CN209493410U - Remove the device of whole hardness in reverse osmosis concentrated water - Google Patents

Remove the device of whole hardness in reverse osmosis concentrated water Download PDF

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Publication number
CN209493410U
CN209493410U CN201822107893.6U CN201822107893U CN209493410U CN 209493410 U CN209493410 U CN 209493410U CN 201822107893 U CN201822107893 U CN 201822107893U CN 209493410 U CN209493410 U CN 209493410U
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import
hardness
thickener
tank
crystallizer
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CN201822107893.6U
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黎泽华
张巧云
张和兴
韩慧铭
刘渊
苏英强
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Jinke Environmental Ltd By Share Ltd
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Jinke Environmental Ltd By Share Ltd
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Abstract

The utility model relates to a kind of devices of whole hardness in removal reverse osmosis concentrated water, including permanent hardness eliminates unit, temporary hardness eliminates unit and residual hardness eliminates unit;It includes crystallizer, thickener and centrifugal dehydrator that permanent hardness, which eliminates unit, the import of crystallizer is connect with strong brine intake line, the import of crystallizer is also connect with the dosing tank for flocculant and crystal seed to be added, the magma outlet of crystallizer is connect with the import of thickener, and the import of the discharge port and centrifugal dehydrator of thickener connects;It includes sequentially connected quick lime reaction tank, coagulative precipitation tank, flocculation sedimentation tank and sedimentation basin that temporary hardness, which eliminates unit, the water out of crystallizer, the water out of thickener, centrifugal dehydrator water out connect with the import of quick lime reaction tank;It includes chelating resin filter that residual hardness, which eliminates unit, and the water out of sedimentation basin is connect with the import of chelating resin filter, and the outlet of chelating resin filter connects discharge pipe line.

Description

Remove the device of whole hardness in reverse osmosis concentrated water
Technical field
The utility model belongs to technical field of sewage, and in particular to a kind of to remove whole hardness in reverse osmosis concentrated water Device.
Background technique
Reverse osmosis membrane because its treatment effeciency height, effluent quality is good, simple operation and other advantages and be widely used in regeneration effluent In zero-emission engineering.However reverse osmosis producing water ratio can only achieve 75% or so, the processing of reverse osmosis concentrated water be technically and Problem economically.If concentrated water is directly discharged in environment, highly concentrated salt water will cause ecological environment serious It influences, and causes the waste of water resource.The processing method of reverse osmosis concentrated water mainly includes surface water discharge, deep-well note at present It penetrates, spray, thermal evaporation etc..But above method fails to well utilize reverse osmosis concentrated water, does not reduce concentrate fundamentally Discharge, also create the waste of water resource.
Particularly, for sulfate concentration in water, the processing of calcium ion concentration and the very high strong brine of Na ion concentration, Presently, there are the problem of there are three aspect: first is that highly concentrated strong brine is because contain antisludging agent, so that the difficulty of Crystallization Separation Degree increases;Second is that the strong brine high for sulphates content, general processing method is to be converted to permanent hardness (calcium sulfate) For temporary hardness (calcium carbonate), but the higher cost for the sodium carbonate being newly introduced;Third is that being adsorbed because Na ion concentration is high The limitation of equation, residual hardness cannot be replaced with Na-ion exchanger.
Utility model content
The purpose of this utility model is at least to solve one of above-mentioned problems of the prior art, the purpose be by with What lower technical solution was realized:
The utility model proposes a kind of devices of whole hardness in removal reverse osmosis concentrated water, including permanent hardness to eliminate list Member, temporary hardness eliminate unit and residual hardness eliminates unit;The permanent hardness eliminate unit include crystallizer, thickener and The import of centrifugal dehydrator, the crystallizer is connect with strong brine intake line, and the import of the crystallizer is also and for being added Flocculant is connected with the dosing tank of crystal seed, and the magma outlet of the crystallizer is connect with the import of the thickener, the stiff The discharge port of device is connect with the import of the centrifugal dehydrator;It includes sequentially connected quick lime that the temporary hardness, which eliminates unit, Reaction tank, coagulative precipitation tank, flocculation sedimentation tank and sedimentation basin, the water out of the crystallizer, the water out of the thickener, institute The water out for stating centrifugal dehydrator is connect with the import of the quick lime reaction tank;It includes chela that the residual hardness, which eliminates unit, Resin filter, the water out of the sedimentation basin are connect with the import of the chelating resin filter, the chelating resin mistake The outlet of filter connects discharge pipe line.
It further includes the second thickener and the second centrifugal dehydrator that the temporary hardness, which eliminates unit, second thickener Import is connect with the outlet of the sedimentation basin, and the discharge port of second thickener is connect with the import of the second centrifugal dehydrator, Import of the water out with the chelating resin filter of the water out of second thickener, second centrifugal dehydrator Connection.
The chelating resin filter is also connect with regenerated acid dosing tank.
The chelating resin filter is exported equipped with backwash waste, and the backwash waste outlet is reacted with the quick lime The import in pond connects.
The sedimentation basin is inclined-plate clarifying basin, and quick lime dosing tank is equipped on the quick lime reaction tank, described mixed Solidifying sedimentation basin is equipped with coagulant dosing tank, and flocculant dosing tank is equipped on the flocculation sedimentation tank.
The crystallizer includes crystallizing tank, guide shell, blender and capping, and the crystallizing tank is arranged in the guide shell Inside, the blender are arranged in the guide shell, and the blender is propeller agitator, and the import of the crystallizer is set It sets in the middle and lower part of the crystallizing tank, is exported in the bottom of the crystallizing tank equipped with the magma, the top of the crystallizing tank is set There is settling section, forms ring cavity, the water out setting of the crystallizer between the top of the crystallizing tank and the outer wall of the capping In the bottom of the ring cavity.
The top of the crystallizing tank is equipped with outward in the expansion segment of 30 ° of angles expansion, is equipped at the top of the expansion segment perpendicular The region that the overflow baffle directly arranged, the expansion segment and overflow baffle are formed is the settling section, the overflow baffle and institute It states and forms the ring cavity between the outer wall of capping.
The device of whole hardness in a kind of removal reverse osmosis concentrated water, including permanent hardness eliminates unit, temporary hardness is eliminated Unit and residual hardness eliminate unit;It includes crystallizer, thickener and centrifugal dehydrator that the permanent hardness, which eliminates unit, described The import of crystallizer is connect with strong brine intake line, the import of the crystallizer also with for be added flocculant and crystal seed plus Medicine-chest connection, the crystallizer magma outlet is connect with the import of the thickener, the discharge port of the thickener with it is described The import of centrifugal dehydrator connects;It includes sequentially connected quick lime reaction tank, coagulating sedimentation that the temporary hardness, which eliminates unit, Pond, flocculation sedimentation tank and sedimentation basin, the water out of the crystallizer, the water out of the thickener, the centrifugal dehydrator Water out is connect with the import of the quick lime reaction tank;It includes more medium filter and chela that the residual hardness, which eliminates unit, Resin filter, the water out of the sedimentation basin are connect with the import of the more medium filter, the more medium filter Outlet connect with the import of the chelating resin filter, the outlet of the chelating resin filter connects discharge pipe line.
It further includes the second thickener and the second centrifugal dehydrator that the temporary hardness, which eliminates unit, second thickener Import is connect with the outlet of the sedimentation basin, and the discharge port of second thickener is connect with the import of the second centrifugal dehydrator, The water out of second thickener, second centrifugal dehydrator water out with the import of the more medium filter connect It connects.
The chelating resin filter is also connect with regenerated acid dosing tank, the chelating resin filter and multi-medium filtering Backwash waste outlet is equipped on device, the backwash waste of the chelating resin filter exports anti-with the more medium filter Wastewater outlet is washed to connect with the import of the quick lime reaction tank.
Utility model has the advantages that
The processing unit that the utility model is proposed can either eliminate the permanent hardness in strong brine, can also eliminate temporarily Hardness, additionally it is possible to eliminate residual hardness, the concentration of the calcium and magnesium cation in salt water goes to zero after treatment, is conducive to salt water Next step concentration and zero discharge treatment.In addition, the utility model treatment process need not quote other displacer reagents, medicine is saved Agent cost, but also good calcium sulphate crystal has been recycled, farthest save resource.
Detailed description of the invention
By reading the following detailed description of the preferred embodiment, various other advantages and benefits are common for this field Technical staff will become clear.The drawings are only for the purpose of illustrating a preferred embodiment, and is not considered as practical to this Novel limitation.And throughout the drawings, the same reference numbers will be used to refer to the same parts.In the accompanying drawings:
Fig. 1 is the structural schematic diagram of the utility model embodiment one;
Fig. 2 is the structural schematic diagram of the utility model embodiment two.
Specific embodiment
The illustrative embodiments of the disclosure are more fully described below with reference to accompanying drawings.Although showing this public affairs in attached drawing The illustrative embodiments opened, it being understood, however, that may be realized in various forms the disclosure without the reality that should be illustrated here The mode of applying is limited.It is to be able to thoroughly understand the disclosure on the contrary, providing these embodiments, and can be by this public affairs The range opened is fully disclosed to those skilled in the art.
It should be understood that term used herein merely for description particular example embodiment purpose, and have no intention into Row limitation.Unless the context clearly indicates otherwise, otherwise singular " one " as used in the text, "one" and " described " Can also indicate to include plural form.The terms "include", "comprise", " containing " and " having " are inclusives, and therefore It indicates the presence of stated feature, step, operations, elements, and/or components, but presence or addition one or more is not precluded A other feature, step, operation, component, assembly unit, and/or their combination.
Although can be described in the text using term first, second, third, etc. multiple element, component, region, layer and/ Or section, still, these component, assembly units, region, layer and/or section should not be limited by these terms.These terms can be only For a component, assembly unit, region, layer or section are distinguished with another region, layer or section.Unless context clearly refers to Out, do not implied that when otherwise the term and other numerical terms of such as " first ", " second " etc use in the text sequence or Person's order.Therefore, first element discussed below, component, region, layer or section are in the introduction for not departing from example embodiment In the case of can be referred to as second element, component, region, layer or section.
For ease of description, an element as illustrated in the diagram can be described use space relativeness term in the text Either feature is relative to another element or the relationship of feature, these relativeness terms are, for example, " inside ", " outside ", " interior Side ", " outside ", " following ", " lower section ", " above ", " top " etc..This spatial correlation term is intended to include removing to retouch in figure The different direction of device in use or operation except the orientation drawn.For example, being retouched if the device in figure is overturn State for " below other elements or feature " either the element " below other elements or feature " will then be orientated " Above other elements or feature " either " above other elements or feature ".Therefore, exemplary term " in ... lower section " can To include in orientation upper and under.In addition device can be oriented and (be rotated by 90 ° or in other directions) and used herein Spatial correlation descriptor correspondingly explains.
Embodiment one:
As shown in Figure 1, the utility model proposes a kind of device of whole hardness in removal reverse osmosis concentrated water, including it is permanent Hardness eliminates unit 1, temporary hardness eliminates unit 2 and residual hardness eliminates unit 3.It includes crystallization that permanent hardness, which eliminates unit 1, The import of device 101, thickener 102 and centrifugal dehydrator 103, crystallizer 101 is connect with strong brine intake line, crystallizer 101 Import also connect with the dosing tank 104 for flocculant and crystal seed to be added, the outlet of the magma of crystallizer 101 and thickener 102 Import connection, the discharge port of thickener 102 connect with the import of centrifugal dehydrator 103.It includes suitable that temporary hardness, which eliminates unit 2, Quick lime reaction tank 201, coagulative precipitation tank 202, flocculation sedimentation tank 203 and the sedimentation basin 204 of secondary connection, the water of crystallizer 101 Outlet, the water out of thickener 102, centrifugal dehydrator 103 water out connect with the import of quick lime reaction tank 201.It is surplus It includes chelating resin filter 301 that remaining hardness, which eliminates unit 3, is set in chelating resin filter 301 filled with alpha-amino phosphonate chelating Rouge.The water out of sedimentation basin 204 is connect with the import of chelating resin filter 301, the outlet connection of chelating resin filter 301 Discharge pipe line 302.
Process using whole hardness of utility model device removal reverse osmosis water is as follows:
1) reverse osmosis concentrated water is introduced into crystallizer 101 by strong brine intake line, meanwhile, it is connected by dosing tank 104 Into crystallizer 101, investment can eliminate the flocculant of the peptizaiton of antisludging agent and the calcium sulfate of crystal growth can be promoted brilliant Kind.Concentrated water crystallizes in crystallizer 101, after the magma that crystallization process obtains enters the progress concentration of thickener 102, then conveys It is carried out dehydrating to centrifugal dehydrator 103, the calcium sulfate of low-water-content is obtained after dehydration;The water that crystallization process is isolated is to disappear Except the salt water of permanent hardness, the water that the salt water and thickener 102 and centrifugal dehydrator 103 are isolated is delivered to temporarily hard Degree eliminates unit 2.
2) be delivered to temporary hardness eliminate unit 2 salt water in quick lime reaction tank 201 with Ca (OH)2React life At calcium carbonate, under conditions of pH value is 11, magnesium ion is also precipitated out in the form of magnesium carbonate.Later, salt water again successively in Coagulant is added in coagulative precipitation tank 202, and flocculant is added in flocculation sedimentation tank 203, is finally precipitated in sedimentation basin, from And realize and be separated by solid-liquid separation, liquid obtained after separation is the salt water for eliminating temporary hardness.
3) water for eliminating permanent hardness and temporary hardness is delivered to chelating resin filter 301, can remove in water Contained a small amount of calcium and magnesium cation, makes the concentration of calcium and magnesium cation in salt water go to zero, and the residue so far eliminated in salt water is hard Degree.
Further, it further includes the second thickener 205 and the second centrifugal dehydrator 206 that temporary hardness, which eliminates unit 2, and second The import of thickener 205 is connect with the outlet of sedimentation basin 204, the discharge port of the second thickener 205 and the second centrifugal dehydrator 206 Import connection, the water out of the second thickener 205, the second centrifugal dehydrator 206 water out with chelating resin filter 301 import connection.
Further, chelating resin filter 301 is also connect with regenerated acid dosing tank 303, regenerates chelating tree by pickling Rouge.In addition, chelating resin filter 301 is exported equipped with backwash waste, backwash waste outlet and quick lime reaction tank 201 into Mouth connection, pickling waste waters are neutralized by quick lime, do not generate any waste water.
Further, sedimentation basin 204 is inclined-plate clarifying basin, and quick lime dosing tank is equipped on quick lime reaction tank 201 207, it is equipped with coagulant dosing tank 208 on coagulative precipitation tank 202, flocculant dosing tank is equipped on flocculation sedimentation tank 203 209。
Further, crystallizer 101 includes crystallizing tank 111, guide shell 112, blender 113 and capping 114, guide shell 112 are arranged in the inside of crystallizing tank 111, and blender 113 is arranged in guide shell 112, and blender 113 is propeller agitator, The middle and lower part of crystallizing tank 111 is arranged in the import of crystallizer 101, exports in the bottom of crystallizing tank 111 equipped with magma, crystallizing tank 111 top is equipped with settling section 116, and ring cavity 117, crystallizer are formed between the top of crystallizing tank 111 and the outer wall for covering 114 The bottom of ring cavity 117 is arranged in 101 water out 118.Crystallizer 101 at work, under the promotion of blender 113, water flow It can decline along the inner wall of guide shell 112 and rise along the outer wall of guide shell 112, to form circulation, be stirred by adjusting The revolving speed of device 113 is mixed, the rate of water flow rising and decline can be made into 9 times of 101 strong brine flow velocity of crystallizer, i.e. crystalline substance liquid Reflux ratio is 800%.
Further, the top of crystallizing tank 111 is equipped with outward in the expansion segment of 30 ° of angles expansion, is set at the top of expansion segment There is the overflow baffle 119 arranged vertically, the region that expansion segment and overflow baffle 119 are formed is settling section 116, overflow baffle 119 Ring cavity 117 is formed between the outer wall of capping 114.The salt water of the removal permanent hardness obtained by crystallization is via overflow baffle 119 spill into water out 118, eliminate unit 2 hence into temporary hardness.
Embodiment two:
The present embodiment the difference is that only with embodiment one: it further includes more medium filter that residual hardness, which eliminates unit 3, 304, the water out of sedimentation basin 204 is connect with the import of more medium filter 304, the outlet of more medium filter 304 and chelating The import of resin filter 301 connects, and the outlet of chelating resin filter 301 connects discharge pipe line.The setting of rest part is equal It is identical as previous embodiment.More medium filter 304 can remove trace suspension object in water removal, to avoid the pollution to resin.
In addition, the backwash waste of more medium filter 304 and the acid-bearing wastewater of chelating resin filter 301 can pass through Waste water water pipe is introduced into quick lime reaction tank 201, utilizes backwash waste again.
The preferable specific embodiment of the above, only the utility model, but the protection scope of the utility model is not It is confined to this, anyone skilled in the art within the technical scope disclosed by the utility model, can readily occur in Change or replacement, should be covered within the scope of the utility model.Therefore, the protection scope of the utility model should be with Subject to the scope of protection of the claims.

Claims (10)

1. the device of whole hardness in a kind of removal reverse osmosis concentrated water, which is characterized in that including permanent hardness elimination unit, temporarily Hardness eliminates unit and residual hardness eliminates unit;
It includes crystallizer, thickener and centrifugal dehydrator that the permanent hardness, which eliminates unit, the import of the crystallizer and dense salt Water input conduit connection, the import of the crystallizer are also connect with the dosing tank for flocculant and crystal seed to be added, the crystallization The magma outlet of device is connect with the import of the thickener, and the import of the discharge port of the thickener and the centrifugal dehydrator connects It connects;
The temporary hardness eliminates unit and includes sequentially connected quick lime reaction tank, coagulative precipitation tank, flocculation sedimentation tank and sink Shallow lake pond, the water out of the crystallizer, the water out of the thickener, the centrifugal dehydrator water out with the raw stone The import of grey reaction tank connects;
It includes chelating resin filter, the water out of the sedimentation basin and the chelating resin mistake that the residual hardness, which eliminates unit, The import of filter connects, and the outlet of the chelating resin filter connects discharge pipe line.
2. removing the device of whole hardness in reverse osmosis concentrated water as described in claim 1, which is characterized in that the temporary hardness Eliminating unit further includes the second thickener and the second centrifugal dehydrator, the import of second thickener and going out for the sedimentation basin Mouth connection, the discharge port of second thickener are connect with the import of the second centrifugal dehydrator, and the water of second thickener goes out Mouthful, the water out of second centrifugal dehydrator connect with the import of the chelating resin filter.
3. removing the device of whole hardness in reverse osmosis concentrated water as described in claim 1, which is characterized in that the chelating resin Filter is also connect with regenerated acid dosing tank.
4. removing the device of whole hardness in reverse osmosis concentrated water as claimed in claim 3, which is characterized in that the chelating resin Filter is exported equipped with backwash waste, and the backwash waste outlet is connect with the import of the quick lime reaction tank.
5. such as the device of whole hardness in the described in any item removal reverse osmosis concentrated waters of Claims 1-4, which is characterized in that institute Stating sedimentation basin is inclined-plate clarifying basin, quick lime dosing tank is equipped on the quick lime reaction tank, on the coagulative precipitation tank Equipped with coagulant dosing tank, flocculant dosing tank is equipped on the flocculation sedimentation tank.
6. such as the device of whole hardness in the described in any item removal reverse osmosis concentrated waters of Claims 1-4, which is characterized in that institute Stating crystallizer includes crystallizing tank, guide shell, blender and capping, and the inside of the crystallizing tank is arranged in the guide shell, described Blender is arranged in the guide shell, and the blender is propeller agitator, and the import of the crystallizer is arranged described The middle and lower part of crystallizing tank is exported in the bottom of the crystallizing tank equipped with the magma, and the top of the crystallizing tank is equipped with settling section, Ring cavity is formed between the top of the crystallizing tank and the outer wall of the capping, the water out of the crystallizer is arranged in the ring cavity Bottom.
7. removing the device of whole hardness in reverse osmosis concentrated water as claimed in claim 6, which is characterized in that the crystallizing tank Top is equipped with outward in the expansion segment of 30 ° of angles expansion, and the overflow baffle arranged vertically is equipped at the top of the expansion segment, described The region that expansion segment and overflow baffle are formed is the settling section, and institute is formed between the overflow baffle and the outer wall of the capping State ring cavity.
8. the device of whole hardness in a kind of removal reverse osmosis concentrated water, which is characterized in that including permanent hardness elimination unit, temporarily Hardness eliminates unit and residual hardness eliminates unit;
It includes crystallizer, thickener and centrifugal dehydrator that the permanent hardness, which eliminates unit, the import of the crystallizer and dense salt Water input conduit connection, the import of the crystallizer are also connect with the dosing tank for flocculant and crystal seed to be added, the crystallization The magma outlet of device is connect with the import of the thickener, and the import of the discharge port of the thickener and the centrifugal dehydrator connects It connects;
The temporary hardness eliminates unit and includes sequentially connected quick lime reaction tank, coagulative precipitation tank, flocculation sedimentation tank and sink Shallow lake pond, the water out of the crystallizer, the water out of the thickener, the centrifugal dehydrator water out with the raw stone The import of grey reaction tank connects;
It includes more medium filter and chelating resin filter that the residual hardness, which eliminates unit, the water out of the sedimentation basin with The import of the more medium filter connects, and the outlet of the more medium filter connects with the import of the chelating resin filter It connects, the outlet of the chelating resin filter connects discharge pipe line.
9. removing the device of whole hardness in reverse osmosis concentrated water as claimed in claim 8, which is characterized in that the temporary hardness Eliminating unit further includes the second thickener and the second centrifugal dehydrator, the import of second thickener and going out for the sedimentation basin Mouth connection, the discharge port of second thickener are connect with the import of the second centrifugal dehydrator, and the water of second thickener goes out Mouthful, the water out of second centrifugal dehydrator connect with the import of the more medium filter.
10. removing the device of whole hardness in reverse osmosis concentrated water as claimed in claim 8 or 9, which is characterized in that the chelating Resin filter is also connect with regenerated acid dosing tank, and it is useless that backwash is equipped on the chelating resin filter and more medium filter Water out, the backwash waste outlet of the chelating resin filter and the backwash waste of the more medium filter export and institute State the import connection of quick lime reaction tank.
CN201822107893.6U 2018-12-16 2018-12-16 Remove the device of whole hardness in reverse osmosis concentrated water Active CN209493410U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574307A (en) * 2018-12-16 2019-04-05 金科环境股份有限公司 Remove the device of whole hardness in reverse osmosis concentrated water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109574307A (en) * 2018-12-16 2019-04-05 金科环境股份有限公司 Remove the device of whole hardness in reverse osmosis concentrated water

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