CN212127868U - Electromagnetic strong oxidation coking wastewater advanced treatment system - Google Patents
Electromagnetic strong oxidation coking wastewater advanced treatment system Download PDFInfo
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- CN212127868U CN212127868U CN201922290852.XU CN201922290852U CN212127868U CN 212127868 U CN212127868 U CN 212127868U CN 201922290852 U CN201922290852 U CN 201922290852U CN 212127868 U CN212127868 U CN 212127868U
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- electromagnetic
- water
- filter
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- oxidation reactor
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- 230000003647 oxidation Effects 0.000 title claims abstract description 47
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 47
- 239000002351 wastewater Substances 0.000 title claims abstract description 25
- 238000004939 coking Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000010865 sewage Substances 0.000 claims abstract description 5
- 230000001590 oxidative Effects 0.000 claims abstract description 4
- 210000003660 Reticulum Anatomy 0.000 claims description 18
- 239000003054 catalyst Substances 0.000 claims description 17
- 239000000945 filler Substances 0.000 claims description 10
- 210000000088 Lip Anatomy 0.000 claims description 8
- -1 polypropylene Polymers 0.000 claims description 5
- 238000005273 aeration Methods 0.000 claims description 4
- 238000004065 wastewater treatment Methods 0.000 claims description 4
- 239000004743 Polypropylene Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- CBENFWSGALASAD-UHFFFAOYSA-N ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 3
- 241000195493 Cryptophyta Species 0.000 abstract description 3
- 230000000249 desinfective Effects 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 239000007800 oxidant agent Substances 0.000 abstract description 3
- 238000006864 oxidative decomposition reaction Methods 0.000 abstract description 3
- 239000002244 precipitate Substances 0.000 abstract description 3
- 230000000191 radiation effect Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 238000000746 purification Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 230000005672 electromagnetic field Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000008235 industrial water Substances 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N Cyanogen Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 241000276438 Gadus morhua Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 238000002306 biochemical method Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019516 cod Nutrition 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000003113 dilution method Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M isothiocyanate Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- SMWDFEZZVXVKRB-UHFFFAOYSA-N quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 230000002588 toxic Effects 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
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Abstract
The utility model provides an electromagnetic strong oxidation coking wastewater advanced treatment system relating to the field of water treatment, which comprises a filter, an electromagnetic oxidation reactor, a concentrated water tank and a return water tank; the water inlet end of the filter is communicated with the sewage pipeline, the water outlet end of the filter is communicated with the water inlet end of the electromagnetic oxidation reactor, the water outlet end of the electromagnetic oxidation reactor is communicated with two water outlet branch pipes, one water outlet branch pipe is communicated with the concentrated water tank, and the other water outlet branch pipe is communicated with the water return tank; the utility model discloses under the condition that the oxidant exists, in the forceful electric magnetic field, make the harmful substance of waste water take place strong, self or passive molecule schizolysis, oxidative decomposition reaction, generate to separate away from the water for harmless gas or solid precipitate, reach waste water purification's effect, simultaneously, under the radiation effect of forceful electric magnetic field, make biological cells such as bacterium, alga decomposed, destroy and kill, reach the purpose of disinfecting, algae removal. Has the advantages of low energy consumption and high efficiency.
Description
Technical Field
The utility model belongs to the technical field of water treatment and specifically relates to an electromagnetism strong oxidation coking wastewater advanced treatment system.
Background
Since the 20 th century, the consumption of industrial water worldwide has increased by 30 times, and in Asia, the influence of industrial wastewater pollution is the most serious. In China, the reuse rate of industrial water is only 30%, the daily discharge amount of national divided water is nearly 1.64 hundred million tons, and 80% of the water is directly discharged into a water area without treatment, so that the result of 'water pollution' is caused. Wherein 60 percent of coke in the world is produced in China, and the generated coking wastewater is about 2.7 hundred million tons every year. The coking wastewater is high-concentration organic wastewater which is toxic, harmful and difficult to degrade, wherein a large amount of polycyclic aromatic hydrocarbon compounds and heterocyclic organic compounds exist, and meanwhile, cyanide, thiocyanide and sulfide with extremely high toxicity are contained, so that the treatment difficulty is high. The COD removal rate of the traditional biochemical treatment process is only 50 percent.
At present, coking wastewater treatment approaches mainly comprise a dilution biochemical method, a chemical agent treatment method and the like. Because the coking wastewater has high salt content, a large amount of process water is consumed for dilution in order to meet biochemical conditions, and in addition, heterocyclic and polycyclic aromatic compounds such as phenols, naphthalene, cyanogen, pyridine, quinoline and the like in the wastewater are difficult to biodegrade, so that the biochemical dilution method not only wastes water resources, but also has poor treatment effect, and the effluent cannot stably reach the standard. The chemical agent method removes suspended impurities and organic pollutants in the wastewater by adding a large amount of chemical agents, the effluent quality of the method is unstable, the agent cost is high, secondary pollution is caused, and the difficulty of subsequent desalination treatment is increased by adding the agents, so that the method is gradually eliminated or must be applied in cooperation with other process means at present.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing a strong oxidation coking wastewater advanced treatment system of electromagnetism to solve the difficult problem of current coking wastewater treatment.
The utility model discloses a realize like this: an electromagnetic strong oxidation coking wastewater advanced treatment system is characterized by comprising a filter, an electromagnetic oxidation reactor, a concentrated water tank and a return water tank; the water inlet end of the filter is communicated with a sewage pipeline, the water outlet end of the filter is communicated with the water inlet end of the electromagnetic oxidation reactor, the water outlet end of the electromagnetic oxidation reactor is communicated with two water outlet branch pipes, one water outlet branch pipe is communicated with the concentrated water tank, and the other water outlet branch pipe is communicated with the water return tank;
the bottom of the electromagnetic oxidation reactor is provided with an air inlet, the air inlet is connected with an ozone generator, an aeration plate is arranged at the air inlet, catalyst filler is arranged in the electromagnetic oxidation reactor, and the top of the electromagnetic oxidation reactor is provided with an air outlet; a plurality of high-voltage electrode rods are vertically arranged in the upper part of the electromagnetic oxidation reactor and are connected with a high-voltage generator; the catalyst filler is in a vertical honeycomb shape, and the high-voltage electrode rod is vertically inserted into a honeycomb hole of the catalyst filler.
Preferably, the number of the high voltage electrode rods is less than the number of the honeycomb holes.
Preferably, the catalyst packing is coated with an oxidation catalyst on its outer surface.
Preferably, a support is sleeved outside the high-voltage electrode rod, the upper end of the support is fixed on a box body of the electromagnetic oxidation reactor, a disk-shaped lip edge is arranged at the lower end of the support, and the disk-shaped lip edge abuts against the upper edge of the honeycomb hole after the high-voltage electrode rod extends into the honeycomb hole.
Preferably, a conductivity meter is arranged at the water outlet end of the electromagnetic oxidation reactor.
Preferably, the filter is one of a polypropylene wound filter element filter, a disc filter or a fiber ball filter.
Adopt above-mentioned technical scheme, the utility model discloses under the condition that the oxidant exists, in the forceful electric magnetic field, make the harmful substance of waste water take place strong, self or passive molecule schizolysis, oxidative decomposition reaction, generate to separate away from the water for harmless gas or solid precipitate, reach waste water purification's effect, simultaneously, under the radiation effect of forceful electric magnetic field, make biological cells such as bacterium, alga decomposed, destroy and kill, reach the purpose of disinfecting, algae removal. Has the advantages of low energy consumption and high efficiency.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
Fig. 1 is a schematic structural diagram of the present invention;
fig. 2 is a schematic structural diagram of the catalyst packing of the present invention.
In the figure: 1-filter, 2-electromagnetic oxidation reactor, 3-high voltage electrode bar, 4-concentrated water tank, 5-return water tank, 6-air inlet, 7-ozone generator, 8-aeration plate, 9-catalyst filler, 10-high voltage generator, 11-conductivity meter, 12-support, 13-disk lip.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative work belong to the protection scope of the present invention.
As shown in figure 1 and figure 2, the utility model provides an electromagnetic strong oxidation coking wastewater advanced treatment system, which comprises a filter 1, an electromagnetic oxidation reactor 2, a concentrated water tank 4 and a return water tank 5. Wherein, the water inlet end of the filter 1 is communicated with the sewage pipeline, and the water outlet end of the filter 1 is communicated with the water inlet end of the electromagnetic oxidation reactor 2. The filter 1 is one of a polypropylene wire-wound filter element filter, a disc filter or a fiber ball filter, the filter 1 is used for primary filtering of wastewater discharged from a sewage pipe, and large-particle impurities in the wastewater are trapped in the filter 1.
The water outlet end of the electromagnetic oxidation reactor 2 is communicated with two water outlet branch pipes, one water outlet branch pipe is communicated with the concentrated water tank 4, and the other water outlet branch pipe is communicated with the water return tank 5. An air inlet 6 is arranged at the bottom of the electromagnetic oxidation reactor 2, the air inlet 6 is connected with an ozone generator 7, an aeration plate 8 is arranged at the air inlet 6, a catalyst filler 9 is arranged at the lower part in the electromagnetic oxidation reactor 2, the catalyst filler 9 is in a honeycomb shape, and an oxidation catalyst is coated on the outer surface of the catalyst filler 9. A plurality of high-voltage electrode rods 3 are vertically arranged at the upper part in the electromagnetic oxidation reactor, and the high-voltage electrode rods 3 are connected with a high-voltage generator 10. The high voltage electrode bar 3 is vertically inserted into the honeycomb holes of the catalyst packing 9. Wherein the number of the high voltage electrode rods is less than that of the honeycomb holes.
The outer part of the high-voltage electrode rod 3 is sleeved with a support 12, the upper end of the support 12 is fixed on a box body of the electromagnetic oxidation reactor, the lower end of the support 12 is provided with a disk-shaped lip 13, and after the high-voltage electrode rod 3 extends into a honeycomb hole, the disk-shaped lip 13 is abutted against the upper edge of the honeycomb hole. The support 12 is made of hard insulating materials, and plays a role in supporting and protecting the high-voltage electrode rod, after the high-voltage electrode rod extends into the honeycomb holes, the high-voltage electrode rod is limited at the high-low position in the honeycomb holes under the supporting effect of the support and the disc-shaped lip edges, and the high-voltage electrode rod is not prone to shaking in the honeycomb holes. In the oxidation electrolysis process, the high-voltage electrode bar is not influenced by bubbles and water flow, the position is stable, and the safety of the system is ensured.
A conductivity meter 11 is arranged at the water outlet end of the electromagnetic oxidation reactor. Whether the motor is close to saturation can be judged through the conductivity of the discharged water, when the motor is close to saturation, the high-voltage electrode rod is powered off, ions are desorbed from the electrode rod, water continues to be supplied, and the discharged water is concentrated water.
The utility model discloses well strong electric field coexists with strong oxidation, under the condition that the oxidant exists, in strong electromagnetic field, make the harmful substance of waste water take place strong, self or passive molecule schizolysis, oxidative decomposition reaction, the formation is isolated from the water for harmless gas or solid precipitate, reaches the effect that waste water purifies, simultaneously, under strong electromagnetic field's radiation effect, makes biological cells such as bacterium, alga decomposed, destroys and kills, reaches the purpose of disinfecting, algae removal. Has the advantages of low energy consumption and high efficiency.
Claims (6)
1. An electromagnetic strong oxidation coking wastewater advanced treatment system is characterized by comprising a filter, an electromagnetic oxidation reactor, a concentrated water tank and a return water tank; the water inlet end of the filter is communicated with a sewage pipeline, the water outlet end of the filter is communicated with the water inlet end of the electromagnetic oxidation reactor, the water outlet end of the electromagnetic oxidation reactor is communicated with two water outlet branch pipes, one water outlet branch pipe is communicated with the concentrated water tank, and the other water outlet branch pipe is communicated with the water return tank;
the bottom of the electromagnetic oxidation reactor is provided with an air inlet, the air inlet is connected with an ozone generator, an aeration plate is arranged at the air inlet, catalyst filler is arranged in the electromagnetic oxidation reactor, and the top of the electromagnetic oxidation reactor is provided with an air outlet; a plurality of high-voltage electrode rods are vertically arranged in the upper part of the electromagnetic oxidation reactor and are connected with a high-voltage generator; the catalyst filler is in a vertical honeycomb shape, and the high-voltage electrode rod is vertically inserted into a honeycomb hole of the catalyst filler.
2. A strong electromagnetic oxidative coking wastewater advanced treatment system as set forth in claim 1, wherein the number of the high voltage electrode bars is less than the number of the honeycomb holes.
3. The deep electromagnetic strong oxidation coking wastewater treatment system of claim 1, characterized in that the outer surface of the catalyst packing is coated with an oxidation catalyst.
4. The deep treatment system of electromagnetic strong oxidation coking wastewater according to claim 1, characterized in that a support is sleeved outside the high-voltage electrode rod, the upper end of the support is fixed on the box body of the electromagnetic oxidation reactor, the lower end of the support is provided with a disk-shaped lip edge, and after the high-voltage electrode rod extends into the honeycomb holes, the disk-shaped lip edge abuts against the upper edges of the honeycomb holes.
5. The deep treatment system for electromagnetic strong oxidation coking wastewater as claimed in claim 1, wherein a conductivity meter is arranged at the water outlet end of the electromagnetic oxidation reactor.
6. The deep electromagnetic strong oxidation coking wastewater treatment system of claim 1, wherein the filter is one of a polypropylene wound filter element filter, a disc filter or a fiber ball filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201922290852.XU CN212127868U (en) | 2019-12-18 | 2019-12-18 | Electromagnetic strong oxidation coking wastewater advanced treatment system |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201922290852.XU CN212127868U (en) | 2019-12-18 | 2019-12-18 | Electromagnetic strong oxidation coking wastewater advanced treatment system |
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| Publication Number | Publication Date |
|---|---|
| CN212127868U true CN212127868U (en) | 2020-12-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201922290852.XU Expired - Fee Related CN212127868U (en) | 2019-12-18 | 2019-12-18 | Electromagnetic strong oxidation coking wastewater advanced treatment system |
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| CN (1) | CN212127868U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112979071A (en) * | 2021-02-24 | 2021-06-18 | 北京启元汇通水务科技股份有限公司 | Industrial wastewater treatment standard-reaching direct-discharge system and process method |
| CN112979039A (en) * | 2021-02-24 | 2021-06-18 | 北京启元汇通水务科技股份有限公司 | Industrial wastewater deep oxidation treatment system and treatment method |
-
2019
- 2019-12-18 CN CN201922290852.XU patent/CN212127868U/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112979071A (en) * | 2021-02-24 | 2021-06-18 | 北京启元汇通水务科技股份有限公司 | Industrial wastewater treatment standard-reaching direct-discharge system and process method |
| CN112979039A (en) * | 2021-02-24 | 2021-06-18 | 北京启元汇通水务科技股份有限公司 | Industrial wastewater deep oxidation treatment system and treatment method |
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| Date | Code | Title | Description |
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20201211 Termination date: 20211218 |