CN209342426U - Micro- plastics sampling column and micro- plastics acquisition device - Google Patents
Micro- plastics sampling column and micro- plastics acquisition device Download PDFInfo
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- CN209342426U CN209342426U CN201821583805.3U CN201821583805U CN209342426U CN 209342426 U CN209342426 U CN 209342426U CN 201821583805 U CN201821583805 U CN 201821583805U CN 209342426 U CN209342426 U CN 209342426U
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Abstract
The utility model discloses micro- plastics sampling column, including main column, filtering net plate, upper end cover and lower cover, the upper end cover and lower cover are removably attachable to the top and bottom of main column, form cylindrical inner cavity, and the bottom of inner cavity is arranged in the filtering net plate.Micro- plastics acquisition device, including micro- plastics sampling column, surface layer water sampler and suction pump, flowmeter, switching valve and electric control system.It can be with the micro- plastics of the acquisition of big flow by micro- plastics acquisition device.Compared with prior art, the utility model can effectively be enriched with plastics micro- in water body, improve the 1-2 order of magnitude compared to detection precision of the conventional method to micro- plastics.
Description
Technical field
The application belongs to water body detection field, and the micro- plastics being more particularly, to acquired to micro- plastics in water body are adopted
Sample column and micro- plastics acquisition device.
Background technique
Micro- plastics (Microplastic) refer to size less than the various plastic granules of 5.0mm, microfibre, plastic grain,
The general name of foamed plastics and film etc..Micro- plastics source is extremely complex in marine environment, existing to come from river, blowdown, rubbish heap
Equal terrestrial inputs are put, also there is the marine facies input during operation on the sea and Shipping.Meanwhile some detergent, life
Also containing a large amount of micro- plastic components in the industrial goods such as skin care item and the raw material of industry.Into micro- plastics in environment due to partial size
It is small, density is low, can be migrated under the external force such as wind-force, river, ocean current.Micro- plastic nature is relatively stable, can long-term existence
In environment, but its surface physicochemical property can sunlight, wind-force, the wave the effects of under change.Micro- plastics size is smaller, compares
Surface area is big, hydrophobicity is strong, is the ideal carrier of numerous hydrophobic organic pollutants and heavy metal.Micro- plastics are easily by planktonic organism
It eats by mistake, can be detained for a long time in vivo with fish etc., and transfer and enrichment occur in food web, to ecological environment security
It constitutes a threat to.
The device and method of micro- plastics acquisition not yet standardizes in water body at present, and trawling is most common micro- plastics
Acquisition method.Trawling acquires micro- plastics, and the plankton net for generalling use 333 μm of -335 μm of pore diameter ranges tows one in water
Set a distance calculates the water being enriched with according to network interface size and the distance towed come quantitative, then the substance of collection is transferred to glass
Subsequent analysis is carried out in bottle.
Trawling acquires micro- plastic sample, and there are limitations.In seawater the micro- plastics of larger particles (300 μm of -5mm) concentration compared with
Low, according to existing, micro- plastics concentration of CHINESE OFFSHORE is 0.167 ± 0.138n/m3(Zhao et al.,2014,
Marine Pollution Bulletin, 86,562-568), micro- plastics are acquired using trawling, micro- plastics are easily adsorbed on Buddhist nun
It is online without being enriched to planktonic organism on Long Wangsibi, it, can also even if a other error because plastics total amount micro- in seawater is less
The fluctuation that micro- plastics total amount can be caused big.
Utility model content
The shortcomings that for the above-mentioned prior art or deficiency, the technical problem to be solved by the present invention is to provide one kind to be applicable in
In the micro- plastics of surface water acquire and collecting efficiency is high micro- plastics sampling column and micro- plastics acquisition device.
In order to solve the above technical problems, the utility model has following constitute:
Micro- plastics sampling column, which is characterized in that including main column, filtering net plate, upper end cover and lower cover, the upper end cover and
Lower cover is removably attachable to the top and bottom of the main column, forms a cylindrical inner cavity, the upper end cover is under
Sample inlet and sample outlet are respectively equipped on end cap, for being connected to the outside of the inner cavity and micro- plastics sampling column, the filter
The bottom of the inner cavity is arranged in mesh sheet, close to the sample outlet.
Further, the internal diameter of the main column is 20-80mm.
Further, the length of the main column is 20-120mm.
Further, micro- plastics sampling column, which is characterized in that the aperture of the filtering net plate is 10-300 μm.
Further, the internal chamber wall of the main column is equipped with the groove for installing the filtering net plate, and the filtering net plate is logical
Pressure ring is crossed to be movably arranged on the groove.
Micro- plastics acquisition device, including micro- plastics sampling column, surface layer water sampler and suction pump.
Further, the water inlet of the suction pump connects surface layer water sampler, and the surface layer water sampler is placed in water
Surface layer acquires micro- plastics of surface water, and the water outlet of the suction pump connects the sample inlet of micro- plastics sampling column,
By the suction pump by the superficial water samplers sample to water sample be transported in micro- plastics sampling column.
Further, the surface layer water sampler includes sampling container, buoyant device and adjuster, in the sampling container
It is provided with sampling pipe, thief hatch is provided on the sampling pipe, one end of sampling pipe is connected by the water inlet of water pipe and water pump,
The sampling container is connected to the buoyant device by the adjuster, and adjusts the sampling container by the adjuster
Sampling depth.
Further, micro- plastics acquisition device further includes flowmeter, switching valve and electrical control system, the flow
Meter is connect with the sample outlet of micro- plastics sampling column, and the switching valve is set to the sample inlet of micro- plastics sampling column
Between the water outlet of the suction pump, the electrical control system is connect with the water pump, for providing for the suction pump
Electric power, and control the start and stop of the suction pump.
It is described using the digestion instrument in situ including casing and upper shield based on the digestion procedure in situ of micro- plastics sampling column
The diameter and height of casing are slightly larger than the diameter and height of the main column, and the upper shield is placed into described for the main column
Described sleeve pipe is sealed after stainless steel sleeve pipe, is included the following steps:
The main column for completing sampling is put into the casing of the digestion instrument in situ；
Oxidizing agent solution is added into the inner cavity of the main column, so that the oxidizing agent solution at least covered in main column
Filtering net plate in chamber covers upper shield sealing；
Stand preset time；
It is multiple that the main column is cleaned using ultrapure water；
Dry the main column.
Further, the digestion procedure in situ based on micro- plastics sampling column, the mistake that the oxidizing agent solution is 35%
Hydrogen peroxide solution.
The utility model effectively can be enriched with and be analyzed to plastics micro- in water body；It is adopted using micro- plastics acquisition device
Collect micro- plastics in surface water (including Marine water and surface water body), sampling column is in air-tight state in sampling process
In, bioaccumulation efficiency is greatly improved, ensure that the reliability and accuracy of data.The utility model is examined compared with conventional methods such as trawlnets
The precision of micro- plastics improves the 1-2 order of magnitude out.
Detailed description of the invention
By reading a detailed description of non-restrictive embodiments in the light of the attached drawings below, the application's is other
Feature, objects and advantages will become more apparent upon:
Fig. 1: the utility model is used to acquire the sampling column structure chart of micro- plastics in water body；
Fig. 2: longitudinal sectional view of the sampling column of micro- plastics as shown in Figure 1 along the direction B-B；
Fig. 3: the schematic diagram of micro- plastics acquisition device based on micro- plastics sampling column shown in FIG. 1；
Fig. 4: the schematic diagram of surface layer water sampler；
Fig. 5: the standard PP spectrogram corresponding diagram in the Raman spectrum and database of the laboratory sample collected of embodiment 2；
Fig. 6: the grading analysis statistical results chart based on Raman image figure shown in Fig. 5；
Specific embodiment
Make furtherly below with reference to technical effect of the attached drawing to the design of the utility model, specific structure and generation
It is bright, to be fully understood from the purpose of this utility model, feature and effect.
As shown in Figure 1 and Figure 2, what is provided in an embodiment of the present invention is used to acquire adopting for the micro- plastics of water body
Sample column 1, including main column 11, filtering net plate 15, upper end cover 12 and lower cover 13, the upper end cover 12 and lower cover 13 are detachable
The top and bottom for being connected to the main column 11, a cylindrical inner cavity is formed, on the upper end cover 12 and lower cover 13
It is respectively equipped with sample inlet 17 and sample outlet 18, for being connected to the outside of the inner cavity and micro- plastics sampling column, the strainer
The bottom of the inner cavity is arranged in piece 15, close to the sample outlet 18.
Upper end cover 12, lower cover 13 and main column 11 are detachably connected that there are many connection types it can be selected that in principle
As long as can satisfy the sealing effect of sampling column.Thread connecting mode: it is equipped in the outer wall of 11 upper and lower ends of main column outer
Helicitic texture, upper end cover 12 are equipped with internal thread structure, the internal thread structure of 12 lower end of upper end cover and the outer spiral shell of 11 upper end of main column
The connection of line structure matching, the internal thread structure of 13 upper end of lower cover match connection with the external thread structure of 11 lower end of main column.Card
Detain connection type: the upper end of the outer wall setting buckle structure of 11 upper and lower ends of main column, 12 lower end of upper end cover and lower cover 13 is set
Structure can be scratched with the card of 11 upper end of main column with the matched card slot of 11 buckle structure of main column, the card slot of 12 lower end of upper end cover by setting
Matching connection, the card slot of 13 upper end of lower cover can match connection with the buckle structure of 11 lower end of main column.
The internal diameter of the main column 11 is 20-80mm.The length of main column 11 is 20-120mm.Liquid be free to lead to
The main column 11 is crossed, main column 11 will use oxidant immersion in subsequent digestion process, and 11 internal diameter of main column selects simultaneously
Non- to be the bigger the better, the more big required oxidant of internal diameter is more, in a kind of embodiment of the application, the selection of 11 internal diameter of main column
66mm, length select 100mm for preferable set-up mode.
Groove 14 is set on internal chamber wall at the main column 11 from top to bottom 80mm, for installing filtering net plate 15.Filtering net plate 15 is logical
Pressure ring 16 is crossed to be movably arranged on the groove 14.Pressure ring 16 plays fixed function to filtering net plate 15, prevents filtering net plate 15 from adopting
Positional shift in sample or digestion process.The aperture of filtering net plate 15 is 10-300 μm, and the aperture of general micro- plastics is greater than in the application
The aperture (10-300 μm) of filtering net plate 15, the water sample with micro- plastics are filtered through filter net sheet 15, and micro- plastics can stay in filtering net plate
On 15.Preferably, the diameter of filtering net plate 15 is 66mm.
As shown in Figure 3, Figure 4, a kind of embodiment of the application provides a kind of for acquiring the acquisition device of the micro- plastics of water body,
Including micro- plastics sampling column 1, surface layer water sampler 3 and suction pump 4.The water inlet of suction pump 4 connects the surface layer water sampler
3, the water outlet of suction pump 4 connects the sample inlet 17 of micro- plastics sampling column 1.Since micro- plastics float on water surface, such as
Fruit sample level is too deep then to collect less than micro- plastics.Surface layer water sampler 3 is placed in water body surface layer, and the position of water harvesting layer will control
When convenient for acquiring micro- plastics of surface water.The collected water sample of surface layer water sampler 3 can be transported to by suction pump 4
In micro- plastics sampling column 1.
Surface layer water sampler 3 includes sampling container 31, buoyant device 34 and adjuster 32, is provided with and adopts in sampling container 3
Sample pipe 33, thief hatch is provided on the sampling pipe 33, and one end of sampling pipe 33 is connected by the water inlet of water pipe and suction pump 4
It connects, the sampling container 31 is connected to the buoyant device 34 by the adjuster 32, and adjusts sampling by adjuster 32
The sampling depth of container 3.The quantity of thief hatch has multiple, is distributed in the tube wall surrounding of sampling pipe 33.Thief hatch is placed in superficial water
Under body, water sample can be entered in sampling container 3 by thief hatch.Water sample is being taken out after entering sampling container 3 by sampling pipe 33
It is pumped under the action of water pump 4.In an embodiment of the present invention, adjuster is connected in the upper end of sampling pipe 33
32, the both ends of adjuster 32 have been symmetrically arranged buoyant device 34 --- buoyant spheres.For guarantee micro- plastics collecting quantity and
Quality needs to guarantee the depth of water harvesting layer.Adjuster 32 adjusts the position of buoyant device 34 by moving up and down in sampling pipe 33,
Ensure water harvesting layer 0-5cm below water body surface layer.Wherein, the shape of buoyant device 34 is unrestricted, as long as can be surface layer hydromining
Sample device 3 generates buoyancy.
Micro- plastics acquisition device further includes electrical control system 2, switching valve 5 and flowmeter 6, the electrical control system 2
It is connect with the suction pump 4, for providing electric power for the suction pump 4, and controls the start and stop of the suction pump 4.Electrical equipment control
System 2 is connect with external power supply, is placed in land.The run switch with electrical control system 2 is turned on the power switch, indicator light is bright
It rises, micro- plastics acquisition device is started to work.Switching valve 5 be set to micro- plastics sampling column 1 sample inlet 17 and the pumping
Between the water outlet of water pump 4, switching valve 5 plays the role of being vented and adding drinking-water.When suction pump 4 is started to work, if suction pump 4
In contain air, may result in can not go up water, switching valve 5 before suction pump 4 works to suction pump 4 fill diversion, will draw water
Air discharge in pump 4 is clean, and suction pump 4 can work normally.The lower cover 13 of micro- plastics sampling column 1 is connect with flowmeter 6
The inner wall at place is equipped with internal thread structure, herein and the sample outlet 18 of micro- plastics sampling column 1.It is matched and is connected by helicitic texture
Micro- plastics sampling column 1 and flowmeter 6 make device realize sealing.Flowmeter 6 can control the sample streams of micro- plastics sampling column 1
Amount, it is preferred that the flow that draws water of suction pump 4 is 2.4m3/h.Water sample constantly enters the inner chamber body of micro- plastics sampling column 1, micro- modeling
Material can be enriched on the filtering net plate 15 of 11 lower end of main column.
Using above-mentioned micro- plastics acquisition device, micro- plastic sample in water body is acquired by multiple groups embodiment, and to being adopted
Micro- plastic grain of collection carries out the analysis work such as technology and feature record.
Embodiment one
Acquire the design parameter of water body example are as follows: certain sea area seawater；Sample duration: 100min；Adopt water volume: 1.630m3。
This acquisition sample record is ES01.
It is in micro- plastic analysis identification work to pass that micro- plastics in collected ES01 sample are separated with other impurity
Important step.Therefore it needs the micro- plastics sampling column 1 for being enriched the micro- plastic sample of seawater carrying out resolution processing in situ.Seawater
In containing the organic matters such as algae, need to remove these organic matters before carrying out micro- plastics identification.In the utility model embodiment
Based on the digestion procedure in situ of micro- plastics sampling column, it is used as and is disappeared using stainless steel sleeve pipe (with matching stainless steel upper shield)
Device is solved, the diameter and height of selected stainless steel sleeve pipe are slightly larger than the diameter and height of main column 11.
Digestion procedure in situ is as described below:
The micro- plastics sampling column 1 disassembly upper end cover 12 and lower cover 13 of sampling will be completed, only stays main column 11 to be put into stainless
In steel sleeve；
The hydrogenperoxide steam generator that 50ml concentration is 35% is added into the inner cavity of main column 11, and it is close to cover stainless steel upper shield
Envelope；Hydrogen peroxide is a kind of strong oxidizer, can clear up the organic substances such as the algae on filtering net plate 15；
It stands for 24 hours, carries out digestion process sufficiently；
Main column 11 is taken out, is cleaned main column more than 11 times using ultrapure water, gets rid of the dioxygen remained on filtering net plate 15
Water；
Main column 11 after cleaning is put into 45 ° of insulating boxs, main column 11 is dried.Hydrogen peroxide can sufficiently decompose sample
Organic matter in product, and micro- plastics of relative inertness can be retained.
In order to micro- plastics qualitative, quantitative in collected sample analysis, need to identify micro- plastics.It is right
Micro- plastics are divided into two step of visual assessment and instrumental to the identification of micro- plastics.Visual assessment is using stereomicroscope to doubtful
Micro- plastic grain carry out count and feature record etc. work, this step can only often identify doubtful micro- plastic grain, also
Need can excessively subsequent instrumental step be corrected.Instrumental uses micro ft-ir spectroscopy instrument (Nicolet iN 10)
Accurate identification is carried out to the chemical structure of doubtful micro- plastic grain, judges whether it is plastic material and determines its specific polymerization
Species.Following table is the change using micro ft-ir spectroscopy instrument to doubtful micro- plastic grain of collected micro- plastic sample ES01
Learn the comparative analysis situation of structure and micro- plastic components (polyethylene terephthalate (PET), polyethylene (PE) etc.):
Table 1: micro- plastic sample ES01 infrared spectrometer (Nicolet iN 10) analyzes data
It can see from the data in table, in micro- collected micro- plastic sample ES01 of plastics acquisition device institute, there is 12
Sample identifies that shape is similar to the shape of micro- plastics by visual observation, is identified by micro ft-ir spectroscopy instrument, finds these samples
In the chemical structure of doubtful micro- plastic grain and the polymer architecture of micro- plastics have 50% or more, some are even up to 90% or more
Similarity, can thus be concluded that in these samples collected and to contain micro- plastics really.
Wherein, in the present embodiment micro- micro- plastics of plastic sample ES01 kind concentrations: 7.35/m3.Contemporary literature report
The micro- plastics concentration level of road China Seas and vicinity: 0.167 ± 0.138n/m3(Zhao et al.,2014,Marine
Pollution Bulletin,86,562-568).The utility model detects micro- plastics concentration and is higher by 44 times than document report, says
Bright the utility model can effectively be enriched with plastics micro- in water body；Surface water is acquired using micro- plastics sampling apparatus
Micro- plastics in (including Marine water and surface water body), sampling column are in sealed shape in sampling process and in digestion process
In state, bioaccumulation efficiency is greatly improved, ensure that the reliability and accuracy of data；Resolution processing in situ is directly in sampling column
It carries out, does not need an enriched sample and be first transferred out to clear up again, reduce error, and save pre-treatment time, excellent effect.
The utility model patent improves the 1-2 order of magnitude compared with the conventional methods such as trawlnet detection precision.
Embodiment two
Acquire the design parameter of water body example are as follows: certain laboratory tap water acquires water body volume 50L, this acquisition sample
It is recorded as ES02.
Tap water is injected in experiment pool, and polypropylene (PP) particle of a little 100 μ m diameter or so is added, uses micro- plastics
Acquisition device acquires micro- plastic grain in experiment pool, and the aperture of filtering net plate 15 selects 20 μm.Because being substantially free of in tap water
There are the organic matters such as algae, therefore do not need resolution processing, in the present embodiment, resolution step can be omitted.
After sampling, the filtering net plate 15 in main column 11 is removed, places and is dried in 45 DEG C of baking ovens, then directly divided
Analysis identification.
Instrumental uses Raman spectrometer (LabRAM XploRA PLUS), and excitation wavelength is 532nm and 785nm, object
Mirror: 50 × LWD.Raman spectrum is as fingerprint chromatogram, it is possible to authenticate different types of polymer, by filter membrane carry out Raman at
Picture can know distribution and the dimension information of particle.
As shown in figure 5, the standard PP in the Raman spectrum and database of the present embodiment ES02 laboratory sample collected is composed
Figure corresponding diagram.
Particulate matter statistical analysis:
Image is converted by black and white by system software first, as shown in Figure 6.Then grading analysis is executed, is
The place of grain is labeled color；It has good positioning after particle, the dimension information of partial size (etc. specific surface areas diameter) can be provided.At this
In analysis, 53 particles are found altogether, the diameter of most of particle is at 100 μm hereinafter, biggish particle is up to 400 μm or so.
The present embodiment can illustrate the acquisition that can simulate micro- plastics in laboratory conditions using micro- plastics acquisition device
Situation, micro- plastics acquisition device are effectively enriched micro- plastics in tap water water sample.
Above embodiments are only to illustrate the technical solution of the utility model and non-limiting, reference only to preferred embodiment pair
The utility model is described in detail.Those skilled in the art should understand that can be to the technology of the utility model
Scheme is modified or equivalent replacement, without departing from the spirit and scope of the technical scheme of the present invention, should all cover in this reality
With in novel scope of the claims.
Claims (8)
1. micro- plastics sampling column, which is characterized in that including main column, filtering net plate, upper end cover and lower cover, the upper end cover is under
End cap is removably attachable to the top and bottom of the main column, forms a cylindrical inner cavity, the upper end cover and lower end
It covers and is respectively equipped with sample inlet and sample outlet, for being connected to the outside of the inner cavity and micro- plastics sampling column, the strainer
Piece setting is in the inner cavity, close to the sample outlet.
2. micro- plastics sampling column according to claim 1, which is characterized in that the internal diameter of the main column is 20-80mm.
3. micro- plastics sampling column according to claim 1, which is characterized in that the length of the main column is 20-120mm.
4. micro- plastics sampling column according to claim 1, which is characterized in that the aperture of the filtering net plate is 10-300 μm.
5. micro- plastics sampling column according to claim 1, which is characterized in that the internal chamber wall of the main column is equipped with for pacifying
The groove of the filtering net plate is filled, the filtering net plate is movably arranged on the groove by pressure ring.
6. micro- plastics acquisition device, which is characterized in that including as described in any one of claims 1 to 5 micro- plastics sampling column,
Surface layer water sampler and suction pump, the water inlet of the suction pump connect surface layer water sampler, and the superficial water sampling is placed in
Water body surface layer, acquires micro- plastics of surface water, and the sampling that the water outlet of the suction pump connects micro- plastics sampling column enters
Mouthful, by the suction pump by the superficial water samplers sample to water sample be transported in micro- plastics sampling column.
7. micro- plastics acquisition device according to claim 6, which is characterized in that the surface layer water sampler includes that sampling is held
Device, buoyant device and adjuster are provided with sampling pipe in the sampling container, thief hatch are provided on the sampling pipe, sample
One end of pipe is connected by the water inlet of water pipe and suction pump, and the sampling container is connected to the buoyancy by the adjuster
Device, and adjust by the adjuster sampling depth of the sampling container.
8. micro- plastics acquisition device according to claim 6, which is characterized in that micro- plastics acquisition device further includes stream
Meter, switching valve and electrical control system, the flowmeter are connect with the sample outlet of micro- plastics sampling column, the conversion
Valve is set between the sample inlet of micro- plastics sampling column and the water outlet of the suction pump, the electrical control system with
The suction pump connection, for providing electric power for the suction pump, and controls the start and stop of the suction pump.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109506984A (en) * | 2018-09-27 | 2019-03-22 | 蔡明红 | Micro- plastics sampling column, micro- plastics acquisition device and digestion procedure in situ |
| CN113758875A (en) * | 2021-08-30 | 2021-12-07 | 江苏天瑞仪器股份有限公司 | Ball valve passage structure for underground water in-situ detection device |
| CN113777082A (en) * | 2021-08-30 | 2021-12-10 | 江苏天瑞仪器股份有限公司 | Groundwater normal position detection device with more than anticipated velocity of flow |
| RU210299U1 (en) * | 2021-12-29 | 2022-04-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | DEVICE FOR STATIONARY SAMPLING OF MICROPLASTICS IN WATER COURSES |
| RU2782144C1 (en) * | 2021-12-29 | 2022-10-21 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | Method for sampling microplastics in water courses |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109506984A (en) * | 2018-09-27 | 2019-03-22 | 蔡明红 | Micro- plastics sampling column, micro- plastics acquisition device and digestion procedure in situ |
| CN113758875A (en) * | 2021-08-30 | 2021-12-07 | 江苏天瑞仪器股份有限公司 | Ball valve passage structure for underground water in-situ detection device |
| CN113777082A (en) * | 2021-08-30 | 2021-12-10 | 江苏天瑞仪器股份有限公司 | Groundwater normal position detection device with more than anticipated velocity of flow |
| CN113777082B (en) * | 2021-08-30 | 2024-07-16 | 江苏天瑞仪器股份有限公司 | Groundwater normal position detection device with expected velocity of flow is above |
| CN113758875B (en) * | 2021-08-30 | 2024-08-02 | 江苏天瑞仪器股份有限公司 | Ball valve channel structure for underground water in-situ detection device |
| RU210299U1 (en) * | 2021-12-29 | 2022-04-06 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | DEVICE FOR STATIONARY SAMPLING OF MICROPLASTICS IN WATER COURSES |
| RU2782144C1 (en) * | 2021-12-29 | 2022-10-21 | Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" | Method for sampling microplastics in water courses |
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| GR01 | Patent grant |