CN211921402U - Flexible electronic device intermediate layer - Google Patents
Flexible electronic device intermediate layer Download PDFInfo
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- CN211921402U CN211921402U CN202020224335.2U CN202020224335U CN211921402U CN 211921402 U CN211921402 U CN 211921402U CN 202020224335 U CN202020224335 U CN 202020224335U CN 211921402 U CN211921402 U CN 211921402U
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Abstract
The utility model provides a flexible electron device intermediate level. The flexible electronic device interlayer comprises: the flexible electronic device comprises a flexible electronic device, adhesive films arranged on one side or two sides of the flexible electronic device, and release films optionally arranged on the outer sides of the adhesive films. The preparation process comprises the following steps: unreeling a flexible electronic device coil stock; and continuously attaching the packaging film to one side or two sides of the flexible electronic device by a rolling method to obtain the middle layer of the flexible electronic device. The utility model provides a flexible electron device intermediate level can play the guard action to flexible electron device, avoids flexible electron device by the fish tail or receive the influence of factors such as ultraviolet ray, water, oxygen in storage, transportation and encapsulation process, can compound with shell materials such as glass more easily, has improved the production efficiency of low reaches product, can not change current encapsulation equipment, technology and operation method, and the facilitate promotion is used.
Description
Technical Field
The utility model belongs to the technical field of flexible electron device, concretely relates to flexible electron device intermediate level.
Background
With the development of electronic information technology, flexible intelligent devices become more and more the mainstream of current intelligent devices, such as flexible solar cells, flexible thin film batteries, flexible thin film capacitors, flexible OLEDs, flexible electronic writing paper, flexible thin film sensors, flexible thermochromic thin films, flexible photochromic thin films, flexible electrochromic thin films and other flexible electronic devices. Taking a flexible electrochromic film as an example, the market demand of the flexible electrochromic film in intelligent equipment is increasingly strong. Electrochromism refers to a phenomenon in which optical properties (reflectivity, transmittance, absorption, and the like) of a material are stably and reversibly changed by an applied electric field, and is visually represented as reversible changes in color and/or transparency. Materials having electrochromic properties are referred to as electrochromic materials, and devices made with electrochromic materials are referred to as electrochromic devices. At present, industrialized electrochromic devices comprise electrochromic intelligent dimming glass, electrochromic displays, automatic anti-glare rearview mirrors of automobiles and the like, and have huge application markets in the fields of automobiles, airplanes, intelligent buildings and the like. Emerging flexible thin film electrochromic devices have become a hotspot for research. The flexible electrochromic film has the advantages of simple processing technology, controllable cost and the like, can be manufactured by roll-to-roll and is convenient for large-scale production.
However, in the existing packaging process of the flexible electrochromic film, a layer of glue and a layer of electrochromic film are generally laminated on a carrier such as glass layer by layer on the basis of a sheet type flexible electrochromic film. The process is complicated, the mass production efficiency is not high, the error is large during stacking, and a large amount of manpower and material resources need to be paid. In addition, the common base material of the flexible electrochromic film is a flexible material, and the flexible electrochromic film is easily scratched and deformed in the processes of storage and transportation before being packaged, and is also easily influenced by ultraviolet rays, water, oxygen and the like when being exposed in the air. Therefore, the existing flexible electrochromic film is difficult to store, complicated to package and not suitable for being directly sold as a product. Also, the above-mentioned drawbacks exist in other flexible electronic devices.
Therefore, in order to overcome the above drawbacks, a new product capable of protecting the flexible electronic device and improving the packaging efficiency is to be researched.
SUMMERY OF THE UTILITY MODEL
Not enough to prior art exists, the utility model aims to provide a flexible electron device intermediate level. The utility model provides a flexible electron device intermediate level can play the guard action to flexible electron device, avoids flexible electron device by the fish tail or receive the influence of factors such as ultraviolet ray, water, oxygen in storage, transportation and encapsulation process, and this flexible electron device intermediate level can not change current encapsulation equipment, technology and operation method, and the facilitate promotion is used.
To achieve the purpose, the utility model adopts the following technical proposal:
the utility model provides a flexible electron device intermediate level, the flexible electron device intermediate level includes: the flexible electronic device comprises a flexible electronic device, adhesive films arranged on one side or two sides of the flexible electronic device, and release films optionally arranged on the outer sides of the adhesive films.
The utility model discloses in flexible electron device includes the electron device that flexibility needs encapsulation such as flexible solar cell, flexible film battery, flexible film electric capacity, flexible OLED, flexible electron writing paper, flexible film sensor, flexible thermochromic film, flexible photochromic film, flexible electrochromic film. For convenience of explanation, the flexible electronic device takes the flexible electrochromic film as an example, and details of the structure and the preparation process of the flexible electronic device intermediate layer of the invention are described below; it can be understood that the structure and the preparation process of other flexible electronic device intermediate layers are all similar to the above, and the utility model discloses no longer give unnecessary details one by one, but all should be contained in the protection scope of the utility model. Specifically, the flexible electrochromic film refers to a flexible electrochromic device film including a multi-layered structure such as a substrate, a conductive layer, an electrochromic layer, an electrolyte layer, an ion storage layer, and the like.
The above-mentioned "release film optionally provided on the outer side of the adhesive film" means that the release film may or may not be provided on the outer side of the adhesive film. The "outer side of the adhesive film" refers to the side of the adhesive film away from the flexible electrochromic film. In the art, a common intermediate layer (interlayer) generally refers to an adhesive film, and in the present invention, when the flexible electronic device is a flexible electrochromic film, the provided product has an electrochromic function and can be used like an adhesive film, and can be referred to as a flexible electrochromic intermediate layer; when the flexible electronic device is other devices listed above, such as a flexible solar cell, it may be referred to as a flexible solar cell interlayer. Therefore, to the utility model discloses all kinds of flexible electron device that the aforesaid enumerated, the utility model provides a product is collectively called flexible electron device intermediate level.
In the utility model, when both sides of the flexible electronic device are provided with the glue films, the glue films on both sides are mutually independent, can be the same or different; the outer sides of the two side adhesive films can be mutually independently arranged or not provided with release films. Specifically, use flexible electron device as flexible electrochromic film for the example, the utility model provides a flexible electron device intermediate level includes following five kinds of structures:
in an embodiment of the present invention, the flexible electronic device intermediate layer includes: the flexible electrochromic film and set up in flexible electrochromic film one side glued membrane.
In an embodiment of the present invention, the flexible electronic device intermediate layer includes: the flexible electrochromic film, set up in flexible electrochromic film one side glued membrane, and set up in the type membrane of gluing the membrane outside.
In an embodiment of the present invention, the flexible electronic device intermediate layer includes: the flexible electrochromic film comprises a flexible electrochromic film and a first adhesive film and a second adhesive film which are respectively arranged on two sides of the flexible electrochromic film.
In an embodiment of the present invention, the flexible electronic device intermediate layer includes: the flexible electrochromic film, set up respectively in first glued membrane and the second glued membrane of flexible electrochromic film both sides to and set up in the first glued membrane outside is from the type membrane.
In an embodiment of the present invention, the flexible electronic device intermediate layer includes: the flexible electrochromic film, set up respectively in the first glued membrane and the second glued membrane of flexible electrochromic film both sides to and set up in the first glued membrane outside is from type membrane and set up in the second glued membrane outside is from type membrane. Generally, the flexible electronic device intermediate layer adopts such a structure.
When the flexible electronic device in the prior art, such as an electrochromic film, is applied to a downstream product, double-sided glue needs to be sandwiched layer by layer one by one, a large amount of manpower and material resources need to be consumed, and the production efficiency is low; meanwhile, the electrochromic film is easy to scratch and deform in the storage and transportation processes, and is easily influenced by ultraviolet rays, water, oxygen and the like, so that the electrochromic film is difficult to store, is complicated to package and is not suitable to be directly sold as a product.
The utility model provides a flexible electron device intermediate level is the intermediate product of the flexible electron device product after the preparation encapsulation, and it can play the guard action to electrochromic film, avoids electrochromic film by the fish tail or receive the influence of factors such as ultraviolet ray, water, oxygen in storage, transportation and encapsulation process. When the flexible electronic device intermediate layer is used, the release film is removed (if the release film exists), the existing common intermediate layer can be directly replaced to be compounded with shell materials such as glass, and the encapsulated electrochromic device product is prepared without changing the existing encapsulation equipment, process and operation method, so that the flexible electronic device intermediate layer is convenient to popularize and apply; compared with the traditional independent chip type electrochromic thin film, in the process of directly preparing the electrochromic laminated glass by using the flexible electronic device intermediate layer, the lamination does not need to be placed layer by layer, so that the production efficiency of downstream products is improved. Similarly, to other flexible electron device, like flexible solar cell, flexible film battery, flexible film electric capacity, flexible OLED, flexible electron writing paper, flexible film sensor, flexible thermochromism film, flexible photochromism film and other flexible electron device that the flexibility needs the encapsulation, the utility model provides a flexible electron device intermediate level, it also can play the guard action to the flexible electron device of encapsulation in.
In one embodiment of the present invention, the thickness of the flexible electronic device is 10 to 10000 μm, for example, 10 μm, 20 μm, 30 μm, 40 μm, 50 μm, 60 μm, 70 μm, 80 μm, 90 μm, 100 μm, 120 μm, 150 μm, 180 μm, 200 μm, 220 μm, 250 μm, 280 μm, 300 μm, 320 μm, 350 μm, 380 μm, 400 μm, 450 μm, 500 μm, 550 μm, 600 μm, 650 μm, 700 μm, 750 μm, 800 μm, 850 μm, 900 μm, 950 μm, 1000 μm, 2000 μm, 3000 μm, 5000 μm, 8000 μm, 10000 μm, or the like; more preferably 100-400 μm.
In one embodiment of the present invention, the thickness of the adhesive film is 10 to 3000 μm, for example, 10 μm, 20 μm, 30 μm, 40 μm, 50 μm, 60 μm, 70 μm, 80 μm, 90 μm, 100 μm, 120 μm, 150 μm, 180 μm, 200 μm, 220 μm, 250 μm, 280 μm, 300 μm, 320 μm, 350 μm, 380 μm, 400 μm, 450 μm, 500 μm, 550 μm, 600 μm, 650 μm, 700 μm, 750 μm, 760 μm, 800 μm, 850 μm, 900 μm, 950 μm, 1000 μm, 1200 μm, 1500 μm, 2000 μm, 2200 μm, 2500 μm, 2800 μm or 3000 μm; more preferably 100-400 μm.
The utility model discloses in, when flexible electron device both sides all were provided with the glued membrane, the glued membrane of both sides is mutually independent, and its thickness, material etc. can be the same, also can be different.
In one embodiment of the present invention, the thickness of the release film is 1000 μm or less, for example, 1000 μm, 900 μm, 800 μm, 700 μm, 600 μm, 500 μm, 400 μm, 380 μm, 350 μm, 320 μm, 300 μm, 280 μm, 250 μm, 220 μm, 200 μm, 180 μm, 150 μm, 120 μm, 100 μm, 90 μm, 80 μm, 70 μm, or 50 μm; more preferably 200 μm or less.
In an embodiment of the present invention, the width of the adhesive film is greater than or equal to the width of the flexible electronic device.
By using a wider adhesive film, the edge sealing section can be arranged on the edge of the middle layer of the flexible electronic device after the layers are compounded. The compounding of the edge adhesive film can be carried out while the rolling compounding is carried out in the area of the flexible electronic device; or the area of the middle flexible electronic device can be firstly rolled and compounded, and then the glue films at the edges can be rolled and compounded by another pair of rollers. Generally, a softer rubber roller (hardness less than or equal to 70A, preferably less than or equal to 50A) can be used. The width of the sealing edge depends on the thickness of the inner flexible electronic device and the thickness of the adhesive film. The flexible electronic device intermediate layer with the edge sealing section can be directly packaged and used subsequently, and the edge sealing section can be cut off and used.
In one embodiment of the present invention, the adhesive film is transparent, translucent, opaque, light-filtering, colored, specular-reflecting, or haze-containing.
The utility model discloses in, the glued membrane material can be as required (for example decorative, functional) decorate and make the product obtain specific nature. For example, by doping with a particular substance (e.g., TiO)2Powder, SiO2Powder, Al2O3Powder or nano-particle, etc.), dye pigment, control of local crystallinity and degree of crosslinking, to control color, haze, increase or decrease of productThe product has the advantages of reducing absorption and/or reflection of electromagnetic waves with specific wavelengths, further forming specific patterns on the product, and realizing the functions of blocking ultraviolet rays, blocking infrared rays, reflecting ultraviolet rays, reflecting infrared rays, transmitting 4g or 5g communication signals and the like.
In an embodiment of the present invention, the adhesive film is a pressure-sensitive adhesive film or a hot-melt adhesive film.
For example, the main material of the pressure-sensitive adhesive film may be rubber, polyacrylate, polyvinyl ether, ethylene and its copolymer, EVA (ethylene-vinyl acetate copolymer), EEA (ethylene-ethyl acrylate copolymer), EAA (ethylene-acrylic acid copolymer), EVAL (ethylene-vinyl acetate-vinyl alcohol terpolymer), polyurethane, polyester, polyvinyl chloride, or silicone.
For example, the main material of the hot melt adhesive film may be ethylene and its copolymer, ethylene and vinyl acetate copolymer, polyamide, polyolefin hot melt adhesive (e.g. PE, PP), polystyrene (e.g. SBS, SIS), amorphous α -olefin copolymer, Thermoplastic Polyurethane (TPU), polyvinyl butyral (PVB), polyester, ionic resin, or silicone.
The utility model discloses it is right the preparation technology in flexible electron device intermediate level does not have special restriction, exemplarily, can adopt following technology:
(1) unreeling a flexible electronic device coil stock;
(2) continuously attaching packaging films to one side or two sides of the flexible electronic device processed in the step (1) by a rolling method, wherein the packaging films are adhesive films or composite films of the adhesive films and release films; and obtaining the flexible electronic device intermediate layer.
Taking a flexible electronic device as a flexible electrochromic film as an example:
when the electrochromic film in the prior art is applied to downstream products, double-sided adhesive needs to be sandwiched layer by layer one by one, the process is complicated, errors during lamination are large, a large amount of manpower and material resources need to be consumed, and the mass production efficiency is low.
Moreover, no mature process for attaching the hot melt adhesive to the surface of the electrochromic film exists in the prior art, because the outermost layer of the electrochromic film is usually made of plastic such as PET (polyethylene terephthalate), and the extrusion temperature of the hot melt adhesive (such as PVB) is 160-250 ℃, which is far higher than the temperature that the general plastic such as PET can bear, and when the hot melt adhesive is extruded and coated on the surface of the electrochromic film in a melting manner, the damage to the electrochromic film can be caused. If the surface of the electrochromic film is adhered with the pressure-sensitive adhesive in a coating mode, the production equipment cost is higher, and the production process is more complicated.
The preparation process adopted by the utility model directly uses the mature glue film on the market, and is compounded with the flexible electrochromic film in an innovative roll-to-roll rolling mode to prepare the flexible electronic device intermediate layer; the flexible electronic device intermediate layer can be conveniently compounded with shell materials such as glass and the like to prepare an encapsulated electrochromic device product, so that the production efficiency is obviously improved, the risk of a production process is reduced, and the flexibility is increased. Similarly, to other flexible electron device, like flexible solar cell, flexible film battery, flexible film electric capacity, flexible OLED, flexible electron writing paper, flexible film sensor, flexible thermochromism film, flexible photochromism film and other flexibility flexible electron device that need encapsulation, the utility model provides a preparation technology in flexible electron device intermediate level, it has obviously improved production efficiency equally, has reduced production technology's risk to the flexibility has been increased.
The utility model discloses in, to the two-sided flexible electron device intermediate level that all has the glued membrane, can use a pair of roller simultaneously in the attached glued membrane in flexible electron device both sides when the roll-in, also can use two pairs of rollers to succeed attached glued membrane in flexible electron device both sides.
In the utility model, the unreeling speed in the step (1) can be 0.01-5 m/min.
The utility model discloses in, can also include in step (1) right flexible electron device carries out surface treatment in order to improve surface tension, surface treatment is plasma treatment, ultraviolet ozone washing or corona treatment.
The utility model discloses in, preparation technology can also include: and (3) after the packaging film is attached in the step (2), detecting and recording attachment defects through machine vision.
The utility model discloses there is not special restriction to the kind of machine vision detection, for example can be CCD vision detection. For defective (bubbles, wrinkles, impurities, etc.) parts, subsequent cutting can be performed.
The utility model discloses in, in step (2) the glued membrane can be pressure-sensitive glued membrane, the temperature of roll-in is 18-90 ℃.
In the utility model, the adhesive film in the step (2) can be a hot melt adhesive film, and the rolling temperature is 18-160 ℃.
Note that, in the present invention, the temperature of the roll refers to the temperature of the roller used. In the rolling process, the contact time of the roller and the adhesive film is short, the roller is not in direct contact with the flexible electronic device, and the actual temperature of the flexible electronic device is lower than that of the roller, so that when the hot melt adhesive film is used, the rolling temperature can be slightly higher than the bearing temperature of the flexible electronic device.
The middle layer of the flexible electronic device using the hot melt adhesive film is pre-laminated by rolling at a low temperature, so that the adhesive film and the flexible electronic device can be bonded to a certain extent and cannot be easily dislocated. The hot melt adhesive film with certain normal temperature viscosity or pressure-sensitive performance can be directly rolled at normal temperature. When downstream products, such as electrochromic glass with a G + F + G structure, are to be prepared, initial pressing and final pressing are carried out, and the bonding stability of the products can be ensured.
In the present invention, the material of the roller pair used for rolling may be rubber, plastic, metal or a combination thereof, preferably silicone rubber, resin or steel. For the middle layer of the flexible electronic device using the hot melt adhesive film without the release film, in order to prevent the adhesive film from being adhered to the roller, an anti-sticking coating layer, such as silica gel or polytetrafluoroethylene (Teflon), can be additionally arranged on the surface of the roller. For the middle layer of the flexible electronic device without the release film, a diaphragm can be added between the layers during rolling; or low-temperature rolling and low-temperature storage.
The utility model discloses in, in step (2) the roller centering that the roll-in adopted has at least one to be whole heating roller, whole heating roller is the roller that the surface is whole heatable.
The surface of the hot melt adhesive film is usually provided with an embossed structure so that air bubbles between layers are discharged when the hot melt adhesive film is vacuum laminated or rolled. If the rolling in the step (2) adopts an integral heating roller, the embossing structure on the surface of the hot melt adhesive film is easy to flatten, which is not beneficial to the subsequent composition of the flexible electronic device intermediate layer and the shell materials such as glass and the like. Therefore, it is preferable that the surface of the adhesive film of the intermediate layer of the flexible electronic device is embossed again after the rolling in the step (2) is completed.
Or, at least one of the roller pairs adopted by the rolling in the step (2) is a local heating roller, and the local heating roller is a roller with a locally heatable surface.
Preferably, the locally heated roller surface has a heated region and a non-heated region, the non-heated region being continuous.
Preferably, the area of the non-heating area on the surface of the local heating roller is larger than that of the heating area.
The non-heating area on the surface of the local heating roller can use materials such as low heat conduction rubber, plastics and the like; the heating zone can be made of metal, plastic and the like with high heat conductivity. The flexible electronic device intermediate layer pressed by the local heating roller can be directly attached and packaged without an additional embossing process.
Or, at least one of the roller pairs used in the rolling in the step (2) is a local pressurizing roller, the surface of the local pressurizing roller is provided with a pressurizing area and a non-pressurizing area, and the pressurizing area is raised compared with the non-pressurizing area and/or the hardness of the pressurizing area is greater than that of the non-pressurizing area.
Preferably, the height of the protrusion is 100-; for example, it may be 100. mu.m, 150. mu.m, 200. mu.m, 250. mu.m, 300. mu.m, 350. mu.m, 400. mu.m, 450. mu.m, 500. mu.m, 600. mu.m, 700. mu.m, 800. mu.m, 900. mu.m, 1000. mu.m, 1100. mu.m, 1200. mu.m, 1300. mu.m, 1500. mu.m, 1800. mu.m, 2000. mu.m, or the like.
Preferably, the non-pressurized zones of the surface of the locally pressurized roll are continuous.
Preferably, the area of the non-pressurized area of the surface of the local pressurized roller is larger than that of the pressurized area.
When the local pressurizing roller is rolled, the pressure intensity of the pressurizing area is greater than that of the non-pressurizing area, and finally, the hot melt adhesive film is formed on the additionally pressurized local part to be adhered and fixed with the flexible electronic device. For example, the locally pressurized roller may have the following structure:
a) the hardness of the material of the roller surface is consistent, and the pressurizing area is slightly convex;
b) the roller surface has no bulge, the material with higher hardness (such as rubber-coated steel roller, Teflon and other resins) is used in the pressurized area, and the material with lower hardness (such as soft silicon rubber) is used in the non-pressurized area;
or c) the pressurized area is slightly convex, and the material with higher hardness is used in the pressurized area, and the material with lower hardness is used in the non-pressurized area.
The flexible electronic device intermediate layer formed by rolling through the local pressing roller can be directly subjected to subsequent laminating packaging without an additional embossing process.
Or, at least one of the roller pairs used for rolling in the step (2) is a local pressurizing and heating roller, and the surface of the local pressurizing and heating roller is provided with a pressurizing area, a heating area and a non-pressurizing heating area.
The non-pressurized heating zone refers to a zone that is neither pressurized nor heated. The pressing and heating zones of the surface of the locally pressurized and heated roll may be the same zone (i.e., the zone is both pressurized and heated) or may be different zones (i.e., the pressing and heating zones are separate from each other). For a locally pressurized heated roller, the manner in which it achieves surface local pressurization can be the same as for a locally pressurized roller.
Adopt the utility model provides a preparation technology obtains behind the flexible electron device intermediate level, can the rolling reserve, also can directly get into the technology of follow-up preparation low reaches product. Taking a flexible electronic device as an example of a flexible electrochromic film, the subsequent process comprises the following steps:
cutting, half-cutting, electrode arrangement, aging, cleaning and testing the middle layer of the flexible electronic device, and then compounding the middle layer with a shell material;
the cutting method can be as follows: laser, die cutting, engraving or water jet;
the half-cutting method can be as follows: laser and die cutting;
the method of electrode placement may be: printing;
the aging method can be as follows: illumination, ultraviolet illumination, infrared illumination and heating;
the cleaning method can be as follows: mechanical cleaning, laser cleaning and plasma cleaning;
the items tested may be: CCD visual detection, film thickness detection, resistance and sheet resistance detection, transmittance detection of specific wavelength or wavelength combination, and roughness detection;
the compounding method can be as follows: direct bonding, roll bonding, vacuum bonding, thermal lamination, and hot rolling;
the housing material may be glass or other transparent material, light reflective material, non-transparent material, or combinations thereof.
Compared with the prior art, the utility model discloses following beneficial effect has:
the utility model provides a flexible electron device intermediate level is the intermediate product of the flexible electron device product after the preparation encapsulation, and it can play the guard action to flexible electron device, avoids flexible electron device by the fish tail or receive the influence of factors such as ultraviolet ray, water, oxygen in storage, transportation and encapsulation process. The flexible electronic device intermediate layer can directly replace the existing common intermediate layer to be compounded with shell materials such as glass and the like to prepare a packaged flexible electronic device product, so that the production efficiency is obviously improved, the risk of a production process is reduced, the flexibility is increased, the existing packaging equipment, process and operation method can not be changed, and the popularization and the application are convenient.
Drawings
Fig. 1 is a schematic cross-sectional structure diagram of an intermediate layer of a flexible electronic device provided in embodiment 1 of the present invention.
Fig. 2 is a schematic view of a manufacturing process of the intermediate layer of the flexible electronic device provided in embodiment 1 of the present invention.
Fig. 3 is a schematic diagram of a process for preparing a downstream product of the flexible electronic device intermediate layer provided in embodiment 1 of the present invention.
Fig. 4 is a schematic view of a manufacturing process of the intermediate layer of the flexible electronic device provided in embodiment 2 of the present invention.
Fig. 5 is a schematic diagram of a manufacturing process of a downstream product of the flexible electronic device intermediate layer provided in embodiment 2 of the present invention.
Fig. 6 is a schematic view of a manufacturing process of the intermediate layer of the flexible electronic device provided in embodiment 3 of the present invention.
Fig. 7 is a schematic structural view of a roller for attaching a glue film in embodiment 3 of the present invention.
Fig. 8 is a schematic structural view of a roller for attaching a glue film in embodiment 4 of the present invention.
Fig. 9 is a schematic structural view of a roller for attaching a glue film in embodiment 5 of the present invention.
Fig. 10 is a schematic cross-sectional view of an intermediate layer of a flexible electronic device according to embodiment 6 of the present invention.
Fig. 11 is a schematic view of a manufacturing process of the intermediate layer of the flexible electronic device provided in embodiment 6 of the present invention.
Fig. 12 is a schematic structural view of a roller for attaching a glue film in embodiment 6 of the present invention.
Fig. 13 is a schematic structural view of a roller for attaching a glue film in embodiment 7 of the present invention.
Fig. 14 is a schematic structural view of a roller for attaching a glue film in embodiment 8 of the present invention.
Fig. 15 is a schematic structural view of a roller for attaching a glue film in embodiment 9 of the present invention.
Detailed Description
The technical solution of the present invention is further explained by the following embodiments with reference to the accompanying drawings. It should be understood by those skilled in the art that the specific embodiments described are merely to aid in understanding the present invention and should not be considered as specific limitations of the present invention.
Example 1
The embodiment provides a flexible electronic device interlayer, as shown in fig. 1, including a flexible electronic device, a first adhesive film and a second adhesive film respectively disposed on two sides of the flexible electronic device, and a first release film disposed on an outer side of the first adhesive film and a second release film disposed on an outer side of the second adhesive film;
wherein, the flexible electronic device is a flexible electrochromic film.
It should be noted that the structure of the flexible electronic device shown in fig. 1 only indicates that it has a multi-layer structure when it is a flexible electrochromic film, and should not be construed as having only three layers.
The embodiment also provides a preparation process of the intermediate layer of the flexible electronic device, as shown in fig. 2, including the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.4 mm);
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, a pressure-sensitive adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the pressure-sensitive adhesive film, wherein the heavy release film is on the outermost side, the thickness of the pressure-sensitive adhesive film is 0.2mm, and the main component of the pressure-sensitive adhesive film is polymethyl methacrylate) to two sides of the flexible electrochromic film treated in the step (1) by using a pair of rubber rollers through a rolling method to obtain the middle layer of the flexible electronic device;
(3) and visually detecting the attaching defects by the CCD, recording or marking, and rolling for later use or entering a next production line.
The intermediate layer of the flexible electronic device provided in this embodiment enters a production line for preparing downstream products, as shown in fig. 3, the preparation process of the downstream products includes:
(a) laser cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing the heavy release film on one side of the prepared sheet-type flexible electronic device intermediate layer, and attaching the heavy release film on the plane glass;
(d) and removing the heavy release film on the other side, and pasting the heavy release film on the other side and the other piece of glass.
The flexible electronic device middle layer provided by the embodiment can protect the electrochromic film, prevent the electrochromic film from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, can be more easily compounded with shell materials such as glass and the like, improves the production efficiency of downstream products, can not change the existing packaging equipment, process and operation method, and is convenient to popularize and apply.
Example 2
The embodiment provides an interlayer of a flexible electronic device, which has the same structure as that of embodiment 1, and the preparation process is shown in fig. 4, and comprises the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.1mm), and carrying out corona treatment on the flexible electrochromic film to improve the surface tension;
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, a pressure-sensitive adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the pressure-sensitive adhesive film, wherein the heavy release film is on the outermost side, the thickness of the pressure-sensitive adhesive film is 0.1mm, and the main component of the pressure-sensitive adhesive film is polymethyl methacrylate) to two sides of the flexible electrochromic film treated in the step (1) by using two pairs of rubber rollers to obtain a middle layer of the flexible electronic device;
(3) and visually detecting the attached defects by the CCD, recording or marking, and rolling for later use.
The intermediate layer of the flexible electronic device provided in this embodiment enters a production line for preparing downstream products, as shown in fig. 5, the preparation process of the downstream products includes:
(a) laser cutting and half cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing the heavy release film on one side of the prepared sheet-type flexible electronic device intermediate layer, and attaching the heavy release film to a first shell (plane glass) by using a rubber roll;
(d) the heavy release film on the other side is removed, and the second shell (plane glass) is attached by a vacuum attaching machine.
The flexible electronic device middle layer provided by the embodiment can protect the electrochromic film, prevent the electrochromic film from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, can be more easily compounded with shell materials such as glass and the like, improves the production efficiency of downstream products, can not change the existing packaging equipment, process and operation method, and is convenient to popularize and apply.
Example 3
The present embodiment provides an interlayer of a flexible electronic device, which has the same structure as that of embodiment 1, and the preparation process is shown in fig. 6, and includes the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.3mm), and carrying out plasma treatment on the flexible electrochromic film to improve the surface tension;
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, an EVA hot melt adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the EVA hot melt adhesive film, wherein the heavy release film is on the outermost side, and the thickness of the EVA hot melt adhesive film is 0.3mm) to two sides of the flexible electrochromic film treated in the step (1) by using a pair of rollers through a rolling method to obtain the middle layer of the flexible electronic device;
(3) the CCD visually detects the attaching defects, records or marks the attaching defects, and enters the next production line;
the roller used in the step (2) is structurally shown in fig. 7, and comprises two opposite local heating rollers, wherein the surfaces of the local heating rollers are provided with a heating area and a non-heating area, the heating area is made of a high-heat-conductivity material, the non-heating area is made of a low-heat-conductivity material, the non-heating area is continuous and is larger than the area of the heating area, and the heating areas of the two local heating rollers are aligned with each other; the heating zone was heated to 60 ℃ during rolling, and the non-heating zone was not heated.
The intermediate layer of the flexible electronic device provided by the embodiment enters a production line for preparing downstream products, and the preparation process of the downstream products comprises the following steps:
(a) laser cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing heavy release films on two sides of the prepared interlayer of the sheet type flexible electronic device, and attaching plate glass on two sides in a dust-free workshop to complete sheet combination;
(d) hot pressing for 20 minutes at 90 ℃ and 0.1MPa by using a hot laminating machine;
(e) after hot pressing, the mixture is cured by ultraviolet lamp irradiation with energy of 4000mJ/cm2。
The embodiment adopts the local heating roller, realizes the bonding fixation between the hot melt adhesive film and the flexible electrochromic film at low temperature through local additional heating, the provided flexible electronic device intermediate layer can play a role in protecting the electrochromic film, the electrochromic film is prevented from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, the electrochromic film can be more easily compounded with shell materials such as glass and the like, the production efficiency of downstream products is improved, the existing packaging equipment, process and operation method can not be changed, and the popularization and the application are convenient.
Example 4
This example provides a flexible electronic device interlayer and a process for manufacturing the same, which is different from example 3 in that the roll used in step (2) has a structure as shown in fig. 8, and includes two oppositely disposed partial pressure rolls, the surface of the partial pressure roll has a pressure region and a non-pressure region, the pressure region and the non-pressure region are made of the same material, the pressure region is raised 200 μm compared with the non-pressure region, the non-pressure region is continuous and has an area larger than that of the pressure region, and the pressure regions of the two partial pressure rolls are aligned with each other.
The embodiment adopts the local pressurizing roller, realizes the bonding fixation between the hot melt adhesive film and the flexible electrochromic film at normal temperature through local additional pressurization, the provided flexible electronic device middle layer can play a role in protecting the electrochromic film, the electrochromic film is prevented from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, the flexible electronic device middle layer can be more easily compounded with shell materials such as glass and the like, the production efficiency of downstream products is improved, the existing packaging equipment, process and operation method can not be changed, and the flexible electronic device is convenient to popularize and apply.
Example 5
The embodiment provides an interlayer of a flexible electronic device, which has the same structure as that of embodiment 1, and the preparation process comprises the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.2mm), and carrying out ultraviolet ozone cleaning treatment on the flexible electrochromic film to improve the surface tension;
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, a PVB hot melt adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the PVB hot melt adhesive film, wherein the heavy release film is on the outermost side, and the PVB hot melt adhesive film is 0.4mm in thickness) to two sides of the flexible electrochromic film treated in the step (1) by using a pair of rollers through a rolling method to obtain a flexible electronic device interlayer;
(3) embossing on the surface of the adhesive film by using surface embossing equipment, visually detecting the attached defects by using a CCD (charge coupled device), recording or marking, and entering a next production line;
wherein, the roller used in the step (2) has a structure as shown in fig. 9, and comprises two integral heating rollers which are oppositely arranged; the roller was heated to 140 ℃ during rolling.
The intermediate layer of the flexible electronic device provided by the embodiment enters a production line for preparing downstream products, and the preparation process of the downstream products comprises the following steps:
(a) laser cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing heavy release films on two sides of the prepared interlayer of the sheet type flexible electronic device, and attaching plate glass on two sides in a dust-free workshop to complete sheet combination;
(d) hot pressing for 30 minutes at 100 ℃ and 0.1MPa by using a hot laminating machine to finish primary pressing;
(e) after the completion of the initial pressure, the final pressure was completed by hot pressing at 130 ℃ under 1.0MPa in an autoclave for 60 minutes.
The embodiment adopts the integral heating roller, realizes the bonding fixation between the hot melt adhesive film and the flexible electrochromic film at low temperature, the provided flexible electronic device middle layer can play a role in protecting the electrochromic film, the electrochromic film is prevented from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the storage, transportation and packaging processes, the flexible electronic device middle layer can be more easily compounded with shell materials such as glass and the like, the production efficiency of downstream products is improved, the existing packaging equipment, process and operation method can not be changed, and the popularization and the application are convenient.
Example 6
The embodiment provides a flexible electronic device interlayer, as shown in fig. 10, including a flexible electronic device, a first adhesive film disposed on one side of the flexible electronic device, and a first release film disposed on an outer side of the first adhesive film;
wherein, the flexible electronic device is a flexible electrochromic film.
It should be noted that the structure of the flexible electronic device shown in fig. 10 only indicates that it has a multi-layer structure when it is a flexible electrochromic film, and should not be construed as having only three layers.
The embodiment also provides a preparation process of the intermediate layer of the flexible electronic device, as shown in fig. 11, including the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.4mm), and carrying out corona treatment on the flexible electrochromic film to improve the surface tension;
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, an EVA hot melt adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the EVA hot melt adhesive film, wherein the heavy release film is on the outermost side, and the thickness of the EVA hot melt adhesive film is 0.2mm) to one side of the flexible electrochromic film treated in the step (1) by using a pair of rollers through a rolling method to obtain the middle layer of the flexible electronic device;
(3) then the CCD visually detects the jointed defects, records or marks the defects and rolls the defects for standby;
wherein, the roller used in the step (2) has a structure as shown in fig. 12, and comprises a local heating roller and a rubber roller which are oppositely arranged; the surface of the local heating roller is provided with a heating area and a non-heating area, the heating area is made of high-heat-conduction materials, the non-heating area is made of low-heat-conduction materials, and the non-heating area is continuous and is larger than the area of the heating area; the heating zone of the local heating roller is heated to 80 ℃ during rolling, and the non-heating zone and the rubber roller are not heated.
The intermediate layer of the flexible electronic device provided by the embodiment enters a production line for preparing downstream products, and the preparation process of the downstream products comprises the following steps:
(a) laser cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing the heavy release film from the prepared interlayer of the sheet-type flexible electronic device, and attaching plate glass to the adhesive film on one side in a dust-free workshop to complete sheet combination;
(d) hot pressing for 20 minutes at 90 ℃ and 0.1MPa by using a hot laminating machine;
(e) after hot pressing, the mixture is cured by ultraviolet lamp irradiation with energy of 4000mJ/cm2。
The embodiment adopts the matching of a single local heating roller and a common rubber roller, realizes the bonding fixation between the hot-melt adhesive film and the flexible electrochromic film at low temperature by local additional heating, and the provided flexible electronic device intermediate layer can play a role in protecting the electrochromic film, thereby avoiding the electrochromic film from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, being more easily compounded with shell materials such as glass and the like, improving the production efficiency of downstream products, not changing the existing packaging equipment, process and operation method, and being convenient for popularization and application.
Preparation example 7
This example provides a flexible electronic device interlayer and a process for preparing the same, which is different from example 6 in that the roller used in step (2) has a structure as shown in fig. 13, and includes a partially pressurized roller and a steel roller which are oppositely disposed; the surface of the local pressurizing roller is provided with a pressurizing area and a non-pressurizing area, the hardness of the pressurizing area is greater than that of the non-pressurizing area (the material of the pressurizing area is Teflon resin, and the material of the non-pressurizing area is soft silicon rubber), and the non-pressurizing area is continuous and is greater than that of the pressurizing area.
In the embodiment, a single local pressurizing roller is matched with a common steel roller, the bonding and fixing between the hot melt adhesive film and the flexible electrochromic film at normal temperature are realized through local additional pressurization, and the intermediate layer of the flexible electronic device can be rapidly prepared in a large scale by adopting an innovative roll-to-roll rolling production process; the flexible electronic device middle layer can protect the electrochromic film, prevent the electrochromic film from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, can be more easily compounded with shell materials such as glass and the like, improves the production efficiency of downstream products, can not change the existing packaging equipment, process and operation method, and is convenient to popularize and apply.
Preparation example 8
The embodiment provides a flexible electronic device interlayer, the structure of which is the same as that of the embodiment 6, and the preparation process comprises the following steps:
(1) unreeling a flexible electrochromic film roll material (with the thickness of 0.1 mm);
(2) continuously attaching packaging films (the adopted raw materials are three-layer composite films of a heavy release film, a PVB hot melt adhesive film and a light release film, the light release film is rolled and removed before attachment, the packaging film attached to the surface of the flexible electrochromic film is a composite film of the heavy release film and the PVB hot melt adhesive film, wherein the heavy release film is on the outermost side, and the thickness of the PVB hot melt adhesive film is 0.1mm) to one side of the flexible electrochromic film treated in the step (1) by using a pair of rollers through a rolling method to obtain a flexible electronic device interlayer;
(3) embossing on the surface of the adhesive film by using surface embossing equipment, visually detecting the attached defects by using a CCD (charge coupled device), recording or marking, and rolling for later use;
wherein, the roller used in the step (2) has a structure as shown in fig. 14, and comprises an integral heating roller and a rubber roller which are oppositely arranged; when in rolling, the integral heating roller is heated to 120 ℃, and the rubber roller is not heated.
The intermediate layer of the flexible electronic device provided by the embodiment enters a production line for preparing downstream products, and the preparation process of the downstream products comprises the following steps:
(a) laser cutting;
(b) printed electrode arrangement and flexible connection terminal lead-out;
(c) removing the heavy release film on one side of the prepared middle layer of the sheet-type flexible electronic device, and attaching plate glass to the adhesive film on one side in a dust-free workshop to complete sheet combination;
(d) hot pressing for 30 minutes at 100 ℃ and 0.1MPa by using a hot laminating machine to finish primary pressing;
(e) after the completion of the initial pressure, the final pressure was completed by hot pressing at 130 ℃ under 1.0MPa in an autoclave for 60 minutes.
The embodiment adopts the cooperation of a single integral heating roller and a common rubber roller, realizes the bonding fixation between the hot melt adhesive film and the flexible electrochromic film at low temperature, the provided flexible electronic device intermediate layer can play a role in protecting the electrochromic film, the electrochromic film is prevented from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, the electrochromic film can be more easily compounded with shell materials such as glass and the like, the production efficiency of downstream products is improved, the existing packaging equipment, process and operation method can not be changed, and the popularization and the application are convenient.
Example 9
This example provides a flexible electronic device interlayer and a process for manufacturing the same, the process being different from example 4 in that the roller used in step (2) has a structure as shown in fig. 15, and includes two oppositely disposed local pressurized heating rollers, the surface of the local pressurized heating roller has a pressurized heating region and a non-pressurized heating region, the hardness of the pressurized heating region is greater than that of the non-pressurized heating region (the material of the pressurized heating region is encapsulated steel, and the material of the non-pressurized region is soft silicone rubber), the non-pressurized heating region is continuous and has an area greater than that of the pressurized heating region, and the pressurized heating regions of the two local pressurized heating rollers are aligned with each other; the pressure and temperature of the pressurized heating area are higher than those of the non-pressurized heating area during rolling.
The embodiment adopts the local pressurizing and heating roller, the bonding fixation between the hot melt adhesive film and the flexible electrochromic film is realized through local additional pressurizing and heating, the provided flexible electronic device middle layer can play a role in protecting the electrochromic film, the electrochromic film is prevented from being scratched or influenced by factors such as ultraviolet rays, water, oxygen and the like in the processes of storage, transportation and packaging, the electrochromic film can be more easily compounded with shell materials such as glass and the like, the production efficiency of downstream products is improved, the existing packaging equipment, process and operation method can not be changed, and the popularization and the application are facilitated.
The embodiment of the utility model provides a specific embodiment when flexible electron device is flexible electrochromic film has been given, can understand, can be with the utility model discloses a flexible electrochromic film replacement in the above-mentioned embodiment is the flexible electron device of other types, for example flexible solar cell, flexible film battery, flexible film electric capacity, flexible OLED, flexible electron writing paper, flexible film sensor, flexible thermochromic film, flexible photochromic film etc. realize the preparation in the flexible electron device intermediate level that corresponds the type, obtain the flexible electron device intermediate level product that corresponds the type, the embodiment of the utility model provides a no longer give unnecessary details and the specific embodiment that corresponds with every kind of flexible electron device one by one. The utility model provides a flexible electron device intermediate level can play the guard action to flexible electron device, avoids flexible electron device by the fish tail or receive the influence of factors such as ultraviolet ray, water, oxygen in storage, transportation and encapsulation process, can compound with shell materials such as glass more easily, has improved the production efficiency of low reaches product, can not change current encapsulation equipment, technology and operation method, and the facilitate promotion is used.
Claims (10)
1. A flexible electronic device interlayer, comprising: the flexible electronic device comprises a flexible electronic device, adhesive films arranged on one side or two sides of the flexible electronic device, and release films optionally arranged on the outer sides of the adhesive films.
2. The flexible electronic interlayer of claim 1, wherein the flexible electronic device has a thickness of 10 to 10000 μm.
3. The interlayer of claim 2, wherein the thickness of the flexible electronic device is 100-400 μm.
4. The flexible electronic device interlayer of claim 1, wherein the adhesive film has a thickness of 10 to 3000 μm.
5. The interlayer of claim 4, wherein the adhesive film has a thickness of 100-400 μm.
6. The flexible electronic device interlayer of claim 1, wherein the release film has a thickness of 1000 μm or less.
7. The flexible electronic device interlayer of claim 6, wherein the release film has a thickness of 200 μm or less.
8. The flexible electronic device interlayer of claim 1, wherein the adhesive film has a width equal to or greater than a width of the flexible electronic device.
9. The flexible electronic device interlayer of claim 1, wherein the adhesive film is a pressure sensitive adhesive film or a hot melt adhesive film.
10. The flexible electronic device interlayer of any of claims 1-9, wherein the flexible electronic device is a flexible solar cell, a flexible thin film battery, a flexible thin film capacitor, a flexible OLED, a flexible electronic writing paper, a flexible thin film sensor, a flexible thermochromic thin film, a flexible photochromic thin film, or a flexible electrochromic thin film.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN114512563A (en) * | 2022-04-21 | 2022-05-17 | 南通市乐能电力有限公司 | High-efficient solar cell dual glass assembly processing equipment |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114512563A (en) * | 2022-04-21 | 2022-05-17 | 南通市乐能电力有限公司 | High-efficient solar cell dual glass assembly processing equipment |
| CN114512563B (en) * | 2022-04-21 | 2022-07-12 | 南通市乐能电力有限公司 | High-efficient solar cell dual glass assembly processing equipment |
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