CN209412110U - A kind of device improving fluidized bed production vinyl acetate yield and quality - Google Patents
A kind of device improving fluidized bed production vinyl acetate yield and quality Download PDFInfo
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- CN209412110U CN209412110U CN201822179962.4U CN201822179962U CN209412110U CN 209412110 U CN209412110 U CN 209412110U CN 201822179962 U CN201822179962 U CN 201822179962U CN 209412110 U CN209412110 U CN 209412110U
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Abstract
The utility model discloses a kind of devices of raising fluidized bed production vinyl acetate yield and quality, including acetic acid tank (1), 1# pumps (2), acetic acid cooler (3), reaction solution cooler (4), 1# regulating valve (5), 2# pumps (6), reaction solution buffer tank (7), 2# regulating valve (8), liquid drop separator (9), three-stage gas knockout tower (10) and fluidized-bed reactor (13), it is characterized in that: by improving process and increasing apparatus, mixed gas in Dichlorodiphenyl Acetate ethylene synthase process is separated, including recovery of acetic acid ethylene product, wash the miscellaneous gas acetaldehyde of light component in mixed reaction gas, peace and quiet acetylene gas.The device of the utility model, pass through the separation of reaction gas in Dichlorodiphenyl Acetate ethylene production, major product vinyl acetate not only can be effectively recycled, while greatly reducing light-component gas side reaction generation during fluidized bed production vinyl acetate, effectively improves vinyl acetate quality.
Description
Technical field
The utility model relates to a kind of devices of raising fluidized bed production vinyl acetate yield and quality.
Background technique
Vinyl acetate is a kind of important Organic Ingredients, even more important one of 50 kinds of Organic Chemicals in the world,
In practice, vinyl acetate by self-polymerization or with other monomer polymerizations, polyvinyl acetate, polyethylene mainly can be generated
Alcohol, vinyl acetate-ethylene copolymerization emulsions, vinyl acetate-chloride copolymer, polyethylene nitrile comonomer and acetal resin etc.
Derivative, these derivatives are in the side such as coating, slurry, adhesive, polyvinyl, film, leather processing, synthetic fibers, soil improvement
Face has extensive use.
From Beijing Orient petrochemical industry limited liability company (former Beijing Organic Chemical Plant) introduction acetylene method fluidisation in 1963
Since bed technique, China's vinyl acetate production technique stable development.With the development of polyvinyl alcohol, home and abroad vinyl acetate city
Field constantly expands, and price is continuously improved, this just needs that existing production technology is continuously improved and optimized, to improve vinyl acetate
Yield and quality.
The vinyl acetate of China's production at present mainly uses carbide acetylene method, gas acetylene method, three kinds of ethylene process.In calcium carbide
During producing vinyl acetate by acetylene method, there is high requirement to the circulation acetylene gas entered in fluidized-bed reactor, if mixed
It is bad to close acetylene gas separating effect in gas knockout tower, the gas contents such as acetaldehyde, vinyl acetate are excessively high in mixing acetylene gas will
It will cause foreign gas and side reaction occur in fluidized-bed reactor, such as crotonaldehyde generates, vinyl acetate autohemagglutination.If simultaneously
Vinyl acetate content height in acetylene gas is recycled, easily causes catalyst and vinyl acetate to bond and blocks reactor distributing plate hole, make gas
Be unevenly distributed, fluidized state it is poor, form vicious circle, side reaction increases, as acetone generates, aceticanhydride generates, acetylene polymer is raw
At etc., seriously affect vinyl acetate product quality.Therefore, need to device to gas knockout tower and technique improve, with
Reduce the content of the foreign gases such as acetaldehyde, the vinyl acetate in purification acetylene gas.
Utility model content
The purpose of this utility model is to provide a kind of device of raising fluidized bed production vinyl acetate yield and quality, institutes
Technical problems to be solved are: by the way that apparatus structure is rationally arranged, recycling vinyl acetate gas, washing reaction in reaction gas
Aldehydes gas in gas, thus peace and quiet acetylene gas, foreign gas in reduction system.
The utility model is to realize goal of the invention, is adopted the following technical scheme that
The utility model discloses a kind of device of raising fluidized bed production vinyl acetate yield and quality, feature exists
In: including acetic acid tank, 1# pump, acetic acid cooler, reaction solution cooler, 1# regulating valve, 2# pump, reaction solution caching
Tank, 2# regulating valve, liquid drop separator, three-stage gas knockout tower and fluidized-bed reactor；
The third section of the three-stage gas knockout tower be divided under three sections of knockout tower and three sections of knockout tower on；
Bottom under three sections of the knockout tower is provided with three sections of knockout tower lower reaction gas entrances, under three sections of the knockout tower
Lower part be provided with three sections of lower liquid headers of knockout tower；The bottom of three sections of lower liquid headers of knockout tower is provided with separation
Three sections of lower bottom part outlets of tower；Three sections of knockout tower lower filler pressures are provided with above three sections of lower liquid headers of the knockout tower
Three sections of lower filler devices of knockout tower are distributed on three sections of lower filler indents of the knockout tower in slot；Under three sections of the knockout tower
Top, three sections of knockout tower lower reaction solution entrances are provided with above three sections of lower filler devices of knockout tower；
Bottom on three sections of the knockout tower is provided with three sections of knockout tower upper reaction gas entrances；On three sections of the knockout tower
Lower part be provided with three sections of knockout tower upper liquid headers, the bottoms of three sections of the knockout tower upper liquid headers are provided with separation
Three sections of upper bottom portion outlets of tower；Three sections of knockout tower upper filler pressures are provided with above three sections of the knockout tower upper liquid headers
Three sections of knockout tower upper filler devices are distributed in slot on three sections of the knockout tower upper filler indents；On three sections of the knockout tower
It is provided with acetic acid spray thrower above filler device, is provided with wire packing mist eliminator above the acetic acid spray thrower；?
Three sections of upper tops of the knockout tower are provided with three sections of upper top reaction gas outlets of knockout tower；
Three sections of lower bottom part outlets of the knockout tower and three sections of upper bottom portion outlets of the knockout tower are in reaction solution buffer tank
Reaction solution buffer tank top entry；The reaction solution buffer tank outlet of the reaction solution buffer tank is connected to the entrance of 2# pump,
The reacted liquid cooler in outlet of the 2# pump is connected to three sections of knockout tower lower reaction solution entrances, the outlet of the 2# pump
Also it is communicated with 1# regulating valve；Reaction solution leads to after being pumped into the cooling of reaction solution cooler by 2# pump portion in reaction solution buffer tank
It crosses three sections of knockout tower lower reaction solution entrances to enter under three sections of knockout tower, another part reaction solution is sent into production by 1# regulating valve
Recovery system；
The outlet of the acetic acid tank is successively connected to acetic acid spray thrower through 1# pump and acetic acid cooler, in acetic acid tank
Acetic acid enters on three sections of knockout tower after being pumped into the cooling of acetic acid cooler by 1# through acetic acid spray thrower；
The top of the liquid drop separator is equipped with liquid drop separator upper entrance, top is equipped at the top of liquid drop separator
Mouth, lower part are provided with liquid drop separator fluid reservoir, and the bottom of the liquid drop separator fluid reservoir is equipped with liquid drop separator bottom and goes out
Mouthful；Three sections of upper top reaction gas outlets of the knockout tower are connected to liquid drop separator upper entrance；Liquid drop separator top exit
It is connected to the fluidized-bed reactor entrance of fluidized-bed reactor, liquid drop separator outlet at bottom is connected to instead by 2# regulating valve
Answer the reaction solution buffer tank upper entrance of liquid buffer tank；
The fluidized-bed reactor outlet of the fluidized-bed reactor is in one section of knockout tower of three-stage gas knockout tower
Entrance.
Three sections of lower filler devices of the knockout tower and three sections of the knockout tower upper filler devices are Pall ring.
One section of the knockout tower of three-stage gas knockout tower and two sections of knockout tower structurally and functionally with market existing structure phase
Together, removal catalyst fines, recovery of acetic acid ethylene and acetic acid are respectively used to.
Compared with prior art, the beneficial effects of the utility model are embodied in:
1, the utility model improves existing gas separation tower apparatus, after the processing of the device of the utility model, institute
In peace and quiet acetylene gas vinyl acetate content 0.02%-0.08%, acetaldehyde be reduced to by 1.5%- by 1.58%-2.09%
2.5% is down to 0.21%-0.4%, not only high efficiente callback vinyl acetate product, but also effectively washes out in mixing acetylene gas
The light components foreign gas such as acetaldehyde reduces impurity content in circulation acetylene gas, effectively controls side reaction, improves vinyl acetate
Product quality.
2, using the device of the utility model, the vinyl acetate product in hybrid reaction gas can be effectively recycled, reduces fluidisation
Distribution plate orifices blocking, effectively controls side reaction, while can extend in reactor the distribution grid time between overhauls(TBO), mentions in bed reactor
High efficiency.
3, using the device of the utility model, the aldehydes gas in hybrid reaction gas can be effectively washed out, reduces crotonaldehyde
Equal side reactions object generates, and improves vinyl acetate product quality.
3, using the device of the utility model, peace and quiet acetylene gas source can be provided for fluidized-bed reactor, reduced in reaction gas
Foreign gas efficiently improves acetylene conversion per pass, improves vinyl acetate product quality.
Detailed description of the invention
Fig. 1 is the schematic device that the utility model improves that fluidized bed produces vinyl acetate yield and quality.
Figure label: 1 acetic acid tank；2 1# pump；3 acetic acid coolers；4 reaction solution coolers；5 1# regulating valves；6
2# pump；7 reaction solution buffer tanks；The outlet of 7a reaction solution buffer tank；7b reaction solution buffer tank upper entrance；7c reaction solution caches tank deck
Portion's entrance；8 2# regulating valves；9 liquid drop separators；9a liquid drop separator outlet at bottom；9b liquid drop separator fluid reservoir；9c liquid
Drip separator upper entrance；9d liquid drop separator top exit；10 three-stage gas knockout towers；Under 11 three sections of knockout towers； 11a
Three sections of lower bottom part outlets of knockout tower；Three sections of lower liquid headers of 11b knockout tower；Three sections of 11c knockout tower lower reaction gas entrances； 11d
Three sections of knockout tower lower filler indents；Three sections of lower filler devices of 11e knockout tower；Three sections of 11f knockout tower lower reaction solution entrances；12 points
From on three sections of tower；The three sections of upper bottom portion outlets of 12a knockout tower；Three sections of 12b knockout tower upper liquid headers；On three sections of 12c knockout tower
Reaction gas entrance；Three sections of 12d knockout tower upper filler indents；Three sections of 12e knockout tower upper filler devices；12f acetic acid spray thrower； 12g
Wire packing mist eliminator；The three sections of upper top reaction gas outlets of 12h knockout tower；13 fluidized-bed reactors；13a fluidized-bed reactor enters
Mouthful；The outlet of 13b fluidized-bed reactor.
Specific embodiment
It elaborates with reference to the accompanying drawing to the embodiments of the present invention, the present embodiment is with the utility model technology
Implemented under premised on scheme, the detailed implementation method and specific operation process are given, but the protection of the utility model
Range is not limited to the following embodiments.
As shown in Figure 1, the following device for improving fluidized bed production vinyl acetate yield and quality is arranged in the present embodiment first:
It is slow including acetic acid tank 1,1# pump 2, acetic acid cooler 3, reaction solution cooler 4,1# regulating valve 5,2# pump 6, reaction solution
Deposit tank 7,2# regulating valve 8, liquid drop separator 9, three-stage gas knockout tower 10 and fluidized-bed reactor 13；
One section of the knockout tower of three-stage gas knockout tower 10 and two sections of knockout tower structurally and functionally with market existing structure
Identical, third section is divided under three sections of knockout tower 11 and three sections upper 12 of knockout tower；
11 bottom is provided with three sections of knockout tower lower reaction gas entrance 11c under three sections of knockout tower, 11 under three sections of knockout tower
Lower part be provided with three sections of knockout tower lower liquid header 11b；The bottom of three sections of knockout tower lower liquid header 11b is provided with point
Three sections from tower lower bottom parts export 11a；Three sections of lower fillers of knockout tower are provided with above three sections of knockout tower lower liquid header 11b
Three sections of knockout tower lower filler device 11e are distributed on three sections of knockout tower lower filler indent 11d in indent 11d；At three sections of knockout tower
Lower 11 top is provided with three sections of knockout tower lower reaction solution entrance 11f above three sections of knockout tower lower filler device 11e；
The bottom that three sections upper 12 of knockout tower is provided with three sections of knockout tower upper reaction gas entrance 12c；At three sections upper 12 of knockout tower
Lower part be provided with three sections of knockout tower upper liquid header 12b, the bottoms of three sections of knockout tower upper liquid header 12b are provided with point
Three sections from tower upper bottom portions export 12a；Three sections of knockout tower upper fillers are provided with above three sections of knockout tower upper liquid header 12b
Three sections of knockout tower upper filler device 12e are distributed in indent 12d on three sections of knockout tower upper filler indent 12d；In knockout tower three
Acetic acid spray thrower 12f is provided in section above filler device 12e, is provided with wire packing above acetic acid spray thrower 12f
Mist eliminator 12g；Three sections of knockout tower upper 12 tops are provided with three sections of upper top reaction gas outlet 12h of knockout tower；
Three sections of upper bottom portion outlet 12a of three sections of lower bottom part outlet 11a of knockout tower and knockout tower are connected to reaction solution buffer tank 7
Reaction solution buffer tank top entry 7c；The reaction solution buffer tank outlet 7a of reaction solution buffer tank 7 is connected to the entrance of 2# pump 6,
The reacted liquid cooler 4 in outlet of 2# pump 6 is connected to three sections of knockout tower lower reaction solution entrance 11f, and the outlet of 2# pump 6 is also
It is communicated with 1# regulating valve 5；
The outlet of acetic acid tank 1 is successively connected to acetic acid spray thrower 12f through 1# pump 2 and acetic acid cooler 3；
The top of liquid drop separator 9 is equipped with liquid drop separator upper entrance 9c, top is equipped with liquid drop separator top exit
9d, lower part are provided with liquid drop separator fluid reservoir 9b, and the bottom of liquid drop separator fluid reservoir 9b is equipped with liquid drop separator bottom and goes out
Mouth 9a；Three sections of upper top reaction gas outlet 12h of knockout tower are connected to liquid drop separator upper entrance 9c；Go out at the top of liquid drop separator
Fluidized-bed reactor the entrance 13a, liquid drop separator outlet at bottom 9a that mouth 9d is connected to fluidized-bed reactor 13 pass through 2# tune
Section valve 8 is connected to the reaction solution buffer tank upper entrance 7b of reaction solution buffer tank 7；
The fluidized-bed reactor outlet 13b of fluidized-bed reactor 13 is connected to one section of knockout tower of three-stage gas knockout tower
Entrance.
When it is implemented, three sections of knockout tower lower filler device 11e and three sections of knockout tower upper filler device 12e are Pall ring.
Using above-mentioned apparatus, the method for improving fluidized bed production vinyl acetate quality, including recovery of acetic acid ethylene are produced
Three the miscellaneous gas acetaldehyde of light component, peace and quiet acetylene gas unit processes in product, washing hybrid reaction gas, the specific steps are as follows:
Step 1, recovery of acetic acid ethylene product
Reaction mixture gas in vinyl acetate synthesis production process sequentially enters the knockout tower of three-stage gas knockout tower 10
One section and two sections of progresss initial gross separations of knockout tower, obtain include acetaldehyde, vinyl acetate, acetylene gas initial gross separation after reaction mix
Gas；
Reaction mixture gas (temperature is 10 DEG C -15 DEG C) enters through three sections of knockout tower lower reaction gas entrance 11c after initial gross separation
11 bottom under three sections of knockout tower；After the reacted liquid cooler 4 of reaction solution is cooling, gained temperature is 5 DEG C of -10 DEG C of low-temp reaction liquid
Enter 11 top, flow 80-85m under three sections of knockout tower through three sections of knockout tower lower reaction solution entrance 11f3/h；In knockout tower three
In section lower 11, low-temp reaction liquid is flowed from above to below, reaction mixture gas flows from bottom to top, reaction mixture gas and low-temp reaction
Liquid carries out being sufficiently mixed contact in a manner of reverse convection in three sections of knockout tower lower filler device 11e, makes reaction mixture gas temperature
It reduces, vinyl acetate gas is condensed into liquid in reaction mixture gas, and low-temp reaction liquid that flows from above to below mixes reaction
The condensate liquid of vinyl acetate washes out in gas, and reaction solution converges in three sections of knockout tower lower liquid header 11b after washing, by separating
Three sections of lower bottom part outlet 11a of tower flow into reaction solution buffer tank 7；
Reaction solution in reaction solution buffer tank 7 is sent out by 2# pump 6, after reaction solution reacted liquid cooler 4 in part is cooling
11 are recycled under into three sections of knockout tower, and part reaction solution enters production recovery system by 1# regulating valve 5；
Reaction solution is mainly to be made of acetic acid and vinyl acetate, and volume ratio is about 1:1；
The miscellaneous gas acetaldehyde of light component in step 2, washing hybrid reaction gas
Enter separation through three sections of knockout tower upper reaction gas entrance 12c through under three sections of knockout tower 11 treated reaction mixture gas
It three sections upper 12 of tower, flows from bottom to top；Through the low temperature high-purity acetic acid after cooling of acetic acid cooler 3, (temperature is controlled at 20 DEG C -22
DEG C, concentration is greater than and 98%) enters three sections upper 12 of knockout tower by acetic acid spray thrower 12f, sprays from top to bottom, spray flow 5-
7m3/h；Spray acetic acid with three sections of knockout tower under 11 do not wash complete a small amount of vinyl acetate condensate liquid and acetaldehyde condensate liquid point
It is washed in a manner of reverse convection again in filler device 12e upper from three sections of tower, makes three sections of knockout tower upper temperature 18 ± 2
DEG C, principle is melted according to phase patibhaga-nimitta, acetaldehyde condensate liquid and vinyl acetate condensate liquid can be washed effectively by high-purity acetic acid in reaction gas；Instead
Should gas it is washed after by three sections of knockout tower it is upper 12 top be arranged wire packing mist eliminator 12g in entrainment acetaldehyde condense
Liquid, vinyl acetate condensate liquid carry out secondary supplementary set, and reaction solution converges three sections of knockout tower upper liquid header 12b after washing, supplementary set,
Reaction solution buffer tank 7 is flowed by three sections of upper bottom portion outlet 12a of knockout tower；
After reaction mixture gas isolates acetaldehyde, vinyl acetate gas by under three sections of knockout tower 11 and three sections upper 12 of knockout tower,
Obtain carrying secretly the preliminary purification acetylene gas of micro acetaldehyde, vinyl acetate condensate liquid；
Step 3, peace and quiet acetylene gas
Carry micro acetaldehyde secretly, the preliminary purification acetylene gas of vinyl acetate condensate liquid is gone out by three sections of upper top reaction gas of knockout tower
(flow control is in 7500-8500m by mouth 12h3/ h, the voltage-controlled system of the bottom column of three-stage knockout tower is in 18-20Kpa, top drum pressure
Control is in 15-18Kpa) it will not be separated in acetylene gas into the progress gas-liquid separation of liquid drop separator 9 through water conservancy diversion and eddy current effect
Thorough condensate liquid falls into liquid drop separator fluid reservoir 9b, generates dry, peace and quiet acetylene gas by going out at the top of liquid drop separator
Mouth 9d enters in 13 device of fluidized-bed reactor, provides peace and quiet acetylene gas for fluidized-bed reactor；Liquid drop separator fluid reservoir 9b
In condensate liquid enter in reaction solution buffer tank 7 through 2# regulating valve 8 from reaction solution buffer tank upper entrance 7b.
After apparatus and method of the present invention is handled, vinyl acetate content is by 1.58%- in the peace and quiet acetylene gas of gained
2.09%, which is reduced to 0.02%-0.08%, acetaldehyde, is down to 0.21%-0.4% by 1.5%-2.5%.
The foregoing is merely exemplary embodiment of the present invention, are not intended to limit the invention, all of the invention
Made any modifications, equivalent replacements, and improvements etc., should all be included in the protection scope of the present invention within spirit and principle.
Claims (2)
1. it is a kind of improve fluidized bed production vinyl acetate yield and quality device, it is characterised in that: including acetic acid tank (1),
1# pumps (2), acetic acid cooler (3), reaction solution cooler (4), 1# regulating valve (5), 2# pump (6), reaction solution buffer tank
(7), 2# regulating valve (8), liquid drop separator (9), three-stage gas knockout tower (10) and fluidized-bed reactor (13)；
The third section of the three-stage gas knockout tower (10) is divided under three sections of knockout tower (11) and three sections of knockout tower upper (12)；
The bottom of (11) is provided with three sections of knockout tower lower reaction gas entrances (11c) under three sections of the knockout tower, in the knockout tower
The lower part of (11) is provided with three sections of knockout tower lower liquid headers (11b) under three sections；Three sections of lower liquid headers of the knockout tower
The bottom of (11b) is provided with three sections of lower bottom part outlets (11a) of knockout tower；In three sections of the knockout tower lower liquid headers (11b)
Top be provided with three sections of knockout tower lower filler indents (11d), be distributed on three sections of the knockout tower lower filler indents (11d)
Three sections of knockout tower lower filler devices (11e)；Under three sections of the knockout tower top of (11), be located at three sections of knockout tower lower fillers dresses
It sets and is provided with three sections of knockout tower lower reaction solution entrances (11f) above (11e)；
The bottom of three sections of the knockout tower upper (12) is provided with three sections of knockout tower upper reaction gas entrance (12c)；In the knockout tower
The lower part of three sections upper (12) is provided with three sections of knockout tower upper liquid header (12b), three sections of the knockout tower upper liquid headers
The bottom of (12b) is provided with three sections of upper bottom portion outlets (12a) of knockout tower；At three sections of the knockout tower upper liquid header (12b)
Top be provided with three sections of knockout tower upper filler indent (12d), be distributed on three sections of the knockout tower upper filler indent (12d)
Three sections of knockout tower upper filler device (12e)；Acetic acid spray is provided with above three sections of the knockout tower upper filler device (12e)
Device (12f) is provided with wire packing mist eliminator (12g) above the acetic acid spray thrower (12f)；At three sections of the knockout tower
Three sections of upper top reaction gas outlets (12h) of knockout tower are provided at the top of upper (12)；
Three sections of upper bottom portion outlets (12a) of three sections of lower bottom part outlets (11a) of the knockout tower and the knockout tower are connected to reaction solution
The reaction solution buffer tank top entry (7c) of buffer tank (7)；The reaction solution buffer tank of the reaction solution buffer tank (7) exports (7a)
It is connected to the entrance of 2# pump (6), the reacted liquid cooler (4) in outlet of the 2# pump (6) is connected under three sections of knockout tower
The outlet of reaction solution entrance (11f), the 2# pump (6) is also communicated with 1# regulating valve (5)；
The outlet of the acetic acid tank (1) is successively connected to acetic acid spray thrower (12f) through 1# pump (2) and acetic acid cooler (3)；
The top of the liquid drop separator (9) is equipped with liquid drop separator upper entrance (9c), top is equipped at the top of liquid drop separator
Outlet (9d), lower part are provided with liquid drop separator fluid reservoir (9b), and the bottom of the liquid drop separator fluid reservoir (9b) is equipped with liquid
Drip separator bottom outlet (9a)；Three sections of upper top reaction gas outlets (12h) of the knockout tower are connected to liquid drop separator top
Entrance (9c)；Liquid drop separator top exit (9d) is connected to the fluidized-bed reactor entrance (13a) of fluidized-bed reactor (13),
Liquid drop separator outlet at bottom (9a) is connected on the reaction solution buffer tank of reaction solution buffer tank (7) by 2# regulating valve (8)
Portion's entrance (7b)；
The fluidized-bed reactor outlet (13b) of the fluidized-bed reactor (13) is connected to the knockout tower of three-stage gas knockout tower
One section of entrance.
2. the device according to claim 1 for improving fluidized bed production vinyl acetate yield and quality, it is characterised in that: institute
Stating three sections of knockout tower lower filler devices (11e) and three sections of the knockout tower upper filler device (12e) is Pall ring.
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| CN201822179962.4U CN209412110U (en) | 2018-12-25 | 2018-12-25 | A kind of device improving fluidized bed production vinyl acetate yield and quality |
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| CN201822179962.4U CN209412110U (en) | 2018-12-25 | 2018-12-25 | A kind of device improving fluidized bed production vinyl acetate yield and quality |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109467503A (en) * | 2018-12-25 | 2019-03-15 | 内蒙古蒙维科技有限公司 | A kind of device and method improving fluidized bed production vinyl acetate yield and quality |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109467503A (en) * | 2018-12-25 | 2019-03-15 | 内蒙古蒙维科技有限公司 | A kind of device and method improving fluidized bed production vinyl acetate yield and quality |
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