CN209421113U - A kind of bronze-colored watch chain, watchcase and wrist-watch - Google Patents

A kind of bronze-colored watch chain, watchcase and wrist-watch Download PDF

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Publication number
CN209421113U
CN209421113U CN201821956997.8U CN201821956997U CN209421113U CN 209421113 U CN209421113 U CN 209421113U CN 201821956997 U CN201821956997 U CN 201821956997U CN 209421113 U CN209421113 U CN 209421113U
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film
substrate
utility
compound
model
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CN201821956997.8U
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Chinese (zh)
Inventor
温景成
杨志
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Hunan Morning Nano Robot Co Ltd
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Hunan Morning Nano Robot Co Ltd
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Abstract

The utility model provides a kind of bronze-colored watch chain, watchcase and wrist-watch.Bronze-colored watch chain provided by the utility model includes: substrate；It is compound in the Ti film of the substrate surface；The compound TiN film with the Ti film surface；It is compound in the C film on the TiN film surface；It is compound in the transparent paint film of the C film surface.The utility model sets gradually Ti film, TiN film, C film and transparent paint film in watch chain substrate surface, greatly improves the wearability of watch chain, and then improves its service life and guarantee its exterior quality.

Description

A kind of bronze-colored watch chain, watchcase and wrist-watch
Technical field
The utility model relates to wrist-watch accessory technical field, in particular to a kind of bronze-colored watch chain, watchcase and wrist-watch.
Background technique
Wrist-watch, also known as watch are to be worn in wrist to timing or show the instrument of time, including watch chain (or table Band), watchcase, the accessories such as dial plate.During wrist-watch, watch chain and watchcase are the accessories for frequently being contacted or being rubbed, therefore, It is most important that it has good wearability.
Currently, the structure of watch chain or watchcase accessory is usually substrate-ZrCxFilm, due to ZrCxC content is higher in film layer, leads Cause accessory wearability poor, film layer is easy to fall off, and is affected the usability of wrist-watch, and fall film to make accessory irregular colour, is affected Accessory exterior quality.
Utility model content
In view of this, the present invention provides a kind of bronze-colored watch chain, watchcase and wrist-watches.It is provided by the utility model to match Part product is able to ascend its wearability.
The utility model provides a kind of bronze-colored watch chain, comprising:
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
In one embodiment of the utility model, the Ti film with a thickness of 0.3 μm；The TiN film with a thickness of 1.0 μm。
In one embodiment of the utility model, the C film with a thickness of 2.0 μm.
In one embodiment of the utility model, the transparent paint film with a thickness of 2.0 μm.
In one embodiment of the utility model, the substrate is stainless steel substrate, aluminum alloy base material, Copper base material, copper Alloy base material, iron-based material or iron alloy substrates.
The utility model additionally provides a kind of watchcase, comprising:
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
In one embodiment of the utility model, the Ti film with a thickness of 0.3 μm；The TiN film with a thickness of 1.0 μm。
In one embodiment of the utility model, the C film with a thickness of 2.0 μm；The transparent paint film with a thickness of 2.0μm。
In one embodiment of the utility model, the substrate is stainless steel substrate, aluminum alloy base material, Copper base material, copper Alloy base material, iron-based material or iron alloy substrates.
The utility model additionally provides a kind of wrist-watch, including watch chain described in above-mentioned technical proposal and/or above-mentioned technical side Watchcase described in case.
The utility model provides a kind of bronze-colored watch chain, comprising: substrate；It is compound in the Ti film of the substrate surface；It is multiple Close the TiN film with the Ti film surface；It is compound in the C film on the TiN film surface；It is compound in the transparent paint film of the C film surface. The utility model sets gradually Ti film, TiN film, C film and transparent paint film in watch chain substrate surface, greatly improves the wear-resisting of watch chain Property, and then improve its service life and guarantee its exterior quality.
Detailed description of the invention
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is the embodiments of the present invention, for those of ordinary skill in the art, without creative efforts, also Other attached drawings can be obtained according to the attached drawing of offer.
Fig. 1 is the schematic diagram for the watch chain that one embodiment of the utility model provides；
Fig. 2 is the sectional view for the watch chain that one embodiment of the utility model provides.
Specific embodiment
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work Every other embodiment obtained, fall within the protection scope of the utility model.
The utility model provides a kind of bronze-colored watch chain, comprising:
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
Referring to Fig. 1, Fig. 1 is the schematic diagram for the watch chain that one embodiment of the utility model provides, it can be seen that watch chain table Face is bright and clean, appearance is that high-quality is bronze-colored.Referring to fig. 2, the section for the watch chain that Fig. 2 provides for one embodiment of the utility model Figure, wherein 1 is substrate, and 2 be Ti film, and 3 be TiN film, and 4 be C film, and 5 be transparent paint film.
Substrate 1 is preferably metal base.In some embodiments of the utility model, the substrate be stainless steel substrate, Aluminum alloy base material, Copper base material, copper alloy substrate, iron-based material or iron alloy substrates.The utility model is to the shape of the substrate, knot Structure etc. is not particularly limited, and is type of substrate well known to those skilled in the art.
1 surface recombination Ti film 2 of substrate.In some embodiments of the utility model, the Ti film with a thickness of 0.3 μm.
2 surface recombination TiN film 3 of Ti film.In some embodiments of the utility model, the TiN film with a thickness of 1.0 μ m。
3 surface recombination C film 4 of TiN film.In some embodiments of the utility model, the C film with a thickness of 2.0 μm.
C film surface composite transparent paint film 5.The utility model is not particularly limited the paint vehicle of the transparent paint film, for this Convention transparent paint vehicle known to the technical staff of field.In some embodiments of the utility model, the transparent paint film With a thickness of 2.0 μm.
Test result shows that watch chain provided by the utility model has passed through 48 hours artificial perspirations and tested (reference standard QB/ T4775-2014), perspiration resistance corrodes；After (reference standard GB/T33725-2017) is tested in friction, does not occur film layer and fall off, outside Sight is not affected by destruction, still keeps bright and clean uniform ancient silver color；(reference standard QB/T4775-2014) is tested through resistance to oxidation, it is resistance to Up to 80 DEG C, 8 hours non-discolouring not to peel off oxidizing temperature, has excellent oxidative resistance.
In the utility model, the watch chain can be made in the following manner:
Ti film, TiN film, C film and the transparent paint film of coating are successively plated in substrate surface, obtains watch chain.
Wherein, when plating Ti film, it is preferred to use vacuum magnetron sputtering coating film technique can be such that film layer has and preferably combine Power.Actual conditions are as follows: using watch chain substrate as substrate, with titanium (Ti) for target, coating chamber Ar throughput is 200~220Sccm, Vacuum degree is 0.1~0.5Pa, and coating temperature is 20~150 DEG C.
When plating TiN film, it is preferred to use vacuum magnetron sputtering coating film technique.Actual conditions are as follows: to plate the substrate after Ti film For substrate, with titanium (Ti) for target, coating chamber Ar throughput is 200~220Sccm, N2Flow is 200~220Sccm, vacuum Degree is 0.1~0.5Pa, and total gas pressure is 0.3~0.5Pa, and coating temperature is 20~150 DEG C.
When plating C film, it is preferred to use vacuum magnetron sputtering coating film technique.Actual conditions are as follows: being with the substrate after plating TiN film Substrate, with carbon (C) for target, coating chamber Ar throughput is 200~220Sccm, and vacuum degree is 0.1~0.5Pa, and coating temperature is 20~150 DEG C.
After plating C film, polishing and cleaning treatment are preferably also carried out.The utility model does not have the polishing and cleaning treatment It is specifically limited, it is operated according to processing means well known to those skilled in the art.
After cleaning treatment of polishing, transparent paint film is coated.The utility model is not particularly limited coating method, for example brushes The conventional coating operation such as painting or spraying.It after coating, is preferably also dried, and then obtains bronze-colored watch chain product.
In the utility model, when plating Ti film, TiN film and C film, it is preferred to use continuous magnetron sputtering, it can be by means of multicell Continuous coating device carries out, and by continuous magnetron sputtering, it is bronze-colored multiple disposably to obtain that compactness is good, surface smoothness is high Film layer is closed, and continuous production is more advantageous to makes being consistent property of quality of colour.
The utility model additionally provides a kind of watchcase, comprising:
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
The utility model sets gradually Ti film, TiN film, C film and transparent paint film in watchcase substrate surface, greatly improves table The wearability of chain, and then improve its service life and guarantee its exterior quality.
The substrate is preferably metal base.In some embodiments of the utility model, the substrate is stainless base steel Material, aluminum alloy base material, Copper base material, copper alloy substrate, iron-based material or iron alloy substrates.Shape of the utility model to the substrate Shape, structure etc. are not particularly limited, and are type of substrate well known to those skilled in the art.
The substrate surface composite Ti film.In some embodiments of the utility model, the Ti film with a thickness of 0.3 μ m。
The compound TiN film of Ti film surface.In some embodiments of the utility model, the TiN film with a thickness of 1.0 μm。
The TiN film surface recombination C film.In some embodiments of the utility model, the C film with a thickness of 2.0 μm.
The C film surface composite transparent paint film.The utility model is not particularly limited the paint vehicle of the transparent paint film, is Convention transparent paint vehicle well known to those skilled in the art.In some embodiments of the utility model, the transparent paint film With a thickness of 2.0 μm.
Test result shows that watchcase provided by the utility model has passed through 48 hours artificial perspirations and tested (reference standard QB/ T4775-2014), perspiration resistance corrodes；After (reference standard GB/T33725-2017) is tested in friction, does not occur film layer and fall off, outside Sight is not affected by destruction, still keeps bright and clean uniform ancient silver color；(reference standard QB/T4775-2014) is tested through resistance to oxidation, it is resistance to Oxidizing temperature has excellent oxidative resistance up to 80 DEG C.
In the utility model, the watchcase can be made in the following manner:
Ti film, TiN film, C film and the transparent paint film of coating are successively plated in substrate surface, obtains watchcase.
Wherein, when plating Ti film, it is preferred to use vacuum magnetron sputtering coating film technique can be such that film layer has and preferably combine Power.Actual conditions are as follows: using watchcase substrate as substrate, with titanium (Ti) for target, coating chamber Ar throughput is 200~220Sccm, Vacuum degree is 0.1~0.5Pa, and coating temperature is 20~150 DEG C.
When plating TiN film, it is preferred to use vacuum magnetron sputtering coating film technique.Actual conditions are as follows: to plate the substrate after Ti film For substrate, with titanium (Ti) target, coating chamber Ar throughput is 200~220Sccm, N2Flow is 200~220Sccm, vacuum degree For 0.1~0.5Pa, total gas pressure is 0.3~0.5Pa, and coating temperature is 20~150 DEG C.
When plating C film, it is preferred to use vacuum magnetron sputtering coating film technique.Actual conditions are as follows: being with the substrate after plating TiN film Substrate, with carbon (C) target, coating chamber Ar throughput is 200~220Sccm, and vacuum degree is 0.1~0.5Pa, coating temperature 20 ~150 DEG C.
After plating C film, polishing and cleaning treatment are preferably also carried out.The utility model does not have the polishing and cleaning treatment It is specifically limited, it is operated according to processing means well known to those skilled in the art.
After cleaning treatment of polishing, transparent paint film is coated.The utility model is not particularly limited coating method, for example brushes The conventional coating operation such as painting or spraying.It after coating, is preferably also dried, and then obtains bronze-colored watchcase product.
In the utility model, when plating Ti film, TiN film and C film, it is preferred to use continuous magnetron sputtering, it can be by means of multicell Continuous coating device carries out, and by continuous magnetron sputtering, it is bronze-colored multiple disposably to obtain that compactness is good, surface smoothness is high Film layer is closed, and continuous production is more advantageous to makes being consistent property of quality of colour.
The utility model additionally provides a kind of wrist-watch, including watch chain as described in the above technical scheme and/or above-mentioned technology Watchcase described in scheme.
The above is only the preferred embodiment of the utility model, it is noted that for the common skill of the art For art personnel, without departing from the principle of this utility model, several improvements and modifications can also be made, these improve and Retouching also should be regarded as the protection scope of the utility model.

Claims (10)

1. a kind of bronze-colored watch chain characterized by comprising
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
2. watch chain according to claim 1, which is characterized in that the Ti film with a thickness of 0.3 μm；The thickness of the TiN film Degree is 1.0 μm.
3. watch chain according to claim 1, which is characterized in that the C film with a thickness of 2.0 μm.
4. watch chain according to claim 1, which is characterized in that the transparent paint film with a thickness of 2.0 μm.
5. watch chain according to claim 1, which is characterized in that the substrate is stainless steel substrate, aluminum alloy base material, copper-based Material, copper alloy substrate, iron-based material or iron alloy substrates.
6. a kind of watchcase characterized by comprising
Substrate；
It is compound in the Ti film of the substrate surface；
It is compound in the TiN film of the Ti film surface；
It is compound in the C film on the TiN film surface；
It is compound in the transparent paint film of the C film surface.
7. watchcase according to claim 6, which is characterized in that the Ti film with a thickness of 0.3 μm；The thickness of the TiN film Degree is 1.0 μm.
8. watchcase according to claim 6, which is characterized in that the C film with a thickness of 2.0 μm；The transparent paint film With a thickness of 2.0 μm.
9. watchcase according to claim 6, which is characterized in that the substrate is stainless steel substrate, aluminum alloy base material, copper-based Material, copper alloy substrate, iron-based material or iron alloy substrates.
10. a kind of wrist-watch, which is characterized in that including watch chain according to any one of claims 1 to 5 and/or claim 6~ Watchcase described in any one of 9.
CN201821956997.8U 2018-11-26 2018-11-26 A kind of bronze-colored watch chain, watchcase and wrist-watch Active CN209421113U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821956997.8U CN209421113U (en) 2018-11-26 2018-11-26 A kind of bronze-colored watch chain, watchcase and wrist-watch

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821956997.8U CN209421113U (en) 2018-11-26 2018-11-26 A kind of bronze-colored watch chain, watchcase and wrist-watch

Publications (1)

Publication Number Publication Date
CN209421113U true CN209421113U (en) 2019-09-24

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201821956997.8U Active CN209421113U (en) 2018-11-26 2018-11-26 A kind of bronze-colored watch chain, watchcase and wrist-watch

Country Status (1)

Country Link
CN (1) CN209421113U (en)

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