CN211079354U - Electrolytic device for manganese electrolysis - Google Patents
Electrolytic device for manganese electrolysis Download PDFInfo
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- CN211079354U CN211079354U CN201922024784.2U CN201922024784U CN211079354U CN 211079354 U CN211079354 U CN 211079354U CN 201922024784 U CN201922024784 U CN 201922024784U CN 211079354 U CN211079354 U CN 211079354U
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- anolyte
- chamber
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- outlet
- inlet
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Abstract
The utility model relates to an electrochemistry field, concretely relates to electrolytic device for manganese electrolysis. The method comprises the following steps: the device comprises a box body, a partition plate, an ionic membrane device, an anode plate, a cathode plate, an anolyte chamber, an upper anolyte chamber, a lower anolyte chamber, a catholyte chamber, an anolyte inlet, an anolyte outlet, a catholyte inlet, a catholyte outlet and a lead copper bar. By completely isolating the reaction of the catholyte chamber and the anolyte chamber and respectively arranging the inlet and the outlet on the catholyte chamber and the anolyte chamber, the problems of small operation space and high labor intensity of viewing the cell of the traditional structure liquid phase index are solved; the problem of difficult control of the index of the bath solution is solved by arranging the overflow groove.
Description
Technical Field
The utility model relates to an electrochemistry field, concretely relates to electrolytic device for manganese electrolysis.
Background
The electrolytic manganese metal electrolytic tank has the advantages that most of the prior electrolytic manganese metal electrolytic tanks adopt a diaphragm frame body to support a diaphragm bag structure, and the cathode and the anode are communicated with each other and are isolated by the diaphragm bag part, or cannot meet the production requirements by adopting ionic membrane electrolysis. The existing manganese electrolysis device has the advantages of small structural liquid phase index operation space, high labor intensity of the cell and difficult control of the cell liquid index.
SUMMERY OF THE UTILITY MODEL
In order to solve the problems, the utility model discloses isolated catholyte chamber and anolyte chamber completely to set up exit respectively at catholyte chamber and anolyte chamber.
The utility model discloses a realize through following technical scheme.
An electrolysis apparatus for manganese electrolysis, comprising: the device comprises a box body, a partition plate, an ionic membrane device, an anode plate, a cathode plate, an anolyte chamber, an upper anolyte chamber, a lower anolyte chamber, a catholyte chamber, an anolyte inlet, an anolyte outlet, a catholyte inlet, a catholyte outlet and a lead copper bar;
the baffle is arranged at the lower part 1/3 of the box body to divide the box body into an upper space and a lower space, and a through hole is arranged in the middle of the baffle;
the ionic membrane device comprises a fixed base and an ionic membrane group, wherein the ionic membrane group is of a square-cylindrical cavity structure formed by 2 support plates which are oppositely arranged and 2 ionic membranes which are oppositely arranged, a plurality of strip-shaped holes are formed in the fixed base in parallel, and the number of the ionic membrane group is consistent with that of the strip-shaped holes, is respectively arranged above the strip-shaped holes and is in sealing connection with the periphery of the strip-shaped holes;
the fixed base is arranged on the through hole of the partition plate, the square cylindrical cavity of the ion membrane group is communicated with the lower space of the box body through the strip-shaped hole to form an anolyte chamber, the upper part of the partition plate is provided with a plurality of upper anolyte chambers, and the lower part of the partition plate is provided with a lower anolyte chamber; the space inside the box body except the anode liquid chamber is a cathode liquid chamber;
the anode plate is inserted into the upper anolyte chamber, and the cathode plate is inserted into the catholyte chamber;
the anolyte inlet and the anolyte outlet are both connected with the anolyte chamber, and the catholyte inlet and the catholyte outlet are both connected with the catholyte chamber;
the lead copper bar comprises a cathode copper bar and an anode copper bar which are respectively connected with the cathode plate and the anode plate.
Further, the electrolysis apparatus for manganese electrolysis further comprises an overflow tank which is disposed at an upper edge of an upper side wall of the tank and is perpendicular to the upper anolyte chambers disposed side by side, and communicates with all the upper anolyte chambers through connection pipes.
Furthermore, the anolyte inlet is arranged at the lower edge of the side wall of the lower part of the box body, and the anolyte outlet is arranged outside the overflow groove and communicated with the overflow groove.
Furthermore, the catholyte inlet is arranged at the lower edge of the side wall of the upper part of the box body, the catholyte outlet is arranged at the upper edge of the side wall of the upper part of the box body, and the catholyte outlet and the overflow groove are not overlapped.
Furthermore, a closed connecting seat is arranged at the joint of the strip-shaped hole and the ion membrane group.
Furthermore, the top of the box body is provided with a polar plate fixing frame.
Further, handles are arranged at the tops of the cathode plate and the anode plate.
Furthermore, the anolyte inlet, the anolyte outlet, the catholyte inlet and the catholyte outlet are respectively connected with the flow guide pipe.
Furthermore, a plurality of supports are arranged between the partition board and the bottom of the box body.
The utility model discloses a beneficial effect does: by completely isolating the reaction of the catholyte chamber and the anolyte chamber and respectively arranging the inlet and the outlet on the catholyte chamber and the anolyte chamber, the problems of small operation space and high labor intensity of viewing the cell of the traditional structure liquid phase index are solved; the overflow groove is arranged to solve the problem that the index of the tank liquor is difficult to control; the lead copper bars are respectively positioned at the two upper edges of the groove body in the vertical direction and are supported by the outer extension plates, so that the lead copper bars are conveniently connected with the direct current rectifier cabinet; the cathode chamber and the anode chamber are isolated to carry out electrolysis, the opposite positions are separated by adopting an ionic membrane, an upper anolyte chamber of the electrolytic cell is communicated with a lower anolyte chamber of the electrolytic cell box body, and a plurality of catholyte chamber spaces between the sequentially separated anolyte chambers are communicated with a cathode chamber around the upper part of the electrolytic cell box body, so that smooth liquid flow is ensured; the height of the anode overflow groove is the height of the liquid level in the groove body, and the heights of the cathode and anode liquid levels are consistent, so that the liquid levels of the cathode and anode systems are effectively controlled through the anode overflow groove.
Drawings
Fig. 1 is a perspective view of the utility model;
fig. 2 is a top view of the utility model;
FIG. 3 is a perspective view of the case of the utility model;
fig. 4 is a schematic sectional structure of the utility model;
fig. 5 is a schematic sectional structure of the utility model;
fig. 6 is a schematic sectional structure of the utility model;
fig. 7 is a schematic view of a transparent three-dimensional structure of the present invention.
In the figure: the device comprises a box body 1, a partition plate 2, an ionic membrane device 3, a fixed base 3-1, a support plate 3-2, an ionic membrane 3-3, an anode plate 4, a cathode plate 5, an anolyte chamber 6-1, an anolyte chamber 6-2, a catholyte chamber 7, an anolyte inlet 8, an anolyte outlet 9, a catholyte inlet 10, a catholyte outlet 11, a lead copper bar 12, an overflow groove 13, a connecting pipe 14 and a support 15.
Detailed Description
As shown in fig. 1 to 7: an electrolytic device for manganese electrolysis, comprising: the device comprises a box body 1, a partition plate 2, an ionic membrane device 3, an anode plate 4, a cathode plate 5, an anolyte chamber 6, an upper anolyte chamber 6-1, a lower anolyte chamber 6-2, a catholyte chamber 7, an anolyte inlet 8, an anolyte outlet 9, a catholyte inlet 10, a catholyte outlet 11 and a lead copper bar 12;
the baffle plate 2 is arranged at the lower part 1/3 of the box body 1 to divide the box body 1 into an upper space and a lower space, and a through hole is formed in the middle of the baffle plate 2; the ionic membrane device 3 comprises a fixed base 3-1 and an ionic membrane group, the structure of the ionic membrane group is a square cylindrical cavity structure formed by 2 support plates 3-2 which are oppositely arranged and 2 ionic membranes 3-3 which are oppositely arranged, a plurality of strip-shaped holes are arranged on the fixed base 3-1 in parallel, and the number of the ionic membrane group is consistent with that of the strip-shaped holes, is respectively arranged above the strip-shaped holes and is in sealing connection with the periphery of the strip-shaped holes;
the fixed base 3-1 is arranged on a through hole of the partition plate 2, a square cylindrical cavity of the ion membrane group is communicated with the lower space of the box body 1 through a strip-shaped hole to form an anolyte chamber 6, a plurality of upper anolyte chambers 6-1 are positioned on the upper part of the partition plate 2, and a lower anolyte chamber 6-2 is positioned on the lower part of the partition plate 2; the space in the box body 1 except the anode liquid chamber 6 is a cathode liquid chamber 7; therefore, in the upper part of the box body, besides the periphery of the ion membrane device is the cathode liquid chamber 7, the spaces between the anode liquid chambers which are arranged at intervals in sequence are also the cathode liquid chambers, and the two cathode liquid chambers are communicated. Inserting the anode plates 4 of the same number into the upper anolyte chambers 6-1 and inserting the cathode plates 5 of the same number into the catholyte chambers 7 between the upper anolyte chambers 6-1 which are arranged at intervals in sequence according to the number of the upper anode chambers;
the anolyte inlet 8 and the anolyte outlet 9 are both connected with the anolyte chamber 6, and the catholyte inlet 10 and the catholyte outlet 11 are both connected with the catholyte chamber 7;
the lead copper bar 12 comprises a cathode copper bar and an anode copper bar, and is respectively connected with the cathode plate 5 and the anode plate 4.
The electrolyzer apparatus for manganese electrolysis further comprises an overflow launder 13 which is disposed at the upper edge of the upper side wall of the tank 1 and is perpendicular to the upper anolyte chambers 6-1 disposed side by side, and communicates with all the upper anolyte chambers 6-1 through connecting pipes 14.
The anolyte inlet 8 is arranged at the lower edge of the side wall of the lower part of the box body 1, and the anolyte outlet 9 is arranged outside the overflow groove 13 and communicated with the overflow groove 13.
The catholyte inlet 10 is arranged at the lower edge of the side wall of the upper part of the box body 1, the catholyte outlet 11 is arranged at the upper edge of the side wall of the upper part of the box body 1, and the position of the catholyte outlet 11 is not coincident with the position of the overflow groove 13.
The joint of the strip-shaped hole and the ion membrane group is provided with a closed connecting seat. The top of the box body 1 is provided with a polar plate fixing frame. The top of the cathode plate 5 is provided with a handle. The anolyte inlet 8, the anolyte outlet 9, the catholyte inlet 10 and the catholyte outlet 11 are respectively connected with the flow guide pipe. A plurality of supports 15 are arranged between the clapboard 2 and the bottom of the box body 1.
The utility model discloses a use does: injecting electrolyte containing manganese ions into an anolyte inlet 8, enabling the electrolyte to permeate into a catholyte chamber 6 through an ionic membrane 3-3, connecting a lead copper bar 12 with a direct-current power supply, further electrifying and ionizing, continuously injecting the electrolyte, then drawing the cathode plate attached with manganese out of an electrolytic bath, separating the manganese attached to the cathode plate, and repeating the operation to produce electrolytic manganese. And the catholyte chamber and the anolyte chamber are overhauled and cleaned regularly by disassembling and assembling the ion module.
Claims (9)
1. An electrolysis apparatus for manganese electrolysis, comprising: the device comprises a box body (1), a partition plate (2), an ionic membrane device (3), an anode plate (4), a cathode plate (5), an anolyte chamber (6), an upper anolyte chamber (6-1), a lower anolyte chamber (6-2), a catholyte chamber (7), an anolyte inlet (8), an anolyte outlet (9), a catholyte inlet (10), a catholyte outlet (11) and a lead copper bar (12);
the partition plate (2) is arranged at the lower part 1/3 of the box body (1) and divides the box body (1) into an upper space and a lower space, and a through hole is formed in the middle of the partition plate (2);
the ion membrane device (3) comprises a fixed base (3-1) and an ion membrane group, the ion membrane group is of a square-cylindrical cavity structure formed by 2 support plates (3-2) which are oppositely arranged and 2 ion membranes (3-3) which are oppositely arranged, a plurality of strip-shaped holes are arranged on the fixed base (3-1) in parallel, and the number of the ion membrane group is consistent with that of the strip-shaped holes, is respectively arranged above the strip-shaped holes and is hermetically connected with the periphery of the strip-shaped holes;
the fixed base (3-1) is arranged on the through hole of the partition plate (2), the square cylindrical cavity of the ion membrane group is communicated with the lower space of the box body (1) through the strip-shaped hole to form the anolyte chamber (6), the upper part of the partition plate (2) is provided with a plurality of upper anolyte chambers (6-1), and the lower part of the partition plate (2) is provided with a lower anolyte chamber (6-2); the space in the box body (1) except the anode liquid chamber (6) is the cathode liquid chamber (7);
the anode plate (4) is inserted into the upper anolyte chamber (6-1), and the cathode plate (5) is inserted into the catholyte chamber (7);
the anolyte inlet (8) and the anolyte outlet (9) are both connected with an anolyte chamber (6), and the catholyte inlet (10) and the catholyte outlet (11) are both connected with a catholyte chamber (7);
the lead copper bar (12) comprises a cathode copper bar and an anode copper bar, and is respectively connected with the cathode plate (5) and the anode plate (4).
2. The electrolyzer of manganese electrolysis according to claim 1 further comprising an overflow launder (13), said overflow launder (13) being placed at the upper edge of the upper side wall of the tank (1) and perpendicular to the upper anolyte chambers (6-1) placed side by side and communicating with all the upper anolyte chambers (6-1) through connecting pipes (14).
3. The electrolyzer for manganese electrolysis according to claim 2, characterized in that the anolyte inlet (8) is open at the lower edge of the lower side wall of the tank (1) and the anolyte outlet (9) is arranged outside the overflow launder (13) and communicates with the overflow launder (13).
4. The electrolyzer of manganese electrolysis according to claim 3, characterized in that the catholyte inlet (10) opens at the lower edge of the upper side wall of the box (1), the catholyte outlet (11) is located at the upper edge of the upper side wall of the box (1), and the catholyte outlet (11) is not coincident with the position of the overflow launder (13).
5. The electrolyzer of claim 1 wherein the junction of the strip-shaped hole and the set of ionic membranes is provided with a sealed connecting seat.
6. The electrolyzer for manganese electrolysis according to claim 1 characterized in that the top of the box (1) is provided with a plate holder.
7. An electrolysis apparatus for manganese electrolysis according to claim 1, wherein the top of said cathode plate (5) is provided with a handle.
8. The electrolyzer of claim 1 characterized in that the anolyte inlet (8), the anolyte outlet (9), the catholyte inlet (10) and the catholyte outlet (11) are connected to the draft tube, respectively.
9. An electrolysis apparatus for manganese electrolysis according to claim 1, wherein a plurality of seats (15) are provided between said partition (2) and the bottom of said tank (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201922024784.2U CN211079354U (en) | 2019-11-21 | 2019-11-21 | Electrolytic device for manganese electrolysis |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201922024784.2U CN211079354U (en) | 2019-11-21 | 2019-11-21 | Electrolytic device for manganese electrolysis |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN211079354U true CN211079354U (en) | 2020-07-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201922024784.2U Active CN211079354U (en) | 2019-11-21 | 2019-11-21 | Electrolytic device for manganese electrolysis |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN211079354U (en) |
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2019
- 2019-11-21 CN CN201922024784.2U patent/CN211079354U/en active Active
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| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20211220 Address after: 755100 floor 03, Huaxia special steel living area, Shikong Town Industrial Park, Zhongning County, Zhongwei City, Ningxia Hui Autonomous Region Patentee after: Ningxia Tianyuan manganese Material Research Institute (Co.,Ltd.) Address before: Shikong Town, Zhongning County, Zhongwei City, Ningxia Hui Autonomous Region Patentee before: NINGXIA TIANYUAN MANGANESE INDUSTRY GROUP Co.,Ltd. |
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| TR01 | Transfer of patent right |