CN211706335U - VOC normal temperature condensation processing system utilizing active carbon static activity - Google Patents

VOC normal temperature condensation processing system utilizing active carbon static activity Download PDF

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CN211706335U
CN211706335U CN201922261653.6U CN201922261653U CN211706335U CN 211706335 U CN211706335 U CN 211706335U CN 201922261653 U CN201922261653 U CN 201922261653U CN 211706335 U CN211706335 U CN 211706335U
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高军
张承全
曹昌盛
夏云飞
谢午豪
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Tongji University
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Abstract

本实用新型公开一种利用活性炭静活性的VOC常温冷凝处理系统及方法,涉及工业排放VOCs处理技术领域,该系统包括VOCs预处理系统、脱附冷凝系统、辅助吸附床C、吸附床A和吸附床B;吸附床A和B通过吸附进气阀门与吸附风机相连;吸附风机连有VOCs预处理系统;吸附床A和B通过吸附出气阀门与大气相连;吸附床A和B之间通过串联阀门Ab和Ba串行闭合连接;吸附床A、吸附床B和辅助吸附床C两端分别通过脱附冷凝阀门与脱附冷凝系统两端相连。采用本实用新型系统的处理方法充分利用了活性炭的静活性,降低成本,延长使用寿命,并且回收的有机溶剂纯度较高,回收效率高;采用“2+1”模式使得控制策略更加简单,运行更加可靠。

Figure 201922261653

The utility model discloses a VOC room temperature condensation treatment system and method utilizing the static activity of activated carbon, and relates to the technical field of industrial emission VOCs treatment. The system comprises a VOCs pretreatment system, a desorption condensation system, an auxiliary adsorption bed C, an adsorption bed A and an adsorption Bed B; Adsorption beds A and B are connected to the adsorption fan through the adsorption inlet valve; the adsorption fan is connected to the VOCs pretreatment system; Ab and Ba are serially closed and connected; both ends of adsorption bed A, adsorption bed B and auxiliary adsorption bed C are respectively connected to both ends of the desorption condensation system through desorption condensation valves. The treatment method using the system of the utility model makes full use of the static activity of the activated carbon, reduces the cost, prolongs the service life, and the recovered organic solvent has high purity and high recovery efficiency; the "2+1" mode makes the control strategy simpler and the operation more reliable.

Figure 201922261653

Description

一种利用活性炭静活性的VOC常温冷凝处理系统A VOC room temperature condensation treatment system using activated carbon static activity

技术领域technical field

本实用新型涉及工业排放VOCs处理技术领域,特别是涉及一种利用活性炭静活性的VOC常温冷凝处理系统。The utility model relates to the technical field of industrial emission VOCs treatment, in particular to a VOC room temperature condensation treatment system utilizing the static activity of activated carbon.

背景技术Background technique

大气中的挥发性有机物(VOCs)对植物和动物生命造成严重伤害,并且影响人类健康例如刺激眼睛、引起呼吸道问题、引发癌症等。作为有机溶剂应用于诸如喷涂、家具等行业的VOCs可占大气VOCs排放源的35-40%。在上述行业中,VOCs常见的处理手段包括:吸附、吸收、冷凝等回收方法和直接燃烧、催化氧化、生物处理、低温等离子体和光催化等破坏方法;实际应用时一般组合上述方法的两种或者三种。其中活性炭吸附浓缩结合冷凝回收的VOCs处理方法后续处理更加方便简单,而且经济效益高,是比较理想的处理方法。Volatile organic compounds (VOCs) in the atmosphere cause serious damage to plant and animal life and affect human health such as eye irritation, respiratory problems, cancer and the like. VOCs used as organic solvents in industries such as spraying and furniture can account for 35-40% of atmospheric VOCs emission sources. In the above industries, common treatment methods for VOCs include: adsorption, absorption, condensation and other recovery methods and direct combustion, catalytic oxidation, biological treatment, low temperature plasma and photocatalysis and other destruction methods; in practical applications, two or more of the above methods are generally combined. three. Among them, the VOCs treatment method of activated carbon adsorption concentration combined with condensation recovery is more convenient and simple, and has high economic benefits, which is an ideal treatment method.

罗福坤等人提出一种活性炭吸附、N2脱附回收处理有机废气的工艺,吸附结束后采用N2真空4~10KPa循环加热脱附后经双级冷凝设备冷凝,残留的VOCs采用新鲜空气吹扫后送入另一吸附器吸附。该专利能有效脱附出VOCs气体并冷凝,但是最后采用新鲜空气吹扫仍面临安全风险且影响活性炭适用寿命。和雅妮等人提出一种活性炭吸附热氮气脱附冷凝回收系统,脱附气体后采用三级冷凝,脱附后管道中的不凝气体进入辅助活性炭吸附器吸附,此专利仍存在三级冷凝能耗高、设备热应力及气密性要求高的问题。Luo Fukun et al. proposed a process of activated carbon adsorption and N2 desorption to recover and treat organic waste gas. After adsorption, N2 vacuum 4-10KPa cycle heating and desorption is used, and then it is condensed by a two-stage condensing device, and the residual VOCs are purged with fresh air. into another adsorber for adsorption. The patent can effectively desorb and condense VOCs gas, but the final use of fresh air purging still faces safety risks and affects the service life of activated carbon. He Yani et al. proposed an activated carbon adsorption hot nitrogen desorption condensation recovery system. After desorption of gas, three-stage condensation is used. After desorption, the non-condensable gas in the pipeline enters the auxiliary activated carbon adsorber for adsorption. There is still three-stage condensation in this patent. High energy consumption, equipment thermal stress and high air tightness requirements.

本人也曾提出一种常温冷凝辅助提纯的VOCs处理系统及其处理方法,采用三个相同床轮换吸附净化、脱附冷凝、辅助提纯,实现脱附冷凝后床体残留量非常少以保证正常吸附周期内的排放VOCs浓度达标。此专利实现了常温冷凝同时保证的吸附效率达标,降低了工艺难度、设备成本和运行能耗,但是该专利与其他类似专利相同仅利用了活性炭的动活性,并且对活性炭吸附脱附性能要求较高,要求辅助吸附时吸附量大于冷凝残余量与动态吸附量之和,否则会出现转移不足导致吸附净化后排放浓度不达标的弊端。I have also proposed a VOCs treatment system and its treatment method for assisted purification by normal temperature condensation, using three identical beds to alternate adsorption purification, desorption condensation, and auxiliary purification to achieve a very small residual amount in the bed after desorption and condensation to ensure normal adsorption. The concentration of VOCs emitted during the cycle meets the standard. This patent realizes the adsorption efficiency at the same time of normal temperature condensation, and reduces the process difficulty, equipment cost and operating energy consumption. However, this patent, like other similar patents, only utilizes the kinetic activity of activated carbon, and has higher requirements on the adsorption and desorption performance of activated carbon. It is required that the adsorption amount during auxiliary adsorption is greater than the sum of the condensation residual amount and the dynamic adsorption amount, otherwise there will be the disadvantage of insufficient transfer and the emission concentration after adsorption and purification will not meet the standard.

现阶段VOCs的吸附浓缩冷凝回收方法普遍面临着如下四个问题:需深度冷凝因此冷凝和加热能耗都大幅提高;系统设备、管道和阀门承受大温差造成应力损失且气密性难以满足;冷凝后吸附床仍残留的一部分VOCs造成下一阶段的吸附效率下降或者采用新鲜空气热吹扫面临爆炸风险;仅利用了活性炭的吸附动活性,浪费了部分活性炭的吸附能力。At present, the adsorption, concentration, condensation and recovery methods of VOCs generally face the following four problems: deep condensation is required, so the energy consumption of condensation and heating is greatly increased; system equipment, pipes and valves are subjected to large temperature differences, resulting in stress loss and difficult to meet air tightness; condensation; Part of the VOCs still remaining in the latter adsorption bed will cause the next stage of the adsorption efficiency to drop, or the use of fresh air hot purging will face the risk of explosion; only the adsorption kinetic activity of activated carbon is used, and part of the adsorption capacity of activated carbon is wasted.

实用新型内容Utility model content

本实用新型的目的是提供一种利用活性炭静活性的VOC常温冷凝处理系统,以解决上述现有技术存在的问题,充分利用活性炭的吸附能力,可节约活性炭的使用,同时实现利用常规高效冷源甚至天然冷源液化回收VOCs,大幅降低了冷凝能耗和设备成本。The purpose of this utility model is to provide a VOC room temperature condensation treatment system utilizing the static activity of activated carbon, so as to solve the problems existing in the above-mentioned prior art, make full use of the adsorption capacity of activated carbon, save the use of activated carbon, and realize the utilization of conventional high-efficiency cold sources at the same time. Even natural cold source liquefaction recovers VOCs, which greatly reduces condensation energy consumption and equipment costs.

为实现上述目的,本实用新型提供了如下方案:For achieving the above object, the utility model provides the following scheme:

本实用新型提供一种利用活性炭静活性的VOC常温冷凝处理系统,包括VOCs预处理系统、脱附冷凝系统和辅助吸附床C,所述辅助吸附床C一侧设置有两台并联的吸附床A和吸附床B;所述吸附床A通过吸附进气阀门Aa1与吸附风机相连,所述吸附床B通过吸附进气阀门Ba1与所述吸附风机相连;所述吸附风机连接有所述VOCs预处理系统;所述吸附床A通过吸附出气阀门Aa2与大气相连,所述吸附床B通过吸附出气阀门Ba2与大气相连;所述吸附床A和吸附床B之间通过串联阀门Ab和串联阀门Ba串行闭合连接;所述吸附床A两端分别通过脱附冷凝阀门Ad1和脱附冷凝阀门Ad2与脱附冷凝系统两端相连,吸附床B两端分别通过脱附冷凝阀门Bd1和脱附冷凝阀门Bd2与脱附冷凝系统两端相连,吸附床C两端分别通过脱附冷凝阀门Cd1和脱附冷凝阀门Cd2与脱附冷凝系统两端相连。The utility model provides a VOC room temperature condensation treatment system utilizing the static activity of activated carbon, comprising a VOCs pretreatment system, a desorption condensation system and an auxiliary adsorption bed C, and two parallel adsorption beds A are arranged on one side of the auxiliary adsorption bed C and adsorption bed B; the adsorption bed A is connected with the adsorption fan through the adsorption inlet valve Aa1, and the adsorption bed B is connected with the adsorption fan through the adsorption inlet valve Ba1; the adsorption fan is connected with the VOCs pretreatment system; the adsorption bed A is connected to the atmosphere through the adsorption gas outlet valve Aa2, and the adsorption bed B is connected to the atmosphere through the adsorption gas outlet valve Ba2; between the adsorption bed A and the adsorption bed B, the series valve Ab and the series valve Ba are connected together. The two ends of the adsorption bed A are connected with the two ends of the desorption condensation system through the desorption condensation valve Ad1 and the desorption condensation valve Ad2 respectively, and the two ends of the adsorption bed B are respectively connected through the desorption condensation valve Bd1 and the desorption condensation valve. Bd2 is connected to both ends of the desorption condensation system, and both ends of the adsorption bed C are connected to both ends of the desorption condensation system through the desorption condensation valve Cd1 and the desorption condensation valve Cd2 respectively.

可选的,所述脱附冷凝系统包括依次串行连接的气气换热器、常温冷凝系统、三通蝶阀、脱附风机、截止阀和加热器;所述三通蝶阀包括I通路、II通路和III通路,所述常温冷凝系统与I通路连接,所述脱附风机与II通路连接,所述II通路与所述脱附风机之间的连接管路上连接有与所述气气换热器连接的第一支路,所述III通路通过第二支路与所述气气换热器连接;所述辅助吸附床C通过阀门Cp1和阀门Cp2连接在所述截止阀两端;所述脱附冷凝阀门Ad1、脱附冷凝阀门Bd1和脱附冷凝阀门Cd1通过第一脱附冷凝管道与所述加热器连接,所述脱附冷凝阀门Ad2、脱附冷凝阀门Bd2和脱附冷凝阀门Cd2通过第二脱附冷凝管道与所述气气换热器连接。Optionally, the desorption condensing system includes a gas-air heat exchanger, a normal temperature condensing system, a three-way butterfly valve, a desorption fan, a stop valve and a heater that are serially connected in sequence; the three-way butterfly valve includes I passage, II Passage and passage III, the normal temperature condensing system is connected with the I passage, the desorption fan is connected with the II passage, and the connecting pipeline between the II passage and the desorption fan is connected with the gas-gas heat exchange The first branch connected to the device, the III passage is connected to the gas-gas heat exchanger through the second branch; the auxiliary adsorption bed C is connected to both ends of the stop valve through the valve Cp1 and the valve Cp2; the The desorption condensation valve Ad1, the desorption condensation valve Bd1 and the desorption condensation valve Cd1 are connected to the heater through the first desorption condensation pipeline, and the desorption condensation valve Ad2, the desorption condensation valve Bd2 and the desorption condensation valve Cd2 It is connected with the gas-gas heat exchanger through a second desorption condensation pipeline.

可选的,还包括氮气补充系统,所述氮气补充系统包括氮气源和在线氧含量检测仪,所述氮气源通过氮气补充阀门n1与第二脱附冷凝管道相连,所述第一脱附冷凝管道连接有氮气补充阀门n2,所述氮气补充阀门n2通过在线氧含量检测仪与所述VOCs预处理系统前端的吸附管道相连。Optionally, it also includes a nitrogen supplement system, the nitrogen supplement system includes a nitrogen source and an on-line oxygen content detector, the nitrogen source is connected to the second desorption condensation pipeline through a nitrogen supplement valve n1, and the first desorption condensation The pipeline is connected with a nitrogen supplementary valve n2, and the nitrogen supplementary valve n2 is connected with the adsorption pipeline at the front end of the VOCs pretreatment system through an online oxygen content detector.

可选的,所述吸附床A与所述吸附出气阀门Aa2之间设置有VOCs浓度传感器Av,所述吸附床B与所述吸附出气阀门Ba2之间设置有VOCs浓度传感器Bv,所述气气换热器与所述常温冷凝系统之间设置有VOCs浓度传感器Cv,所述截止阀一端与所述阀门Cp2之间设置有VOCs浓度传感器Dv。Optionally, a VOCs concentration sensor Av is arranged between the adsorption bed A and the adsorption gas outlet valve Aa2, and a VOCs concentration sensor Bv is arranged between the adsorption bed B and the adsorption gas outlet valve Ba2. A VOCs concentration sensor Cv is arranged between the heat exchanger and the normal temperature condensing system, and a VOCs concentration sensor Dv is arranged between one end of the shut-off valve and the valve Cp2.

可选的,所述常温冷凝系统包括VOCs储液罐和常温冷凝器,所述常温冷凝器能够采用常规高效冷源或天然冷源。Optionally, the normal temperature condensation system includes a VOCs liquid storage tank and a normal temperature condenser, and the normal temperature condenser can use a conventional high-efficiency cold source or a natural cold source.

可选的,所述吸附风机和所述脱附风机均为防爆变频风机。Optionally, both the adsorption fan and the desorption fan are explosion-proof variable frequency fans.

本实用新型还提供一种利用上述活性炭静活性的VOC常温冷凝处理系统的处理方法,包括如下步骤:The utility model also provides a treatment method for the VOC normal temperature condensation treatment system utilizing the static activity of the above-mentioned activated carbon, comprising the following steps:

步骤10、设备调试,关闭所有吸附进气阀门Aa1、吸附进气阀门Ba1和所有吸附出气阀门Aa2、吸附出气阀门Ba2,打开所有剩余阀门,然后开启氮气源,将系统管道和设备内的气体均置换为氮气,当在线氧含量检测仪显示氧气含量低于5%时关闭所有阀门和氮气源;Step 10. Equipment debugging, close all adsorption inlet valves Aa1, adsorption inlet valves Ba1 and all adsorption outlet valves Aa2, adsorption outlet valves Ba2, open all remaining valves, and then turn on the nitrogen source to remove the gas in the system pipeline and equipment. Replace with nitrogen, when the online oxygen content detector shows that the oxygen content is lower than 5%, close all valves and nitrogen sources;

步骤20、开启吸附进气阀门Aa1和吸附出气阀门Aa2,有机废气经预处理系统降温除颗粒后送入吸附床A,净化达标后排入大气;Step 20. Open the adsorption inlet valve Aa1 and the adsorption outlet valve Aa2, and the organic waste gas is cooled and removed by the pretreatment system and then sent to the adsorption bed A, and discharged into the atmosphere after being purified to the standard;

步骤30、当吸附床A后的VOCs浓度传感器Av显示值达到排放标准的50%时,关闭吸附出气阀门Aa2,打开串联阀门Ab,吸附床B串联在吸附床A后面,废气依次经过吸附床A和吸附床B再排入大气,直至VOCs浓度传感器Av显示吸附床A已达饱和吸附量,无法继续吸附,然后吸附床A进入脱附阶段,吸附床B继续吸附;Step 30. When the displayed value of the VOCs concentration sensor Av behind the adsorption bed A reaches 50% of the emission standard, close the adsorption outlet valve Aa2, open the series valve Ab, the adsorption bed B is connected in series behind the adsorption bed A, and the exhaust gas passes through the adsorption bed A in turn. and adsorption bed B and then discharged into the atmosphere until the VOCs concentration sensor Av shows that the adsorption bed A has reached the saturated adsorption capacity and cannot continue the adsorption, and then the adsorption bed A enters the desorption stage, and the adsorption bed B continues to adsorb;

步骤40、吸附床A脱附前,打开氮气补充阀门n1、氮气补充阀门n2和氮气源,将吸附床A内的气体置换为氮气送入吸附管道内,当在线氧含量检测仪显示氧气含量低于5%时关闭氮气补充阀门n1、n2和氮气源;然后依次开启脱附冷凝阀门Ad1、脱附冷凝阀门Ad2、截止阀、脱附风机和加热器,三通蝶阀切换到I通路、III三通路处,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统,直至无冷凝液流出;Step 40. Before the adsorption bed A is desorbed, open the nitrogen supplement valve n1, the nitrogen supplement valve n2 and the nitrogen source, and replace the gas in the adsorption bed A with nitrogen and send it into the adsorption pipeline. When the online oxygen content detector shows that the oxygen content is low At 5%, close the nitrogen supplementary valves n1, n2 and the nitrogen source; then open the desorption condensing valve Ad1, the desorption condensing valve Ad2, the shut-off valve, the desorption fan and the heater in turn, and the three-way butterfly valve is switched to I channel, III three. At the passage, when the displayed value of the VOCs concentration sensor Cv reaches the condensing concentration, the condensing system is turned on until no condensate flows out;

步骤50、关闭截止阀,开启阀门Cp1和阀门Cp2,将三通蝶阀切换到I通路、II通路处,从吸附床A出来的高温高浓度VOCs气体经冷却后送入吸附床C内吸附变为低浓度气体再加热,此时可将吸附床A内的VOCs继续脱附出来,直至VOCs浓度传感器Cv显示吸附床A内再无VOCs脱附出来,然后开启截止阀、关闭阀门Cp1、阀门Cp2和加热器,将吸附床A内的活性炭冷却下来;Step 50, close the stop valve, open the valve Cp1 and the valve Cp2, switch the three-way butterfly valve to the I channel and the II channel, and the high-temperature and high-concentration VOCs gas from the adsorption bed A is cooled and sent to the adsorption bed C for adsorption. The low-concentration gas is reheated. At this time, the VOCs in the adsorption bed A can continue to be desorbed until the VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed A. Then open the stop valve, close the valve Cp1, the valve Cp2 and The heater cools the activated carbon in the adsorption bed A;

步骤60、当吸附床B后的VOCs浓度传感器Bv显示值达到排放标准的50%时,关闭吸附出气阀门Ba2,打开串联阀门Ba,吸附床A串联在吸附床B后面,废气依次经过吸附床B和吸附床A再排入大气,直至VOCs浓度传感器Bv显示吸附床B已达饱和吸附量,无法继续吸附,然后吸附床B进入脱附阶段,吸附床A继续吸附;Step 60. When the displayed value of the VOCs concentration sensor Bv behind the adsorption bed B reaches 50% of the emission standard, close the adsorption outlet valve Ba2, open the series valve Ba, the adsorption bed A is connected in series behind the adsorption bed B, and the exhaust gas passes through the adsorption bed B in turn. and adsorption bed A and then discharged into the atmosphere until the VOCs concentration sensor Bv shows that the adsorption bed B has reached the saturated adsorption capacity and cannot continue to adsorb, and then the adsorption bed B enters the desorption stage, and the adsorption bed A continues to adsorb;

步骤70、吸附床B脱附前,打开氮气补充阀门n1、氮气补充阀门n2和氮气源,将吸附床B内的气体置换为氮气送入吸附管道内,当在线氧含量检测仪显示氧气含量低于5%时关闭氮气补充阀门n1、氮气补充阀门n2和氮气源;然后依次开启脱附冷凝阀门Bd1、脱附冷凝阀门Bd2、截止阀、脱附风机和加热器,三通蝶阀切换到I通路、III通路处,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统,直至无冷凝液流出;Step 70: Before the desorption of the adsorption bed B, open the nitrogen supplement valve n1, the nitrogen supplement valve n2 and the nitrogen source, and replace the gas in the adsorption bed B with nitrogen and send it into the adsorption pipeline. When the online oxygen content detector shows that the oxygen content is low At 5%, close the nitrogen supplement valve n1, nitrogen supplement valve n2 and nitrogen source; then open the desorption condensing valve Bd1, the desorption condensing valve Bd2, the stop valve, the desorption fan and the heater in turn, and the three-way butterfly valve is switched to the I channel , III passage, when the VOCs concentration sensor Cv display value reaches the condensing concentration, open the condensing system until no condensate flows out;

步骤80、关闭截止阀,开启阀门Cp1、阀门Cp2,将三通蝶阀切换到I通路、II通路位置,从吸附床B出来的高温高浓度VOCs气体经冷却后送入吸附床C内吸附变为低浓度气体再加热,此时可将吸附床B内的VOCs继续脱附出来,直至VOCs浓度传感器Cv显示吸附床B内再无VOCs脱附出来,然后开启截止阀、关闭阀门Cp1、阀门Cp2和加热器,将吸附床B内的活性炭冷却下来;Step 80, close the stop valve, open the valve Cp1 and the valve Cp2, switch the three-way butterfly valve to the I channel and the II channel position, and the high temperature and high concentration VOCs gas from the adsorption bed B is cooled and sent to the adsorption bed C for adsorption to become. The low-concentration gas is reheated. At this time, the VOCs in the adsorption bed B can continue to be desorbed until the VOCs concentration sensor Cv shows that no VOCs are desorbed in the adsorption bed B. Then open the stop valve, close the valve Cp1, the valve Cp2 and The heater cools the activated carbon in the adsorption bed B;

步骤90、重复上述步骤30-80;Step 90, repeat the above steps 30-80;

步骤100、当辅助吸附床C后的VOCs浓度传感器Dv显示吸附床C达到设定转移极限量,开启脱附冷凝阀门Cd1、脱附冷凝阀门Cd2、截止阀,将三通蝶阀切换到I通路、III通路处,开启脱附风机和加热器,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统,直至无冷凝液流出,关闭加热器,将吸附床C内的活性炭冷却下来。Step 100, when the VOCs concentration sensor Dv behind the auxiliary adsorption bed C shows that the adsorption bed C has reached the set transfer limit, open the desorption condensation valve Cd1, the desorption condensation valve Cd2, and the stop valve, and switch the three-way butterfly valve to the I channel, At passage III, turn on the desorption fan and heater. When the displayed value of the VOCs concentration sensor Cv reaches the condensing concentration, turn on the condensing system until no condensate flows out, turn off the heater, and cool down the activated carbon in the adsorption bed C.

本实用新型相对于现有技术取得了以下技术效果:The utility model has achieved the following technical effects with respect to the prior art:

本实用新型提供的利用活性炭静活性的VOCs常温冷凝处理系统及其方法,根据活性炭对VOCs的突破曲线特性并结合活性炭吸附等温线特性,采用2+1模式运行,其中“2”代表相同两床(A\B)轮换吸附,负责直接处理排放废气,其运行工况包括:单床吸附、前串联吸附、脱附冷凝、提纯转移、后串联吸附;其中“1”代表辅助床(C),C床填充活性炭量一般大于A\B床并且C床不负责废气吸附净化,其运行工况包括:辅助吸附和脱附冷凝。通过利用活性炭静活性并采用常温冷凝结合严格匹配的辅助吸附床辅助提纯,降低了成本和系统能耗,高效回收了VOCs溶剂。根据活性炭对VOCs的突破曲线特性,在吸附床即将突破时及切换串联工况,使得该吸附床活性炭完全吸附饱和,因此在设计活性炭吸附床时可大幅降低活性炭成本和吸附床体积。采用常温冷凝,避免了深度冷凝,降低了能耗和工艺难度,并降低了系统内流体温差,降低了设备及管道的热应力要求,从而使得整个方案经济可行。严格匹配辅助吸附床的活性炭用量,使得辅助吸附床可完全吸附来自冷凝后吸附床A或B内残留的VOCs,使得吸附床A、B下一周期的吸附效率仍可维持在较高水平,而且辅助吸附床吸附结束后可进一步脱附并将脱附出来的VOCs冷凝回收,从而维持较高的VOCs回收率且辅助床脱附后的VOCs浓度更高,也使得冷凝效率更高,冷凝能耗更低。The VOCs room temperature condensation treatment system and method using the static activity of activated carbon provided by the utility model, according to the characteristics of the breakthrough curve of activated carbon to VOCs combined with the characteristics of activated carbon adsorption isotherm, adopt the 2+1 mode of operation, wherein "2" represents the same two beds (A\B) Rotational adsorption, responsible for the direct treatment of exhaust gas, its operating conditions include: single bed adsorption, front series adsorption, desorption condensation, purification transfer, rear series adsorption; where "1" represents auxiliary bed (C), The amount of activated carbon filled in the C bed is generally larger than that of the A\B bed, and the C bed is not responsible for the adsorption and purification of waste gas. Its operating conditions include: auxiliary adsorption and desorption condensation. By utilizing the static activity of activated carbon and using normal temperature condensation combined with a strictly matched auxiliary adsorption bed for auxiliary purification, the cost and system energy consumption are reduced, and the VOCs solvent is efficiently recovered. According to the breakthrough curve characteristics of activated carbon to VOCs, when the adsorption bed is about to break through and switch the series working conditions, the activated carbon of the adsorption bed is completely saturated with adsorption, so the cost of activated carbon and the volume of the adsorption bed can be greatly reduced when designing the activated carbon adsorption bed. The use of room temperature condensation avoids deep condensation, reduces energy consumption and process difficulty, reduces the temperature difference of fluids in the system, and reduces the thermal stress requirements of equipment and pipelines, thus making the entire solution economically feasible. Strictly match the amount of activated carbon in the auxiliary adsorption bed, so that the auxiliary adsorption bed can completely adsorb the VOCs remaining in the adsorption bed A or B after condensation, so that the adsorption efficiency of the adsorption bed A and B in the next cycle can still be maintained at a high level, and After the adsorption of the auxiliary adsorption bed is completed, it can be further desorbed and the desorbed VOCs can be condensed and recovered, so as to maintain a high VOCs recovery rate and a higher concentration of VOCs after desorption of the auxiliary adsorption bed, which also makes the condensation efficiency higher and condensation energy consumption. lower.

附图说明Description of drawings

为了更清楚地说明本实用新型实施例或现有技术中的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本实用新型的一些实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其他的附图。In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the accompanying drawings required in the embodiments will be briefly introduced below. Obviously, the drawings in the following description are only of the present invention. For some embodiments of the present invention, for those of ordinary skill in the art, other drawings can also be obtained according to these drawings without any creative effort.

图1为为本实用新型的利用活性炭静活性的VOCs常温冷凝处理系统的示意图;Fig. 1 is the schematic diagram of the VOCs normal temperature condensation treatment system utilizing activated carbon static activity of the present invention;

其中,1为VOCs预处理系统、2为吸附风机、3为氮气源、4为在线氧含量检测仪、5为气气换热器、6为常温冷凝系统、7为三通蝶阀、8为脱附风机、9为加热器、10为截止阀。Among them, 1 is VOCs pretreatment system, 2 is adsorption fan, 3 is nitrogen source, 4 is online oxygen content detector, 5 is gas-air heat exchanger, 6 is normal temperature condensation system, 7 is three-way butterfly valve, 8 is dehydrator With fan, 9 is heater, 10 is stop valve.

具体实施方式Detailed ways

下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present utility model will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present utility model. Obviously, the described embodiments are only a part of the embodiments of the present utility model, rather than all the implementations. example. Based on the embodiments of the present invention, all other embodiments obtained by those of ordinary skill in the art without creative work fall within the protection scope of the present invention.

本实用新型的目的是提供一种利用活性炭静活性的VOC常温冷凝处理系统,以解决上述现有技术存在的问题,充分利用活性炭的吸附能力,可节约活性炭的使用,同时实现利用常规高效冷源甚至天然冷源液化回收VOCs,大幅降低了冷凝能耗和设备成本。The purpose of this utility model is to provide a VOC room temperature condensation treatment system utilizing the static activity of activated carbon, so as to solve the problems existing in the above-mentioned prior art, make full use of the adsorption capacity of activated carbon, save the use of activated carbon, and realize the utilization of conventional high-efficiency cold sources at the same time. Even natural cold source liquefaction recovers VOCs, which greatly reduces condensation energy consumption and equipment costs.

为使本实用新型的上述目的、特征和优点能够更加明显易懂,下面结合附图和具体实施方式对本实用新型作进一步详细的说明。In order to make the above objects, features and advantages of the present utility model more clearly understood, the present utility model will be described in further detail below with reference to the accompanying drawings and specific embodiments.

本实用新型提供一种利用活性炭静活性的VOCs常温冷凝处理系统及其方法,如图1所示,该系统包括:两台并联的吸附床A和吸附床B、一台辅助吸附床C、VOCs预处理系统1、氮气补充系统和脱附冷凝系统。吸附床A、吸附床B通过吸附进气阀门Aa1、吸附进气阀门Ba1与VOCs预处理系统1和吸附风机2相连,通过吸附出气阀门Aa2、吸附出气阀门Ba2与大气相连,吸附床A、吸附床B之间通过串联阀门Ab和串联阀门Ba相连;吸附床A、吸附床B及辅助吸附床C通过脱附冷凝阀门Ad1、脱附冷凝阀门Ad2、脱附冷凝阀门Bd1、脱附冷凝阀门Bd2、脱附冷凝阀门Cd1、脱附冷凝阀门Cd2与脱附冷凝系统相连,脱附冷凝系统包括气气换热器5、常温冷凝系统6、三通蝶阀7、脱附风机8、加热器9和截止阀10;氮气补充系统通过氮气补充阀门n1、氮气补充阀门n2与脱附冷凝管道相连,氮气补充阀门n2另一侧与VOCs预处理系统1前端的吸附管道相连,氮气补充系统包括氮气源3和在线氧含量检测仪4;辅助吸附床C还通过阀门Cp1、阀门Cp2连接在截止阀10两侧。The utility model provides a room temperature condensation treatment system for VOCs using the static activity of activated carbon and a method thereof. As shown in FIG. 1, the system includes: two parallel adsorption beds A and B, an auxiliary adsorption bed C, VOCs Pretreatment system 1, nitrogen supplementary system and desorption condensation system. The adsorption bed A and the adsorption bed B are connected to the VOCs pretreatment system 1 and the adsorption fan 2 through the adsorption inlet valve Aa1 and the adsorption inlet valve Ba1, and are connected to the atmosphere through the adsorption outlet valve Aa2 and the adsorption outlet valve Ba2. Beds B are connected through series valve Ab and series valve Ba; adsorption bed A, adsorption bed B and auxiliary adsorption bed C are connected through desorption condensation valve Ad1, desorption condensation valve Ad2, desorption condensation valve Bd1, and desorption condensation valve Bd2 , Desorption condensing valve Cd1, desorption condensing valve Cd2 are connected with desorption condensing system, desorption condensing system includes gas-air heat exchanger 5, normal temperature condensing system 6, three-way butterfly valve 7, desorption fan 8, heater 9 and Stop valve 10; the nitrogen supplementary system is connected to the desorption condensation pipeline through the nitrogen supplementary valve n1 and the nitrogen supplementary valve n2, and the other side of the nitrogen supplementary valve n2 is connected to the adsorption pipeline at the front end of the VOCs pretreatment system 1, and the nitrogen supplementary system includes a nitrogen source 3 and the online oxygen content detector 4; the auxiliary adsorption bed C is also connected to both sides of the stop valve 10 through the valve Cp1 and the valve Cp2.

本实用新型的处理方法步骤如下:The steps of the processing method of the present invention are as follows:

步骤10、在设备调试阶段,关闭所有吸附进气阀门Aa1、吸附进气阀门Ba1和所有吸附出气阀门Aa2、吸附出气阀门Ba2,打开所有剩余阀门,然后开启氮气源,将系统管道和设备内的气体均置换为氮气,当在线氧含量检测仪4显示氧气含量低于5%时关闭所有阀门和氮气源3。Step 10. In the equipment debugging stage, close all adsorption inlet valves Aa1, adsorption inlet valves Ba1, all adsorption outlet valves Aa2, adsorption outlet valves Ba2, open all remaining valves, and then turn on the nitrogen source, and connect the system pipes and equipment to the All gases are replaced with nitrogen, and when the online oxygen content detector 4 shows that the oxygen content is lower than 5%, all valves and nitrogen sources 3 are closed.

步骤20、随生产流水线同步开启吸附风机2、开启吸附进气阀门Aa1和吸附出气阀门Aa2,有机废气经预处理系统降温除颗粒后送入吸附床A,净化达标后排入大气;Step 20, synchronously open the adsorption fan 2 with the production line, open the adsorption inlet valve Aa1 and the adsorption outlet valve Aa2, the organic waste gas is cooled by the pretreatment system to remove particles and then sent to the adsorption bed A, and discharged into the atmosphere after the purification reaches the standard;

步骤30、当吸附床A后的VOCs浓度传感器Av显示值达到排放标准的50%时,关闭吸附阀门Aa2,打开串联阀门Ab,提高吸附风机2的频率保持吸附风量不变,吸附床B串联在吸附床A后面,废气依次经过吸附床A和吸附床B再排入大气直至VOCs浓度传感器Av显示吸附床A已达饱和吸附量,无法继续吸附,然后吸附床A进入脱附阶段,降低吸附风机2的频率保持吸附风量不变,吸附床B继续吸附;Step 30. When the displayed value of the VOCs concentration sensor Av behind the adsorption bed A reaches 50% of the emission standard, close the adsorption valve Aa2, open the series valve Ab, increase the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, and the adsorption bed B is connected in series After the adsorption bed A, the exhaust gas passes through the adsorption bed A and the adsorption bed B in turn and is discharged into the atmosphere until the VOCs concentration sensor Av shows that the adsorption bed A has reached the saturated adsorption capacity, and the adsorption cannot be continued. Then the adsorption bed A enters the desorption stage, and the adsorption fan is lowered. The frequency of 2 keeps the adsorption air volume unchanged, and the adsorption bed B continues to adsorb;

步骤40、吸附床A脱附前,打开氮气补充阀门n1、氮气补充阀门n2和氮气源3,将吸附床A内的气体置换为氮气送入吸附管道内,当在线氧含量检测仪4显示氧气含量低于5%时关闭氮气补充阀门n1、氮气补充阀门n2和氮气源3;然后依次开启脱附冷凝阀门Ad1、脱附冷凝阀门Ad2、截止阀、脱附风机和加热器,三通蝶阀切换到I通路、III三通路处,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统,直至无冷凝液流出;Step 40, before the adsorption bed A is desorbed, open the nitrogen supplementary valve n1, the nitrogen supplementary valve n2 and the nitrogen source 3, replace the gas in the adsorption bed A with nitrogen and send it into the adsorption pipeline, when the online oxygen content detector 4 displays oxygen When the content is less than 5%, close the nitrogen supplementary valve n1, nitrogen supplementary valve n2 and nitrogen source 3; then open the desorption condensing valve Ad1, the desorption condensing valve Ad2, the stop valve, the desorption fan and the heater in turn, and the three-way butterfly valve switches When the VOCs concentration sensor Cv display value reaches the condensing concentration, open the condensing system until no condensate flows out;

步骤50、此时吸附床A无VOCs脱附出来,但此时吸附床A内VOCs冷凝残留量会影响下一周期的吸附效率,因此需将吸附床A内的残留VOCs转移到辅助吸附床C内;关闭截止阀10,开启阀门Cp1、阀门Cp2,将三通蝶阀7切换到I通路、II通路处,提高脱附风机8的频率保持脱附风量不变,从吸附床A出来的高温高浓度VOCs气体经冷却后送入吸附床C内吸附变为低浓度气体再加热,此时可将吸附床A内的VOCs继续脱附出来,直至VOCs浓度传感器Cv显示吸附床A内再无VOCs脱附出来,然后开启截止阀10、关闭阀门Cp1、阀门Cp2和加热器,将吸附床A内的活性炭冷却下来,然后依次关闭脱附风机2、冷凝系统6、脱附冷凝阀门Ad1、脱附冷凝阀门Ad2和截止阀10;Step 50: At this time, no VOCs are desorbed from the adsorption bed A, but the residual VOCs condensation in the adsorption bed A will affect the adsorption efficiency of the next cycle. Therefore, the residual VOCs in the adsorption bed A need to be transferred to the auxiliary adsorption bed C. Close the stop valve 10, open the valve Cp1 and the valve Cp2, switch the three-way butterfly valve 7 to the I channel and the II channel, increase the frequency of the desorption fan 8 to keep the desorption air volume unchanged, and the high temperature from the adsorption bed A is high. After cooling, the concentrated VOCs gas is sent to the adsorption bed C for adsorption and becomes a low-concentration gas for reheating. At this time, the VOCs in the adsorption bed A can continue to be desorbed until the VOCs concentration sensor Cv shows that there is no more VOCs in the adsorption bed A. Attached, then open the stop valve 10, close the valve Cp1, the valve Cp2 and the heater, cool down the activated carbon in the adsorption bed A, and then turn off the desorption fan 2, the condensation system 6, the desorption condensation valve Ad1, and the desorption condensation. Valve Ad2 and globe valve 10;

步骤60、当吸附床B后的VOCs浓度传感器Bv显示值达到排放标准的50%时,关闭吸附阀门Ba2,打开串联阀门Ba,提高吸附风机2的频率保持吸附风量不变,吸附床A串联在吸附床B后面,废气依次经过吸附床B和A再排入大气直至VOCs浓度传感器Bv显示吸附床B已达饱和吸附量,无法继续吸附,然后吸附床B进入脱附阶段,降低吸附风机2的频率保持吸附风量不变,吸附床A继续吸附;Step 60. When the display value of the VOCs concentration sensor Bv behind the adsorption bed B reaches 50% of the emission standard, close the adsorption valve Ba2, open the series valve Ba, increase the frequency of the adsorption fan 2 to keep the adsorption air volume unchanged, and the adsorption bed A is connected in series After the adsorption bed B, the exhaust gas passes through the adsorption beds B and A in turn and is discharged into the atmosphere until the VOCs concentration sensor Bv shows that the adsorption bed B has reached the saturated adsorption capacity, and the adsorption cannot be continued. Then the adsorption bed B enters the desorption stage, reducing the adsorption fan 2. The frequency keeps the adsorption air volume unchanged, and the adsorption bed A continues to adsorb;

步骤70、吸附床B脱附前,打开氮气补充阀门n1、氮气补充阀门n2和氮气源3,将吸附床B内的气体置换为氮气送入吸附管道内,当在线氧含量检测仪4显示氧气含量低于5%时关闭氮气补充阀门n1、氮气补充阀门n2和氮气源3;然后依次开启脱附冷凝阀门Bd1、脱附冷凝阀门Bd2、截止阀10、脱附风机8和加热器9,三通蝶阀7切换到I通路、III通路处,此时高温氮气将吸附床B内的VOCs脱附出来,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统6,直至无冷凝液流出;Step 70. Before desorption of the adsorption bed B, open the nitrogen supplementary valve n1, the nitrogen supplementary valve n2 and the nitrogen source 3, replace the gas in the adsorption bed B with nitrogen and send it into the adsorption pipeline, when the online oxygen content detector 4 displays oxygen When the content is less than 5%, close the nitrogen supplement valve n1, nitrogen supplement valve n2 and nitrogen source 3; then open the desorption condensing valve Bd1, the desorption condensing valve Bd2, the stop valve 10, the desorption fan 8 and the heater 9 in turn, three The butterfly valve 7 is switched to the I passage and the III passage. At this time, the high temperature nitrogen will desorb the VOCs in the adsorption bed B. When the VOCs concentration sensor Cv display value reaches the condensing concentration, the condensing system 6 is turned on until no condensate flows out;

步骤80、此时吸附床B无VOCs脱附出来,但此时吸附床B内VOCs冷凝残留量会影响下一周期的吸附效率,因此需将吸附床B内的残留VOCs转移到辅助吸附床C内;关闭截止阀10,开启阀门Cp1\Cp2,将三通蝶阀7切换到I通路、II通路位置,提高脱附风机8的频率保持脱附风量不变,从吸附床B出来的高温高浓度VOCs气体经冷却后送入吸附床C内吸附变为低浓度气体再加热,此时可将吸附床B内的VOCs继续脱附出来,直至VOCs浓度传感器Cv显示吸附床B内再无VOCs脱附出来,然后开启截止阀10、关闭阀门Cp1\Cp2和加热器,将吸附床B内的活性炭冷却下来,然后依次关闭脱附风机2、冷凝系统6、脱附冷凝阀门Bd1、脱附冷凝阀门Bd2和截止阀10;Step 80: At this time, no VOCs are desorbed from the adsorption bed B, but the residual VOCs condensation in the adsorption bed B will affect the adsorption efficiency of the next cycle. Therefore, the residual VOCs in the adsorption bed B need to be transferred to the auxiliary adsorption bed C. Close the stop valve 10, open the valves Cp1\Cp2, switch the three-way butterfly valve 7 to the I channel and the II channel position, increase the frequency of the desorption fan 8 to keep the desorption air volume unchanged, and the high temperature and high concentration from the adsorption bed B After the VOCs gas is cooled, it is sent to the adsorption bed C for adsorption and becomes a low-concentration gas and then heated. At this time, the VOCs in the adsorption bed B can continue to be desorbed until the VOCs concentration sensor Cv shows that there is no more VOCs in the adsorption bed B desorbed. out, then open the stop valve 10, close the valves Cp1\Cp2 and the heater, cool down the activated carbon in the adsorption bed B, and then turn off the desorption fan 2, the condensation system 6, the desorption condensation valve Bd1, and the desorption condensation valve Bd2 in turn. and shut-off valve 10;

步骤90、重复上述步骤30-80Step 90, repeat the above steps 30-80

步骤100、当辅助吸附床C后的VOCs浓度传感器Dv显示吸附床C达到转移极限量了,开启脱附冷凝阀门Cd1、脱附冷凝阀门Cd2、截止阀10,将三通蝶阀切换到I通路、III通路处,开启脱附风机8和加热器9,当VOCs浓度传感器Cv显示值达到冷凝浓度时,开启冷凝系统6,直至无冷凝液流出,关闭加热器9,将吸附床C内的活性炭冷却下来。Step 100, when the VOCs concentration sensor Dv behind the auxiliary adsorption bed C shows that the adsorption bed C has reached the transfer limit, open the desorption condensation valve Cd1, the desorption condensation valve Cd2, and the cut-off valve 10, and switch the three-way butterfly valve to the I channel, At passage III, turn on the desorption fan 8 and the heater 9. When the displayed value of the VOCs concentration sensor Cv reaches the condensing concentration, turn on the condensing system 6 until no condensate flows out, turn off the heater 9, and cool the activated carbon in the adsorption bed C. down.

对于给定活性炭该饱和吸附量qb取决于VOCs排放浓度、排风温度和VOCs种类;该冷凝浓度Cc取决于VOCs种类和冷凝温度;该VOCs冷凝残留量qr取决于脱附温度和冷凝浓度Cc;该转移极限量qc取决于冷凝温度和脱附浓度Cd;mc(qc-qr)≥Nmqr,设计辅助吸附床时可取等号计算活性炭用量,并保留20%的富裕量,其中N表示可转移次数。For a given activated carbon, the saturated adsorption amount qb depends on the VOCs emission concentration, exhaust air temperature and the type of VOCs; the condensation concentration Cc depends on the type of VOCs and condensation temperature; the VOCs condensation residual amount qr depends on the desorption temperature and condensation concentration Cc; The transfer limit qc depends on the condensation temperature and the desorption concentration Cd; mc(qc-qr)≥Nmqr, when designing the auxiliary adsorption bed, an equal sign can be used to calculate the amount of activated carbon, and 20% of the surplus is reserved, where N represents the number of transfers .

本实用新型中应用了具体个例对本实用新型的原理及实施方式进行了阐述,以上实施例的说明只是用于帮助理解本实用新型的方法及其核心思想;同时,对于本领域的一般技术人员,依据本实用新型的思想,在具体实施方式及应用范围上均会有改变之处。综上所述,本说明书内容不应理解为对本实用新型的限制。The principles and implementations of the present utility model are described with specific examples in the present utility model, and the descriptions of the above embodiments are only used to help understand the method and the core idea of the present utility model; meanwhile, for those skilled in the art , according to the idea of the present utility model, there will be changes in the specific implementation and application scope. In conclusion, the content of this specification should not be construed as a limitation on the present invention.

Claims (7)

1.一种利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:包括VOCs预处理系统、脱附冷凝系统和辅助吸附床C,所述辅助吸附床C一侧设置有两台并联的吸附床A和吸附床B;所述吸附床A通过吸附进气阀门Aa1与吸附风机相连,所述吸附床B通过吸附进气阀门Ba1与所述吸附风机相连;所述吸附风机连接有所述VOCs预处理系统;所述吸附床A通过吸附出气阀门Aa2与大气相连,所述吸附床B通过吸附出气阀门Ba2与大气相连;所述吸附床A和吸附床B之间通过串联阀门Ab和串联阀门Ba串行闭合连接;所述吸附床A两端分别通过脱附冷凝阀门Ad1和脱附冷凝阀门Ad2与脱附冷凝系统两端相连,吸附床B两端分别通过脱附冷凝阀门Bd1和脱附冷凝阀门Bd2与脱附冷凝系统两端相连,吸附床C两端分别通过脱附冷凝阀门Cd1和脱附冷凝阀门Cd2与脱附冷凝系统两端相连。1. a VOC normal temperature condensation treatment system utilizing active carbon static activity is characterized in that: comprise VOCs pretreatment system, desorption condensation system and auxiliary adsorption bed C, and one side of described auxiliary adsorption bed C is provided with two parallel adsorption Bed A and adsorption bed B; the adsorption bed A is connected with the adsorption fan through the adsorption inlet valve Aa1, and the adsorption bed B is connected with the adsorption fan through the adsorption inlet valve Ba1; the adsorption fan is connected with the VOCs Pretreatment system; described adsorption bed A is connected with the atmosphere through adsorption outlet valve Aa2, and described adsorption bed B is connected with the atmosphere through adsorption outlet valve Ba2; between described adsorption bed A and adsorption bed B, through series valve Ab and series valve Ba is serially closed and connected; the two ends of the adsorption bed A are connected to the two ends of the desorption condensation system through the desorption condensation valve Ad1 and the desorption condensation valve Ad2 respectively, and the two ends of the adsorption bed B are respectively connected to the two ends of the desorption condensation system through the desorption condensation valve Bd1 and the desorption condensation valve. The condensation valve Bd2 is connected to both ends of the desorption condensation system, and the two ends of the adsorption bed C are respectively connected to both ends of the desorption condensation system through the desorption condensation valve Cd1 and the desorption condensation valve Cd2. 2.如权利要求1所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:所述吸附床A、吸附床B运行工况包括单床吸附、前串联吸附、脱附冷凝、提纯转移、后串联吸附,所述辅助吸附床C运行工况包括辅助吸附和脱附冷凝。2. The VOC normal temperature condensation treatment system utilizing activated carbon static activity as claimed in claim 1, is characterized in that: described adsorption bed A, adsorption bed B operating conditions include single bed adsorption, front series adsorption, desorption condensation, purification Transfer, post-series adsorption, the auxiliary adsorption bed C operating conditions include auxiliary adsorption and desorption condensation. 3.根据权利要求1所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:所述脱附冷凝系统包括依次串行连接的气气换热器、常温冷凝系统、三通蝶阀、脱附风机、截止阀和加热器;所述三通蝶阀包括I通路、II通路和III通路,所述常温冷凝系统与I通路连接,所述脱附风机与II通路连接,所述II通路与所述脱附风机之间的连接管路上连接有与所述气气换热器连接的第一支路,所述III通路通过第二支路与所述气气换热器连接;所述辅助吸附床C通过阀门Cp1和阀门Cp2连接在所述截止阀两端;所述脱附冷凝阀门Ad1、脱附冷凝阀门Bd1和脱附冷凝阀门Cd1通过第一脱附冷凝管道与所述加热器连接,所述脱附冷凝阀门Ad2、脱附冷凝阀门Bd2和脱附冷凝阀门Cd2通过第二脱附冷凝管道与所述气气换热器连接。3. The VOC normal temperature condensation treatment system utilizing the static activity of activated carbon according to claim 1, is characterized in that: the desorption condensation system comprises a gas-air heat exchanger, a normal temperature condensation system, a three-way butterfly valve, Desorption fan, shut-off valve and heater; the three-way butterfly valve includes I passage, II passage and III passage, the normal temperature condensation system is connected with I passage, the desorption fan is connected with II passage, and the II passage is connected with The connecting pipeline between the desorption fans is connected with a first branch connected to the gas-gas heat exchanger, and the III passage is connected to the gas-gas heat exchanger through a second branch; the auxiliary The adsorption bed C is connected to both ends of the stop valve through the valve Cp1 and the valve Cp2; the desorption condensation valve Ad1, the desorption condensation valve Bd1 and the desorption condensation valve Cd1 are connected to the heater through the first desorption condensation pipeline , the desorption condensation valve Ad2, the desorption condensation valve Bd2 and the desorption condensation valve Cd2 are connected to the gas-gas heat exchanger through a second desorption condensation pipeline. 4.根据权利要求3所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:还包括氮气补充系统,所述氮气补充系统包括氮气源和在线氧含量检测仪,所述氮气源通过氮气补充阀门n1与第二脱附冷凝管道相连,所述第一脱附冷凝管道连接有氮气补充阀门n2,所述氮气补充阀门n2通过在线氧含量检测仪与所述VOCs预处理系统前端的吸附管道相连。4. The VOC normal temperature condensation treatment system utilizing the static activity of activated carbon according to claim 3, is characterized in that: it also comprises a nitrogen supplement system, and the nitrogen supplement system comprises a nitrogen source and an on-line oxygen content detector, and the nitrogen source passes through The nitrogen supplementary valve n1 is connected with the second desorption condensation pipeline, the first desorption condensation pipeline is connected with a nitrogen supplementary valve n2, and the nitrogen supplementary valve n2 is adsorbed by the online oxygen content detector with the front end of the VOCs pretreatment system. The pipes are connected. 5.根据权利要求3所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:所述吸附床A与所述吸附出气阀门Aa2之间设置有VOCs浓度传感器Av,所述吸附床B与所述吸附出气阀门Ba2之间设置有VOCs浓度传感器Bv,所述气气换热器与所述常温冷凝系统之间设置有VOCs浓度传感器Cv,所述截止阀一端与所述阀门Cp2之间设置有VOCs浓度传感器Dv。5. The VOC normal temperature condensation treatment system utilizing the static activity of activated carbon according to claim 3 is characterized in that: a VOCs concentration sensor Av is arranged between the adsorption bed A and the adsorption outlet valve Aa2, and the adsorption bed B is provided with a VOCs concentration sensor Av. A VOCs concentration sensor Bv is arranged between the adsorption and gas outlet valve Ba2, a VOCs concentration sensor Cv is arranged between the gas-air heat exchanger and the normal temperature condensation system, and one end of the shut-off valve is between the valve Cp2. A VOCs concentration sensor Dv is provided. 6.根据权利要求3所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:所述常温冷凝系统包括VOCs储液罐和常温冷凝器,所述常温冷凝器能够采用天然冷源。6 . The VOC room temperature condensation treatment system utilizing the static activity of activated carbon according to claim 3 , wherein the room temperature condensation system comprises a VOCs liquid storage tank and a room temperature condenser, and the room temperature condenser can use a natural cold source. 7 . 7.根据权利要求3所述的利用活性炭静活性的VOC常温冷凝处理系统,其特征在于:所述吸附风机和所述脱附风机均为防爆变频风机。7 . The VOC room temperature condensation treatment system utilizing the static activity of activated carbon according to claim 3 , wherein the adsorption fan and the desorption fan are both explosion-proof frequency conversion fans. 8 .
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111013318A (en) * 2019-12-16 2020-04-17 同济大学 A VOC room temperature condensation treatment system and method utilizing the static activity of activated carbon

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