an open-type metal housing 110 having a receiving cavity 111 with a closed end 112 at one end and an open end 113 at the other end;
the supercapacitor body is a double-body supercapacitor 120, a binding band is sleeved on the outer side of the double-body supercapacitor 120, the binding band is an adhesive tape 122, and the adhesive tape can prevent adhesive solution 140 from flowing to the bottom to block an explosion-proof valve of the double-body supercapacitor 120 during adhesive filling; the position of the adhesive tape 122 is located at the lower side of the beam waist slot 121 of the double-body supercapacitor 120;
the double-body supercapacitor 120 with the adhesive tape 121 is placed in the accommodating cavity 111 of the metal shell 110;
and the sealing layer 130 is formed on the end face of the supercapacitor 120 and the open end 113 of the metal shell 110, namely, the sealing layer 130 covers the head of the supercapacitor 100 product.
As shown in fig. 2, the glue filling method of the supercapacitor 100 includes the following steps:
an open-type metal housing 110 is provided,
providing a double body supercapacitor 120; a rubber belt 121 is sleeved on the outer side of the double-body supercapacitor 120 and used for preventing the rubber solution 140 from flowing to the bottom to block the explosion-proof valve of the double-body supercapacitor 120 during rubber filling;
putting the double-body supercapacitor 120 into the accommodating cavity 111 of the metal shell 110;
and (3) performing pouring glue 140 and curing treatment on the open end 113 of the metal shell 110 and the end surface of the supercapacitor body to form a sealing layer 130.
It should be noted that the double-body supercapacitor can be connected in series or in parallel to form a supercapacitor module, and the connection mode of adjacent single supercapacitors is conventional in the art, so for convenience of illustration, the connection mode is not shown in the drawings.
Example 2
As shown in fig. 3, the present embodiment provides a novel supercapacitor, 200, which includes:
an open-type metal housing 210 having a receiving cavity 211 with a closed end 212 at one end and an open end 213 at the other end;
the super capacitor body is a single super capacitor 220, a binding band is sleeved on the outer side of the single super capacitor 220, the binding band is made of foam 222, and glue liquid can be prevented from flowing to the bottom to block an explosion-proof valve of the single super capacitor 220 during glue filling; the position of the foam 222 is located at the lower side of the beam waist groove 221 of the single supercapacitor 220;
the single super capacitor 220 with the foam 221 is arranged in the accommodating cavity 211 of the metal shell 210;
and the sealing layer 230 is formed on the end face of the single supercapacitor 220 and the open end 213 of the metal shell 210, namely, the sealing layer 230 covers the head of the supercapacitor 200 product.
The supercapacitor of the present embodiment is different from the supercapacitor of embodiment 1 in that: (1) the super capacitor body is a single super capacitor; (2) the bandage is made of foam.
Example 3
As shown in fig. 4, the present embodiment provides a supercapacitor 300, which includes:
an open-type metal housing 310 having a receiving cavity 311 with a closed end 312 at one end and an open end 313 at the other end;
the supercapacitor body is a three-body supercapacitor 320, a binding band is sleeved on the outer side of the three-body supercapacitor 320, the binding band is an adhesive tape 322, and glue can be prevented from flowing to the bottom to block an explosion-proof valve of the three-body supercapacitor 320 during glue pouring; the position of the adhesive tape 322 is located at the upper side of the beam waist slot 321 of the three-body supercapacitor 320;
the three-body super capacitor 320 with the adhesive tape 321 is arranged in the accommodating cavity 311 of the metal shell 310;
and the sealing layer 330 is formed on the end face of the three-body supercapacitor 320 and the open end 313 of the metal shell 310, namely, the sealing layer 330 covers the head of the supercapacitor 300 product.
The supercapacitor of the present embodiment is different from the supercapacitor of embodiment 1 in that: (1) the super capacitor body is a three-body super capacitor; (2) the position of the adhesive tape is positioned on the upper side of the girdling groove of the three-body supercapacitor.
The supercapacitor products of examples 1 to 3 were subjected to vibration test, salt spray test, high temperature load, cold and hot shock, high temperature and high humidity test, etc. to check the reliability of the potting product, and no liquid leakage occurred.
The operation method of each test can be seen in the standard operation method specified in the IEC62391 standard, which is specifically as follows:
vibration testing: after vibration, the user can visually see whether the glue is peeled from the shell or the product or not and whether electrolyte is leaked.
High temperature and high humidity test: and (3) placing the mixture for a period of time, such as 1000-2000H, at 65-80 ℃ and 85-90% RH, and visually checking whether liquid leakage exists.
And (3) overvoltage charging test: and (4) carrying out positive charging to ensure that the pressure is excessive, and observing whether the bottom explosion-proof valve is normally opened or not.
High-temperature load: and placing the glass tube in an oven at the temperature of 65-80 ℃ for 1000-2000H, and observing whether liquid leakage exists or not and whether the pouring glue is stripped from the shell or the product or not.
Cold and hot impact: and (3) placing the mixture for 2H at the temperature of minus 40 ℃ and 85 ℃, and visually judging whether liquid leakage exists or not and whether the pouring glue is stripped from the shell or the product or not.
And (3) salt spray testing: the product is placed in a salt spray tank for a period of time, for example, one month, and the housing and product are observed for corrosion perforations and for electrolyte leakage.
The above-mentioned embodiments only express the embodiments of the present invention, and the description thereof is specific and detailed, but the invention can not be understood as the limitation of the patent scope of the present invention, but all the technical solutions obtained by adopting the equivalent substitution or equivalent transformation should fall within the protection scope of the present invention.