CN211777655U - SCR supply injection system using solid ammonium as reducing agent - Google Patents
SCR supply injection system using solid ammonium as reducing agent Download PDFInfo
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- CN211777655U CN211777655U CN201922377641.XU CN201922377641U CN211777655U CN 211777655 U CN211777655 U CN 211777655U CN 201922377641 U CN201922377641 U CN 201922377641U CN 211777655 U CN211777655 U CN 211777655U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/40—Engine management systems
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Abstract
The utility model discloses an use solid-state ammonium to supply with injection system as SCR of reductant, SCR supply with injection system includes ammonia generation unit, ammonia steady voltage unit, ammonia injection unit and the control unit. The ammonia gas generating unit is used for generating ammonia gas; the ammonia gas pressure stabilizing unit is used for receiving the ammonia gas from the ammonia gas generating unit and stabilizing the pressure of the received ammonia gas; the ammonia gas injection unit is used for receiving and injecting ammonia gas from the ammonia gas pressure stabilizing unit; the ammonia generating unit, the ammonia pressure stabilizing unit and the ammonia injection unit are all electrically connected with the control unit. According to the SCR feed injection system provided by the present invention,can absorb NO in the tail gas of the diesel engineXThe method has the advantages that ammonia gas is not required to be generated by heating the urea aqueous solution, and meanwhile, compressed air and a mixing pipe are not required, so that the cost of tail gas treatment is reduced, more space is reserved in a ship engine room, the transient response of the system can be improved, and the emission of the ammonia gas can be better controlled.
Description
Technical Field
The utility model relates to a marine diesel engine tail gas aftertreatment's technical field, more specifically relate to an use solid-state ammonium to supply injection system for SCR (Selective Catalytic Reduction, Selective Catalytic Reduction technique) of reductant.
Background
The Selective Catalytic Reduction (SCR) technology aims at NO in tail gas emission of diesel engineXThe treatment process of (1) is to spray reducing agent ammonia or urea under the action of catalyst to treat NO in tail gasXReduction to N2And H2And O. Use of SCR for NO in marine diesel exhaustXThe mainstream technique of post-processing. The SCR urea supply injection system is a core component of the SCR system and is an actuating mechanism for realizing urea solution supply, accurate metering and atomized injection.
In the prior art, the tail gas after-treatment device of the marine diesel engine mainly adopts urea aqueous solution as a reducing agent NH3The vector of (1). However, when the exhaust gas treatment is carried out using an aqueous urea solutionThere are problems, such as poor ammonia carrying capacity of the aqueous urea solution, and the need to heat the aqueous urea solution above 200 ℃ to be able to evaporate and decompose to produce NH during the exhaust gas treatment process3The problem that a mixing pipe needs to be added to an exhaust pipe of the diesel engine to assist the atomization of the urea aqueous solution by using compressed air, and the urea aqueous solution generates urea crystals to block a nozzle during decomposition is solved.
Accordingly, there is a need to provide an SCR feed injection system using solid ammonium as a reductant to at least partially address the above-mentioned problems.
SUMMERY OF THE UTILITY MODEL
In the summary section a series of concepts in a simplified form is introduced, which will be described in further detail in the detailed description section. The inventive content does not imply any attempt to define the essential features and essential features of the claimed solution, nor is it implied to be intended to define the scope of the claimed solution.
The utility model provides an use solid-state ammonium to supply with injection system as SCR of reductant, the injection system is supplied with to SCR includes:
the ammonia gas generation unit comprises an ammonia gas generation device and an ammonia gas heating device at least partially wound outside the ammonia gas generation device, the ammonia gas generation unit is used for generating ammonia gas, and the ammonia gas generation device is provided with an ammonia gas outlet;
the ammonia gas pressure stabilizing unit comprises a gas transmission pipeline and a pressure reducing valve arranged on the gas transmission pipeline, the gas transmission pipeline is connected with the ammonia gas outlet, and the ammonia gas pressure stabilizing unit is used for receiving the ammonia gas from the ammonia gas generating unit and stabilizing the pressure of the received ammonia gas;
the ammonia gas injection unit comprises an air outlet pipeline, an ammonia gas nozzle arranged at the end part of the air outlet pipeline and a proportional valve arranged on the air outlet pipeline, the air outlet pipeline is connected with the gas transmission pipeline, and the ammonia gas injection unit is used for receiving and injecting ammonia gas from the ammonia gas pressure stabilizing unit; and
and the ammonia gas generation unit, the ammonia gas pressure stabilizing unit and the ammonia gas injection unit are all electrically connected with the control unit.
Optionally, the ammonia gas generation unit comprises:
the first pressure sensor is connected with the ammonia gas generating device and used for detecting the pressure in the ammonia gas generating device; and
the first temperature sensor is connected with the ammonia gas generating device and used for detecting the temperature in the ammonia gas generating device;
wherein the first pressure sensor and the first temperature sensor are both electrically connected with the control unit.
Optionally, the ammonia gas generation unit further comprises:
the safety valve is arranged on the ammonia gas generating device; and
and the feed inlet is arranged on the ammonia gas generating device.
Optionally, the ammonia gas generation unit further comprises a standby ammonia gas generation device, and the standby ammonia gas generation device is used for generating ammonia gas and is connected with the ammonia gas pressure stabilizing unit.
Optionally, the ammonia gas pressure stabilizing unit comprises a filter, an electromagnetic valve, a second pressure sensor and a second temperature sensor, which are arranged on the gas transmission pipeline.
Optionally, the filter is disposed on the gas delivery pipe at a position closer to the ammonia gas generation unit than the electromagnetic valve, the second pressure sensor, and the second temperature sensor.
Optionally, the second pressure sensor and the second temperature sensor are both electrically connected to the control unit.
Optionally, the outside of the gas transmission pipeline is at least partially coated with a pipeline heating device, and the pipeline heating device is electrically connected with the control unit.
Optionally, the ammonia gas injection unit further comprises a flow meter and a check valve arranged on the gas outlet pipeline, and the flow meter is electrically connected with the control unit.
Optionally, the exterior of the ammonia gas generating device is at least partially coated with heat insulation cotton.
According to the utility model provides an use SCR supply injection system of solid-state ammonium as reductant, including ammonia generation unit, ammonia steady voltage unit, ammonia injection unit and the control unit, can produce the ammonia through the mode of heating solid-state ammonium to can absorb the NO in diesel engine's the tail gas through this ammoniaXThe mode that need not produce the ammonia through heating urea aqueous solution, because the characteristic of solid-state ammonium self, need not heat to the temperature that urea aqueous solution can produce the ammonia, make this SCR supply injection system also have higher reduction rate at low temperature, the operational environment's that the SCR supplied injection system temperature range has been improved, do not need compressed air and hybrid tube simultaneously, the cost of tail gas treatment has been reduced, more spaces have been left for the marine engine room, simultaneously because the ammonia direct injection that this SCR supplied injection system to produce to the blast pipe, can improve the transient response nature of system, also can control the emission of ammonia better.
Drawings
The following drawings of the present invention are used herein as part of the present invention for understanding the present invention. There are shown in the drawings, embodiments and descriptions of the invention, which are used to explain the principles of the invention.
In the drawings:
fig. 1 is a schematic diagram of an SCR supply injection system using solid ammonium as a reducing agent according to an embodiment of the present invention.
Description of reference numerals:
100: ammonia gas generation unit 110: ammonia gas generating device
111: ammonia gas heating device 112: first pressure sensor
113: first temperature sensor 114: safety valve
115: a feed inlet 120: spare ammonia generator
200: ammonia gas pressure stabilizing unit 210: gas transmission pipeline
211: pressure reducing valve 212: filter
213: solenoid valve 214: second pressure sensor
215: second temperature sensor 216: pipeline heating device
217: the manual valve 300: ammonia gas injection unit
310: the gas outlet pipeline 311: ammonia gas nozzle
312: proportional valve 313: flow meter
314: check valve 400: control unit
Detailed Description
In the following description, numerous specific details are set forth in order to provide a more thorough understanding of the present invention. It will be apparent, however, to one skilled in the art, that embodiments of the invention may be practiced without one or more of these specific details. In other instances, well-known features have not been described in order to avoid obscuring embodiments of the present invention.
It should be noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments in accordance with the invention. As used herein, the singular is intended to include the plural unless the context clearly dictates otherwise. It will be further understood that the terms "comprises" and/or "comprising," when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
Exemplary embodiments according to the present invention will now be described in more detail with reference to the accompanying drawings. These exemplary embodiments may, however, be embodied in many different forms and should not be construed as limited to only the embodiments set forth herein. It is to be understood that these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the concept of these exemplary embodiments to those skilled in the art. In the drawings, the thicknesses of layers and regions are exaggerated for clarity, and the same elements are denoted by the same reference numerals, and thus the description thereof will be omitted.
The utility model provides an SCR supply injection system using solid ammonium as a reducing agent. As shown in fig. 1, the SCR supply injection system includes an ammonia gas generation unit 100, an ammonia gas pressure stabilization unit 200, an ammonia gas injection unit 300, and a control unit 400.
Specifically, the ammonia gas generation unit 100 may generate ammonia gas using solid ammonium. The ammonia gas generation unit 100 includes an ammonia gas generation device 110 and an ammonia gas heating device 111. Solid ammonium is placed in the ammonia gas generating device 110; the ammonia gas heating device 111 is at least partially wound around the outside of the ammonia gas generating device 110 and is capable of heating the ammonia gas generating device 110, thereby generating ammonia gas. In addition, the ammonia gas generating apparatus 110 also has an ammonia gas outlet for discharging the ammonia gas generated by itself. Preferably, the ammonia gas heating device 111 may be a heating wire wound around the outside of the ammonia gas generating device 110. The heating wire can heat the ammonia gas generating device 110 to make the solid ammonium inside reach the decomposition temperature, and the heating power of the heating wire is set according to the volume, the heating temperature, the heating time and the like of the ammonia gas generating device 110.
The ammonia gas pressure stabilizing unit 200 can receive the ammonia gas from the ammonia gas generating unit 100, and convey the ammonia gas to the ammonia gas injection unit 300 after the pressure of the ammonia gas is kept stable. The ammonia gas pressure stabilizing unit 200 comprises an air pipeline 210 connected with an ammonia gas outlet, and a pressure reducing valve 211 arranged on the air pipeline 210, wherein the pressure reducing valve 211 can stabilize the pressure of ammonia gas in the air pipeline 210.
The ammonia gas injection unit 300 can receive ammonia gas from the ammonia gas pressure stabilizing unit 200 and inject the ammonia gas into an exhaust pipe of the diesel engine, thereby absorbing NO in the diesel exhaust gasX. The ammonia gas injection unit 300 includes an outlet line 310 connected to the gas line 210, and ammonia gas provided at an end of the outlet line 310And a nozzle 311, wherein a proportional valve 312 is further arranged on the gas outlet pipeline 310, and the discharge amount of the ammonia gas in the gas outlet pipeline 310 can be adjusted through the proportional valve 312.
The ammonia gas generating unit 100, the ammonia gas pressure stabilizing unit 200 and the ammonia gas injecting unit 300 are all electrically connected with the control unit 400, specifically, the control unit 400 is electrically connected with the ammonia gas heating device 111 and can control the heating of the ammonia gas heating device 110, so as to control the generation rate of the ammonia gas; the control unit 400 is also electrically connected to the proportional valve 312 and is capable of regulating the displacement of ammonia gas in the outlet line 310 via the proportional valve 312.
According to the utility model provides an use SCR supply injection system of solid-state ammonium as reductant, including ammonia generation unit 100, ammonia steady voltage unit 200, ammonia injection unit 300 and the control unit 400, can produce the ammonia through the mode of heating solid-state ammonium to can absorb the NO in diesel engine's the tail gas through this ammoniaXThe mode that need not produce the ammonia through heating urea aqueous solution, because the characteristic of solid-state ammonium self, need not heat to the temperature that urea aqueous solution can produce the ammonia, make this SCR supply injection system also have higher reduction rate at low temperature, the operational environment's that the SCR supplied injection system temperature range has been improved, do not need compressed air and hybrid tube simultaneously, the cost of tail gas treatment has been reduced, more spaces have been left for the marine engine room, simultaneously because the ammonia direct injection that this SCR supplied injection system to produce to the blast pipe, can improve the transient response nature of system, also can control the emission of ammonia better.
Further, as shown in fig. 1, the ammonia gas generating unit 100 further includes a first pressure sensor 112 and a first temperature sensor 113 electrically connected to the control unit 400. When solid-state ammonium is heated and decomposed in the ammonia gas generating device 110, the pressure in the ammonia gas generating device 110 is increased along with the rise of the temperature, the first pressure sensor 112 and the first temperature sensor 113 are both connected with the ammonia gas generating device 110, and the temperature and the pressure in the ammonia gas generating device 110 can be detected, so that a worker can know the working state of the ammonia gas generating device 110 in real time.
In addition, in the present embodiment, the ammonia gas generation unit 100 further includes a safety valve 114 and a feed port 115 provided in the ammonia gas generation device 110. The safety valve 114 can prevent the pressure inside the ammonia gas generator 110 from being too high, thereby avoiding potential safety hazards. The feed inlet 115 may be used for personnel to add solid ammonium, etc. to the ammonia gas generator 110.
The outside of the ammonia gas generating device 110 is at least partially coated with heat-insulating cotton (not shown), and the heat-insulating cotton can simultaneously coat the ammonia gas generating device 110 and the ammonia gas heating device 111, so that the heat loss is reduced, and the energy consumption is saved. The ammonia gas generating apparatus 110 is constructed as a pressure vessel whose volume can be set according to the consumption amount and replacement cycle of ammonia gas and the actual installation and use.
Preferably, the ammonia gas generating unit 100 further comprises a spare ammonia gas generating device 120, the spare ammonia gas generating device 120 has the same structure as the ammonia gas generating device 110, and is capable of heating solid ammonia to generate ammonia gas and simultaneously conveying the ammonia gas to the ammonia gas pressure stabilizing unit 200, and the spare ammonia gas generating device 120 is also provided with the above-mentioned equipment arranged on the ammonia gas generating device 110, and will not be described in detail herein. Through setting up reserve ammonia generating device 120, can realize one with one and reserve, namely, when using an ammonia generating device 110, another ammonia generating device 110 can regard as reserve, even one of them ammonia generating device 110 breaks down, another ammonia generating device 110 can also guarantee to handle diesel engine tail gas. This can increase the stability of the SCR supply injection system and prolong the replacement period of the ammonia gas generator 110.
In order to ensure the stabilizing effect of the ammonia gas pressure stabilizing unit 200, in the present embodiment, the ammonia gas pressure stabilizing unit 200 further includes a filter 212, an electromagnetic valve 213, a second pressure sensor 214, and a second temperature sensor 215, which are provided on the gas transmission pipeline 210. The filter 212 can filter ammonium salt particles in the gas transmission pipeline 210, the electromagnetic valve 213 can control the on-off of the gas transmission pipeline 210, the second pressure sensor 214 and the second temperature sensor 215 can detect the pressure and the temperature in the gas transmission pipeline 210, and the second pressure sensor 214 and the second temperature sensor 215 are electrically connected with the control unit 400, so that a worker can know the state of ammonia gas in the gas transmission pipeline 210 in real time. Preferably, the filter 212 is provided on the gas piping 210 at a position closer to the ammonia gas generation unit 100 than the electromagnetic valve 213, the second pressure sensor 214, and the second temperature sensor 215, whereby clogging of the electromagnetic valve 213, the second pressure sensor 214, and the second temperature sensor 215 with ammonium salt particles can be avoided. In addition, a manual valve 217 is arranged on the air transmission pipeline 210, so that a worker can control the on-off effect of the air transmission pipeline 210.
Further, the exterior of the gas transmission pipeline 210 is at least partially coated with a pipeline heating device 216, and the pipeline heating device 216 is electrically connected with the control unit 400. Therefore, the control unit 400 can heat the gas transmission pipeline 210 through the pipeline heating device 216, so that the temperature of the gas transmission pipeline 210 is maintained, and the ammonia gas in the gas transmission pipeline 210 is prevented from generating reverse reaction. It is understood that the heating power of the pipe heating apparatus 216 may be set according to the size of the gas transmission pipeline 210, the pressure of the ammonia gas in the gas transmission pipeline 210, and the heating temperature. Preferably, the pipe heating device 216 may be a heating wire wound around the outside of the gas pipeline 210.
As shown in fig. 1, the ammonia gas injection unit 300 further includes a flow meter 313 and a check valve 314 provided on the gas outlet line 310. The flow meter 313 is electrically connected with the control unit 400, and a worker can acquire the flow value of the ammonia gas in the gas outlet pipeline 310 through the flow meter 313. The check valve 314 prevents the flow of ammonia.
In this embodiment, the operator can monitor and control the operation process of the whole SCR supply injection system through the control unit 400, so as to ensure that the tail gas treatment of the diesel engine can be normally performed. The control unit 400 monitors signals such as the temperature and the pressure inside the ammonia gas generating device 110, the pressure and the temperature of ammonia gas in the gas transmission pipeline 210, and the flow rate in the gas outlet pipeline 310, and can control the heating of the ammonia gas generating device 110 by the ammonia gas heating device 111, the heating of the gas transmission pipeline 210 by the pipeline heating device 216, and the flow rate of ammonia gas in the gas outlet pipeline 310, and can also switch the working states of the two ammonia gas generating devices by the electromagnetic valve 213.
The present invention has been described in terms of the above embodiments, but it is to be understood that the above embodiments are for purposes of illustration and description only and are not intended to limit the invention to the described embodiments. Furthermore, it will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that many more modifications and variations are possible in light of the teaching of the present invention and are within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. An SCR feed injection system using solid ammonium as a reductant, the SCR feed injection system comprising:
the ammonia gas generation unit comprises an ammonia gas generation device and an ammonia gas heating device at least partially wound outside the ammonia gas generation device, the ammonia gas generation unit is used for generating ammonia gas, and the ammonia gas generation device is provided with an ammonia gas outlet;
the ammonia gas pressure stabilizing unit comprises a gas transmission pipeline and a pressure reducing valve arranged on the gas transmission pipeline, the gas transmission pipeline is connected with the ammonia gas outlet, and the ammonia gas pressure stabilizing unit is used for receiving the ammonia gas from the ammonia gas generating unit and stabilizing the pressure of the received ammonia gas;
the ammonia gas injection unit comprises an air outlet pipeline, an ammonia gas nozzle arranged at the end part of the air outlet pipeline and a proportional valve arranged on the air outlet pipeline, the air outlet pipeline is connected with the gas transmission pipeline, and the ammonia gas injection unit is used for receiving and injecting ammonia gas from the ammonia gas pressure stabilizing unit; and
and the ammonia gas generation unit, the ammonia gas pressure stabilizing unit and the ammonia gas injection unit are all electrically connected with the control unit.
2. The SCR feed injection system of claim 1, wherein the ammonia gas generation unit comprises:
the first pressure sensor is connected with the ammonia gas generating device and used for detecting the pressure in the ammonia gas generating device; and
the first temperature sensor is connected with the ammonia gas generating device and used for detecting the temperature in the ammonia gas generating device;
wherein the first pressure sensor and the first temperature sensor are both electrically connected with the control unit.
3. The SCR feed injection system of claim 1, wherein the ammonia gas generation unit further comprises:
the safety valve is arranged on the ammonia gas generating device; and
and the feed inlet is arranged on the ammonia gas generating device.
4. The SCR supply injection system using solid ammonium as a reducing agent according to claim 1, wherein the ammonia gas generation unit further comprises a spare ammonia gas generation device, and the spare ammonia gas generation device is used for generating ammonia gas and is connected with the ammonia gas pressure stabilizing unit.
5. The SCR supply injection system of claim 1, wherein the ammonia pressure stabilizing unit comprises a filter, an electromagnetic valve, a second pressure sensor and a second temperature sensor, and the filter, the electromagnetic valve, the second pressure sensor and the second temperature sensor are arranged on the gas pipeline.
6. The system of claim 5, wherein the filter is positioned on the gas delivery conduit at a location closer to the ammonia gas generating unit than the solenoid valve, the second pressure sensor, and the second temperature sensor.
7. An SCR supply injection system with solid ammonium as a reductant according to claim 5, characterised in that the second pressure sensor and the second temperature sensor are both electrically connected to the control unit.
8. The SCR supply injection system of claim 5, wherein the gas pipeline is at least partially coated with a pipeline heating device, and the pipeline heating device is electrically connected to the control unit.
9. The SCR feed injection system of claim 1, wherein the ammonia injection unit further comprises a flow meter and a check valve disposed on the gas outlet line, the flow meter being electrically connected to the control unit.
10. The system of claim 1, wherein the ammonia generator is at least partially coated with insulation wool.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201922377641.XU CN211777655U (en) | 2019-12-23 | 2019-12-23 | SCR supply injection system using solid ammonium as reducing agent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201922377641.XU CN211777655U (en) | 2019-12-23 | 2019-12-23 | SCR supply injection system using solid ammonium as reducing agent |
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| CN211777655U true CN211777655U (en) | 2020-10-27 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113090361A (en) * | 2019-12-23 | 2021-07-09 | 中国船舶重工集团公司第七一一研究所 | SCR supply injection system using solid ammonium as reducing agent |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113090361A (en) * | 2019-12-23 | 2021-07-09 | 中国船舶重工集团公司第七一一研究所 | SCR supply injection system using solid ammonium as reducing agent |
| CN113090361B (en) * | 2019-12-23 | 2024-06-28 | 中国船舶集团有限公司第七一一研究所 | SCR (selective catalytic reduction) supply injection system taking solid ammonium as reducing agent |
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Effective date of registration: 20201228 Address after: 201108 building 6, 4299 Jindu Road, Minhang District, Shanghai Patentee after: Shanghai Qiyao Environmental Protection Technology Co.,Ltd. Address before: 201108 Shanghai city Minhang District Huaning Road No. 3111 Patentee before: China Shipbuilding Industry Corporation 711 Research Institute |