CN209406017U - Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas - Google Patents

Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas Download PDF

Info

Publication number
CN209406017U
CN209406017U CN201821635162.2U CN201821635162U CN209406017U CN 209406017 U CN209406017 U CN 209406017U CN 201821635162 U CN201821635162 U CN 201821635162U CN 209406017 U CN209406017 U CN 209406017U
Authority
CN
China
Prior art keywords
ammonia
hydrogen sulfide
exhaust gas
sulphur
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201821635162.2U
Other languages
Chinese (zh)
Inventor
苏本生
秦翔
魏晓明
马欣欣
王倩
王雯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing University of Chemical Technology
Original Assignee
Beijing University of Chemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing University of Chemical Technology filed Critical Beijing University of Chemical Technology
Priority to CN201821635162.2U priority Critical patent/CN209406017U/en
Application granted granted Critical
Publication of CN209406017U publication Critical patent/CN209406017U/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Landscapes

  • Treating Waste Gases (AREA)

Abstract

The utility model discloses ammonia, sulphur and VOCs devices in a kind of synchronous removal livestock and poultry cultivation exhaust gas, comprising: concatenated deamination module and depriving hydrogen sulphide module;The deamination module includes that ammonia absorbs part and ammonia removal part, spray system is provided in the gas distribution pipe of ammonia absorption part and is inoculated with the polyester sponge filler of activated sludge, ammonia removal partial interior is provided with the needle-shaped filler including multiple biological diaphragm areas, air flow rate sensor is provided in gas distribution pipe, spray system is provided with liquid pump, spray flow rate sensor and pH sensor;The depriving hydrogen sulphide module includes hydrogen sulfide absorption part and hydrogen sulfide removal part, polyester sponge filler is provided in hydrogen sulfide absorption part, hydrogen sulfide removal part is provided with needle-shaped filler, hydrogen sulfide absorption part is provided with air flow rate sensor, and spray system is provided with liquid pump, spray flow rate sensor and pH sensor.

Description

Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas
Technical field
The utility model belongs to technical field of sewage, in particular to ammonia in a kind of synchronous removal livestock and poultry cultivation exhaust gas, Sulphur and VOCs device are suitable for the sulphur removal of livestock and poultry cultivation nitrogen emission and deodorization engineering.
Background technique
With the rapidly development of livestock and poultry breeding industry, intensive, modernization is constantly accelerated, and scale livestock farming is to environment Caused by pollution also result in country attention.Wherein, the foul gas generated during livestock and poultry cultivation not only causes atmosphere dirty Dye, and cultivated animals growth is impacted, serious person even influences the Health and Living quality of perimeter resident.Cause This, how the processing livestock and poultry exhaust gas of safe green, to improve atmospheric environment and improve farm's nearby residents quality of life have Important meaning.
What livestock and poultry cultivation exhaust gas generated be derived from all microorganism is using utilizing fecaluria, sewage and do not digest carbon in feed The result of the nutrient metabolisms such as hydrate, fat, protein, minerals and vitamins effect.Microorganism is not mainly Decomposing organic compounds generate foul gas under complete anaerobic condition.Therefore, the main component of livestock and poultry cultivation exhaust gas has ammonia and waves Hair property amine, sulfur-containing compound (hydrogen sulfide, thioether class, thio-alcohol), volatile fatty acid, aromatic compound.
Livestock and poultry exhaust-gas treatment is exactly to handle its main component ammonia, hydrogen sulfide and volatile fatty acid.Wherein ammonia is de- Except method has physical method, chemical method, catalytic decomposition, catalysis aerobic breakdown and bioanalysis
1. physical method is the most common technology of ammonia processing, i.e., industrial tail gas is absorbed using soft water or weak aqua ammonia as absorbent In ammonia, obtained low concentration ammonium hydroxide further distills, liquefied ammonia utilization is made in rectifying, pressurization, condensation.Shortcoming mainly has: Consume a large amount of water and energy;Recovery ammonia utilization rate is not high, and synthesis ammonia and urea production raw material is caused largely to lose;It generates certain The NO of amountxCause secondary pollution.
2. chemical method is mainly the alkalinity for utilizing ammonia, so that ammonia and acidic materials is reacted and then generate low value-added nitrogen Fertilizer, since the usual volatility of recovered solvent is big, corrosivity is strong, the method for ammonia is answered in industry in chemisorbing purifying industrial tail gas It is gradually eliminated in.
3. catalytic decomposition is that ammonia is thoroughly decomposed into N under the effect of the catalyst2And H2, but there is also very for device at present Otherwise more problems will appear loss, catalyst sulfur poisoning or the generation ammonium salt blockage of catalyst if reaction temperature needs strict control Phenomena such as catalyst, in addition the energy consumption of ammonia catalytic decomposition is high, and operating cost is high, is not suitable for generally using.
4. being catalyzed aerobic breakdown method is that ammonia is catalytically conveted to N under aerobic conditions2And water, decomposition reaction at 300 DEG C just It can carry out, not generate secondary pollution, but method processing ammonia concentration is lower, is not suitable for the processing of higher concentration ammonia, otherwise wants Temperature is improved, energy consumption is increased.
5. the Biochemical method of ammonia is to fill out ammonia-containing gas by porous containing fixation of microbe by biofiltration process Expect that bed, the pollutant in air-flow are absorbed by biomembrane, removal generates CO2, H2O, NO2 -And NO3 -.It is compared with the traditional method, biology Filtering technique has suitable advantage in terms of handling low concentration pollution gas, and the technology also has efficiently, low Meteorological And operating cost, safety operation, low energy expenditure do not generate byproduct, can be converted to many inorganic matters and organic matter harmless Remover the characteristics of.
The common removal methods of hydrogen sulfide mainly have absorption process, absorption method, dry method removal method and wet process removal method.
1. absorption process includes Physical Absorption and chemical absorption method.Physical Absorption method generallys use organic solvent as hydrogen sulfide Absorbent, process is simple, is not required to the heat source of additional steam and other additional sources.Chemical absorption method is usually that hydrogen sulfide is molten Yu Shuihou, using the solution of the strong base-weak acid salt with buffer function such as phenates, phosphate, borate, amino-acid salt etc. or one A little weak base absorption processing.
2. absorption method is the absorption property purification hydrogen sulfide gas using certain porous materials, this method is usually used in handling The lower gas of concentration of hydrogen sulfide.Usually require that adsorbent resistance is low, high without dust, adsorption capacity height, retention degree, due to absorption The unsuitable frequent regeneration of deodorization device, it requires that entrance concentration of hydrogen sulfide cannot be too high, otherwise regeneration frequently, cause waste without Ji.
3. dry method removal is to remove a kind of method of the hydrogen sulfide gas at elemental sulfur or removal of sulphur object, allusion quotation in general Type has Claus method and selective removal method.It is raw material that Claus method, which is using hydrogen sulfide, interior in Crouse's combustion furnace to make A part removal in exhaust gas generates SO2, with the H in air inlet2S reaction generates sulphur recovery.Claus method requires temperature in reactor Degree is necessarily less than 650 DEG C, and the H of exhaust gas2S initial concentration is more than or equal to 15%-20%.Selective removal method is in catalyst Under the action of with the oxygen in air by H2S directly removes as sulphur, the key of this method be develop selectivity it is good, to H2O and excess O2Insensitive high activated catalyst is prepared with the different mixtures of iron-based remover at present.Selective removal method sulphur it is total The rate of recovery can reach 98%-99%.
4. wet process removal is bigger than dry desulfurization processing capacity, operating flexibility is big, and desulfuration efficiency is high.Cardinal principle are as follows:
H2S+Na2CO3—NaHS+NaHCO3
2NaHS+4NaVO3+H2O—Na2V4O9+4NaOH+2S
Na2V4O9+2NaOH+H2O+2ADA—4NaVO3+2HADA
O2+2HADA—2ADA+2H2O
The device problem is: harmful waste liquid processing is difficult, may cause secondary pollution;Micro-tapping is big;By-product makes Drug consumption increases;The sulphur simple substance of generation is of poor quality;Suspended particulate recycling is difficult, easily causes plugged filter etc..
Utility model content
The utility model, which provides, provides a kind of simultaneous denitrification sulphur removal biological treatment device that aerobic, anaerobism combines, mesh Be the harmful components removed in livestock and poultry exhaust gas, and overcome existing processing ammonia, hydrogen sulfide and volatile organic matter technology not Foot.
Technical solution is as follows:
Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas, comprising: concatenated deamination module and devulcanization Hydrogen module;
The deamination module includes that ammonia absorbs part and ammonia removal part, is provided with spray in the gas distribution pipe of ammonia absorption part System and the polyester sponge filler for being inoculated with activated sludge, ammonia removal partial interior are provided with the needle including multiple biological diaphragm areas Shape filler is provided with air flow rate sensor in gas distribution pipe, and spray system is provided with liquid pump, spray flow rate sensor and pH value Sensor;
The depriving hydrogen sulphide module includes hydrogen sulfide absorption part and hydrogen sulfide removal part, and hydrogen sulfide absorption is set in part It is equipped with polyester sponge filler, hydrogen sulfide removal part is provided with needle-shaped filler, and hydrogen sulfide absorption part is provided with gas flow rate biography Sensor, spray system are provided with liquid pump, spray flow rate sensor and pH sensor.
Preferably, ammonia, sulphur and VOCs device include the logical gas of drive gas flow in the synchronous removal livestock and poultry cultivation exhaust gas Body pump, is set to before deamination module.
Preferably, ammonia, sulphur and VOCs device include exhaust gas concentration sensor in the synchronous removal livestock and poultry cultivation exhaust gas, if Before or after setting gas pump.
Preferably, the ammonia absorbs part and hydrogen sulfide absorption part is respectively connected with pH value regulating device.
Preferably, the ammonia absorbs part control ammonia absorption process gas residence time in 15-20s, and pH value is in 7.5-9 Between, spray flow 0.7-35L/min.
Preferably, the hydrogen sulfide absorption partial vulcanization hydrogen residence time, pH value was in 7-8, spray flow in 25s-30s 0.7-35 L/min。
The working principle of whole device is as follows:
Firstly, livestock and poultry exhaust gas enters deamination module, after the absorption and nitrosation that carry out ammonia in part are absorbed in ammonia, obtain Ammonia is entered by spray mode dissolved with ammonia and conversion nitrite nitrogen liquid and removes part, the nitrogen for realizing ammonia is removed by anaerobism ammonia Conversion, the hydrolysis of organic matter in liquid phase is realized by short-cut denitrification;
Then, the deamination liquid and exhaust gas that obtain by deamination resume module enter the hydrogen sulfide absorption of depriving hydrogen sulphide module Part, by way of spray, exhaust gas is introduced directly into deamination liquid, carries out H2H under the absorption of S and aerobic conditions2S is converted into sulphur list Matter, what is obtained is dissolved with H2S and NO3 -Liquid enters hydrogen sulfide removal part, under aerobic and oxygen free condition, by with NO3 -Association The removal of simple substance S is realized with processing, while the VOCs of removal dissolution in the liquid phase is acted on by autotrophic microbe.
It is provided with spray system and biologic packing material in the gas distribution pipe of deamination module ammonia absorption part, is inhaled using spray liquid The ammonia in exhaust gas is received, and by control spray flow, gas residence time and pH value, in the polyester sponge for being inoculated with activated sludge Conversion of the ammonia to nitrite nitrogen is realized in filler.
The deamination module ammonia removal partial interior is provided with needle-shaped filler, realizes short-cut denitrification and the removal of anaerobism ammonia Synergistic effect, by microorganism formed biomembrane be divided into three regions,
Outermost layer completes NH4 +Removal, primary product NO2 -, a small amount of NO3 -
NH occurs under anoxia condition for secondary outer layer4 +And NO2 -Reaction directly generates nitrogen;Part NO simultaneously2 -With the VOC in water Short distance nitration reaction occurs for the organic matter generated with the hydrolysis acidification of organic granular;
The CO that anaerobic organism reaction generates occurs for innermost layer, anoxic organic matter2With the CO contained in exhaust gas2Anaerobism ammonia is provided Carbon source required for removing.
The hydrogen sulfide absorption partial interior setting spray system and biologic packing material of the depriving hydrogen sulphide module, by controlling liquid Body spray flow, gas residence time and pH, spray liquid autolysis oxygen complete H2S first step aerobic reaction in aqueous solution, shape At part simple substance S, complete nutrient solution a part after absorbing and flow back into cyclic absorption exhaust gas in nutrient solution water tank, another part into Enter in hydrogen sulfide removal part;Microorganism in biologic packing material realizes H2S fully absorb and H2S is in biologic packing material to sulphur list The conversion of matter.
The hydrogen sulfide removal part of the depriving hydrogen sulphide module utilizes H remaining in spray liquid2It is produced in S and deamination module Raw a small amount of NO3 -, will using simultaneous denitrification sulphur removal microbial reaction occurs under the action of thiobacillus denitrificans under conditions of anaerobism NO3 -Conversion is for nitrogen, H2S is converted into sulphur simple substance.
Polyester sponge filler is provided in the hydrogen sulfide absorption part of the depriving hydrogen sulphide module, hydrogen sulfide removal part is set It is equipped with needle-shaped filler.
The concentration of livestock and poultry cultivation exhaust gas is between 2-10ppm.
The utility model can combine the synergistic effect between differential responses module using Aerobic-anaerobic device, realize The innoxious removal of nitrogen, sulphur and volatile organic matter.
Advantage of the utility model compared with the prior art has:
1. livestock and poultry cultivation exhaust-gas treatment synchronization process biological device, structure is simple, easy to process, convenient for future popularization and Using.
2. the removal of ammonia, hydrogen sulfide and volatile organic matter is combined, treatment effeciency is improved.
3. step by step, stage by stage, subsystem handle livestock and poultry cultivation exhaust gas, by process flow be divided into ammonia abjection and hydrogen sulfide Deviate from two big modules, while realizing the effect of the collaboration processing between two big modules, not only increases the place of ammonia and hydrogen sulfide Efficiency is managed, and realizes the removal of volatile organic matter.
4. aerobic combine with anaerobic device, the harmless treatment of ammonia and hydrogen sulfide is realized, exhaust gas, which uses, first to be absorbed The mode of post-processing, by controlling operating parameter, during ammonia absorbs, using the oxygen in livestock and poultry exhaust gas by part ammonia Remove into nitrite.Under anaerobic, by absorbing liquid ammonium ion and nitrite ion be converted into nitrogen, realize ammonia The harmless treatment of gas;During hydrogen sulfide absorption, partial vulcanization hydrogen is removed as sulphur list using the oxygen in livestock and poultry exhaust gas Matter.Under anaerobic, using microbial action by hydrogen sulfide absorption liquid sulphur hydrogen radical ion and nitrate ion be converted into Sulphur simple substance and nitrogen.
5. it is low in cost, it is safe and efficient, it is not necessarily to catalyst and additional carbon, exhaust treatment system need to only supplement a small amount of water. 6. forming elemental sulfur can be with recovery section processing cost.
Detailed description of the invention
Ammonia, sulphur and VOCs schematic device in the synchronous removal livestock and poultry cultivation exhaust gas of Fig. 1.
Specific embodiment
To make those skilled in the art more fully understand the technical solution of the utility model, below with reference to embodiment to this Ammonia, sulphur and VOCs device are described in detail in a kind of synchronous removal livestock and poultry cultivation exhaust gas that utility model provides.
Ammonia, sulphur and VOCs device are divided into ammonia abjection module in synchronous removal livestock and poultry cultivation exhaust gas provided by the utility model Deviate from the big module of module two with hydrogen sulfide, and realizes the volatile organic matter in livestock and poultry exhaust gas by the synergistic effect of two big modules Removal.
Embodiment 1
Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas, comprising: concatenated deamination module and devulcanization Hydrogen module;
Deamination module includes that ammonia absorbs part and ammonia removal part, is provided with spray system in the gas distribution pipe of ammonia absorption part With the polyester sponge filler for being inoculated with activated sludge, ammonia removal partial interior is provided with to be filled out including multiple biological the needle-shaped of diaphragm area Expect, air flow rate sensor is provided in gas distribution pipe, and spray system is provided with liquid pump, spray flow rate sensor and pH value sensing Device;
The depriving hydrogen sulphide module includes hydrogen sulfide absorption part and hydrogen sulfide removal part, and hydrogen sulfide absorption is set in part It is equipped with polyester sponge filler, hydrogen sulfide removal part is provided with needle-shaped filler, and hydrogen sulfide absorption part is provided with gas flow rate biography Sensor, spray system are provided with liquid pump, spray flow rate sensor and pH sensor.
Ammonia, sulphur and VOCs device include the logical gas pump of drive gas flow in synchronous removal livestock and poultry cultivation exhaust gas, are set to Before deamination module.
Ammonia, sulphur and VOCs device include exhaust gas concentration sensor in synchronous removal livestock and poultry cultivation exhaust gas, setting gas pump it It is preceding or later.
Ammonia absorbs part and hydrogen sulfide absorption part is respectively connected with pH value regulating device.
Ammonia absorbs part control ammonia absorption process gas residence time in 15-20s, and pH value is between 7.5-9, spray flow For 0.7-35L/min.
The hydrogen sulfide absorption partial vulcanization hydrogen residence time, pH value was in 7-8, spray flow 0.7-35L/min in 25s-30s.
Polyester sponge filler is provided in the hydrogen sulfide absorption part of depriving hydrogen sulphide module, hydrogen sulfide removal part is provided with Needle-shaped filler.
The concentration of livestock and poultry cultivation exhaust gas is between 2-10ppm.
The utility model can combine the synergistic effect between differential responses module using Aerobic-anaerobic device, realize The innoxious removal of nitrogen, sulphur and volatile organic matter.
Specific device process is as follows:
(1) device process
Present apparatus process is divided into gas line and liquid line:
Gas line is livestock and poultry exhaust gas by air-introduced machine introducing ammonia removing module, enters hydrogen sulfide stripping mould after treatment Block is discharged into atmosphere after harmless treatment.
Liquid line is that the absorbing liquid of ammonia is absorbed in ammonia removing module, removes rear portion as repeats itself into ammonia is crossed Absorbing liquid, another part enter hydrogen sulfide stripping module, after the harmless treatment of hydrogen sulfide stripping module, enter back into ammonia Module is removed, the circulation of liquid is completed.
(2) course of work of the utility model is as follows:
1. ammonia absorption process: livestock and poultry exhaust gas is entered by air-introduced machine in the gas distribution pipe of deamination module absorption plant, then It into the polyester sponge filler for being inoculated with activated sludge, inversely contacts, utilizes with the nutrient solution that screw spraying head sprays Ammonia property soluble easily in water fully absorbs ammonia, and passes through the amount of the air inflow of control air-introduced machine and recirculating nutrient solution, control Time of contact processed, promote NH4 +NO is converted under the action of nitrite bacteria2 -.Standing reservoir after absorption is in absorption plant Bottom storage at, partial reflux cyclic absorption exhaust gas into nutrient solution water tank, another part enters in ammonia oxygen reaction unit.
2. anaerobism ammonia removal process: the absorbing liquid of previous step enters in deamination module removal device, in this course, living Property sludge be grown on needle-shaped filler, three regions can be divided by being formed by biomembrane: outermost layer completes NH4 +Removal, lead to Control is crossed, product is mainly NO2 -, a small amount of NO3 -;In secondary outer layer, since NH can occur for anoxic4 +And NO2 -Reaction, directly produce Nitrogen;Part NO simultaneously2 -It can also occur with the organic matter (mainly from the hydrolysis acidification of VOC and organic granular) for being dissolved in water short Journey nitration reaction;CO is generated since anaerobic organism reaction can occur for anoxic organic matter in innermost layer2, the CO of release2With it is useless The CO contained in gas2Carbon source required for anaerobism ammonia removes can be provided.Therefore, denitrogenation can occur simultaneously in this region and takes off Carbon reaction, i.e., remove NH simultaneously3, VOCs and organic granular.
3. hydrogen sulfide absorption process: the livestock and poultry exhaust gas by ammonia absorption process goes successively to depriving hydrogen sulphide and absorbs part In, in this process, H is completed using spray liquid autolysis oxygen2S first step aerobic reaction in aqueous solution forms part Simple substance S.For standing reservoir after absorption at the bottom storage of absorption plant, partial reflux cyclic absorption into nutrient solution water tank is useless Gas, another part enter in hydrogen sulfide reaction unit.
4. hydrogen sulfide removal process: being dissolved in remaining H in spray liquid2S is removed in part into depriving hydrogen sulphide in anaerobism Under the conditions of with deamination during the NO that is formed3 -Simultaneous denitrification sulphur removal microbial reaction, the following 5HS of key reaction process occurs-+ 2NO3 -+7H+→5S+N2+6H2O.Realize completely removing for hydrogen sulfide.
It is explained in detail above in conjunction with example of the embodiment to the utility model, but the utility model is not limited to State example, all protection scopes that any improvement and modification made by the utility model are belonged to the utility model claims.

Claims (6)

1. ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas characterized by comprising concatenated deamination mould Block and depriving hydrogen sulphide module;
The deamination module includes that ammonia absorbs part and ammonia removal part, is provided with spray system in the gas distribution pipe of ammonia absorption part With the polyester sponge filler for being inoculated with activated sludge, ammonia removal partial interior is provided with to be filled out including multiple biological the needle-shaped of diaphragm area Expect, air flow rate sensor is provided in gas distribution pipe, and spray system is provided with liquid pump, spray flow rate sensor and pH value sensing Device;
The depriving hydrogen sulphide module includes hydrogen sulfide absorption part and hydrogen sulfide removal part, and hydrogen sulfide absorption is provided in part Polyester sponge filler, hydrogen sulfide removal part are provided with needle-shaped filler, and hydrogen sulfide absorption part is provided with air flow rate sensor, Spray system is provided with liquid pump, spray flow rate sensor and pH sensor.
2. ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas according to claim 1, which is characterized in that institute Stating ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas includes the logical gas pump of drive gas flow, is set to deamination mould Before block.
3. ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas according to claim 2, which is characterized in that institute Stating ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas includes exhaust gas concentration sensor, before setting gas pump or it Afterwards.
4. ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas according to claim 3, which is characterized in that institute It states ammonia absorption part and hydrogen sulfide absorption part is respectively connected with pH value regulating device.
5. ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas according to claim 4, which is characterized in that institute It states ammonia and absorbs part control ammonia absorption process gas residence time in 15-20s, pH value is between 7.5-9, spray flow 0.7- 35L/min。
6. ammonia, sulphur and VOCs device in synchronous removal livestock and poultry cultivation exhaust gas according to claim 5, which is characterized in that institute The hydrogen sulfide absorption part control hydrogen sulfide residence time is stated in 25s-30s, pH value is in 7-8, spray flow 0.7-35L/min.
CN201821635162.2U 2018-10-09 2018-10-09 Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas Active CN209406017U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821635162.2U CN209406017U (en) 2018-10-09 2018-10-09 Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821635162.2U CN209406017U (en) 2018-10-09 2018-10-09 Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas

Publications (1)

Publication Number Publication Date
CN209406017U true CN209406017U (en) 2019-09-20

Family

ID=67932431

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201821635162.2U Active CN209406017U (en) 2018-10-09 2018-10-09 Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas

Country Status (1)

Country Link
CN (1) CN209406017U (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111359416A (en) * 2020-03-18 2020-07-03 生态环境部环境规划院 Ammonia gas purification system for agriculture
WO2022214154A1 (en) * 2021-04-07 2022-10-13 Hasni Abdelmallek Device and method for eliminating dust, smoke, gas and vapours expelled into the environment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111359416A (en) * 2020-03-18 2020-07-03 生态环境部环境规划院 Ammonia gas purification system for agriculture
WO2022214154A1 (en) * 2021-04-07 2022-10-13 Hasni Abdelmallek Device and method for eliminating dust, smoke, gas and vapours expelled into the environment

Similar Documents

Publication Publication Date Title
CN106310890B (en) A kind of method of bioanalysis removing sour gas
CN101200332A (en) Method for removing nitrate nitrogen from aquaculture water
CN106215687A (en) Biofilter odor treating device and method
CN110639358B (en) Resource process for synchronously removing VOCs, sulfides and ammonia sulfur in waste gas by chemical coupling and biology
Barbusiński et al. Use of biological methods for removal of H2S from biogas in wastewater treatment plants–a review
WO2009059615A1 (en) Method for producing a nitrogenous fertilizer from nitrogen-containing material of biogenous and industrial origin
CN209406017U (en) Ammonia, sulphur and VOCs device in a kind of synchronous removal livestock and poultry cultivation exhaust gas
CN113636640B (en) Biological trickling filter pilot test device and short-cut nitrification domestication method using same
CN100340326C (en) Purification for stink and organic waste gas
CN107349769A (en) A kind of beer waste water foul smell puies forward mark processing system and technique
CN106467352B (en) Method for recycling and deodorizing odor resources for sludge biological drying technology
CN104190226B (en) Complexing absorption and aerobic denitrification combined smoke denitration process
CN103611416B (en) The odor removal of reciprocating living beings filter bed composite alkali liquor
CN208097804U (en) A kind of hybrid biological treatment exhaust device equipped with regenerated reactor
CN109289459A (en) A kind of synchronous technique for removing ammonia, sulphur and VOCs in livestock and poultry cultivation exhaust gas
CN218834108U (en) Biological washing and filtering treatment system for VOCs organic waste gas
CN110252126A (en) Zinc cation filtration deodorization technique and system
CN104324607A (en) Biological deodorization method for sodium methyl mercaptide tail gas treatment
CN205435469U (en) Biological method exhaust treatment device of second grade
CN205216578U (en) Composite module biofiltration purifier
CN207951120U (en) A kind of device for cultivating place ammonia processing
CN113101800A (en) Volatile organic compound treatment reaction system and application thereof
CN207203825U (en) A kind of beer waste water foul smell puies forward mark processing system
EP2077146A2 (en) Method and device for removal of hydrogen sulfide from biogas
CN203625132U (en) Bio-denitrogenation reactor for garbage leachate

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant