CN211706335U - VOC normal temperature condensation processing system utilizing active carbon static activity - Google Patents

VOC normal temperature condensation processing system utilizing active carbon static activity Download PDF

Info

Publication number
CN211706335U
CN211706335U CN201922261653.6U CN201922261653U CN211706335U CN 211706335 U CN211706335 U CN 211706335U CN 201922261653 U CN201922261653 U CN 201922261653U CN 211706335 U CN211706335 U CN 211706335U
Authority
CN
China
Prior art keywords
adsorption
valve
condensation
desorption
adsorption bed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201922261653.6U
Other languages
Chinese (zh)
Inventor
高军
张承全
曹昌盛
夏云飞
谢午豪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tongji University
Original Assignee
Tongji University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tongji University filed Critical Tongji University
Priority to CN201922261653.6U priority Critical patent/CN211706335U/en
Application granted granted Critical
Publication of CN211706335U publication Critical patent/CN211706335U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Abstract

The utility model discloses a VOC normal temperature condensation treatment system and method using active carbon static activity, which relates to the technical field of industrial discharge VOCs treatment, and comprises a VOCs pretreatment system, a desorption condensation system, an auxiliary adsorption bed C, an adsorption bed A and an adsorption bed B; the adsorption beds A and B are connected with an adsorption fan through an adsorption air inlet valve; the adsorption fan is connected with a VOCs pretreatment system; the adsorption beds A and B are connected with the atmosphere through an adsorption gas outlet valve; the adsorption beds A and B are connected in series in a closed way through series valves Ab and Ba; the two ends of the adsorption bed A, the adsorption bed B and the auxiliary adsorption bed C are respectively connected with the two ends of the desorption condensation system through desorption condensation valves. The treatment method adopting the system of the utility model makes full use of the static activity of the active carbon, reduces the cost, prolongs the service life, and has higher purity of the recovered organic solvent and high recovery efficiency; and a 2+1 mode is adopted, so that the control strategy is simpler and the operation is more reliable.

Description

VOC normal temperature condensation processing system utilizing active carbon static activity
Technical Field
The utility model relates to an industry discharges VOCs and handles technical field, especially relates to an utilize active carbon static active VOC normal atmospheric temperature condensation processing system.
Background
Volatile Organic Compounds (VOCs) in the atmosphere cause serious damage to plant and animal life and affect human health such as eye irritation, respiratory problems, cancer induction, and the like. VOCs used as organic solvents in industries such as spray coating, furniture, etc. may account for 35-40% of atmospheric VOCs emissions. Common treatment means for VOCs in the above industry include: adsorption, absorption, condensation and other recovery methods and direct combustion, catalytic oxidation, biological treatment, low-temperature plasma, photocatalysis and other destruction methods; in practice, two or three of the above methods are generally combined. The VOCs treatment method combining activated carbon adsorption concentration and condensation recovery is more convenient and simpler in subsequent treatment and high in economic benefit, and is an ideal treatment method.
Lufukun et al propose a process for activated carbon adsorption and N2 desorption recovery treatment of organic waste gas, after adsorption, N2 vacuum 4-10 KPa circulation heating desorption is adopted, then condensation is carried out by a double-stage condensation device, and residual VOCs are blown by fresh air and then sent to another adsorber for adsorption. This patent can effectively desorb out the VOCs gas and the condensation, but adopts fresh air to sweep still to face safe risk and influence active carbon life of application at last. Yani et al propose a hot nitrogen gas desorption condensation recovery system of active carbon adsorption, adopt tertiary condensation behind the desorption gas, the noncondensable gas in the pipeline gets into supplementary active carbon adsorber absorption after the desorption, this patent still has the problem that tertiary condensation energy consumption is high, equipment thermal stress and gas tightness require highly.
The inventor also provides a system and a method for treating VOCs through normal-temperature condensation-assisted purification, wherein three same beds are used for alternate adsorption purification, desorption condensation and assisted purification, so that the residual quantity of a bed body after desorption condensation is very small to ensure that the concentration of discharged VOCs in a normal adsorption period reaches the standard. This patent has realized that the adsorption efficiency of normal atmospheric temperature condensation assurance simultaneously is up to standard, has reduced the technology degree of difficulty, equipment cost and operation energy consumption, but this patent is the same with other similar patents and has only utilized the activity that moves of active carbon to it is higher to active carbon adsorption desorption performance requirement, and the adsorption capacity is greater than condensation residual and dynamic adsorption capacity sum when requiring supplementary absorption, otherwise can appear shifting not enough to lead to adsorbing the drawback that purifies the back emission concentration not up to standard.
At present, the adsorption, concentration and condensation recovery method of VOCs generally faces the following four problems: deep condensation is needed, so that the energy consumption for condensation and heating is greatly improved; stress loss caused by large temperature difference borne by system equipment, pipelines and valves and gas tightness are difficult to meet; a part of VOCs still remaining in the adsorption bed after condensation causes the reduction of the adsorption efficiency of the next stage or faces the explosion risk by adopting fresh air hot purging; only the adsorption dynamic activity of the activated carbon is utilized, and the adsorption capacity of part of the activated carbon is wasted.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing an utilize active carbon static active VOC normal atmospheric temperature condensation processing system to solve the problem that above-mentioned prior art exists, the absorbent capacity of make full use of active carbon can practice thrift the use of active carbon, realizes utilizing the liquefaction of conventional high-efficient cold source or even natural cold source to retrieve VOCs simultaneously, has reduced condensation energy consumption and equipment cost by a wide margin.
In order to achieve the above object, the utility model provides a following scheme:
the utility model provides a VOC normal temperature condensation treatment system utilizing the static activity of active carbon, which comprises a VOCs pretreatment system, a desorption condensation system and an auxiliary adsorption bed C, wherein one side of the auxiliary adsorption bed C is provided with two adsorption beds A and B which are connected in parallel; the adsorption bed A is connected with an adsorption fan through an adsorption air inlet valve Aa1, and the adsorption bed B is connected with the adsorption fan through an adsorption air inlet valve Ba 1; the adsorption fan is connected with the VOCs pretreatment system; the adsorption bed A is connected with the atmosphere through an adsorption gas outlet valve Aa2, and the adsorption bed B is connected with the atmosphere through an adsorption gas outlet valve Ba 2; the adsorption bed A and the adsorption bed B are in serial closed connection through a serial valve Ab and a serial valve Ba; the two ends of the adsorption bed A are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Ad1 and a desorption condensation valve Ad2, the two ends of the adsorption bed B are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Bd1 and a desorption condensation valve Bd2, and the two ends of the adsorption bed C are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Cd1 and a desorption condensation valve Cd 2.
Optionally, the desorption condensation system comprises a gas-gas heat exchanger, a normal temperature condensation system, a three-way butterfly valve, a desorption fan, a stop valve and a heater which are connected in series in sequence; the three-way butterfly valve comprises a passage I, a passage II and a passage III, the normal temperature condensing system is connected with the passage I, the desorption fan is connected with the passage II, a connecting pipeline between the passage II and the desorption fan is connected with a first branch connected with the gas-gas heat exchanger, and the passage III is connected with the gas-gas heat exchanger through a second branch; the auxiliary adsorption bed C is connected to both ends of the cutoff valve through a valve Cp1 and a valve Cp 2; desorption condensation valve Ad1, desorption condensation valve Bd1 and desorption condensation valve Cd1 through first desorption condensation pipeline with heater connection, desorption condensation valve Ad2, desorption condensation valve Bd2 and desorption condensation valve Cd2 through second desorption condensation pipeline with the gas heat exchanger is connected.
Optionally, the system further comprises a nitrogen supplementing system, wherein the nitrogen supplementing system comprises a nitrogen source and an online oxygen content detector, the nitrogen source is connected with the second desorption condensation pipeline through a nitrogen supplementing valve n1, the first desorption condensation pipeline is connected with a nitrogen supplementing valve n2, and the nitrogen supplementing valve n2 is connected with the adsorption pipeline at the front end of the VOCs pretreatment system through the online oxygen content detector.
Optionally, a VOCs concentration sensor Av is arranged between the adsorption bed a and the adsorption gas outlet valve Aa2, a VOCs concentration sensor Bv is arranged between the adsorption bed B and the adsorption gas outlet valve Ba2, a VOCs concentration sensor Cv is arranged between the gas-gas heat exchanger and the normal temperature condensing system, and a VOCs concentration sensor Dv is arranged between one end of the stop valve and the valve Cp 2.
Optionally, the normal temperature condensing system includes VOCs liquid storage pot and normal temperature condenser, normal temperature condenser can adopt conventional high-efficient cold source or natural cold source.
Optionally, the adsorption fan and the desorption fan are explosion-proof variable frequency fans.
The utility model also provides an utilize the processing method of the quiet active VOC normal atmospheric temperature condensation processing system of above-mentioned active carbon, including following step:
step 10, debugging equipment, closing all adsorption air inlet valves Aa1, adsorption air inlet valves Ba1, all adsorption air outlet valves Aa2 and adsorption air outlet valves Ba2, opening all the rest valves, then starting a nitrogen source, replacing the gas in a system pipeline and the equipment with nitrogen, and closing all the valves and the nitrogen source when an online oxygen content detector shows that the oxygen content is lower than 5%;
step 20, opening an adsorption air inlet valve Aa1 and an adsorption air outlet valve Aa2, cooling the organic waste gas by a pretreatment system, removing particles, sending the organic waste gas into an adsorption bed A, purifying the organic waste gas to reach the standard, and discharging the organic waste gas into the atmosphere;
step 30, when the display value of the VOCs concentration sensor Av behind the adsorption bed A reaches 50% of the emission standard, closing an adsorption gas outlet valve Aa2, opening a series valve Ab, connecting the adsorption bed B behind the adsorption bed A in series, and discharging the waste gas into the atmosphere after passing through the adsorption bed A and the adsorption bed B in sequence until the VOCs concentration sensor Av displays that the adsorption bed A reaches the saturated adsorption amount and cannot continue to adsorb, and then, entering a desorption stage by the adsorption bed A and continuing to adsorb by the adsorption bed B;
step 40, before desorption of the adsorption bed A, opening a nitrogen supplement valve n1, a nitrogen supplement valve n2 and a nitrogen source, replacing the gas in the adsorption bed A with nitrogen and sending the nitrogen into an adsorption pipeline, and closing the nitrogen supplement valves n1 and n2 and the nitrogen source when the online oxygen content detector shows that the oxygen content is lower than 5%; then opening a desorption condensation valve Ad1, a desorption condensation valve Ad2, a stop valve, a desorption fan and a heater in sequence, switching a three-way butterfly valve to a passage I and a passage III, and opening a condensation system when the display value of a VOCs concentration sensor Cv reaches the condensation concentration until no condensate flows out;
step 50, closing the stop valve, opening a valve Cp1 and a valve Cp2, switching the three-way butterfly valve to a passage I and a passage II, cooling high-temperature and high-concentration VOCs gas discharged from the adsorption bed A, sending the cooled high-temperature and high-concentration VOCs gas into the adsorption bed C, adsorbing the low-concentration VOCs gas, changing the low-concentration VOCs gas into low-concentration gas, reheating the low-concentration gas, continuously desorbing VOCs in the adsorption bed A until a VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed A, then opening the stop valve, closing the valve Cp1, the valve Cp2 and a heater, and cooling down activated carbon in the adsorption bed;
step 60, when the value displayed by the concentration sensor Bv of the VOCs behind the adsorption bed B reaches 50% of the emission standard, closing the adsorption gas outlet valve Ba2, opening the serial valve Ba, connecting the adsorption bed A behind the adsorption bed B in series, and discharging the waste gas into the atmosphere after passing through the adsorption bed B and the adsorption bed A in sequence until the concentration sensor Bv of the VOCs shows that the adsorption bed B reaches the saturated adsorption capacity and cannot continue to adsorb, and then, entering the desorption stage by the adsorption bed B, and continuing to adsorb by the adsorption bed A;
step 70, before desorption of the adsorption bed B, opening a nitrogen supplement valve n1, a nitrogen supplement valve n2 and a nitrogen source, replacing the gas in the adsorption bed B with nitrogen and sending the nitrogen into an adsorption pipeline, and closing the nitrogen supplement valve n1, the nitrogen supplement valve n2 and the nitrogen source when the online oxygen content detector shows that the oxygen content is lower than 5%; then opening a desorption condensation valve Bd1, a desorption condensation valve Bd2, a stop valve, a desorption fan and a heater in sequence, switching a three-way butterfly valve to a passage I and a passage III, and opening a condensation system when the display value of the VOCs concentration sensor Cv reaches the condensation concentration until no condensate flows out;
step 80, closing the stop valve, opening a valve Cp1 and a valve Cp2, switching the three-way butterfly valve to the positions of the passage I and the passage II, cooling the high-temperature and high-concentration VOCs gas coming out of the adsorption bed B, sending the cooled high-temperature and high-concentration VOCs gas into the adsorption bed C to be adsorbed into low-concentration gas, reheating the low-concentration gas, continuously desorbing the VOCs in the adsorption bed B until a VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed B, then opening the stop valve, closing the valve Cp1, the valve Cp2 and the heater, and cooling the activated carbon in the adsorption bed B;
step 90, repeating the steps 30-80;
step 100, when a concentration sensor Dv of VOCs behind the auxiliary adsorption bed C displays that the adsorption bed C reaches a set transfer limit, a desorption condensation valve Cd1, a desorption condensation valve Cd2 and a stop valve are opened, a three-way butterfly valve is switched to a passage I and a passage III, a desorption fan and a heater are opened, when a display value of the concentration sensor Cv of VOCs reaches a condensation concentration, a condensation system is opened until no condensate flows out, the heater is closed, and the activated carbon in the adsorption bed C is cooled down.
The utility model discloses for prior art gain following technological effect:
the utility model provides a VOCs normal temperature condensation processing system and method using active carbon static activity, which adopts 2+1 mode operation according to the breakthrough curve characteristic of active carbon to VOCs and the combination of active carbon adsorption isotherm characteristic, wherein, 2 represents the same two beds (A \ B) alternate adsorption and is responsible for directly treating the discharged waste gas, the operation condition comprises single bed adsorption, front series adsorption, desorption condensation, purification transfer and back series adsorption; wherein "1" represents auxiliary bed (C), the filling active carbon amount of C bed is generally greater than A \ B bed and C bed is not responsible for waste gas adsorption and purification, its operating condition includes: auxiliary adsorption and desorption condensation. Through utilizing the static activity of the active carbon and adopting the normal temperature condensation combined with the auxiliary adsorption bed with strict matching for auxiliary purification, the cost and the system energy consumption are reduced, and the VOCs solvent is efficiently recovered. According to the characteristic of the breakthrough curve of the activated carbon to the VOCs, when the adsorption bed is about to break through and the series working condition is switched, the activated carbon of the adsorption bed is completely adsorbed and saturated, so that the cost of the activated carbon and the volume of the adsorption bed can be greatly reduced when the activated carbon adsorption bed is designed. And the normal temperature condensation is adopted, so that the deep condensation is avoided, the energy consumption and the process difficulty are reduced, the temperature difference of fluid in the system is reduced, and the thermal stress requirement of equipment and pipelines is reduced, so that the whole scheme is economical and feasible. Strictly match the active carbon quantity of supplementary adsorption bed, make supplementary adsorption bed can adsorb completely and come from remaining VOCs in condensation back adsorption bed A or the B, make the adsorption efficiency of adsorption bed A, B next cycle still can maintain higher level, but further desorption and the VOCs condensation recovery that comes out with desorption after supplementary adsorption bed adsorption finishes moreover, thereby it is higher to maintain higher VOCs rate of recovery and the VOCs concentration after supplementary bed desorption, also make condensation efficiency higher, the condensation energy consumption is lower.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required to be used in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without inventive labor.
Fig. 1 is a schematic view of the utility model of a normal temperature condensation treatment system for VOCs using active carbon static activity;
wherein, 1 is VOCs pretreatment systems, 2 is adsorption fans, 3 is nitrogen source, 4 is online oxygen content detector, 5 is gas-gas heat exchanger, 6 is normal temperature condensing system, 7 is three-way butterfly valve, 8 is desorption fans, 9 is heater, 10 is stop valve.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative work belong to the protection scope of the present invention.
The utility model aims at providing an utilize active carbon static active VOC normal atmospheric temperature condensation processing system to solve the problem that above-mentioned prior art exists, the absorbent capacity of make full use of active carbon can practice thrift the use of active carbon, realizes utilizing the liquefaction of conventional high-efficient cold source or even natural cold source to retrieve VOCs simultaneously, has reduced condensation energy consumption and equipment cost by a wide margin.
In order to make the above objects, features and advantages of the present invention more comprehensible, the present invention is described in detail with reference to the accompanying drawings and the detailed description.
The utility model provides an utilize active carbon static activity's VOCs normal atmospheric temperature condensation processing system and method thereof, as shown in figure 1, this system includes: two parallel adsorption beds A and B, an auxiliary adsorption bed C, VOCs pretreatment system 1, a nitrogen supplement system and a desorption condensation system. The adsorption bed A and the adsorption bed B are connected with the VOCs pretreatment system 1 and the adsorption fan 2 through an adsorption air inlet valve Aa1 and an adsorption air inlet valve Ba1, connected with the atmosphere through an adsorption air outlet valve Aa2 and an adsorption air outlet valve Ba2, and connected with each other through a series valve Ab and a series valve Ba; the adsorption bed A, the adsorption bed B and the auxiliary adsorption bed C are connected with a desorption condensation system through a desorption condensation valve Ad1, a desorption condensation valve Ad2, a desorption condensation valve Bd1, a desorption condensation valve Bd2, a desorption condensation valve Cd1 and a desorption condensation valve Cd2, and the desorption condensation system comprises a gas-gas heat exchanger 5, a normal temperature condensation system 6, a three-way butterfly valve 7, a desorption fan 8, a heater 9 and a stop valve 10; the nitrogen supplementing system is connected with a desorption condensation pipeline through a nitrogen supplementing valve n1 and a nitrogen supplementing valve n2, the other side of the nitrogen supplementing valve n2 is connected with an adsorption pipeline at the front end of the VOCs pretreatment system 1, and the nitrogen supplementing system comprises a nitrogen source 3 and an online oxygen content detector 4; the auxiliary adsorbent bed C is also connected to both sides of the cut-off valve 10 via valves Cp1 and Cp 2.
The processing method of the utility model comprises the following steps:
step 10, in the equipment debugging stage, closing all the adsorption air inlet valves Aa1, the adsorption air inlet valve Ba1, all the adsorption air outlet valves Aa2 and the adsorption air outlet valve Ba2, opening all the rest valves, then opening a nitrogen source, replacing the gas in the system pipeline and the equipment with nitrogen, and closing all the valves and the nitrogen source 3 when the online oxygen content detector 4 shows that the oxygen content is lower than 5%.
Step 20, synchronously opening the adsorption fan 2, opening an adsorption air inlet valve Aa1 and an adsorption air outlet valve Aa2 along with the production line, cooling the organic waste gas by a pretreatment system, removing particles, then sending the organic waste gas into an adsorption bed A, purifying the organic waste gas to reach the standard, and then discharging the organic waste gas into the atmosphere;
step 30, when the display value of the VOCs concentration sensor Av behind the adsorption bed A reaches 50% of the emission standard, closing the adsorption valve Aa2, opening the series valve Ab, improving the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, connecting the adsorption bed B behind the adsorption bed A in series, sequentially passing the waste gas through the adsorption bed A and the adsorption bed B, then discharging the waste gas into the atmosphere until the VOCs concentration sensor Av shows that the adsorption bed A reaches the saturated adsorption volume and cannot continue to adsorb, then, entering a desorption stage by the adsorption bed A, reducing the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, and continuing to adsorb by the adsorption bed B;
step 40, before desorption of the adsorption bed A, opening a nitrogen supplement valve n1, a nitrogen supplement valve n2 and a nitrogen source 3, replacing the gas in the adsorption bed A with nitrogen and sending the nitrogen into an adsorption pipeline, and closing the nitrogen supplement valve n1, the nitrogen supplement valve n2 and the nitrogen source 3 when the online oxygen content detector 4 shows that the oxygen content is lower than 5%; then opening a desorption condensation valve Ad1, a desorption condensation valve Ad2, a stop valve, a desorption fan and a heater in sequence, switching a three-way butterfly valve to a passage I and a passage III, and opening a condensation system when the display value of a VOCs concentration sensor Cv reaches the condensation concentration until no condensate flows out;
step 50, no VOCs is desorbed from the adsorption bed A at the moment, but the condensation residual quantity of the VOCs in the adsorption bed A at the moment influences the adsorption efficiency of the next period, so that the residual VOCs in the adsorption bed A needs to be transferred into the auxiliary adsorption bed C; closing the stop valve 10, opening the valve Cp1 and the valve Cp2, switching the three-way butterfly valve 7 to the passage I and the passage II, increasing the frequency of the desorption fan 8 to keep the desorption air volume unchanged, cooling the high-temperature and high-concentration VOCs gas coming out of the adsorption bed a, sending the cooled high-temperature and high-concentration VOCs gas into the adsorption bed C, adsorbing the low-concentration VOCs gas, and then reheating the low-concentration VOCs gas, continuously desorbing the VOCs in the adsorption bed a until the VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed a, then opening the stop valve 10, closing the valve Cp1, the valve Cp2 and the heater, cooling down the activated carbon in the adsorption bed a, and then sequentially closing the desorption fan 2, the condensing system 6, the desorption condensation valve Ad1, the desorption condensation valve Ad2 and the stop valve 10;
step 60, when the value displayed by the concentration sensor Bv of the VOCs behind the adsorption bed B reaches 50% of the emission standard, closing the adsorption valve Ba2, opening the series valve Ba, improving the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, connecting the adsorption bed A behind the adsorption bed B in series, discharging the waste gas into the atmosphere through the adsorption beds B and A in sequence until the concentration sensor Bv of the VOCs shows that the adsorption bed B reaches the saturated adsorption volume and cannot continue to adsorb, then, entering the desorption stage by the adsorption bed B, reducing the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, and continuing to adsorb by the adsorption bed A;
step 70, before desorption of the adsorption bed B, opening a nitrogen supplement valve n1, a nitrogen supplement valve n2 and a nitrogen source 3, replacing the gas in the adsorption bed B with nitrogen and sending the nitrogen into an adsorption pipeline, and closing the nitrogen supplement valve n1, the nitrogen supplement valve n2 and the nitrogen source 3 when the online oxygen content detector 4 shows that the oxygen content is lower than 5%; then opening a desorption condensation valve Bd1, a desorption condensation valve Bd2, a stop valve 10, a desorption fan 8 and a heater 9 in sequence, switching a three-way butterfly valve 7 to a passage I and a passage III, desorbing VOCs in the adsorption bed B by high-temperature nitrogen at the moment, and opening a condensation system 6 when the display value of a VOCs concentration sensor Cv reaches the condensation concentration until no condensate flows out;
80, desorbing no VOCs in the adsorption bed B at the moment, wherein the residual VOCs in the adsorption bed B after condensation influences the adsorption efficiency of the next period, so that the residual VOCs in the adsorption bed B needs to be transferred into the auxiliary adsorption bed C; closing the stop valve 10, opening a valve Cp1\ Cp2, switching the three-way butterfly valve 7 to the positions of the passage I and the passage II, increasing the frequency of the desorption fan 8 to keep the desorption air volume unchanged, cooling the high-temperature high-concentration VOCs gas coming out of the adsorption bed B, sending the cooled high-temperature high-concentration VOCs gas into the adsorption bed C to be adsorbed into low-concentration gas, heating the low-concentration gas, continuously desorbing VOCs in the adsorption bed B until the VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed B, then opening the stop valve 10, closing the valve Cp1\ Cp2 and the heater to cool down the activated carbon in the adsorption bed B, and then closing the desorption fan 2, the condensing system 6, the desorption condensation valve Bd1, the desorption condensation valve Bd2 and the stop valve 10 in sequence;
step 90, repeating the above steps 30-80
Step 100, when the concentration sensor Dv of the VOCs behind the auxiliary adsorption bed C shows that the adsorption bed C reaches the transfer limit, opening a desorption condensation valve Cd1, a desorption condensation valve Cd2 and a stop valve 10, switching a three-way butterfly valve to a passage I and a passage III, opening a desorption fan 8 and a heater 9, when the display value of the concentration sensor Dv of the VOCs reaches the condensation concentration, opening a condensation system 6 until no condensate flows out, closing the heater 9, and cooling down the activated carbon in the adsorption bed C.
The saturated adsorption amount qb for a given activated carbon depends on the discharge concentration of VOCs, the exhaust air temperature and the type of VOCs; the condensation concentration Cc depends on the VOCs species and the condensation temperature; the condensation residual quantity qr of the VOCs depends on the desorption temperature and the condensation concentration Cc; the transfer limit qc depends on the condensation temperature and desorption concentration Cd; mc (qc-qr) is not less than Nmqr, and the dosage of the activated carbon can be calculated by taking equal sign when the auxiliary adsorption bed is designed, and 20 percent of margin is reserved, wherein N represents transferable times.
The utility model discloses a concrete example is applied to explain the principle and the implementation mode of the utility model, and the explanation of the above example is only used to help understand the method and the core idea of the utility model; meanwhile, for the general technical personnel in the field, according to the idea of the present invention, there are changes in the concrete implementation and the application scope. In summary, the content of the present specification should not be construed as a limitation of the present invention.

Claims (7)

1. The utility model provides an utilize active carbon static active VOC normal atmospheric temperature condensation processing system which characterized in that: the device comprises a VOCs pretreatment system, a desorption and condensation system and an auxiliary adsorption bed C, wherein two adsorption beds A and B which are connected in parallel are arranged on one side of the auxiliary adsorption bed C; the adsorption bed A is connected with an adsorption fan through an adsorption air inlet valve Aa1, and the adsorption bed B is connected with the adsorption fan through an adsorption air inlet valve Ba 1; the adsorption fan is connected with the VOCs pretreatment system; the adsorption bed A is connected with the atmosphere through an adsorption gas outlet valve Aa2, and the adsorption bed B is connected with the atmosphere through an adsorption gas outlet valve Ba 2; the adsorption bed A and the adsorption bed B are in serial closed connection through a serial valve Ab and a serial valve Ba; the two ends of the adsorption bed A are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Ad1 and a desorption condensation valve Ad2, the two ends of the adsorption bed B are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Bd1 and a desorption condensation valve Bd2, and the two ends of the adsorption bed C are respectively connected with the two ends of the desorption condensation system through a desorption condensation valve Cd1 and a desorption condensation valve Cd 2.
2. A VOC ambient condensation processing system using active carbon static activity according to claim 1, wherein: the operation conditions of the adsorption bed A and the adsorption bed B comprise single-bed adsorption, front series adsorption, desorption condensation, purification transfer and rear series adsorption, and the operation condition of the auxiliary adsorption bed C comprises auxiliary adsorption and desorption condensation.
3. The VOC ambient condensation processing system using active carbon static activity according to claim 1, characterized in that: the desorption and condensation system comprises a gas-gas heat exchanger, a normal temperature condensation system, a three-way butterfly valve, a desorption fan, a stop valve and a heater which are sequentially connected in series; the three-way butterfly valve comprises a passage I, a passage II and a passage III, the normal temperature condensing system is connected with the passage I, the desorption fan is connected with the passage II, a connecting pipeline between the passage II and the desorption fan is connected with a first branch connected with the gas-gas heat exchanger, and the passage III is connected with the gas-gas heat exchanger through a second branch; the auxiliary adsorption bed C is connected to both ends of the cutoff valve through a valve Cp1 and a valve Cp 2; desorption condensation valve Ad1, desorption condensation valve Bd1 and desorption condensation valve Cd1 through first desorption condensation pipeline with heater connection, desorption condensation valve Ad2, desorption condensation valve Bd2 and desorption condensation valve Cd2 through second desorption condensation pipeline with the gas heat exchanger is connected.
4. The VOC ambient temperature condensation treatment system using the static activity of the activated carbon as claimed in claim 3, wherein: the system is characterized by further comprising a nitrogen supplementing system, wherein the nitrogen supplementing system comprises a nitrogen source and an online oxygen content detector, the nitrogen source is connected with a second desorption condensation pipeline through a nitrogen supplementing valve n1, the first desorption condensation pipeline is connected with a nitrogen supplementing valve n2, and the nitrogen supplementing valve n2 is connected with an adsorption pipeline at the front end of the VOCs pretreatment system through the online oxygen content detector.
5. The VOC ambient temperature condensation treatment system using the static activity of the activated carbon as claimed in claim 3, wherein: the adsorption bed A with be provided with VOCs concentration sensor Av between the valve of gas a2 out of adsorbing, adsorption bed B with be provided with VOCs concentration sensor Bv between the valve of gas a2 out of adsorbing, the gas heat exchanger with be provided with VOCs concentration sensor Cv between the normal atmospheric temperature condensing system, stop valve one end with be provided with VOCs concentration sensor Dv between the valve Cp 2.
6. The VOC ambient temperature condensation treatment system using the static activity of the activated carbon as claimed in claim 3, wherein: the normal temperature condensing system comprises a VOCs liquid storage tank and a normal temperature condenser, and the normal temperature condenser can adopt a natural cold source.
7. The VOC ambient temperature condensation treatment system using the static activity of the activated carbon as claimed in claim 3, wherein: the adsorption fan and the desorption fan are explosion-proof variable frequency fans.
CN201922261653.6U 2019-12-16 2019-12-16 VOC normal temperature condensation processing system utilizing active carbon static activity Active CN211706335U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201922261653.6U CN211706335U (en) 2019-12-16 2019-12-16 VOC normal temperature condensation processing system utilizing active carbon static activity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201922261653.6U CN211706335U (en) 2019-12-16 2019-12-16 VOC normal temperature condensation processing system utilizing active carbon static activity

Publications (1)

Publication Number Publication Date
CN211706335U true CN211706335U (en) 2020-10-20

Family

ID=72818168

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201922261653.6U Active CN211706335U (en) 2019-12-16 2019-12-16 VOC normal temperature condensation processing system utilizing active carbon static activity

Country Status (1)

Country Link
CN (1) CN211706335U (en)

Similar Documents

Publication Publication Date Title
CN111013318A (en) VOC normal-temperature condensation treatment system and method utilizing static activity of activated carbon
CN111389175B (en) Series targeted adsorption and parallel desorption organic waste gas treatment device
CN205760441U (en) A kind of scattered adsorption, the organic exhaust gas purifying system of concentration desorption and regeneration
CN210171129U (en) VOCs processing system of supplementary purification of normal atmospheric temperature condensation
CN106422647B (en) Low liquefaction temperature organic waste gas recovery device
CN110681690A (en) Device and method for repairing polluted soil through continuous vacuum thermal desorption
CN107051116A (en) A kind of organic waste gas treatment system
CN211706335U (en) VOC normal temperature condensation processing system utilizing active carbon static activity
CN208340417U (en) N-butanol exhaust treatment system
CN110508096A (en) VOC gas activated carbon adsorption total system
CN110075658B (en) VOCs treatment system for normal temperature condensation auxiliary purification and treatment method thereof
CN207042186U (en) A kind of organic waste gas treatment system
CN206778138U (en) The adjustable activated carbon adsorption/desorption complexes of Wet-dry
CN109985485B (en) Device and method for adsorbing, recovering and purifying high-concentration gas
CN210936435U (en) Continuous vacuum thermal desorption polluted soil remediation device
CN208032239U (en) A kind of VOCs high-level cleaners
US7377964B2 (en) Device for processing discharging exhaust gas
CN104772035A (en) Volatile organic compound processing device
CN111135710A (en) High-efficient oil gas clean system
CN218221759U (en) Solvent recovery equipment of pharmaceutical factory
CN210441684U (en) Energy-conserving and constant temperature and humidity's VOCs processing system that admits air
CN211913237U (en) Recovery system of small-flow organic waste gas
CN220214421U (en) Adsorption and desorption system for realizing concentration reduction treatment of VOCs (volatile organic compounds) by resin combined with activated carbon
CN217662415U (en) Active carbon adsorption concentration catalytic combustion system
CN216171184U (en) VOC gas adsorber adsorbs high concentration compensating system

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant