CN212142641U - Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system - Google Patents

Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system Download PDF

Info

Publication number
CN212142641U
CN212142641U CN201922377424.0U CN201922377424U CN212142641U CN 212142641 U CN212142641 U CN 212142641U CN 201922377424 U CN201922377424 U CN 201922377424U CN 212142641 U CN212142641 U CN 212142641U
Authority
CN
China
Prior art keywords
wastewater
weak acid
water
acid cation
regeneration
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201922377424.0U
Other languages
Chinese (zh)
Inventor
王仁雷
唐国瑞
衡世权
时孝磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huadian Electric Power Research Institute Co Ltd
Original Assignee
Huadian Electric Power Research Institute Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huadian Electric Power Research Institute Co Ltd filed Critical Huadian Electric Power Research Institute Co Ltd
Priority to CN201922377424.0U priority Critical patent/CN212142641U/en
Application granted granted Critical
Publication of CN212142641U publication Critical patent/CN212142641U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The utility model discloses a heat-engine plant weak acid cation bed regeneration wastewater quality-divided recycling system, which comprises a weak acid cation bed, a drainage ditch, a wastewater collecting pool, a cooling tower and a desulfurization reuse water pool; the utility model discloses to the regeneration preface characteristics of weak acid cation bed, open to the pump and stop and carried out optimal design, can realize weak acid cation bed regeneration stage sparge water and regeneration waste water branch matter and collect the retrieval and utilization. In addition, a certain amount of cooling tower circulating water is introduced in the regeneration and replacement stage to dilute, neutralize and inhibit scale of the regeneration wastewater, so that scaling of calcium sulfate in a wastewater pool and a conveying pipeline can be effectively avoided, the amount of alkali used for neutralization is reduced, and the problem of recycling of weak acid cation bed regeneration wastewater is well solved.

Description

Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system
Technical Field
The utility model belongs to the technical field of industrial waste water treatment technique and specifically relates to a weak acid cation bed regeneration waste water divides matter recycling system of thermal power plant.
Background
The weak acid cation bed is a common water treatment device in a thermal power plant, generally adopts sulfuric acid regeneration, and the regeneration process comprises the following steps: stopping → backwashing → acid regeneration → replacement → forward washing → commissioning. The water for regeneration is softened water, and generally, a regeneration period is about 4 hours. All the wastewater in the regeneration stage is discharged to a wastewater collection tank through a drainage ditch at present, and the wastewater is reused or discharged after being adjusted by adding alkali and pH. However, the amount of wastewater generated by the regeneration wastewater collection treatment process is large, the wastewater is not recycled according to quality, calcium sulfate precipitates are easily formed due to the fact that the wastewater contains a large amount of calcium ions and sulfate ions, scaling is separated out in a wastewater tank, a wastewater pump and a conveying pipeline, so that blockage and equipment failure are caused, the wastewater tank is generally cleaned manually 3-4 times every year, and a wastewater discharge system is cleaned chemically in 1-2 years.
SUMMERY OF THE UTILITY MODEL
The utility model aims at the above-mentioned shortcoming and not enough to conventional technique, provide a weak acid cation bed regeneration waste water divides matter recycling system of thermal power plant, can realize regeneration stage sparge water and regeneration waste water and divide matter to retrieve, can effectively avoid calcium sulfate to appear the scale deposit in wastewater disposal basin, pipeline simultaneously to reduce neutralization alkali consumption, solve weak acid cation bed regeneration waste water recycling difficult problem betterly.
The utility model provides a technical scheme that above-mentioned problem adopted is: a heat-engine plant weak acid cation bed regeneration wastewater quality-based recycling system is characterized by comprising a weak acid cation bed, a drainage ditch, a wastewater collection pool, a cooling tower and a desulfurization reuse water pool; the regeneration outlet and the escape canal intercommunication of weak acid cation bed, escape canal and wastewater collection pond intercommunication, wastewater collection pond is connected with the alkali device, wastewater collection pond is through the water inlet intercommunication of recycled water pipe with the cooling tower, the last reclaimed water pump of installing of recycled water pipe, wastewater collection pond is still through the water inlet intercommunication in multiplexing water pipe and the multiplexing pond of desulfurization, install multiplexing water pump on the multiplexing water pipe, circulating water drain pipe and wastewater collection pond intercommunication are passed through to the outlet of cooling tower, the last circulating water drain pump of installing of circulating water drain pipe.
Further, the recovery water pump and the reuse water pump are arranged in parallel.
Furthermore, a valve is installed on the recycling water pipe, a recycling branch is led out of the recycling water pipe, the recycling branch is communicated to the waste water collecting tank, and the valve is installed on the recycling branch.
Furthermore, a valve is installed on the reuse water pipe, a recirculation branch is led out of the reuse water pipe, the recirculation branch is communicated to the waste water collecting tank, and the valve is installed on the recirculation branch.
Furthermore, a valve is arranged on the circulating water drainage pipe.
Further, the weak acid cation bed is regenerated by sulfuric acid.
Compared with the prior art, the utility model, have following advantage and effect:
1) the regeneration step sequence characteristic of the weak acid cation bed is fully utilized, backwashing and forward washing drainage with good water quality is effectively recovered, and the regeneration wastewater amount is reduced by about 50%;
2) a certain amount of circulating water is introduced into the weak acid regeneration wastewater, so that the effect of diluting can be achieved, the concentrations of calcium ions and sulfate ions in the wastewater are greatly reduced, and calcium sulfate is not easy to separate out;
3) a certain amount of circulating water is introduced into the weak acid regeneration wastewater, and the water quality stabilizer reserved in the circulating water can play a role in inhibiting calcium sulfate scaling to a certain extent;
4) circulating water (30-40 ℃) with relatively high temperature is introduced into the weak acid regeneration wastewater, so that the water temperature of the wastewater is increased, and the solubility of calcium sulfate is increased;
5) circulating water (8.5-9) with relatively high pH is introduced into the weak acid regeneration wastewater, so that an acid-base neutralization effect can be achieved, the pH value of the wastewater is increased, and the solubility of calcium sulfate is increased.
Drawings
Fig. 1 is a schematic structural diagram of an embodiment of the present invention.
In the figure: weak acid cation bed 1, escape canal 2, waste water collecting pool 3, add alkali device 4, recovery water pump 5, cooling tower 6, multiplexing water pump 7, desulfurization multiplexing pond 8, circulating water drain pump 9, recycled water pipe 10, circulating water drain pipe 11, multiplexing water pipe 12.
Detailed Description
The present invention will be described in further detail by way of examples with reference to the accompanying drawings, which are illustrative of the present invention and are not intended to limit the present invention.
Example 1.
Referring to fig. 1, in this embodiment, a weak acid cation bed regeneration wastewater quality-divided recycling system for a thermal power plant includes a weak acid cation bed 1, a drainage ditch 2, a wastewater collection tank 3, an alkali adding device 4, a recovery water pump 5, a cooling tower 6, a reuse water pump 7, a desulfurization reuse water tank 8, and a circulating water drainage pump 9.
Weak acid cation bed 1's regeneration outlet and escape canal 2 intercommunication, escape canal 2 and waste water collecting tank 3 intercommunication, waste water collecting tank 3 is connected with alkalifying device 4, waste water collecting tank 3 communicates through the water inlet of recycled water pipe 10 with cooling tower 6, install recycled water pump 5 on the recycled water pipe 10, waste water collecting tank 3 still communicates with the water inlet of the multiplexing pond 8 of desulfurization through multiplexing water pipe 12, install multiplexing water pump 7 on multiplexing water pipe 12, the outlet of cooling tower 6 passes through circulating water drain pipe 11 and waste water collecting tank 3 intercommunication, install circulating water drain pump 9 on circulating water drain pipe 11.
In this embodiment, the recycle water pump 5 and the reuse water pump 7 are arranged in parallel, and the recycle water pump 5, the reuse water pump 7 and the circulating water drain pump 9 are all provided with a plurality of.
In this embodiment, a valve is installed on the recycling water pipe 10, a recycling branch is led out from the recycling water pipe 10, the recycling branch is communicated to the waste water collecting tank 3, and the valve is installed on the recycling branch. The valve is arranged on the multiplexing water pipe 12, a recirculation branch is led out from the multiplexing water pipe 12 and communicated to the waste water collecting tank 3, and the valve is arranged on the recirculation branch. And a valve is arranged on the circulating water drainage pipe 11.
In this example, the weak acid cation bed 1 is regenerated with sulfuric acid.
The working process is as follows: the regeneration process of the weak acid cation bed 1 comprises the following steps: the process comprises the following steps of shut-down → backwashing → acid regeneration → replacement → forward washing → delivery, and the quality-based recycling process is as follows:
a) after the weak acid cation bed 1 is shut down, backwashing is firstly carried out, backwashing drainage enters a wastewater collection tank 3 through a drainage ditch 2, after backwashing is finished, a recovery water pump 5 is started, backwashing drainage is recovered to a cooling tower 6 until the wastewater collection tank 3 reaches the lowest liquid level; the backwashing drainage is close to the water quality of the raw water, the total dissolved solid is low, the turbidity is low, the hardness is low, the water quality is good, and the water quality requirement of the cooling tower for water supplement is basically met;
b) acid is fed into a weak acid cation bed 1 for regeneration and replacement, regenerated wastewater enters a wastewater collection tank 3 through a drainage ditch 2, a circulating water drainage pump 9 is started at the same time, circulating water in a cooling tower 6 is sent to the wastewater collection tank 3 to be fully mixed with the regenerated wastewater, the circulating water drainage pump 9 is stopped after replacement is finished, then an alkali adding device 4 is put into operation to adjust the pH value, a reuse water pump 7 is started after the pH value is qualified, and the mixed wastewater is sent to a desulfurization reuse water tank 8 to be used as process water supplement of a limestone-gypsum wet desulfurization system until the wastewater collection tank 3 reaches the lowest liquid level;
c) the weak acid cation bed 1 is washed before being put into operation, the forward washing drainage enters a wastewater collection pool 3 through a drainage ditch 2, and after the forward washing is finished, a recovery water pump 5 is started to recover the forward washing drainage to a cooling tower 6 until the wastewater collection pool 3 reaches the lowest liquid level; the quality of the forward washing drainage is close to that of raw water, the total dissolved solid is low, the turbidity is low, the hardness is low, the water quality is good, and the water quality requirement of a cooling tower for water supplement is basically met.
The quality-divided recycling process makes full use of the regeneration step sequence characteristic of the weak acid cation bed 1, and recycles backwashing and forward washing drainage water with better water quality to the cooling tower 6 to be used as water supplement, so that the regeneration wastewater amount is reduced by about 50%. The characteristics of high pH value, high water temperature, water stabilizer and the like of circulating water in the cooling tower 6 are fully utilized to dilute, neutralize and scale-inhibit high-salinity wastewater generated in the regeneration and replacement stages of the weak acid cation bed 1, so that scaling of calcium sulfate in the wastewater collection tank 3, the conveying pipeline and the desulfurization reuse water tank 8 can be effectively avoided, the amount of alkali used for neutralization is reduced, and the problem of recycling of weak acid regeneration wastewater is well solved.
Example 2.
A raw water pretreatment system of certain thermal power plant in Shaanxi adopts weak acid positive bed softeningThe daily average treatment capacity of the treatment process is about 20000m3Generating about 1600m of regeneration waste water3. The weak acid cation bed regeneration sequence is as follows: back washing (30 min, 120 m)3Per) → acid regeneration (90 min, 100 m)3Perh) → Displacement (30 min, 100 m)3H) → Positive Wash (60 min, 180 m)3H). The weak acid cation bed generates about 440 m of wastewater once3The content of sulfate ions in the regeneration wastewater is about 3400mg/L, and the content of calcium ions is about 2000 mg/L.
After the technology is modified, water is discharged in the back washing stage and the front washing stage (about 240 m)3) Is recycled to the cooling tower through a recycling water pump to be used as water replenishing, water discharging in the regeneration and replacement stage (about 200 m)3) Circulating water (about 350 m) with cooling tower3) And after fully mixing, recycling the mixture to a desulfurization multiplexing water tank through a multiplexing water pump to be used as process water supplement of a limestone-gypsum wet desulfurization system. Thereby reducing the amount of high-salinity wastewater by about 54 percent and reducing the annual reduction by about 30 ten thousand meters3The water-saving effect is obvious. The problem of calcium sulfate scaling in a weak acid regeneration wastewater discharge system is well solved, the annual discharge system cleaning and chemical cleaning cost is saved by about 70 ten thousand yuan, and the economic benefit is obvious.
Those not described in detail in this specification are well within the skill of the art.
Although the present invention has been described with reference to the above embodiments, it should not be construed as being limited to the scope of the present invention, and any modifications and alterations made by those skilled in the art without departing from the spirit and scope of the present invention should fall within the scope of the present invention.

Claims (5)

1. A system for recycling regenerated wastewater of a weak acid cation bed of a thermal power plant by different qualities is characterized by comprising a weak acid cation bed (1), a drainage ditch (2), a wastewater collecting pool (3), a cooling tower (6) and a desulfurization reuse water pool (8); the regeneration outlet and escape canal (2) intercommunication of weak acid cation bed (1), escape canal (2) and wastewater collection pond (3) intercommunication, wastewater collection pond (3) are connected with and add alkali device (4), wastewater collection pond (3) are through the water inlet intercommunication of recovery water pipe (10) and cooling tower (6), install recovered water pump (5) on recovered water pipe (10), wastewater collection pond (3) are still through the water inlet intercommunication of multiplexing water pipe (12) and desulfurization multiplexing pond (8), install multiplexing water pump (7) on multiplexing water pipe (12), the outlet of cooling tower (6) passes through circulating water drain pipe (11) and wastewater collection pond (3) intercommunication, install circulating water drain pump (9) on circulating water drain pipe (11).
2. The system for recycling weak acid cation bed regeneration wastewater of a thermal power plant according to claim 1, wherein the recovery water pump (5) and the reuse water pump (7) are arranged in parallel.
3. The system for recycling weak acid cation bed regeneration wastewater of a thermal power plant according to claim 1, wherein a valve is installed on the recovery water pipe (10), a recirculation branch is led out from the recovery water pipe (10), the recirculation branch is communicated to the wastewater collection tank (3), and a valve is installed on the recirculation branch.
4. The system for recycling weak acid cation bed regeneration wastewater of a thermal power plant according to claim 1, wherein a valve is installed on the reuse water pipe (12), a recirculation branch is led out from the reuse water pipe (12), the recirculation branch is communicated to the wastewater collection tank (3), and a valve is installed on the recirculation branch.
5. The system for recycling weak acid cation bed regeneration wastewater of a thermal power plant according to claim 1, wherein a valve is installed on the circulating water drainage pipe (11).
CN201922377424.0U 2019-12-26 2019-12-26 Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system Active CN212142641U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201922377424.0U CN212142641U (en) 2019-12-26 2019-12-26 Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201922377424.0U CN212142641U (en) 2019-12-26 2019-12-26 Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system

Publications (1)

Publication Number Publication Date
CN212142641U true CN212142641U (en) 2020-12-15

Family

ID=73704713

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201922377424.0U Active CN212142641U (en) 2019-12-26 2019-12-26 Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system

Country Status (1)

Country Link
CN (1) CN212142641U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111001445A (en) * 2019-12-26 2020-04-14 华电电力科学研究院有限公司 System and method for recycling weak acid cation bed regeneration wastewater of thermal power plant according to quality

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111001445A (en) * 2019-12-26 2020-04-14 华电电力科学研究院有限公司 System and method for recycling weak acid cation bed regeneration wastewater of thermal power plant according to quality

Similar Documents

Publication Publication Date Title
CN102276085B (en) Recycling treatment method for discharge water of circulating water from power plant
CN102964024B (en) Wastewater zero discharge system of chlorine-alkali industry
CN103058421A (en) Treatment method for recycling circulating sewage in power plant
CN104591444A (en) Reverse osmosis concentrated water treatment technique
CN112142233A (en) Thermal power plant circulating water and sewage water full-membrane-process zero-emission treatment system and method
CN212025040U (en) Electrodialysis desalination treatment system for circulating water and sewage of thermal power plant
CN212142641U (en) Weak acid cation bed regeneration waste water of thermal power plant divides matter recycling system
CN104086011B (en) Be applicable to the technique of zero discharge of viscose fibre industry acid station waste water
CN111001445A (en) System and method for recycling weak acid cation bed regeneration wastewater of thermal power plant according to quality
CN202865020U (en) Chlor-alkali industrial wastewater zero discharge system
CN113174598A (en) Water recycling method for tunnel type steel pipe acid pickling phosphating production line
CN202193673U (en) Sewerage reclamation treatment system for power plant circulating water
CN215102447U (en) Processing apparatus of thermal power plant waste water
CN202390285U (en) Corrugated paper wastewater recycling system
CN201835379U (en) Water-saving operation device
CN204198531U (en) One rushes version water-circulation filtering device
CN211004914U (en) Sewage treatment and purification system
CN209853921U (en) Gasification buck removes hard turbidity reduction device
CN112875804A (en) Process for reducing ultrafiltration self-water utilization rate and improving water yield recovery rate
CN203754528U (en) Device for treating waste water during production of glass
CN220364447U (en) Device for recycling regenerated wastewater of primary desalting system in segmented mode
CN201932960U (en) Washing water utilizing device for lemon acid sugar washing procedure
CN213569890U (en) Thermal power plant circulating water blowdown water full membrane method zero release processing system
CN205295026U (en) Desalinized water energy saving and emission reduction system
CN219297296U (en) Reclaimed water recycling equipment capable of realizing grouping energy-saving operation

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant