CN210505993U - Experimental device for cracking sludge through dielectric barrier discharge - Google Patents

Experimental device for cracking sludge through dielectric barrier discharge Download PDF

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Publication number
CN210505993U
CN210505993U CN201921494577.7U CN201921494577U CN210505993U CN 210505993 U CN210505993 U CN 210505993U CN 201921494577 U CN201921494577 U CN 201921494577U CN 210505993 U CN210505993 U CN 210505993U
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sludge
voltage electrode
discharge
plasma generator
quartz glass
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杨长河
董嘉琦
熊匡
刘涛
彭一鸣
胡骏
郭林松
周世暄
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Lattice Power Jiangxi Corp
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Abstract

The utility model discloses a mud experimental apparatus is explaided in dielectric barrier discharge belongs to sludge treatment technical field. The utility model discloses a mud experimental apparatus is explaided in dielectric barrier discharge, including plasma generator, transformer, oscilloscope and discharge reaction container, the input of plasma generator is connected with the transformer, the oscilloscope with plasma generator's output is connected; by Ca (OH)2Combined with application research of DBD plasma discharge to improve sludge biodegradability, strong current, high energy density, strong ultraviolet radiation and strong shock wave generated in DBD discharge process are used for breaking sludgeThe microbial cells, ozone generated during the discharge process, OH and alkali act in combination to enhance the effect of sludge pretreatment.

Description

Experimental device for cracking sludge through dielectric barrier discharge
Technical Field
The utility model belongs to the technical field of sludge treatment, concretely relates to dielectric barrier discharges and explains mud experimental apparatus.
Background
In recent years, along with the continuous progress of national environmental protection consciousness, people pay more attention to the harmlessness, reduction and resource treatment of excess sludge in municipal sewage plants. Anaerobic digestion is an ideal treatment technology for resourceful treatment of excess sludge in sewage plants because it has good treatment capacity and can generate fuel such as methane during the treatment process.
However, the disposal of the anaerobic sludge digestion technology in actual production is limited to a certain extent. The reason is that the hydrolysis stage in the anaerobic digestion three stages takes longer time, so that the shortening of the anaerobic digestion time of the sludge is significant and the acceleration of the process of the stage is significant. This can be achieved by breaking the cell walls (membranes) of the microorganisms. The main cell wall breaking ideas at present are physical/mechanical, chemical, biological pretreatment and combined pretreatment methods.
Among physical/mechanical methods, hydrothermal method is one of the more common methods, such as Jose (Abelleira-Pereira J.M., Perez-Elvira S.I.Sanchez-Onej., et al.enhancement of methane production in a microbial and biological diagnostic of a second sewage slurry along with thermal hydrolysis [ J ] Water research,2015,71:330-40.) through experiments, the methane yield of sludge hydrothermally pretreated at 170 ℃ for half an hour is 60% higher than that of sludge without hydrothermal pretreatment. However, because a large amount of heat needs to be input in the heating process, the energy consumption is high, and therefore, the application in practical engineering has certain limitations.
The chemical pretreatment process needs to add chemical agents, so the actual effect is limited, and the actual engineering application is still difficult. Experiments of Shipu jade (Yupu jade, grand force, thank exism, Zhenghui, Qiubun. ozone pretreatment on the influence of residual sludge characteristics and anaerobic digestion [ J ]. environmental engineering reports, 2017,11(06):3740 and 3746.) show that after the residual sludge is treated by ozone for 10 minutes, the methane yield reaches 318.29ml, and is improved by about 4 times compared with the methane yield of the sludge without pretreatment. However, the dissolution rate of ozone in water is low, the problem of difficult aeration exists, and the input ozone amount is far larger than the actual dissolution, so the use of ozone in sludge pretreatment is limited.
The biological pretreatment method still has more uncontrollable factors in the actual application process. Zhaoweina (Zhaoweina. behavior research of promoting excess sludge decrement by a thermophilic enzyme dissolving method [ D ].2008.) and the like utilize thermophilic bacteria to pretreat sludge, and under the condition that the culture temperature is 65 ℃, the TSS and VSS dissolving rates of the sludge can reach 32 percent and 48 percent, and are improved by 12 percent and 20 percent compared with those of the sludge which is not inoculated. However, the condition for the microorganism to become the dominant strain in the sludge is still required. With this limitation, the use of microbiological methods in sludge pretreatment is limited.
Disclosure of Invention
The invention aims to solve the defects of the prior art and provide the experimental device for breaking the sludge by dielectric barrier discharge.
The invention adopts the following technical scheme:
the utility model provides a dielectric barrier discharge sludge cracking experimental device, which comprises a plasma generator, a transformer, an oscilloscope and a discharge reaction container, wherein the input end of the plasma generator is connected with the transformer, and the oscilloscope is connected with the output end of the plasma generator;
the discharge reaction vessel includes:
a threaded copper rod;
the high-voltage electrode is connected with one end of the threaded copper rod, and the other end of the threaded copper rod is connected with a power output end of the plasma generator through a lead;
a quartz glass container, the high voltage electrode being in close contact with the bottom of the quartz glass container to obtain uniform discharge;
the low-voltage electrode is arranged opposite to and parallel to the high-voltage electrode;
the low-voltage electrode is arranged at the bottom of the sludge reaction tank and is in close contact with the bottom of the sludge reaction tank;
the low-voltage electrode is connected with the power output end of the plasma generator through a lead and is grounded;
and insulating plates are covered outside the quartz glass container and the sludge reaction tank, and the threaded copper rod vertically penetrates through the insulating plates.
In some embodiments, the panel under the ya keli has been placed to the bottom of discharge reaction vessel, be equipped with several ya keli posts on the ya keli panel, the ya keli top panel is connected to the other end of ya keli post, just the screw thread bar copper passes the ya keli top panel.
In some embodiments, the power supply of the plasma generator adopts a TDGC 2-1 type single-phase contact self-coupling voltage regulator, and the oscilloscope is a GDS-820C oscilloscope. The regulator regulates the voltage of 220V for civil use to the voltage required by the experiment and inputs the voltage into the plasma generator, and the voltage regulator can regulate the voltage. The plasma generator has a current regulation function, can regulate current flow in the process of generating plasma, monitors voltage, current and discharge frequency in the discharge process in real time by means of a GDS-820C oscilloscope, and regulates the voltage and the current by means of a transformer and the plasma generator;
in some embodiments, the high-voltage electrode is a rectangular copper plate, and is 9cm long, 8cm wide and 0.15cm thick; the length of the threaded copper rod is 30 cm; the thickness of the quartz glass container is 0.2cm, and the size of the high-voltage electrode 8 is smaller than the bottom area of the quartz glass container; the quartz glass container is filled with copper sulfate pentahydrate solution, so that the uniform discharge in the discharge process is ensured, and the high-voltage electrode is prevented from being overheated in the discharge process due to the evaporation of the copper sulfate pentahydrate solution.
In some embodiments, the sludge reaction tank is an acrylic reaction tank, and has a size consistent with that of the quartz glass container, and the low-voltage electrode is a rectangular copper plate, and has a size consistent with that of the high-voltage electrode.
The invention also provides application of the experimental device for breaking sludge by dielectric barrier discharge in sludge pretreatment, which comprises the following steps:
step one, taking sludge to be treated for later use;
step two, mixing the sludge to be treated with Ca (OH)2Uniformly mixing, and carrying out alkaline substance pretreatment;
and step three, placing the sludge pretreated by the alkaline substances in a sludge reaction tank 10 of a dielectric barrier discharge sludge cracking experimental device, and performing discharge plasma pretreatment, wherein the discharge voltage is 10-12 Kv, the discharge frequency is 11-12 KHz, and the discharge time is 10-24 min.
In some embodiments, the Ca (OH) in step two2The adding concentration of the sludge to be treated is 0.02 mol/L-0.05 mol/L, Ca (OH)2The adding time is 10 min-60 min.
In some embodiments, the discharge voltage in step three is 10.62Kv, the discharge frequency is 12KHz, and the discharge time is 23.8 min.
In some embodiments, the Ca (OH) in step two2The adding concentration of the sludge to be treated is 0.03mol/L, Ca (OH)2The adding time of (2) is 60 min.
In some examples, 100ml of 1mol/L copper sulfate pentahydrate solution is added during the discharge plasma pretreatment in step three.
Compared with the prior art, the invention has the beneficial effects that:
the invention is realized by Ca (OH)2Combined with application research of DBD plasma discharge to improve sludge biodegradability, microbial cells in sludge are broken by means of strong current, high energy density, strong ultraviolet radiation and strong shock waves generated in the DBD discharge process, and microbial cells in sludge are broken in the discharge processThe combined action of ozone, OH and alkali produced in the process enhances the effect of sludge pretreatment.
The concentration of SCOD (soluble activated sludge) of the pretreated sludge is 1993.4mol/L, the concentration of protein is 331.1mol/L, the concentration of polysaccharide is 225.8mol/L, the concentration of ammonia nitrogen is 145.2mol/L, and the pH value is 7.999.
After the sludge pretreated by the method is subjected to anaerobic fermentation, the methane yield can reach 361 ml.
Drawings
FIG. 1 is a process flow diagram of the present invention;
FIG. 2 is a schematic diagram of an experimental device for breaking sludge by dielectric barrier discharge according to the present invention;
in the figure: 1. a plasma generator; 2. a transformer; 3. an oscilloscope; 4. a low voltage electrode; 5. a threaded copper rod; 6. a quartz glass container; 7. copper sulfate pentahydrate solution; 8. a high voltage electrode; 9. sludge sample liquid; 10. a sludge reaction tank; 11. an insulating plate; 12. an acrylic column; 13. an acrylic upper panel; 14. a wire; 15. inferior panel of inferior gram force.
Detailed Description
The preferred embodiments of the present invention will be described in detail below with reference to the accompanying drawings so that the advantages and features of the present invention can be more easily understood by those skilled in the art, and the scope of the present invention will be more clearly and clearly defined.
The invention provides a dielectric barrier discharge sludge cracking experimental device which comprises a plasma generator 1, a transformer 2, an oscilloscope 3 and a discharge reaction container, wherein the input end of the plasma generator 1 is connected with the transformer 2, and the oscilloscope 3 is connected with the output end of the plasma generator 1;
the discharge reaction vessel includes:
a threaded copper rod 5;
the high-voltage electrode 8 is connected with one end of the threaded copper rod 5, and the other end of the threaded copper rod 5 is connected with a power supply output end of the plasma generator 1 through a lead;
a quartz glass container 6, the high voltage electrode 8 is closely contacted with the bottom of the quartz glass container 6 to obtain uniform discharge;
the low-voltage electrode 4 is arranged opposite to and parallel to the high-voltage electrode 8;
the low-voltage electrode 4 is arranged at the bottom of the sludge reaction tank 10 and is in close contact with the bottom of the sludge reaction tank 10;
the low-voltage electrode 4 is connected with the power output end of the plasma generator 1 through a lead and is grounded;
the quartz glass container 6 and the sludge reaction tank 10 are covered with an insulating plate 11, and the threaded copper rod 5 vertically penetrates through the insulating plate 11.
In one embodiment, the panel 15 under the ya keli has been placed to the bottom of discharge reaction vessel, be equipped with several ya keli posts 12 under the ya keli on the panel 15, ya keli upper panel 13 is connected to the other end of ya keli post 12, just screw thread bar copper 5 passes yakeli upper panel 13.
In one embodiment, the power supply of the plasma generator 1 adopts a TDGC 2-1 type single-phase contact self-coupling voltage regulator, and the oscilloscope 3 is a GDS-820C oscilloscope. The regulator regulates the voltage of 220V for civil use to the voltage required by the experiment and inputs the voltage into the plasma generator, and the voltage regulator can regulate the voltage. The plasma generator has a current regulation function, can regulate current flow in the process of generating plasma, monitors voltage, current and discharge frequency in the discharge process in real time by means of a GDS-820C oscilloscope, and regulates the voltage and the current by means of a transformer and the plasma generator;
in one embodiment, the high voltage electrode 8 is a rectangular copper plate, and has a length of 9cm, a width of 8cm and a thickness of 0.15 cm; the length of the threaded copper rod is 5 cm; the thickness of the quartz glass container 6 is 0.2cm, and the size of the high-voltage electrode 8 is smaller than the bottom area of the quartz glass container 6.
In one embodiment, the quartz glass vessel 6 contains a copper sulfate pentahydrate solution 7 to ensure uniform discharge during discharge and to avoid overheating of the high voltage electrode during discharge due to evaporation of the copper sulfate pentahydrate solution.
In one embodiment, the sludge reaction tank 10 is an acrylic reaction tank and has a size consistent with that of the quartz glass container 6, and the low-voltage electrode 4 is a rectangular copper plate and has a size consistent with that of the high-voltage electrode 8.
The invention also provides application of the experimental device for breaking sludge by dielectric barrier discharge in sludge pretreatment, which comprises the following steps:
step one, taking sludge to be treated for later use;
step two, mixing the sludge to be treated with Ca (OH)2Mixing, pretreating with alkaline substance (Ca (OH))2The addition of the compound is beneficial to promoting the generation of DBD discharge plasma active substances such as OH and the like and promoting the disintegration of sludge microbial cells;
and step three, placing the sludge pretreated by the alkaline substances in a sludge reaction tank 10 of a dielectric barrier discharge sludge cracking experimental device, and performing discharge plasma pretreatment, wherein the discharge voltage is 10-12 Kv, the discharge frequency is 11-12 KHz, and the discharge time is 10-24 min.
In one embodiment, the Ca (OH) in step two2The adding concentration of the sludge to be treated is 0.02 mol/L-0.05 mol/L, Ca (OH)2The adding time is 10 min-60 min.
In one embodiment, the discharge voltage in step three is 10.62Kv, the discharge frequency is 12KHz, and the discharge time is 23.8 min.
In one embodiment, the Ca (OH) in step two2The adding concentration of the sludge to be treated is 0.03mol/L, Ca (OH)2The adding time of (2) is 60 min.
In one embodiment, when the discharge plasma pretreatment is performed in step three, 100ml of 1mol/L copper sulfate pentahydrate solution is added.
The source of the sludge to be treated is not particularly limited in the present invention, and sludge known to those skilled in the art may be used. For example, the method provided by the invention can be used for treating excess sludge and can also be used for treating sludge.
In the invention, the excess sludge is sludge generated by sewage treatment, comprises scum and microbial community and is a secondary product after sewage biochemical treatment in a sewage plant;
the sludge to be pretreated and Ca (OH) are treated2The order of addition at the time of mixing is not particularly limited, and may be any order of addition known to those skilled in the art. The invention preferably begins with the addition of Ca (OH) to the sludge to be pretreated2After stirring, a DBD discharge pretreatment is performed.
In order to further illustrate the present invention, the method for pretreating sludge provided by the present invention will be described in detail with reference to examples, but they should not be construed as limiting the scope of the present invention.
Examples
As shown in figure 1, 500ml of sludge to be pretreated is taken from a sludge discharge well of a secondary sedimentation tank of a sewage treatment plant, and 0.015mol of Ca (OH) is added2
Mixing the two materials uniformly by a magnetic stirrer, stirring for 60min, and transferring to a DBD discharge device.
And adjusting various parameters of the DBD discharge device, wherein the discharge voltage is 10.62Kv, the discharge frequency is 12KHz, and the discharge time is 23.80 min.
The concentration of SCOD (soluble activated sludge) of the pretreated sludge is 1993.4mol/L, the concentration of protein is 331.1mol/L, the concentration of polysaccharide is 225.8mol/L, the concentration of ammonia nitrogen is 145.2mol/L, and the pH value is 7.999.
Transferring the sludge into a conical flask for medium-temperature anaerobic fermentation, and collecting methane gas by adopting a drainage method. And (5) performing anaerobic fermentation for 21 d. The methane production was determined to be 361 ml.
The sludge pretreatment method comprises the following steps: mixing the sludge to be pretreated with Ca (OH)2Uniformly mixing, and carrying out alkaline substance pretreatment. Ca (OH)2The adding concentration of (A) is 0.03 mol/L. Ca (OH)2The adding time of (2) is 60 min. And then, the DBD discharge plasma pretreatment is carried out by adopting the experimental device for breaking sludge by dielectric barrier discharge, wherein the DBD discharge condition is that the discharge voltage is 10.62Kv, the discharge frequency is 12KHz, and the discharge time is 23.82 min. Ca (OH)2The addition of the active substance is beneficial to promoting DBD discharge plasmaOH, etc., and promote the cell breakdown of sludge microorganisms. The experimental results show that the product of Ca (OH)2The SCOD of the sludge subjected to combined pretreatment with the DBD discharge plasma is 1993.4mol/L, the protein concentration is 331.1mol/L, the polysaccharide concentration is 225.8mol/L, the ammonia nitrogen concentration is 145.2mol/L, and the pH value is 7.999. The gas production under the combined treatment experimental conditions reaches a maximum of 386ml, while the original sludge is only 261ml under the normal conditions.
As shown in fig. 2, the experimental apparatus for cracking sludge by dielectric barrier discharge of the present invention comprises a plasma generator 1, a transformer 2, an oscilloscope 3 and a discharge reaction vessel, wherein an input end of the plasma generator 1 is connected with the transformer 2, the oscilloscope 3 is connected with an output end of the plasma generator 1, a power supply of the plasma generator 1 adopts a TDGC 2-1 type single-phase contact type autotransformer, and the oscilloscope 3 is a GDS-820C oscilloscope;
the discharge reaction vessel includes:
a threaded copper rod 5;
the high-voltage electrode 8 is connected with one end of the threaded copper rod 5, the other end of the threaded copper rod 5 is connected with a power output end of the plasma generator 1 through a lead, the high-voltage electrode 8 is a rectangular copper plate, and is 9cm long, 8cm wide and 0.15cm thick; the length of the threaded copper rod is 5 cm; the thickness of the quartz glass container 6 is 0.2cm, and the size of the high-voltage electrode 8 is smaller than the bottom area of the quartz glass container 6;
the high-voltage electrode 8 is tightly contacted with the bottom of the quartz glass container 6, a copper sulfate pentahydrate solution 7 is filled in the quartz glass container 6, so that the uniform discharge in the discharge process is ensured, and the high-voltage electrode is prevented from being overheated in the discharge process due to the evaporation of the copper sulfate pentahydrate solution;
the low-voltage electrode 4 is arranged opposite to and parallel to the high-voltage electrode 8;
the low-voltage electrode 4 is arranged at the bottom of the sludge reaction tank 10 and is in close contact with the bottom of the sludge reaction tank 10, the sludge reaction tank 10 is an acrylic reaction tank and has the same size as the quartz glass container 6, and the low-voltage electrode 4 is a rectangular copper plate and has the same size as the high-voltage electrode 8;
the low-voltage electrode 4 is connected with the power output end of the plasma generator 1 through a lead and is grounded;
the quartz glass container 6 and the sludge reaction tank 10 are covered with an insulating plate 11, and the threaded copper rod 5 vertically penetrates through the insulating plate 11;
panel 15 under the ya keli has been placed to above-mentioned discharge reaction vessel's bottom, be equipped with several ya keli posts 12 under the ya keli on the panel 15 the yakeli top panel 13 is connected to the other end of yakeli post 12, just screw thread bar 5 passes yakeli top panel 13.
The embodiments of the present invention have been described in detail with reference to the above examples, but the present invention is not limited to the above embodiments, and various changes can be made without departing from the spirit of the present invention within the knowledge of those skilled in the art.

Claims (5)

1. The experimental device for cracking sludge through dielectric barrier discharge is characterized by comprising a plasma generator (1), a transformer (2), an oscilloscope (3) and a discharge reaction container, wherein the input end of the plasma generator (1) is connected with the transformer (2), and the oscilloscope (3) is connected with the output end of the plasma generator (1);
the discharge reaction vessel includes:
a threaded copper bar (5);
the high-voltage electrode (8), the high-voltage electrode (8) is connected with one end of the threaded copper rod (5), and the other end of the threaded copper rod (5) is connected with the power output end of the plasma generator (1) through a lead;
the quartz glass container (6), the said high voltage electrode (8) is contacted closely with the bottom of the quartz glass container (6);
the low-voltage electrode (4), this low-voltage electrode (4) and stated high-voltage electrode (8) are relatively parallel to set up;
the low-voltage electrode (4) is arranged at the bottom of the sludge reaction tank (10) and is in close contact with the bottom of the sludge reaction tank (10);
the low-voltage electrode (4) is connected with the power output end of the plasma generator (1) through a lead (14) and is grounded;
the quartz glass container (6) and the sludge reaction tank (10) are covered with an insulating plate (11), and the threaded copper rod (5) vertically penetrates through the insulating plate (11).
2. The experimental device for testing sludge breakdown through dielectric barrier discharge according to claim 1, wherein an acrylic lower panel (15) is placed at the bottom of the discharge reaction container, a plurality of acrylic columns (12) are arranged on the acrylic lower panel (15), the other ends of the acrylic columns (12) are connected with an acrylic upper panel (13), and the threaded copper rods (5) penetrate through the acrylic upper panel (13).
3. The experimental device for sludge breakdown through dielectric barrier discharge according to claim 1, wherein a TDGC 2-1 type single-phase contact type self-coupling voltage regulator is adopted as a power supply of the plasma generator (1), and the oscilloscope (3) is a GDS-820C oscilloscope.
4. The experimental device for sludge breakdown through dielectric barrier discharge according to claim 1, wherein the high-voltage electrode (8) is a rectangular copper plate, and is 9cm long, 8cm wide and 0.15cm thick; the length of the threaded copper rod (5) is 30 cm; the thickness of the quartz glass container (6) is 0.2cm, and the size of the high-voltage electrode (8) is smaller than the bottom area of the quartz glass container (6); the quartz glass container (6) is filled with blue vitriol solution (7).
5. The experimental device for sludge breakdown through dielectric barrier discharge according to claim 4, wherein the sludge reaction tank (10) is an acrylic reaction tank and has the same size as the quartz glass container (6), and the low-voltage electrode (4) is a rectangular copper plate and has the same size as the high-voltage electrode (8).
CN201921494577.7U 2019-09-09 2019-09-09 Experimental device for cracking sludge through dielectric barrier discharge Expired - Fee Related CN210505993U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110422977A (en) * 2019-09-09 2019-11-08 南昌大学 Dielectric barrier discharge breaking sludge experimental provision and its application in pretreating sludge
CN114436489A (en) * 2021-11-30 2022-05-06 中国水产科学研究院渔业机械仪器研究所 Method for improving anaerobic fermentation effect of activated sludge by using low-temperature plasma technology

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110422977A (en) * 2019-09-09 2019-11-08 南昌大学 Dielectric barrier discharge breaking sludge experimental provision and its application in pretreating sludge
CN114436489A (en) * 2021-11-30 2022-05-06 中国水产科学研究院渔业机械仪器研究所 Method for improving anaerobic fermentation effect of activated sludge by using low-temperature plasma technology

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