CN209338258U - A kind of device of Processing Ag ammonia waste water - Google Patents

A kind of device of Processing Ag ammonia waste water Download PDF

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Publication number
CN209338258U
CN209338258U CN201821658253.8U CN201821658253U CN209338258U CN 209338258 U CN209338258 U CN 209338258U CN 201821658253 U CN201821658253 U CN 201821658253U CN 209338258 U CN209338258 U CN 209338258U
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CN
China
Prior art keywords
pump
membrane separator
settling vessel
connects
waste water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201821658253.8U
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Chinese (zh)
Inventor
张光辉
徐晓天
郭美彤
樊伟
顾平
侯立安
董丽华
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Tianjin University
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Tianjin University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin University filed Critical Tianjin University
Priority to CN201821658253.8U priority Critical patent/CN209338258U/en
Application granted granted Critical
Publication of CN209338258U publication Critical patent/CN209338258U/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Abstract

The utility model discloses a kind of device of Processing Ag ammonia waste water, including intake pump, water inlet of the waste pipe through intake pump connection settling vessel top, the supernatant of settling vessel connects the water inlet on membrane separator top through intermediate lift pump, and the hollow-fibre membrane in membrane separator is connect by outlet pipe with fluid flowmeter, water outlet pump;Precipitating reagent adds the feeding opening that pump connects settling vessel top by chemical feed pipe, and PAC adds the feeding opening that pump connects membrane separator top by chemical feed pipe;Aeration tube of the air blower through gas flowmeter junctional membrane separator bottom.Equipment operation is simple, and treatment effeciency is high.

Description

A kind of device of Processing Ag ammonia waste water
Technical field
The present invention relates to a kind of wastewater treatment equipments, are exactly a kind of devices of Processing Ag ammonia waste water.
Background technique
During chemical silvering, silver-colored ammonia is gradually reduced and fails, and generates silver-colored ammonia waste liquid, silver is mainly with [Ag (NH3)2]+ [Ag (NH3)]+Form exists.Soluble silver salt and collargol are easily absorbed by blood of human body, generate serious prestige to human health The side of body.Sulphide precipitation is common silver-containing waste water processing method, but sulfide may excessively generate colloid or more sulphur networks Object is closed, is not suitable for selection critical point in engineer application and adds, cause the concentration of mercury out not up to standard.
Summary of the invention
The purpose of this utility model is, in order to improve the treatment effeciency of silver-colored ammonia waste water, proposes a kind of efficient silver-colored ammonia waste water Processing unit, using contact break-precipitating-united method of absorption-UF membrane to realize the qualified discharge of silver-colored ammonia waste water and returning for silver It receives.
To solve problems of the prior art, the purpose of this utility model can be accomplished by the following way: a kind of Silver-colored ammonia waste water processing unit, including intake pump, waste pipe through intake pump connection settling vessel top water inlet, settling vessel it is upper Clear liquid connects the water inlet on membrane separator top through intermediate lift pump, and the hollow-fibre membrane in membrane separator passes through outlet pipe and liquid Flowmeter body, water outlet pump connection;Precipitating reagent adds the feeding opening that pump connects settling vessel top by chemical feed pipe, and it is logical that PAC adds pump Cross the feeding opening on chemical feed pipe connection membrane separator top;Aeration tube of the air blower through gas flowmeter junctional membrane separator bottom.
The settling vessel top is installed by blender.
The utility model has the advantages that
The utility model has the following advantages compared with prior art: equipment operation is simple, and treatment effeciency is high.Vulcanized sodium and trip From silver ion form silver sulfide precipitating, due to the adsorbable remaining Trace Silver of Powdered Activated Carbon, by Middle hollow fiber membrane, Removal efficiency can be improved.The utility model wastewater treatment equipment comes using contact break-precipitating-united method of absorption-UF membrane Remove the silver ion in desilver ammonia waste water.To make the processing up to standard of silver-colored ammonia waste water and discharge, while realizing the recycling of silver.
Detailed description of the invention
Fig. 1 is the utility model structure diagram.
1- intake pump;2- settling vessel;3- blender;4- intermediate lift pump;5- membrane separator;6- hollow-fibre membrane;7- liquid Flowmeter body;8- water outlet pump;9- aeration tube;10- gas flowmeter;11- air blower;12- precipitating reagent storage tank;13- precipitating reagent is thrown Add pump;14-PAC storage tank;15-PAC adds pump;16-PAC tank mixer.
Specific embodiment
As follows referring to attached drawing 1: a kind of silver-colored ammonia waste water processing unit of continuous operation, it is heavy that waste pipe is connected through intake pump 1 The water inlet on 2 top of shallow lake device, the supernatant of settling vessel 2 connect the water inlet on 5 top of membrane separator, film point through intermediate lift pump 4 It is connect by outlet pipe with fluid flowmeter 7, water outlet pump 8 from the hollow-fibre membrane 6 in device 5;Precipitating reagent adds pump 13 by adding Pencil connects the feeding opening on 2 top of settling vessel, and PAC adds the feeding opening that pump 15 connects 5 top of membrane separator by chemical feed pipe;Drum Blower 11 connects the aeration tube 9 of 5 bottom of membrane separator through gas flowmeter 10;2 top of settling vessel is installed by blender 3.
Settling vessel is Organic glass column,Blender is stainless steel material, and stirring intensity is 182s-1;Membrane separator is Organic glass column,Inside is equipped with 1 hollow-fibre membrane, nominal pore size It is 0.22 μm, effective area 0.5m2.Intake pump is pipeline pump, and vulcanized sodium adds pump, PAC adds pump and water outlet pump is compacted Dynamic pump, fluid flowmeter and gas flowmeter are spinner flowmeter.Device using PLC (programmable controller control) control, Fully automatic operation, PLC are programmed using general technology.Device be daily continuous operation 12h, wherein settling vessel be 7 intermittent water inflows and Water outlet, by Liquid level;Membrane separator is that interval is discharged, and in every 10 minutes circulations, is discharged 8 minutes, sky aeration 2 minutes.
Test result shows: the dosage of vulcanized sodium is 6.5mg/L, and the dosage of active carbon is 0.2g/L, and settling vessel is anti- 20min between seasonable, when precipitating 5min, the silver concentration of UF membrane water outlet is being 0.3mg/L, removal rate 98%, and water outlet reaches " dirt Water comprehensive discharge standard " (GB 8978-1996) requirement, provide the new and effective device of one kind for the processing of silver-colored ammonia waste water.

Claims (2)

1. a kind of device of Processing Ag ammonia waste water, including intake pump, which is characterized in that waste pipe connects settling vessel through intake pump The water inlet on top, the water inlet of the supernatant of settling vessel through intermediate lift pump connection membrane separator top, in membrane separator Hollow-fibre membrane is connect by outlet pipe with fluid flowmeter, water outlet pump;Precipitating reagent adds pump and connects settling vessel by chemical feed pipe The feeding opening on top, PAC add the feeding opening that pump connects membrane separator top by chemical feed pipe;Air blower connects through gas flowmeter Connect the aeration tube of membrane separator bottom.
2. a kind of device of Processing Ag ammonia waste water according to claim 1, which is characterized in that the settling vessel top installation Blender.
CN201821658253.8U 2018-10-12 2018-10-12 A kind of device of Processing Ag ammonia waste water Expired - Fee Related CN209338258U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821658253.8U CN209338258U (en) 2018-10-12 2018-10-12 A kind of device of Processing Ag ammonia waste water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821658253.8U CN209338258U (en) 2018-10-12 2018-10-12 A kind of device of Processing Ag ammonia waste water

Publications (1)

Publication Number Publication Date
CN209338258U true CN209338258U (en) 2019-09-03

Family

ID=67745470

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201821658253.8U Expired - Fee Related CN209338258U (en) 2018-10-12 2018-10-12 A kind of device of Processing Ag ammonia waste water

Country Status (1)

Country Link
CN (1) CN209338258U (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205842A (en) * 2018-10-12 2019-01-15 天津大学 A kind of processing method of silver ammonia waste water

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109205842A (en) * 2018-10-12 2019-01-15 天津大学 A kind of processing method of silver ammonia waste water

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20190903

Termination date: 20201012

CF01 Termination of patent right due to non-payment of annual fee