CN209693391U - The device in diaphragm process improvement salt-soda soil - Google Patents
The device in diaphragm process improvement salt-soda soil Download PDFInfo
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- CN209693391U CN209693391U CN201920389217.4U CN201920389217U CN209693391U CN 209693391 U CN209693391 U CN 209693391U CN 201920389217 U CN201920389217 U CN 201920389217U CN 209693391 U CN209693391 U CN 209693391U
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Abstract
A kind of diaphragm process administers the device in salt-soda soil, belongs to Saline-alkali Field Control technical field.The purpose of this utility model is by cation-exchange membrane migration cation when electrolysis, to complete the device for extracting the diaphragm process improvement salt-soda soil that caustic alkali administers salt-soda soil with salt, alkali, nitre in the electrolysis salt-soda soil of diaphragm process special designing.Portion's insulating mounting has the outwardly extending cathode conductive material in both ends to the utility model in the frame, it is placed on one in frame section in cathode conductive material and is set with cation-exchange membrane, the sealing of cation-exchange membrane both ends, it is provided with limbers on the cathode conductive material being placed in cation-exchange membrane cladding, the frame two sides parallel insulation in cathode conductive material two sides is equipped with anode conducting material.The utility model does not use any chemical substance, does not generate secondary pollution, and governance process only needs consuming electric power, and one-time formed permanently to administer all types of weight degree salt-soda soil, economic benefit almost maintains an equal level with control expense, administers salt-soda soil equal to no expense.
Description
Technical field
The utility model belongs to Saline-alkali Field Control technical field.
Background technique
Salt-soda soil is that caustic alkali compounds content is exceeded, wherein salt, alkali, nitre, be caustic alkali cation and different yin
The different compounds that ion combination generates all are to cause because alkali cation content is excessively high in soil after all, especially
With sodium, potassium, calcium for main causticity base cations, these alkali metal cations are different according to region in the soil, environment is different,
Anions In Soils substance has been differently formed various saline and alkaline compound depositions causes plant that can not grow survival in the soil, also leads
Many diverse divisions in region salt-soda soil have been caused, have brought great trouble to Saline-alkali Field Control.
The method for administering salt-soda soil at present mainly has: water conservancy, chemistry, physics, biological modification, above-mentioned several improvement periods
Length, regulation effect are poor, costly, cause all kinds of modifying agents of investment mutual since the alkali metal ion in salt-soda soil largely exists
It converts to alleviate the growth cycle of plant, but alkali metal ion adsorbs convert different saline and alkaline, nothings repeatedly in the soil always
Method is thoroughly decomposed and is left.
The patent of Publication No. 201210151129.3 and publication number 201220265874.6 disclose it is a kind of administer it is saline and alkaline
The method and apparatus on ground are with electric energy work done, but anode and cathode be in the same electrolytic cell, and no membrane technique setting is
Caustic alkali can not be extracted, some sour gas can only be generated.
Summary of the invention
The purpose of this utility model is with salt, alkali, nitre in the electrolysis salt-soda soil of diaphragm process special designing, and when electrolysis is logical
Cation-exchange membrane migration cation is crossed, the diaphragm process for completing extraction caustic alkali improvement salt-soda soil administers the dress in salt-soda soil
It sets.
Portion's insulating mounting has the outwardly extending cathode conductive material in both ends to the utility model in the frame, in cathode conduction material
Material, which is placed on one in frame section, is set with cation-exchange membrane, and the sealing of cation-exchange membrane both ends is placed in cation-exchange membrane
It is provided with limbers on cathode conductive material in cladding, the frame two sides parallel insulation in cathode conductive material two sides is equipped with sun
Pole conductive material;Cathode conductive material one end is communicated by return pipe with collecting tank, and the other end passes through water inlet pipe and collecting tank phase
It is logical, water pump is installed on water inlet pipe;The cathode chamber that anode conducting material, cathode conductive material and cation-exchange membrane are constituted is flat
Row is synchronous and contacts with salt-soda soil.
The frame of the utility model is anode, and cathode conductive material and cation-exchange membrane constitute cathode chamber, frame, cathode
Cathode chamber parallel synchronous that conductive material and cation-exchange membrane are constituted simultaneously is contacted with salt-soda soil.
The utility model structure is simple, easy for operation.Using chlorine industry diaphragm process as starting point, with special side
The machinery equipment of formula method design, walk or orient in salt-soda soil by diaphragm process, be electrolysed salt in salt-soda soil,
Alkali, nitre, production caustic alkali, produce caustic alkali while administering salt-soda soil and sour gas generates economic benefit, do not use and appoint
What chemical substance, does not generate secondary pollution, and governance process only needs consuming electric power, it is one-time formed permanently administer it is all types of light
Heavy salinizedly, economic benefit almost maintains an equal level with control expense, administers salt-soda soil equal to no expense.The utility model is salt-soda soil
Relatively effective disposable improvement in rebuilding and improving is suitable for all types salt-soda soil, including it is aging promote yield, without anti-
It is multiple, it is pollution-free, any chemical substance is not used, the salt in salt-soda soil has simply directly been decomposed, alkali, nitre, has removed caustic alkali,
Consuming electric power is only needed in the process, and structure is simple, cheap, takes effect at that time, and the caustic alkali of extraction and other compounds can be with
It sells, generates economic benefit.
Detailed description of the invention
Fig. 1 is the utility model structure diagram;
Fig. 2 is the A-A direction view of the utility model Fig. 1;
Fig. 3 is structural schematic diagram of the utility model with frame directly as anode.
Specific embodiment
The utility model is divided into two kinds of structure type according to the setting means of anode
The first is: the utility model is insulated in the middle part of frame 5 the outwardly extending cathode conductive material 3 in both ends,
Cation-exchange membrane 9 is set on one section that cathode conductive material 3 is placed in frame 5,9 both ends of cation-exchange membrane seal,
It is provided with limbers 10 on the cathode conductive material 3 being placed in the cladding of cation-exchange membrane 9, the frame in 3 two sides of cathode conductive material
5 two sides parallel insulation of frame is equipped with anode conducting material 4;3 one end of cathode conductive material is communicated by return pipe 2 with collecting tank 6,
The other end is communicated by water inlet pipe 7 with collecting tank 6, and water pump 8 is equipped on water inlet pipe 7;Anode conducting material 4, cathode are conductive
Cathode chamber parallel synchronous that material 3 and cation-exchange membrane 9 are constituted simultaneously is contacted with salt-soda soil 1.
Second is: the frame 5 of the utility model is anode, and cathode conductive material 3 and cation-exchange membrane 9 constitute cathode
Room, cathode chamber parallel synchronous that frame 5, cathode conductive material 3 and cation-exchange membrane 9 are constituted simultaneously are contacted with salt-soda soil 1.
In the first form, frame 5 is only a common shelf, only serves the work of the frame bodies such as support and fastening
It is by being insulated on frame 5 with, anode, and in second of form, frame 5 plays two kinds of functions, that is, plays support
The effects of with fastening, and at the same time playing the role of anode.In this way in the first form, anode conducting material 3 and salt-soda soil 1
Form anode chamber after contact, cathode cation-exchange membrane and cathode form cathode chamber, and in second of form, frame 5 with it is saline and alkaline
Ground 1 forms anode chamber after contacting, cathode cation-exchange membrane and cathode form cathode chamber.
The method of the utility model is using diaphragm process: device being lain on salt-soda soil, anode part, negative pole part
Point, parallel synchronous contacted with the muddy water in salt-soda soil, addition water is recycled with water pump in collecting tank, and the water in collecting tank passes through yin always
Pole room internal circulation is contacted by the hole above cathode with cation-exchange membrane, and cation-exchange membrane is contacted with salt-soda soil, sun
Pole is contacted with salt-soda soil, is contacted since two electrodes are all synchronized with salt-soda soil, and thus forming salt-soda soil is anode chamber, salt-soda soil
Muddy water be anode electrolyte form complete diaphragm cell using cation-exchange membrane as cut-off rule.
The utility model is using the diaphragm process of the device in diaphragm process improvement salt-soda soil on Saline-alkali Field Control
Using.
When the utility model is used, be suspended in tractor or equipment, can by enter return pipe be fixed on tractor or
In equipment, and the anode and cathode installed in frame and frame has to contact with salt-soda soil, and collecting tank can be placed in tractor
Or in equipment.
The utility model is further explained in detail and is illustrated below in conjunction with attached drawing:
The utility model walk or orient in salt-soda soil by diaphragm process, decomposed by raw material of salt-soda soil
Salt, alkali, nitre, production caustic alkali, production sour gas in salt-soda soil, produce caustic alkali while administering salt-soda soil and generate warp
Benefit of helping does not generate secondary pollution, governance process only needs consuming electric power, one-time formed permanent without using any chemical substance
All types of weight degree salt-soda soil is administered, economic benefit almost maintains an equal level with control expense, administers salt-soda soil equal to no expense.
For the utility model using anode and salt-soda soil as the anode chamber of electrolytic cell, the saline-alkali water and soil in salt-soda soil are anode electricity
Xie Zhi, using cation-exchange membrane plus cathode as the cathode chamber of electrolytic cell, cathode chamber part is diaphragm and yin using diaphragm as line of demarcation
Pole design is independent area of space, forms the cathode of electrolytic tank room of autonomous closure, has water circulation system, receives with caustic alkali
Collect tank, add water in collecting tank, independent internal circulation system is generated under the ringing of water pump, the water in the circulatory system is yin
Pole room electrolyte, when anode and cathode connect direct current when being placed on the muddy water in salt-soda soil simultaneously under keeping certain spacer conditions
Electricity, anode are contacted using salt-soda soil muddy water as electrolyte with the cation-exchange membrane of cathode chamber, and cation-exchange membrane passes through interior circulation
Water and cathode contacts form a complete diaphragm cell, salt, alkali, nitre, quilt under the action of direct current in salt-soda soil
It decomposes, salt, alkali, nitre, anionic reactive generate sour gas in anode and salt-soda soil, and sour gas is dissolved directly into salt-soda soil
Middle generation acid water adjusts salt-soda soil pH value simultaneously.Cation enters cathode chamber by cation-exchange membrane toward cathodic migration
Reaction generates caustic alkali.The internal circulation system of cathode chamber recycles the high concentration caustic solution near cathode and the gas of generation
It comes out in collecting tank, causticity alkali soluble is taken out when the caustic sodium concentration in lasting electrolytic process in collecting tank is close to saturation state
Liquid forms caustic product by evaporation process and sells or be prepared into the higher economic benefit of other products generations.
The utility model cathode chamber has independent internal-circulation type electrolysis system, and the mud or water in anode and salt-soda soil connect
Touching, by way of diaphragm process, electrolytic salt, alkali, nitre, forms the diaphragm cell electrolysis system of complete set, with row
It the modes such as walks, move, fixing, extract caustic alkali or generating other compounds.Caustic alkali is produced while administering salt-soda soil.
Salt-soda soil main component based on causticity alkali cpd, by salt, alkali, nitre, for, the salt-soda soil condition administered needs
Reach the standard of conductivity with muddy water or wetness, reaction condition is diaphragm electrolysis.
Sodium chloride salt
Cathode chamber (cathode) reaction: 2H+ (hydrogen ion)+2e=H2 ↑ (hydrogen)
Anode chamber's (anode) reaction: 2Cl- (chloride ion) -2e=Cl2 ↑ (chlorine)
Overall reaction: 2NaCl+2H2O=electrolysis=2NaOH+H2 ↑+Cl2 ↑
Anode chamber generates chlorine and returns salt-soda soil, and cathode chamber generates sodium hydroxide (collection processing)
The Northeast's soda alkaline land is mainly sodium carbonate salt (Na2CO3)
Use the electrolytically generated hydrogen of cation-exchange membrane and oxygen
Anode chamber generates oxygen and can be discharged into environment, and cathode chamber generates sodium hydroxide (collection processing).
Saltcake (sodium sulphate Na2SO4)
Anode chamber generates acidic materials, and cathode chamber generates sodium hydroxide.(collection processing).
The utility model is using chlorine industry diaphragm process as starting point, the machinery equipment that method designs in a particular manner,
In the utility model referred to as (electrolysis machine), move, walk in salt-soda soil, fixing, mode is by diaphragm process, with salt
It is alkali raw material, salt, alkali, nitre, the extraction caustic alkali being electrolysed in salt-soda soil administer improvement salt while generating acid compound
Alkali, including administer acid soil.
It is boundary, diaphragm preferred cationic exchange membrane, anode part and the independent electricity of each self-forming of cathode portion with diaphragm
The room Xie Chi, wherein the inert electrode specification, shape, size of anode part, designed according to cathode chamber, wherein anode part with it is saline and alkaline
The saline-alkali water or soil on ground contact.As the electrolyte at anode, being formed with salt-soda soil muddy water is sun for soil or saline-alkali water
The anode chamber of pole electrolyte.
The cathode chamber of the utility model cathode of electrolytic tank part is designed to using diaphragm as the band of the built-in inert electrode of outer wall
There is the caustic alkali production of internal circulation system, collect, storage, comprehensive machinery equipment,
The utility model diaphragm and cathode design are independent area of space, form the cathode of electrolytic tank room of autonomous closure,
The cathode chamber both ends of sealing are connect by the pipeline with water pump with caustic alkali collecting tank, and addition water makees electrolyte in collecting tank,
Water in water pump circulating collection tank continues through cathode of electrolytic tank room, forms independent cathode chamber internal circulation system.
The diaphragm outer wall of cathode chamber is contacted with the saline-alkali water in salt-soda soil or soil, is equal to and is connected with anode chamber's electrolyte,
Form complete diaphragm cell.
When work, anode is contacted with salt-soda soil simultaneously with cathode chamber, and two interelectrode distances are according to the Current Voltage of setting
It being set, after positive and negative anodes connect direct current, the Ghandler motion that faces south of the anion in salt-soda soil is dynamic, and cation is to movable cathode, and two
Electrode place causticity alkali cpd contained in the region of salt-soda soil, salt, nitre, are decomposed at alkali, and anion loses electricity on anode
Oxidation reaction occurs for son, has adjusted salt-soda soil pH value while generating sour gas and muddy water dissolution chemical combination generation acid water.
Cation passes through diaphragm and enters cathode chamber, and electronics is obtained on cathode, and reduction reaction occurs, and generates caustic alkali, holds
In continuous electrolytic process, the internal circulation system of cathode chamber recycles the gas of the high concentration caustic alkali near cathode and generation to come
Into collecting tank, the caustic sodium concentration in lasting electrolytic process in collecting tank is gradually increased, and is taken out when close to saturation state severe
Property aqueous slkali, adding water again works on, that is, caustic alkali out of salt-soda soil, the aqueous caustic of taking-up is through pervaporation
Processing forms caustic product or is prepared into other products, and sour gas caused by anode chamber also collects and is prepared into production
Product, told acid soil recycle extraction sour gas using anion-exchange membrane using anode chamber and carry out improvement improvement.
Wherein energy source is any machinery equipment that can provide electric energy, including charging equipment, used direct current galvanic electricity
Pressure is by the Current Voltage within the scope of the conductivity size intelligent control output safety of salt-soda soil water and soil contained substance.
The utility model membrane portions, Industrial membranes material mainly have cotton or chemical & blended fabric, cellular plastic, asbestos board, from
Proton exchange, biscuit ware etc., amberplex, RO reverse osmosis membrane, lithium-ion membrane, asbestos diaphragm, the utility model are suitable
For the isolation method of any material composition, and a variety of diaphragm combined applications can be used simultaneously, effect is most preferably cationic
Exchange membrane, anion-exchange membrane.Addition other materials protect diaphragm, and cathode is not limited in position used in diaphragm, is formed
Electrolytic cell shape design is electrolysed improvement improvement salt-soda soil extraction caustic alkali with diaphragm cell and other compounds is without limitation
Purpose.
Electrode material selects corrosion-resistant inert electrode, the strong material of electric conductivity, preferably permeable graphite felt.Electrode shape, knot
Structure, without limitation, be with cylindrical, hollow electrode it is best, be electrolysed the configuration of electrodes of machine without limitation, single group include multiple groups simultaneously
Connection, series connection, on-demand combined application.
Anode chamber and cathode chamber can generate gas at work, additional gas collects, processing, etc. equipment collect gas sale
Or it is prepared into compound, unwanted gas is blown in air by exhaust fan to be diluted.
Anode part collects sour gas using anion-exchange membrane, and additional water pumping takes the water in salt-soda soil quickly through sun
Polar region, the sour gas generated to anode region are quickly dissolved into salt-soda soil, increase the meltage of sour gas, adjust salt-soda soil
PH value.
Diaphragm process combination manufacture is at the machinery equipment referred to as (electrolysis machine) for pulling walking, using power machine in salt
Walking is pulled in alkali ground, anode part contacts to form diaphragm cell with cathode portion with salt-soda soil.Machinery equipment shape size
For limitation, anode discharges to salt-soda soil, and cathode discharges to salt-soda soil by interior cyclic electrolysis matter and diaphragm, forms diaphragm type electricity
Xie Chi is towed in salt-soda soil under the drive of power machine, carries out diaphragm process to salt-soda soil in traveling, extracts causticity
Alkali and sour gas administer improvement salt-soda soil,
Including power machine portable type, manufactured electrolytic cell shape is mounted on power machine and carries without limitation,
It is not contacted with salt-soda soil, the segmentation of electrolytic cell medial septum, side anode chamber, side cathode chamber, anode chamber extracts salt with water pump
Saline-alkali water in alkali ground cycles through anode chamber, and cathode chamber collects caustic alkali, and power machine carries electrolytic cell in salt-soda soil expert
It walks, to extract salt-soda soil water cyclic electrolysis ruling by law reason salt-soda soil, large scale equipment designs multiple groups electrolytic cell machine, in parallel or in series
Shape, size, form, the as needed design of work in combination, anode chamber and cathode chamber point.
Wherein electrode uses electric wire series and parallel,
Wherein cathode chamber connects series and parallel using water pipe.
The generator for being wherein electrolysed machine can design on tractor output shaft,
The generator for being wherein electrolysed machine can be designed to be docked by drive apparatus with tractor dynamic power on electrolysis machine body,
Docking mode is without limitation.
Wherein electrolysis machine can design installation and be independent machinery equipment, with generating set perhaps charging equipment or
The electrolysis machine walked using the ontology energy.
The mating power of Saline-alkali Field Control machinery equipment has the large machines of pilot steering, the machine of remote driving, intelligent GPS
Satellite three-point fix technology, laser SLAM is positioned immediately and map structuring, carries out planning property automatically walk using SLAM, vision is led
Navigate vSLAM, and virtual wall, the walking of number of types of intelligent planning carry out bow word, Back Word, intelligence similar to sweeping robot
Walking manner, these types are closed application with electrolysis machine equipment group and are administered to salt-soda soil.
Directional type, fixed equipment, mobile device are separated among manufacturer's standard electrolytic cell with diaphragm, use water pump cyclic salt
The saline-alkali water on alkali ground cycles through anode electrolysis pond, extracts the caustic alkali in salt-soda soil and extracts sour gas simultaneously, this is practical
It is novel to be equally applicable to polluted source processing.
Aging arable land causes soil seriously to pollute or the exceeded production of other compounds contents since fertilizer and pesticide is used for a long time
Amount decline, wherein the residual for ultimately forming various salts, compound, Suo Youyang are mutually converted in chemical fertilizer, pesticide, meeting in the soil
Amberplex and anion-exchange membrane are targetedly electrolysed soil, propose that the exceeded compound of content makes in soil
Compound trim again, cleaning have activated soil, use anion-exchange membrane and cation-exchange membrane as needed, and specific aim mentions
It takes anion or cation eliminate, change, activation, chemical composition of soil, promotes yield, complete arable land and administer.To severe dirt
The soil of dye and water body are equally applicable.
In the utility model, 1 standard for reaching conductivity for the salt-soda soil with water or wetness in Fig. 1, with chlor-alkali work
The electrolytic cell of industry diaphragm process is starting point, design electrolysis machine.
Anode electrode construction;Anode is corrosion-resistant inactive, conductive material.
Cathode portion cathode chamber construction;Pref. cylindrical cathode chamber, cathode chamber construction by cation-exchange membrane, cathode, into
Water pipe, outlet pipe, collecting tank, water pump, the closed circulation set up jointly cathode chamber, wherein cathode match drainage tube shape
Corrosion-resistant conductive material, such as;Length 100cm diameter 8cm, cation-exchange membrane (tubulose) cover outside cathode, close to tie
Merge and both ends seal, such as 10 centimetres of seal length, water body and extraneous circulation, yin in cathode tube is isolated in cation-exchange membrane
The both ends of pole pipe are separately connected water inlet pipe and outlet pipe, and water inlet pipe is connect with outlet pipe with collecting tank, and addition water is electrolyte, by
Water pump drives circulation, thus constructs the cathode chamber of the interior circulation of complete set.
The utility model is electrolysed machine assembling:
Cathode in cathode chamber does insulation and is fixed on electrode framework, and anode does insulation and is fixed on electrode framework, anode
Certain electrode distance, such as 10 centimetres of spacing are kept between the outer diameter of cathode, positive and negative electrode is parallel installation, and main body is formed
Rectangular frame structure, collecting tank, water pump are placed in above machinery equipment frame and are connect with cathode chamber by pipeline, are formed complete
Machinery equipment form.Anode is contacted with cathode parallel, synchronization, with 1 salt-soda soil when working condition, forms complete diaphragm electrolysis
Pond form, wherein frame using corrosion resistant metal frame when directly connect positive pole and do anode chamber, replace anode material band simultaneously
There are framework functions.
Utility model works mode and principle:
The device of the utility model is lain on salt-soda soil, anode part, cathode portion, parallel synchronous and the mud in salt-soda soil
Water contact, the interior addition water of collecting tank are recycled with water pump, and the water in collecting tank passes through cathode chamber internal circulation always, by cathode
The hole in face is contacted with cation-exchange membrane, and cation-exchange membrane is contacted with salt-soda soil, and anode is contacted with salt-soda soil, due to two
Electrode is all synchronized with salt-soda soil and is contacted, and thus forming salt-soda soil is anode chamber, and the muddy water in salt-soda soil is the electrolyte of anode, with
Cation-exchange membrane is cut-off rule, forms complete diaphragm cell, has reached operating condition.
After anode and cathode connect direct current, the Ghandler motion that faces south of the anion in salt-soda soil is dynamic, and cation is to movable cathode, and two
A electrode place causticity alkali cpd contained in the region of salt-soda soil, salt, nitre, are decomposed at alkali, and anion loses on anode
Oxidation reaction occurs for electronics, has adjusted salt-soda soil soda acid while generating sour gas and muddy water dissolution chemical combination generation acid water
Degree,
Cation passes through cation-exchange membrane and enters cathode chamber, and electronics is obtained on cathode, and reduction reaction occurs, and generates severe
Property alkali, in lasting electrolytic process, the gas of the internal circulation system of cathode chamber the high concentration caustic alkali near cathode and generation
Circulation comes out in collecting tank, and the caustic sodium concentration in lasting electrolytic process in collecting tank gradually increases, in close saturation shape
Take out careless property solution when state, add water again and work on, the caustic alkali of taking-up by evaporation process formed caustic product or
Person is prepared into other products, and sour gas caused by anode chamber also collects and prepares product, and anode chamber equally administers improvement acid
Property soil,
Machinery equipment falls into muddy water under the weight of the device of the utility model itself, falls into depth just to cover anode portion
Point, cathode portion be it is best, it is different according to the hardness in each piece of salt-soda soil to fall into depth, in increase or reduction collecting tank
Water falls into depth to adjust the set down weight of electrolysis machine to control, this methods forms complete extract in salt-soda soil
Salt, alkali, nitre, the machinery equipment for generating caustic alkali.
Be electrolysed salt-soda soil soil depth depend on electrode power and travel speed, such as two parallel poles lie in it is saline and alkaline
On the muddy water on ground, semicircle diffusion downwards, such as 10 centimetres of electrode spacing are presented in electricity on soil first, are powered on rear positive and negative
The linear distance conductivity of pole is maximum, is electrolysed first, the conductivity of linear distance declines rapidly, then electricity will be in two electricity
Arc is presented in interpolar, and the direction high along conductivity is connected, that is, toward the arc-shaped process in soil depths in salt-soda soil, so electric
The depth in solution salt-soda soil can apply power as needed and be electrolysed the residence time of machine.
The utility model ancillary equipment:
Collecting tank is that electrolyte storage equipment is also caustic alkali collecting device, and hydrogen, water can be generated when due to catholyte
The high concentration caustic alkali that pump circulation goes out is swapped in collecting tank and low concentration of water, and caustic sodium concentration is close to when being saturated in collecting tank
Centralized processing is taken out, while also recycling hydrogen, therefore adds exhaust fan on collecting tank and the hydrogen in collecting tank is quickly arranged
It is put into air and dilutes or additional gas processing equipment.
The mode that positive and negative anodes are exchanged after cathode chamber diaphragm is contaminated removes, and cathode chamber part is removed inert electrode material and changed
For other corrosion-resistant tube type materials, conductive electrode is done using graphite felt and increases electrolytic efficiency, while also reducing cost, manufacturer
Underground in method specification, the component part of cation-exchange membrane will increase different materials and protect to cation-exchange membrane,
It is underground in materials specification.
The material package graphite felt that it is good that anode matches corrosion-resistant anti-impact force does conductive electrode, reduces cost.
Saline-alkali Field Control is raked all-in-one machine, the device integral installation of the utility model on all-hydraulic collapsible planisher,
Such as using 804 tractors, the planisher of carrying is long 2 meters of collapsible planishers, and planisher total length is 6 meters after opening, electricity
Solution electrode is arranged in mode in series or in parallel is mounted on planisher in the following, it is preferred that positive polar diameter is always straight less than cathode chamber part
Before driving direction, positive and negative anodes are alternately arranged for the half of diameter, preferably anode, and 1 meter of overall width, advantage is to pull in traveling two
Electrode contacts sufficiently with salt-soda soil muddy water, and collecting tank is mounted on above tractor or rakes on all-in-one machine, forms electrolysis machine
Add all-in-one machine of raking, all-in-one machine is mounted on tractor hydraulic suspension, and hydraulic suspension control all-in-one machine connects with salt-soda soil muddy water
Depth is touched, the electrode of the electrolysis machinery equipment of the utility model comes into full contact with salt-soda soil, pulls walking saline and alkaline by tractor
Mobile diaphragm electrolysis is carried out on the ground, is walked in salt-soda soil repeatedly, 1 meter of 6 square metres of electrolysis salt-soda soil of every traveling does not need one
Machine tables of equipment solely uses when body machine, such as tractor output shaft drives 50 kilowatts of generator to power to electrolysis electrode, according to every
It operates at full capacity for 10 hours produces electricl energy 500 degree of electricity, decomposes and about produces caustic alkali sterling when extracting salt content in salt-soda soil
200 kilograms, 200 kilograms of sour gas, sour gas is dissolved directly into salt-soda soil at anode, improves the pH value in salt-soda soil,
Huge economic benefit is generated while improveing salt-soda soil, advantage is that work efficiency is high, and the salt-soda soil content after improvement is average, is fitted
Salt-soda soil is administered for large area, is particularly suitable for large area cultivation paddy field, is raked the soil level same with electrolysis salt-soda soil production caustic alkali
Step carries out, and the quick improvement in various degrees of salt-soda soil, current year high yield disposably administers salt-soda soil, do not need to invest repeatedly.
The design of the utility model drone version field machine
Drone version is based on baby tractor, for example, small hand tractor, hand tractor installs rotary cultivator position peace
Fill generator, be connected on the belt pulley of engine by belt and drive electrical power generators, behind pull the utility model electrolysis
Machine, remote control part use multi-channel remote component, such as remote-control car transceiver module, drive straight line horse using generator power supply
Unmanned steering is completed up to the left and right turn arm of control hand tractor, miniature reciprocal telescopic formula motor control engine oil is installed
Door is completed modular power source using relay control high current voltage and is converted, and advantage is that peasant does not have to be remotely controlled work outside into ground
Make, safe, comfortable, entire remote control system adds several hundred yuan of control section cost, is suitble to family Saline-alkali Field Control.
The utility model is intelligent to be designed from running machine,
GPS is used suitable for the combination of various running machines and electrolysis machine suitable for big-and-middle small-scale Saline-alkali Field Control
Satellite three-point fix technology, laser SLAM is positioned immediately and map structuring, carries out planning property automatically walk using SLAM, vision is led
Navigate vSLAM, and number of types of intelligent planning walking carries out bow word, Back Word, intelligent walking module similar to sweeping robot
Signal source replaces drone version baby tractor remote controler part, is passed through with intelligent signal source and line motor and reciprocal telescopic motor
Relay controls the docking of running machine part, and 1,000 yuan of intelligence cost or more, advantage is to be suitble to various areas saline and alkaline
Ground is administered.It does not need to manage, energy while multimachine device large area operation.
The utility model is fixed;Cathode chamber is prepared as barrel shape according to the structure of cylindrical electrode, and any shape is ok,
With cation-exchange membrane for inside and outside segmentation, it is placed in salt-soda soil and is in close contact with the muddy water in salt-soda soil, preferably goed deep into saline and alkaline
In ground soil, inert electrode built in cathode chamber adds water in cathode chamber and does electrolyte, and anode uses graphite rope or other lazy
Property conductive material, centered on cathode chamber, anode starting point and cathode ectosome distance are anode according to the Current Voltage that design applies
Calculated value, the outside radiation shapes of anode are placed in the soil in salt-soda soil, and positive cathode is respectively turned on direct current, the radiated model of anode
Cation in enclosing migrates under the action of electric field force to be entered cathode chamber by diaphragm to cathode site and is collected, directional type improvement
It is simple suitable for sun-generated electric power, wind-power electricity generation, structure, cheap, not labor intensive, the disadvantage is that it is slow to administer speed, not enough
Uniformly, it is suitable for the same improvement salt-soda soil of government.
The generator for being wherein electrolysed machine can design on tractor output shaft.
The generator for being wherein electrolysed machine can be designed to be docked by drive apparatus with tractor dynamic power on electrolysis machine body,
Docking mode is without limitation.
Wherein electrolysis machine can design installation and be independent machinery equipment, with generating set perhaps charging equipment or
The electrolysis machine walked using the ontology energy.
Case verification
It administers salt-soda soil expense to calculate, according to heavy salinized ground standard, salt content is 0.4%-0.6% kilograms, takes centre
0.5% kilogram of value calculating, administer content need when reaching 0.2% or less electroextraction amount every about kilogram 0.3% salt, conversion
It is approximately equal to 3 kilograms/every cubic metre of salt for cubic meter,
Such as;1 hectare area of salt-soda soil be 10000 square metres, if 30 centimetres of controlled depth, 10000 multiplied by 0.3 meter=
3000 cubic metres, 3,000 3 kilograms=9000 kilograms salt of salt content for needing to extract multiplied by every cubic metre are produced according to chlorine industry
Data about 1000kg salt generates chlorine 607kg, sodium hydroxide 681kg
It namely administers 1 hectare of 30 centimetres of heavy salinized ground depth and about produces caustic alkali 6000kg.Sour gas
5000kg.Sour gas is dissolved directly into salt-soda soil at anode, improves the pH value in salt-soda soil, therefore diaphragm electrolysis administers salt
It does not need alkali salt to extract very thorough.
Big appointment is administered heavy salinizedly according to 1 hectare of above-mentioned calculating and produces namely 6 tons of caustic alkali 6000kg, is not calculated
The economic value that sour gas recycling generates only calculates caustic alkali and is produced according to about 3,000 yuan per ton or so of caustic alkali price
Raw about 18000 yuan or so of economic value, removes the expenses such as the electric energy of consuming, about cancels out each other, so controlling equal to no expense
Salt-soda soil is managed, above data refers to chlorine industry capacity data, and caustic alkali production capacity is not accurate to be approximately equal to data in salt-soda soil
Data are only used as reference value.
Claims (2)
1. the device that a kind of diaphragm process administers salt-soda soil, it is characterised in that: be insulated in the middle part of frame (5) have both ends to
The cathode conductive material (3) of outer extension, is set with cationic friendship on one section that cathode conductive material (3) is placed in frame (5)
It changes film (9), the sealing of cation-exchange membrane (9) both ends is placed on the cathode conductive material (3) in cation-exchange membrane (9) cladding
Limbers (10) are provided with, frame (5) two sides parallel insulation in cathode conductive material (3) two sides is equipped with anode conducting material
(4);Cathode conductive material (3) one end is communicated by return pipe (2) with collecting tank (6), and the other end is by water inlet pipe (7) and collects
Tank (6) communicates, and water pump (8) are equipped on water inlet pipe (7);Anode conducting material (4), cathode conductive material (3) and cation
The cathode chamber parallel synchronous of exchange membrane (9) composition is simultaneously contacted with salt-soda soil (1).
2. the device that diaphragm process according to claim 1 administers salt-soda soil, it is characterised in that: frame (5) is anode,
Cathode conductive material (3) and cation-exchange membrane (9) constitute cathode chamber, and frame (5), cathode conductive material (3) and cation are handed over
It changes the cathode chamber parallel synchronous of film (9) composition and is contacted with salt-soda soil (1).
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