CN210160401U - Nitric acid atomizing device of continuous degreasing furnace - Google Patents

Nitric acid atomizing device of continuous degreasing furnace Download PDF

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Publication number
CN210160401U
CN210160401U CN201921023231.9U CN201921023231U CN210160401U CN 210160401 U CN210160401 U CN 210160401U CN 201921023231 U CN201921023231 U CN 201921023231U CN 210160401 U CN210160401 U CN 210160401U
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China
Prior art keywords
pipeline
nitric acid
evaporation
atomizing device
heating
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Withdrawn - After Issue
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CN201921023231.9U
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Chinese (zh)
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刘鹏
徐文立
陈可杰
晁金立
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Ningbo Hengpu Technology Co ltd
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Ningbo Hiper Vacuum Technology Co Ltd
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Abstract

The utility model discloses a nitric acid atomizing device of continuous degreasing furnace, which comprises an acid injection device, a nitrogen heating device and an atomizing device. The acid injection device is connected with an acid injection pipeline; the nitrogen heating device comprises a first heating assembly, and is respectively connected with an air inlet pipeline and an air outlet pipeline; the atomization device comprises an evaporation box, a second heating assembly, an evaporation disc, a support frame and glass balls, wherein the second heating assembly, the evaporation disc, the support frame and the glass balls are arranged in the evaporation box, the support frame is used for supporting the evaporation disc, the glass balls are stacked in the evaporation disc, the evaporation box is respectively connected with an acid injection pipeline, an air outlet pipeline and a mixed gas pipeline, and an outlet of the acid injection pipeline is located above the evaporation disc. Compared with the prior art, the nitric acid atomization device of the utility model consists of three independent parts, and any part can be independently maintained when being out of order, thereby simplifying the maintenance process. And because the glass ball in the evaporating tray can enlarge the effective evaporating area of the nitric acid dripping liquid, the evaporating efficiency of the nitric acid liquid is improved.

Description

Nitric acid atomizing device of continuous degreasing furnace
Technical Field
The utility model relates to a nitric acid gas catalytic degreasing technical field especially relates to a nitric acid atomizing device of continuous degreasing furnace.
Background
The explosive development of Metal Injection Molding (MIM) technology in recent years has driven the technological development of the related device manufacturing industry. The main technological process of the product by using metal injection molding technology includes 1. mixing metal powder and binder, 2. injection molding (green), 3. degreasing (brown), 4. sintering, 5. post-treatment and 6. finishing. Among them, degreasing is a very important link in the process flow of MIM products, which is a process of removing the binder contained in the formed blank (brown blank) before sintering, so that the binder is gradually discharged from different parts of the blank along the tiny channels between the particles without damaging the high strength of the blank. The degreasing process aims to shorten the degreasing time as much as possible under the condition of no defect and deformation, ensure that the chemical components of the degreased brown embryo are controlled within an allowable range, and prepare for the next sintering process.
Different degreasing methods are adopted for different binders of MIM products, and common degreasing methods comprise vacuum degreasing, thermal degreasing, solvent degreasing, siphon degreasing, supercritical fluid extraction degreasing, catalytic degreasing and the like. The catalytic degreasing is a novel degreasing process developed by BASF (BASF), a chemical company well known in germany in the early 90 s of the last century. The process is mainly characterized in that polyformaldehyde is used as a main binder and is rapidly catalyzed and decomposed in an acid atmosphere, and long-chain polyaldehyde resin has good polarity and can be applied to a wide range of powder types, from stainless steel, hard alloy to ceramic. The aldehyde resin can be quickly decomposed into formaldehyde under the catalysis of acidic atmosphere, so that the effect of quickly removing the binder can be achieved. The catalytic degreasing process has the advantages that liquid phase can not be generated during degreasing, the defects that the MIM product is easy to deform and the dimensional precision is difficult to control are avoided, due to the catalytic degreasing, the degreasing time is greatly shortened, the cost is reduced, and the method can be used for producing MIM process product parts with larger sizes. Under the process, a continuous degreasing and continuous sintering system is adopted, so that the continuous production of the MIM product can be realized, and the metal powder injection molding technology becomes a near-net-shape technology with real competitiveness.
The existing nitric acid atomization device has the problems of poor temperature consistency of all internal areas, difficult maintenance and the like, so how to provide a nitric acid atomization device which is simple and convenient to maintain and can realize balanced and sufficient heating is a technical problem to be solved urgently by technical personnel in the field.
SUMMERY OF THE UTILITY MODEL
The utility model aims at providing a nitric acid atomizing device of continuous degrease stove for solve the technical problem that above-mentioned prior art exists, simplify the maintenance process, realize inside equilibrium, abundant heating.
In order to achieve the above object, the utility model provides a following scheme:
the utility model discloses a nitric acid atomizing device of continuous degreasing furnace, include:
the acid injection device is connected with an acid injection pipeline;
the nitrogen heating device comprises a first heating assembly, and is respectively connected with an air inlet pipeline and an air outlet pipeline;
atomizing device, atomizing device include the evaporating chamber and set up in second heating element, evaporating pan, support frame and glass ball in the evaporating chamber, the support frame is used for supporting the evaporating pan, and is a plurality of the glass ball pile up in the evaporating pan, the evaporating chamber respectively with annotate sour pipeline go out the gas pipeline and link to each other, the export of annotating sour pipeline is located the top of evaporating pan, annotate sour pipeline with go out the gas pipeline respectively be used for to nitrogen gas after inputing nitric acid liquid and heating in the evaporating chamber, the evaporating chamber still links to each other with the mist pipeline, the mist pipeline is used for exporting the mist of nitric acid gas and nitrogen gas.
Preferably, the evaporation trays are arranged in a layered manner from top to bottom, and each evaporation tray above the bottommost evaporation tray is provided with a liquid outlet hole, so that nitric acid liquid can flow downwards in sequence among the evaporation trays.
Preferably, the bottom areas of the plurality of evaporation trays are sequentially increased from top to bottom.
Preferably, annotate sour device and include nitric acid bottle, nitric acid pump and flowmeter, the access connection of nitric acid pump has the liquid extraction pipeline, the liquid extraction pipeline inserts in the nitric acid bottle, the export of nitric acid pump pass through connecting line with the import of flowmeter links to each other, the export of flowmeter with the one end of annotating sour pipeline links to each other, the other end of annotating sour pipeline with the evaporation tank links to each other.
Preferably, the liquid pumping pipeline, the connecting pipeline and the acid injection pipeline are PTFE pipelines, and the mixed gas pipeline is an acid-resistant stainless steel pipeline.
Preferably, the nitrogen heating device further comprises a nitrogen heating cylinder and Al2O3Spherical filler, the nitrogen heating cylinder is a transversely arranged sealed cylinder structure and is provided with a plurality of Al2O3The spherical filler pile up in the nitrogen gas cartridge heater, and not piled up fully the nitrogen gas cartridge heater, it inserts to go out the gas piping way pipeline port in the nitrogen gas cartridge heater is located top space department in the nitrogen gas cartridge heater, the inlet line inserts pipeline port in the nitrogen gas cartridge heater is located the bottom of nitrogen gas cartridge heater, and has the filter screen.
Preferably, the first heating assembly is a screw thread type heater, the first heating assembly is fixed on the end face of the nitrogen heating cylinder and is parallel to the axis of the nitrogen heating cylinder, the first heating assembly is multiple and is inserted into the Al2O3The spherical fillers form stacks at different heights.
Preferably, the air inlet pipeline and the air outlet pipeline are both pipelines made of stainless steel materials.
Preferably, the second heating assembly comprises a U-shaped heater and a thermocouple, and is disposed below the evaporation pan.
Preferably, the glass spheres have a variety of diameters.
The utility model discloses for prior art gain following technological effect:
the nitric acid atomization device of the utility model is composed of three independent parts, and any part can be maintained independently when the part goes wrong, thereby simplifying the maintenance process. And because the glass ball in the evaporating tray can enlarge the effective evaporating area of the nitric acid dripping liquid, the evaporating efficiency of the nitric acid liquid is improved. When the method is applied to the continuous degreasing furnace, the specific proportion requirement and the temperature control requirement of the continuous degreasing furnace on the acid gas under the acid degreasing process are ensured, and the stability of the acid degreasing process is greatly improved.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings required to be used in the embodiments will be briefly described below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to these drawings without creative efforts.
FIG. 1 is a schematic view of the overall structure of a nitric acid atomizing device of the continuous degreasing furnace of the present invention;
description of reference numerals: 1-heating the cylinder with nitrogen; 21-an air intake line; 22-gas outlet pipeline; 3, filtering the filter screen; 4-a screw-thread type heater; 5-Al2O3A spherical filler; a 6-U shaped heater; 7-a thermocouple; 8-a support frame; 9-glass spheres; 10-an evaporation pan; 11-an evaporation tank; 12-nitric acid bottle; 13-nitric acid pump; 14-a flow meter; 15-PTFE tubing; 16-mixed gas line.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely with reference to the accompanying drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only some embodiments of the present invention, not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative work belong to the protection scope of the present invention.
The utility model aims at providing a nitric acid atomizing device of continuous degrease stove for solve the technical problem that above-mentioned prior art exists, simplify the maintenance process, realize inside equilibrium, abundant heating.
In order to make the above objects, features and advantages of the present invention more comprehensible, the present invention is described in detail with reference to the accompanying drawings and the detailed description.
As shown in fig. 1, the present embodiment provides a nitric acid atomizing device for a continuous degreasing furnace, which includes an acid injection device, a nitrogen gas heating device, and an atomizing device.
Wherein the acid injection device is connected with an acid injection pipeline; the nitrogen heating device comprises a first heating assembly, and is respectively connected with an air inlet pipeline 21 and an air outlet pipeline 22; the atomization device comprises an evaporation box 11, a second heating assembly arranged in the evaporation box 11, an evaporation disc 10, a support frame 8 and glass balls 9, wherein the support frame 8 is fixed in the evaporation box 11, the support frame 8 is used for supporting the evaporation disc 10, the glass balls 9 are stacked in the evaporation disc 10, the glass balls 9 preferably have various diameters, the evaporation box 11 is respectively connected with an acid injection pipeline and an air outlet pipeline 22, the outlet of the acid injection pipeline is positioned above the evaporation disc 10, the acid injection pipeline and the air outlet pipeline 22 are respectively used for inputting nitric acid liquid and heated nitrogen into the evaporation box 11, the evaporation box 11 is further connected with a mixed gas pipeline 16, and the mixed gas pipeline 16 is used for outputting mixed gas of the nitric acid gas and the nitrogen gas.
During the use, annotate sour device and pour into atomizing device with nitric acid liquid inside, volatilize for gaseous nitric acid in nitric acid atomizing device is inside, simultaneously because nitrogen gas after nitrogen gas heating device heats enters into atomizing device, further increased volatilizing of nitric acid liquid again. Thus, the amount of the nitric acid volatilized from the inside of the evaporation tank 11 is approximately equal to the dropping amount of the nitric acid liquid, and by adjusting the flow rate of the nitrogen gas and the flow rate of the nitric acid liquid at the inlet, a mixed gas of the nitrogen gas and the nitric acid gas in a certain ratio is discharged from the inside of the evaporation tank 11 through the mixed gas line 16. Because the whole nitric acid atomization device system consists of three independent parts, any part can be independently maintained when a problem occurs, and the maintenance process is simplified. And because the glass ball 9 in the evaporating tray 10 can enlarge the effective evaporation area of the nitric acid dripping liquid, the evaporation efficiency of the nitric acid liquid is improved. The mixed gas is finally sent out from the exhaust port positioned at the uppermost part under the flowing of the nitrogen gas flow and enters the required equipment.
In order to fully utilize the space in the evaporation box 11 and further improve the evaporation efficiency, the evaporation pan 10 of the present embodiment is provided with a plurality of evaporation pans 10 layered up and down, and each evaporation pan 10 located above the evaporation pan 10 at the lowest layer has a liquid outlet hole, so that the nitric acid liquid can flow down between the evaporation pans 10 in sequence. By setting the evaporation pan 10 to be a multilayer structure, the effective evaporation area of the nitric acid dropping liquid is further enlarged, and the evaporation efficiency is improved to a certain extent.
In this embodiment, the bottom areas of the evaporation trays 10 are sequentially increased from top to bottom, so that the volume of the evaporation tray 10 at the lower part is larger than that of the evaporation tray 10 at the upper part, and overflow is avoided.
The type of acid injection device is various and can be selected by those skilled in the art according to actual needs. In this embodiment, annotate sour device and include nitric acid bottle 12, nitric acid pump 13 and flowmeter 14, and the access connection of nitric acid pump 13 has the liquid pumping pipeline, and the liquid pumping pipeline inserts in nitric acid bottle 12, and the export of nitric acid pump 13 passes through connecting tube and links to each other with flowmeter 14's import, and flowmeter 14's export links to each other with the one end of annotating sour pipeline, and the other end of annotating sour pipeline links to each other with evaporating case 11. The nitric acid pump 13 is used for pumping the nitric acid liquid stored in the nitric acid bottle 12 into the atomization device, and the nitric acid pump 13 can be adjusted according to the reading of the flowmeter 14.
In this embodiment, the liquid pumping pipeline, the connecting pipeline and the acid injection pipeline are all PTFE pipelines 15, the mixed gas pipeline 16 is an acid-resistant stainless steel pipeline, and those skilled in the art can select other corrosion-resistant pipelines according to actual needs.
In order to ensure the consistency of the temperature of the nitrogen gas entering the evaporation box 11, the nitrogen heating device of the embodiment further comprises a nitrogen heating cylinder 1 and Al2O3A spherical filler 5. The nitrogen heating cylinder 1 is a sealed cylinder structure arranged transversely and is provided with a plurality of Al2O3The spherical filler 5 is stacked in the nitrogen heating cylinder 1, and is not fully stacked in the nitrogen heating cylinder 1. The pipeline port of the air outlet pipeline 22 inserted into the nitrogen heating cylinder 1 is positioned in the top gap of the nitrogen heating cylinder 1, and the pipeline port of the air inlet pipeline 21 inserted into the nitrogen heating cylinder 1 is positioned at the bottom of the nitrogen heating cylinder 1 and is provided with a filter screen 3. Since the gas inlet and outlet are downward and upward, the nitrogen gas is Al-absorbed while passing through the inner space of the cylinder2O3The spherical fillers 5 are uniformly distributed and dispersed, so that nitrogen is heated evenly and fully, and dead angles can not appear.
In this embodiment, the first heating element is a screw thread type heater 4, which is convenient to install. The first heating components are fixed on the end face of the nitrogen heating cylinder 1 and are parallel to the axis of the nitrogen heating cylinder 1, and a plurality of first heating components are inserted with Al2O3The spherical fillers 5 are formed at different heights of the stack body, thereby increasing the Al of the upper layer and the lower layer2O3Temperature uniformity of the spherical filler 5.
In this embodiment, the air inlet pipeline 21 and the air outlet pipeline 22 are both stainless steel pipelines, so that the atomization device and the nitrogen heating device are connected in series from left to right; the acid injection pipeline is a PTFE pipeline 15 which is easy to bend, so that the placing position of the acid injection device can be determined at will and the acid injection device can be placed according to the actual using operation position of the equipment. Those skilled in the art can also use other materials for the inlet line 21 and the outlet line 22, as long as the temperature of the nitrogen gas can be adapted.
In this embodiment, the second heating unit includes a U-shaped heater 6 and a thermocouple 7, and is disposed below the evaporation pan 10. The U-shaped heater 6 can enlarge the heating area, and the thermocouple 7 is used for realizing temperature measurement, thereby adjusting the heating power.
The principle and the implementation mode of the present invention are explained by applying specific examples in the present specification, and the above descriptions of the examples are only used to help understanding the method and the core idea of the present invention; meanwhile, for the general technical personnel in the field, according to the idea of the present invention, there are changes in the concrete implementation and the application scope. In summary, the content of the present specification should not be construed as a limitation of the present invention.

Claims (10)

1. A nitric acid atomizing device of a continuous degreasing furnace is characterized by comprising:
the acid injection device is connected with an acid injection pipeline;
the nitrogen heating device comprises a first heating assembly, and is respectively connected with an air inlet pipeline and an air outlet pipeline;
atomizing device, atomizing device include the evaporating chamber and set up in second heating element, evaporating pan, support frame and glass ball in the evaporating chamber, the support frame is used for supporting the evaporating pan, and is a plurality of the glass ball pile up in the evaporating pan, the evaporating chamber respectively with annotate sour pipeline go out the gas pipeline and link to each other, the export of annotating sour pipeline is located the top of evaporating pan, annotate sour pipeline with go out the gas pipeline respectively be used for to nitrogen gas after inputing nitric acid liquid and heating in the evaporating chamber, the evaporating chamber still links to each other with the mist pipeline, the mist pipeline is used for exporting the mist of nitric acid gas and nitrogen gas.
2. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the plurality of evaporation pans are layered up and down, and each evaporation pan located above the lowermost evaporation pan has a liquid outlet hole, so that the nitric acid liquid can flow down among the evaporation pans in sequence.
3. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 2, wherein the plurality of evaporation pans have bottom areas which are sequentially increased from top to bottom.
4. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the acid injection device comprises a nitric acid bottle, a nitric acid pump and a flow meter, an inlet of the nitric acid pump is connected with a liquid pumping pipeline, the liquid pumping pipeline is inserted into the nitric acid bottle, an outlet of the nitric acid pump is connected with an inlet of the flow meter through a connecting pipeline, an outlet of the flow meter is connected with one end of the acid injection pipeline, and the other end of the acid injection pipeline is connected with the evaporation box.
5. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 4, wherein the liquid extraction pipe, the connecting pipe and the acid injection pipe are all PTFE pipes, and the mixed gas pipe is an acid-resistant stainless steel pipe.
6. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the nitrogen gas heating device further comprises a nitrogen gas heating cylinder and Al2O3Spherical filler, the nitrogen heating cylinder is a transversely arranged sealed cylinder structure and is provided with a plurality of Al2O3The spherical filler pile up in the nitrogen gas cartridge heater, and not piled up fully the nitrogen gas cartridge heater, it inserts to go out the gas piping way pipeline port in the nitrogen gas cartridge heater is located top space department in the nitrogen gas cartridge heater, the inlet line inserts pipeline port in the nitrogen gas cartridge heater is located the bottom of nitrogen gas cartridge heater, and has the filter screen.
7. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 6, wherein the first heating member is a screw heater, the first heating member is fixed to an end surface of the nitrogen gas heating cylinder and is parallel to an axis of the nitrogen gas heating cylinder, the first heating member is plural and is inserted with the Al2O3The spherical fillers form stacks at different heights.
8. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the gas inlet pipeline and the gas outlet pipeline are both stainless steel pipelines.
9. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the second heating assembly comprises a U-shaped heater and a thermocouple, and the second heating assembly is disposed below the evaporation pan.
10. The nitric acid atomizing device of the continuous degreasing furnace as set forth in claim 1, wherein the glass beads have a plurality of diameters.
CN201921023231.9U 2019-07-03 2019-07-03 Nitric acid atomizing device of continuous degreasing furnace Withdrawn - After Issue CN210160401U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110181045A (en) * 2019-07-03 2019-08-30 宁波恒普真空技术有限公司 A kind of nitric acid atomising device of continuous degreasing furnace

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110181045A (en) * 2019-07-03 2019-08-30 宁波恒普真空技术有限公司 A kind of nitric acid atomising device of continuous degreasing furnace
CN110181045B (en) * 2019-07-03 2024-01-30 宁波恒普技术股份有限公司 Nitric acid atomizing device of continuous degreasing furnace

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Address after: No. 365, Xinxing 1st Road, Cixi hi tech Industrial Development Zone, Ningbo City, Zhejiang Province, 315300

Patentee after: Ningbo Hengpu Vacuum Technology Co.,Ltd.

Address before: 315300 no.488-560, North Youth Palace Road, Gutang street, Cixi City, Ningbo City, Zhejiang Province

Patentee before: NINGBO HIPER VACUUM TECHNOLOGY Co.,Ltd.

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Address after: No. 365, Xinxing 1st Road, Cixi hi tech Industrial Development Zone, Ningbo City, Zhejiang Province, 315300

Patentee after: Ningbo Hengpu Technology Co.,Ltd.

Address before: No. 365, Xinxing 1st Road, Cixi hi tech Industrial Development Zone, Ningbo City, Zhejiang Province, 315300

Patentee before: Ningbo Hengpu Vacuum Technology Co.,Ltd.

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