CN209507868U - A kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water - Google Patents
A kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water Download PDFInfo
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- CN209507868U CN209507868U CN201821458133.3U CN201821458133U CN209507868U CN 209507868 U CN209507868 U CN 209507868U CN 201821458133 U CN201821458133 U CN 201821458133U CN 209507868 U CN209507868 U CN 209507868U
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- waste water
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Abstract
The utility model discloses a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water, including electrolytic cell and evaporation tank, electrode slice is plugged with inside the electrolytic cell, the electrolytic cell inner bottom surface is placed with active carbon case, and active carbon is placed with inside active carbon case, one side surface of the electrolytic cell perforation is connected with organic waste water inlet, and is located at the perforation of electrolytic cell side below organic wastewater import and is connected with exhaust gas outlet pipe.In the utility model, provided with electrolytic cell, electrolytic cell is internally provided with electrode slice, is electrolysed after energization to high concentration hard-degraded organic waste water, ozone is filled in high concentration hard-degraded organic waste water, after electrolysis, the ozone molecule in ozone is ionized into the higher oxonium ion of oxidisability, the organic matter difficult to degrade in oxonium ion oxidized waste water, make its quick oxidative degradation, and the active carbon in active carbon case accelerates ozone electrolytic efficiency, saves electric power, is more energy-saving and environmentally friendly.
Description
Technical field
The utility model relates to the advanced processes equipment technical fields of high concentration hard-degraded organic waste water, more particularly to one kind
The advanced processes equipment of energy-saving high concentration hard-degraded organic waste water.
Background technique
The processing of high concentration hard-degraded organic waste water is the problem that sewage treatment circle both at home and abroad is generally acknowledged at present, for this kind of
Waste water, studying both at home and abroad at present more have coking wastewater, pharmacy waste water (including traditional Chinese medicine wastewater), petrochemical industry/oils waste water, spins
Knit/professionals waste water, the so-called high concentration such as dyeing waste water, wastewater from chemical industry, paint waste water refer to the organic concentration of this kind of waste water
(in terms of COD) is higher, and generally in 2000mg/L or more, even as high as every liter of some tens of thousands of to ten tens of thousands of milligrams；So-called difficult drop
Solution, refers to that the biodegradability of this kind of waste water is lower (BOD5/COD value is even lower generally below 0.3), it is difficult to biology drop
Solution, thus in the industry generally by COD concentration be greater than 2000mg/L, BOD5/COD value lower than 0.3 organic wastewater be collectively referred to as it is highly concentrated
Spend organic wastewater with difficult degradation thereby, due to high concentration hard-degraded organic waste water generate and itself the characteristics of attribute, have following main danger
Evil: first is that aerobism endangers: due to biodegradation, high concentrated organic wastewater can make receiving water body anoxic even anaerobism, more
Number aquatic organism will be dead, to generate stench, deteriorates water quality and environment；Second is that sense organ contact scar: high concentrated organic wastewater is not only
So that water body is lost use value, more seriously affects the normal life of the nearby water bodies people；Third is that causing toxicity harm: ultrahigh concentration has
Contain a large amount of toxic organic compounds in machine waste water, can constantly accumulate, store in the natural environments such as water body, soil, finally enter people
Body is detrimental to health.
Advanced oxidation processes mainly have at present: Ozonation, have apparent selectivity to the degradation of organic matter, is produced from centre
Object is more；Electrochemical treatment, by electric current and mass transfer and limit, processing cost is high；Photocatalytic oxidation, low with quantum utilization rate,
The disadvantages of energy consumption is high and catalyst needs reclaiming；Wet oxidation process needs high-temperature high-pressure apparatus at high cost；Fenton reagent is high
Grade oxidation technology, added amount of chemical is big, and the sludge of generation is more etc., in view of the above-mentioned problems, spy proposes a kind of energy-saving high concentration
The advanced processes equipment of organic wastewater with difficult degradation thereby.
Utility model content
Purpose of the utility model is to solve disadvantages existing in the prior art, and the one kind proposed is energy-saving highly concentrated
Spend the advanced processes equipment of organic wastewater with difficult degradation thereby.
To achieve the goals above, the utility model adopts the technical scheme that a kind of energy-saving high-concentration hardly-degradable
The advanced processes equipment of organic wastewater, including electrolytic cell and evaporation tank are plugged with electrode slice, the electrolysis inside the electrolytic cell
Tank inner bottom surface is placed with active carbon case, and active carbon is placed with inside active carbon case, and one side surface of the electrolytic cell perforation connects
It is connected to organic wastewater import, and is located at the perforation of electrolytic cell side below organic wastewater import and is connected with exhaust gas outlet pipe, the exhaust gas
The perforation of outlet pipe bottom surface is welded with waste gas treatment tank, and waste gas treatment tank bottom surface penetrates through and is connected with exhaust pipe, at the exhaust gas
It is located at the perforation of electrolytic cell side below reason case and is connected with ozone inlet pipe, the electrolytic cell bottom surface perforation is connected with water-supply-pipe, and defeated
Water pipe one end, which is located at below electrolytic cell, is welded with the first electric-controlled ball valve, and the water-supply-pipe other end is passed through by self priming pump and water inlet pipe
Lead to and connect, the water inlet pipe other end and the perforation of one upper side of evaporation tank connect, and the evaporation tank other side perforation is connected with cold
But it manages, and the cooling tube other end and collecting box perforation connect, the cooling tube outer surface is welded with cooler, under the cooler
Side is placed with tank for coolant.
It is as above-mentioned technical proposal to further describe:
Waste gas treatment tank inner upper side is welded with alkali soluble liquid case, and is located at waste gas treatment tank below alkali soluble liquid case
Inside is connected with active carbon layer, and exhaust gas outlet pipe bottom surface is located inside alkali soluble liquid case through top surface on waste gas treatment tank.
It is as above-mentioned technical proposal to further describe:
The evaporation tank top surface is welded with servo motor, and servo motor bottom surface is welded with stirring through evaporation tank top surface
Paddle, the evaporation chamber interior wall are welded with heating tube, and the second electric-controlled ball valve of evaporation tank underrun perforation is connected with waste liquid receipts
Header.
It is as above-mentioned technical proposal to further describe:
The perforation of tank for coolant top surface side is connected with cooling efferent duct, and the cooling efferent duct other end is passed through with cooler
Lead to and connect, the tank for coolant side perforation is connected with cooling input pipe, and cooling input pipe other end perforation is connected with circulation
Water pump, the water circulating pump other end are connected by connecting tube and cooler perforation.
It is as above-mentioned technical proposal to further describe:
Ozone inlet pipe one end, which is located at electrolytic cell interior welds, backstop, and backstop is internally located at ozone inlet pipe one
End top surface is welded with fixed link, and the fixed link interior side is welded with shaft, and shaft side is welded with connecting rod, the connecting rod
Spring is elasticly connected between fixed link, gasket has been bolted in described connecting rod one end, and the gasket diameter is big
In ozone inlet pipe diameter, the collecting box top surface is welded with photovoltaic battery plate, is placed with battery below the collecting box.
It is as above-mentioned technical proposal to further describe:
The self priming pump model 40WFB-A2 type No leakage self-controlling self-priming pump, the servo motor model number are
MDME302GCGM type servo motor, the first electric-controlled ball valve model ZRJQ motorized adjustment ball valve, second electric-controlled ball valve
For Q947 fixing type electric ball valve, the water circulating pump model PMD-0411SC acid and alkali-resistance magnetic force discharging pump.
In the utility model, it is provided with electrolytic cell first, electrolytic cell is internally provided with electrode slice, to high concentration after energization
Organic wastewater with difficult degradation thereby is electrolysed, and ozone is filled in high concentration hard-degraded organic waste water, the ozone after electrolysis, in ozone
Molecular ionization is at the higher oxonium ion of oxidisability, and organic matter difficult to degrade in oxonium ion oxidized waste water makes it quickly aoxidize drop
Solution, and the active carbon in active carbon case accelerates ozone electrolytic efficiency, saves electric power, is more energy-saving and environmentally friendly, and is secondly provided with useless
Gas disposal case, waste gas treatment tank inside are equipped with alkali soluble liquid case and active carbon layer, and exhaust gas enters in alkali soluble liquid case by exhaust gas outlet pipe,
The pernicious gas for dissolving in aqueous slkali is absorbed, and the harmful substance contained in remainder of exhaust gas is adsorbed by active carbon layer, clean empty
Gas is outdoor by exhaust pipe discharge, prevents from generating pernicious gas discharge outdoor pollution environment during electrolysis, simultaneously
Play the role of environmental emission reduction, be finally provided with backstop, backstop is located at the port of ozone inlet pipe, when ozone pass through ozone into
When pipe is discharged into electrolytic cell, ozone inlet pipe air pressure inside is greater than electrolytic cell air pressure inside, and gasket is opened, and gasket is revolved along shaft
Turning, spring-compressed, ozone enters electrolytic cell, and when ozone is no longer discharged into, gasket is pushed into ozone inlet pipe port by spring elongation,
Ozone inlet pipe is sealed, high concentration hard-degraded organic waste water is prevented to be guided to inside ozone inlet pipe, prevents suck-back phenomenon
Occur, prevents having preferable practicability inside corrosion ozone inlet pipe.
Detailed description of the invention
Fig. 1 be the utility model proposes a kind of energy-saving high concentration hard-degraded organic waste water advanced processes equipment knot
Structure schematic diagram；
Fig. 2 is the structural schematic diagram of the utility model waste gas treatment tank；
Fig. 3 is the structural schematic diagram of the utility model backstop.
Marginal data:
1- electrolytic cell, the import of 2- organic wastewater, 3- exhaust gas outlet pipe, 4- waste gas treatment tank, 5- exhaust pipe, 6- ozone into
Pipe, 7- backstop, 8- active carbon case, 9- active carbon, the first electric-controlled ball valve of 10-, 11- water-supply-pipe, 12- waste liquid collecting box, 13-
The cooling efferent duct of two electric-controlled ball valves, 14- agitating paddle, 15-, 16- tank for coolant, 17- cooling input pipe, 18- water circulating pump, 19-
Battery, 20- collecting box, 21- photovoltaic battery plate, 22- cooler, 23- cooling tube, 24- servo motor, 25- evaporation tank, 26- add
Heat pipe, 27- water inlet pipe, 28- self priming pump, 29- electrode slice, 30- alkali soluble liquid case, 31- active carbon layer, 32- gasket, 33- connecting rod,
34- fixed link, 35- spring, 36- shaft.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model
Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole
Embodiment.
Referring to Fig.1-3, a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water, including 1 He of electrolytic cell
Evaporation tank 25 is plugged with electrode slice 29 inside electrolytic cell 1, and 1 inner bottom surface of electrolytic cell is placed with active carbon case 8, and active carbon case 8
Inside is placed with active carbon 9, and the perforation of 1 one side surface of electrolytic cell is connected with organic waste water inlet 2, and 2 lower section of organic wastewater import
Positioned at 1 side of electrolytic cell, perforation is connected with exhaust gas outlet pipe 3, and the perforation of 3 bottom surface of exhaust gas outlet pipe is welded with waste gas treatment tank 4, and exhaust gas
The perforation of 4 bottom surface for the treatment of box is connected with exhaust pipe 5, and the perforation of 1 side of electrolytic cell is located at below waste gas treatment tank 4 and is connected with ozone
Inlet pipe 6, the perforation of 1 bottom surface of electrolytic cell are connected with water-supply-pipe 11, and 11 one end of water-supply-pipe is located at below electrolytic cell 1 that be welded with first electric
Ball-handling valve 10,11 other end of water-supply-pipe are connected by self priming pump 28 and the perforation of water inlet pipe 27,27 other end of water inlet pipe and evaporation tank
The perforation connection of 25 1 upper sides, the perforation of 25 other side of evaporation tank are connected with cooling tube 23, and 23 other end of cooling tube and collecting box
20 perforation connections, 23 outer surface of cooling tube is welded with cooler 22, tank for coolant 16 is placed with below cooler 22.
4 inner upper side of waste gas treatment tank is welded with alkali soluble liquid case 30, and is located at exhaust-gas treatment below alkali soluble liquid case 30
Active carbon layer 31 is connected with inside case 4,3 bottom surface of exhaust gas outlet pipe is located inside alkali soluble liquid case 30 through top surface on waste gas treatment tank 4,
25 top surface of evaporation tank is welded with servo motor 24, and 24 bottom surface of servo motor is welded with agitating paddle 14 through 25 top surface of evaporation tank,
25 inner wall of evaporation tank is welded with heating tube 26, and the perforation of 25 the second electric-controlled ball valve of underrun 13 of evaporation tank is connected with waste liquid collecting box
12, the perforation of 16 top surface side of tank for coolant is connected with cooling efferent duct 15, and cooling 15 other end of efferent duct is passed through with cooler 22
Lead to and connect, the perforation of 16 side of tank for coolant is connected with cooling input pipe 17, and cooling 17 other end of input pipe perforation is connected with and follows
Ring water pump 18,18 other end of water circulating pump are connected by connecting tube and the perforation of cooler 22, and 6 one end of ozone inlet pipe is located at electrolytic cell
1 interior welds have backstop 7, and backstop 7 is internally located at 6 one end top surface of ozone inlet pipe and is welded with fixed link 34, fixed link 34
Interior side is welded with shaft 36, and 36 side of shaft is welded with connecting rod 33, is elasticly connected between connecting rod 33 and fixed link 34
Gasket 32 has been bolted in spring 35,33 one end of connecting rod, and 32 diameter of gasket is greater than 6 diameter of ozone inlet pipe, collecting box
20 top surfaces are welded with photovoltaic battery plate 21, are placed with battery 19 below collecting box 20,28 model 40WFB-A2 type of self priming pump without
Leak self-controlling self-priming pump, 24 model MDME302GCGM type servo motor of servo motor, 10 model ZRJQ of the first electric-controlled ball valve
Motorized adjustment ball valve, the second electric-controlled ball valve 13 are Q947 fixing type electric ball valve, and 18 model PMD-0411SC of water circulating pump is resistance to
Soda acid magnetic force discharging pump.
Heating tube 26 inside evaporation tank 25 heats waste water, and waste water evaporation, vapor passes through inside cooling tube 23,
Water circulating pump 18 is discharged into cooler 22 from extraction cold water in tank for coolant 16, is cooled down for vapor, Water vapor condensation Cheng little Shui
Drop, and pool inside flow direction collecting box 20, using the principle of distillation, pure water is extracted, photovoltaic battery plate 21 utilizes luminous energy
Electrical energy for storage is converted into battery 19, clean energy resource, more environmentally-friendly energy conservation is utilized, agitating paddle 14 accelerates waste water to steam
Hair.
Working principle: in use, the present apparatus is moved to suitable position, powering on for the present apparatus, sets inside electrolytic cell 1
It is equipped with electrode slice 29, high concentration hard-degraded organic waste water is electrolysed after energization, it is organic that ozone is filled with high-concentration hardly-degradable
In waste water, after electrolysis, the ozone molecule in ozone is ionized into the higher oxonium ion of oxidisability, in oxonium ion oxidized waste water
Organic matter difficult to degrade makes its quick oxidative degradation, and the active carbon 9 in active carbon case 8 accelerates ozone electrolytic efficiency, saves
Electric power is more energy-saving and environmentally friendly, and alkali soluble liquid case 30 and active carbon layer 31 are equipped with inside waste gas treatment tank 4, and exhaust gas passes through exhaust gas outlet pipe 3
Into in alkali soluble liquid case 30, the pernicious gas for dissolving in aqueous slkali is absorbed, and the harmful substance contained in remainder of exhaust gas is through making a living
Property layer of charcoal 31 adsorb, outdoor is discharged by exhaust pipe 5 in cleaned air, prevents from generating pernicious gas row during electrolysis
Outdoor pollution environment out, while playing the role of environmental emission reduction, backstop 7 is located at the port of ozone inlet pipe 6, when ozone is by smelly
When oxygen inlet pipe 6 is discharged into electrolytic cell 1,6 air pressure inside of ozone inlet pipe is greater than 1 air pressure inside of electrolytic cell, and gasket 32 is opened, and seals
Pad 32 is rotated along shaft 36, and spring 35 compresses, and ozone enters electrolytic cell 1, and when ozone is no longer discharged into, the elongation of spring 35 will sealing
Pad 32 is pushed into 6 port of ozone inlet pipe, is sealed to ozone inlet pipe, prevent high concentration hard-degraded organic waste water be guided to ozone into
Inside pipe 6, the generation of suck-back phenomenon is prevented, prevents having preferable practicability, waste water is by electrolysis inside corrosion ozone inlet pipe 6
After be discharged into evaporation tank 25 through self priming pump 28, the heating tube 26 inside evaporation tank 25 heats waste water, waste water evaporation, water
Steam is by inside cooling tube 23, it is vapor that water circulating pump 18 is discharged into cooler 22 from extraction cold water in tank for coolant 16
Cooling, Water vapor condensation are pooled inside flow direction collecting box 20 at small water droplet, using the principle of distillation, are extracted pure
Water, photovoltaic battery plate 21 are converted into electrical energy for storage in battery 19 using luminous energy, and clean energy resource, more environmentally-friendly section is utilized
Can, agitating paddle 14 accelerates waste water evaporation.
The preferable specific embodiment of the above, only the utility model, but the protection scope of the utility model is not
It is confined to this, anyone skilled in the art is within the technical scope disclosed by the utility model, practical according to this
Novel technical solution and its utility model design are subject to equivalent substitution or change, should all cover the protection model in the utility model
Within enclosing.
Claims (6)
1. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water, including electrolytic cell (1) and evaporation tank (25),
It is characterized in that, being plugged with electrode slice (29) inside the electrolytic cell (1), electrolytic cell (1) inner bottom surface is placed active
Charcoal case (8), and be placed with active carbon (9) inside active carbon case (8), (1) one side surface of the electrolytic cell perforation is connected with organic
Waste water inlet (2), and be located at the perforation of electrolytic cell (1) side below organic wastewater import (2) and be connected with exhaust gas outlet pipe (3), it is described
The perforation of exhaust gas outlet pipe (3) bottom surface is welded with waste gas treatment tank (4), and the perforation of waste gas treatment tank (4) bottom surface is connected with exhaust gas discharge
It manages (5), the perforation of electrolytic cell (1) side is located at below the waste gas treatment tank (4) and is connected with ozone inlet pipe (6), the electrolytic cell
(1) bottom surface perforation is connected with water-supply-pipe (11), and water-supply-pipe (11) one end is located at electrolytic cell (1) lower section and is welded with the first automatically controlled ball
Valve (10), water-supply-pipe (11) other end are connected by self priming pump (28) and water inlet pipe (27) perforation, the water inlet pipe (27)
The other end and the perforation of (25) one upper side of evaporation tank connect, and evaporation tank (25) other side perforation is connected with cooling tube (23),
And cooling tube (23) other end and collecting box (20) perforation connect, cooling tube (23) outer surface is welded with cooler (22),
Tank for coolant (16) are placed with below the cooler (22).
2. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water according to claim 1, feature
It is, waste gas treatment tank (4) the inner upper side is welded with alkali soluble liquid case (30), and is located at below alkali soluble liquid case (30) useless
It is connected with active carbon layer (31) inside gas disposal case (4), exhaust gas outlet pipe (3) bottom surface is through top surface on waste gas treatment tank (4)
It is internal positioned at alkali soluble liquid case (30).
3. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water according to claim 1, feature
It is, evaporation tank (25) top surface is welded with servo motor (24), and servo motor (24) bottom surface is pushed up through evaporation tank (25)
Face is welded with agitating paddle (14), and evaporation tank (25) inner wall is welded with heating tube (26), evaporation tank (25) underrun
Second electric-controlled ball valve (13) perforation is connected with waste liquid collecting box (12).
4. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water according to claim 3, feature
It is, tank for coolant (16) the top surface side perforation is connected with cooling efferent duct (15), and cooling efferent duct (15) other end
It penetrates through and connects with cooler (22), tank for coolant (16) the side perforation is connected with cooling input pipe (17), and cooling input
Pipe (17) other end perforation is connected with water circulating pump (18), and water circulating pump (18) other end passes through connecting tube and cooler
(22) perforation connection.
5. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water according to claim 1, feature
It is, described ozone inlet pipe (6) one end, which is located at electrolytic cell (1) interior welds, to be had backstop (7), and backstop (7) is internally located at
Ozone inlet pipe (6) one end top surface is welded with fixed link (34), and fixed link (34) interior side is welded with shaft (36), and is turned
Axis (36) side is welded with connecting rod (33), is elasticly connected with spring (35) between the connecting rod (33) and fixed link (34), described
Connecting rod (33) one end has been bolted gasket (32), and gasket (32) diameter is greater than ozone inlet pipe (6) diameter, institute
It states collecting box (20) top surface to be welded with photovoltaic battery plate (21), is placed with battery (19) below the collecting box (20).
6. a kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water according to claim 4, feature
It is, self priming pump (28) the model 40WFB-A2 type No leakage self-controlling self-priming pump, servo motor (24) model
MDME302GCGM type servo motor, the first electric-controlled ball valve (10) model ZRJQ motorized adjustment ball valve, described second is automatically controlled
Ball valve (13) is Q947 fixing type electric ball valve, water circulating pump (18) the model PMD-0411SC acid and alkali-resistance magnetic force discharging
Pump.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821458133.3U CN209507868U (en) | 2018-09-06 | 2018-09-06 | A kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821458133.3U CN209507868U (en) | 2018-09-06 | 2018-09-06 | A kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water |
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| Publication Number | Publication Date |
|---|---|
| CN209507868U true CN209507868U (en) | 2019-10-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201821458133.3U Expired - Fee Related CN209507868U (en) | 2018-09-06 | 2018-09-06 | A kind of advanced processes equipment of energy-saving high concentration hard-degraded organic waste water |
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| CN (1) | CN209507868U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111646625A (en) * | 2020-06-19 | 2020-09-11 | 见嘉环境科技（苏州）有限公司 | Water treatment device adopting multistage electrocatalysis evaporation and application method |
| CN114031143A (en) * | 2021-11-23 | 2022-02-11 | 河南科技大学 | Unattended industrial waste liquid treatment and water-hydrogen-electricity cogeneration system and method |
| CN114380448A (en) * | 2022-01-26 | 2022-04-22 | 海宁天纵电子科技有限公司 | Micro-incineration-method-based harmless treatment method for residual liquor of narcotic drugs |
-
2018
- 2018-09-06 CN CN201821458133.3U patent/CN209507868U/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111646625A (en) * | 2020-06-19 | 2020-09-11 | 见嘉环境科技（苏州）有限公司 | Water treatment device adopting multistage electrocatalysis evaporation and application method |
| CN114031143A (en) * | 2021-11-23 | 2022-02-11 | 河南科技大学 | Unattended industrial waste liquid treatment and water-hydrogen-electricity cogeneration system and method |
| CN114380448A (en) * | 2022-01-26 | 2022-04-22 | 海宁天纵电子科技有限公司 | Micro-incineration-method-based harmless treatment method for residual liquor of narcotic drugs |
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