CN209271194U - A kind of regenerator shutdown anti-corrosion system - Google Patents

A kind of regenerator shutdown anti-corrosion system Download PDF

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Publication number
CN209271194U
CN209271194U CN201821986676.2U CN201821986676U CN209271194U CN 209271194 U CN209271194 U CN 209271194U CN 201821986676 U CN201821986676 U CN 201821986676U CN 209271194 U CN209271194 U CN 209271194U
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regenerator
shut
valve
section
hot
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孟春强
邢德山
程文煜
许芸
樊腾飞
谷建功
柴晓琴
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Guodian Environmental Protection Research Institute Co Ltd
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Guodian Environmental Protection Research Institute Co Ltd
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Abstract

The utility model relates to a kind of regenerators to shut down anti-corrosion system, be divided into charge section, bringing-up section, segregation section, cooling section and unloading part from top to bottom inside regenerator;It heats pars infrasegmentalis and is equipped with hot-wind inlet, top is equipped with hot-blast outlet, the first thermometer is equipped at hot-wind inlet, segregation section side is equipped with parsing gas vent, second temperature meter is equipped with inside segregation section, parsing gas vent is connect by parsing gas pipeline with resource utilization device, the first shut-off valve and the second shut-off valve are successively arranged along gas flow direction on the parsing gas pipeline, parsing gas pipeline is connected with compressed air pipe between the first shut-off valve and the second shut-off valve, third shut-off valve is equipped between compressed air pipe and parsing gas pipeline, gas pipeline position between the second shut-off valve and resource utilization device is parsed to connect by outer discharge pipe with chimney, outer discharge pipe is equipped with the 4th shut-off valve, the utility model can be realized after a shutdown, regenerator internal residual is parsed into gas clean-up, prevent regenerator from corroding.

Description

A kind of regenerator shutdown anti-corrosion system
Technical field
The utility model relates to a kind of regenerators to shut down anti-corrosion system, and in particular to one kind is absorption with carbon base catalyst Regenerator and a kind of shutdown operation method in the boiler smoke combined desulfurization and denitration device of agent and catalyst, belong to environment Field of engineering technology.
Background technique
Charcoal base catalysis method flue gas desulfurization and denitrification technical principle are as follows: flue gas under the absorption and catalytic action of carbon base catalyst, SO in flue gas2And O2And H20, which reacts, generates H2SO4, H2SO4It is adsorbed in carbon base catalyst micropore;Charcoal base is utilized simultaneously The catalytic performance of catalyst, NOx and dilution ammonia occur catalytic reduction reaction and generate N in flue gas2, the desulfurization for realizing flue gas is de- Nitre, the carbon base catalyst after adsoption catalysis reaction recycle after being regenerated.Dilution ammonia is injected in desulfuring and denitrifying apparatus, is used It is N by the NOx conversion in flue gas in the denitration reaction for realizing gas cleaning process2
Regenerative process is heated, following chemical reaction occurs for the ADSORPTION STATE sulfuric acid for being adsorbed on carbon base catalyst micropore:
H2SO4 H2O → SO3+2H2O
SO3+1/2C → SO2+1/2CO2
Chemically equation can be seen that in parsing gas containing SO2, a small amount of SO3 and water, and condense shape under cryogenic At diluted acid, and regenerator is steel component, is easily corroded.Carbon base catalyst (or activated coke, active carbon) gas cleaning skill In art, regenerator is main device, and structure is larger, belongs to permanent component, and corrosion phenomenon such as occurs, especially generation inner tube The workload of the corrosion of journey, reparation is very big.
When regenerator runs well, parsing gas is in 400 DEG C or more of hot environment, much higher than the moisture condensation of parsing gas Temperature.After shutdown, temperature is stepped down to room temperature in regenerator, if there is remaining parsing gas, will form the corrosion of acid dew again Raw tower member.
The country with carbon base catalyst (or activated coke, active carbon) be adsorbent, catalyst flue gas desulfurization and denitrification application in, Repeatedly occurs the case where main member pipe corrosion of regenerator operation carbon base catalyst tube side.Using heating regeneration technology Regenerator, the factor in addition to considering structure, parameter etc. also need to select reasonably to shut down operation program, guarantee after a shutdown The not remaining parsing gas of low temperature environment, prevent corrosion regenerator.
Utility model content
In order to solve the problems in the existing technology, provide one kind may be implemented in stopping process and stops the utility model After machine, regenerator internal residual is parsed into gas clean-up, effectively prevent regenerator corrosion of component.
In order to achieve the above object, the utility model proposes technical solution are as follows: a kind of regenerator shuts down anti-corrosion system, Charge section, bringing-up section, segregation section, cooling section and unloading part are divided into inside the regenerator from top to bottom;The bringing-up section Inside is equipped with heating tube, and the heating tube upper and lower ends are connected to charge section and segregation section respectively, and cooling tube is equipped in cooling section, Cooling tube upper and lower ends are connected to segregation section and unloading part respectively;The heating pars infrasegmentalis is equipped with hot-wind inlet, and top is equipped with heat Wind exports, and the first thermometer is equipped at hot-wind inlet, and the segregation section side is equipped with parsing gas vent, is equipped with inside segregation section Second temperature meter.
Be further designed to above-mentioned technical proposal: the hot-blast outlet is connect with hot air circulation blower air inlet, heat Wind circulating fan gas outlet is connect with heater air inlet, and heater air outlet is connect with hot-wind inlet.
The parsing gas vent is connect by parsing gas pipeline with resource utilization device, on the parsing gas pipeline The first shut-off valve and the second shut-off valve are successively arranged along gas flow direction.
The parsing gas pipeline is connected with compressed air pipe between the first shut-off valve and the second shut-off valve, and compression is empty Third shut-off valve is equipped between feed channel and parsing gas pipeline.
Parsing gas pipeline position between the second shut-off valve and resource utilization device passes through outer discharge pipe and chimney Connection, the outer discharge pipe are equipped with the 4th shut-off valve.
The cooling pars infrasegmentalis is equipped with cold air inlet, and top is exported equipped with cold wind, and cooling blower is equipped at cold air inlet.
It is equipped with partition along horizontal cross-section in the middle part of the charge section, the partition is equipped with blanking port.
The charge section two sides are symmetrically arranged with the first nitrogen inlet, and first nitrogen inlet is located at below partition, and first The 5th shut-off valve is equipped at nitrogen inlet.
The unloading part two sides are symmetrically arranged with the second nitrogen inlet, are equipped with the 6th shut-off valve at the second nitrogen inlet.
Above-mentioned regenerator shuts down the shutdown operation method of anti-corrosion system, includes the following steps:
Step 1: closing heater, no longer offer heat source heats carbon base catalyst, and hot air circulation blower operates normally, The conveying of carbon base catalyst operates normally in regenerator;
Step 2: when the detection temperature of the first thermometer is lower than 350 DEG C, and the second temperature meter detection of regenerator segregation section When temperature is lower than 150 DEG C, hot air circulation blower is closed, is stopped to regenerator air blast;
Step 3: closing the 6th shut-off valve, stop injecting nitrogen to regenerator cooling section;
Step 4: closing the 5th shut-off valve, stop injecting nitrogen to regenerator bringing-up section;
Step 5: stopping the operation of resource utilization device;
Step 6: opening the 4th shut-off valve on outer discharge pipe, the first shut-off valve on parsing gas pipeline, isolation are closed Regenerator and external connection;
Step 7: the second shut-off valve is closed, isolation resource utilization device and external connection;
Step 8: opening third shut-off valve, injecting compressed air purges pipeline inside, by remaining parsing gas It is discharged from chimney.
Step 9: stopping the transport of carbon base catalyst.
The invention has the benefit that
The utility model be prevent regenerator after stopping process or shutdown, prevent regenerator from corroding, after shutdown according to It is secondary first to stop heater, no longer carbon base catalyst is heated, weakens the generation of parsing gas until stopping.Hot air circulation during this Blower runs well, and gradually uniformly cooling regenerator, thermal stress bring carbon base catalyst caused by reduction inhomogeneous cooling is even are broken Damage, until dropping to 150 DEG C or less.The nitrogen of a heating section and a cooling section continues to inject, and carbon base catalyst is made to be in anaerobic shape always State, and the parsing gas gradually reduced is delivered to resource utilization unit.After satisfying the requirements, stop hot air circulation blower, so The shut-off valve on parsing gas pipeline is successively closed or opened afterwards, and introduces compressed air and is purged, and eliminates remaining parsing Gas prevents regenerator from corroding.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model embodiment.
In attached drawing, 1- hot air circulation blower;The first thermometer of 2-;3- heater;The 4th shut-off valve of 4-;5- first is turned off Valve;The second shut-off valve of 6-;7- third shut-off valve;8- cooling blower;The 5th shut-off valve of 9-;10- tube side;11- regenerator;12- Two thermometers;13- shell side;The 6th shut-off valve of 14-, the first nitrogen inlet of 15-, the second nitrogen inlet of 16-, 17- hot-wind inlet, 18- hot-blast outlet, 19- cold air inlet, the outlet of 20- cold wind, 21- charge section, 22- bringing-up section, 23- segregation section, 24- cooling section, 25- unloading part, 26- parse gas vent.
Specific embodiment
With reference to the accompanying drawing and specific embodiment the present invention is described in detail.
Embodiment
As shown in Figure 1, a kind of regenerator of the present embodiment shuts down anti-corrosion system, successively divide from top to bottom inside regenerator For charge section 21, bringing-up section 22, segregation section 23, cooling section 24 and unloading part 25;Heating tube, heating tube are equipped with inside bringing-up section 22 Upper and lower ends are connected to charge section 21 and segregation section 23 respectively, and cooling tube, cooling tube upper and lower ends difference are equipped in cooling section 24 It is connected to segregation section 23 and unloading part 25;22 lower part of bringing-up section is equipped with hot-wind inlet 17, and top is equipped with hot-blast outlet 18, and hot wind enters The first thermometer 2 is equipped at mouthfuls 17,23 side of segregation section is equipped with parsing gas vent 26, sets that there are four second inside segregation section 23 Thermometer 12, hot-blast outlet 18 are connect with 1 air inlet of hot air circulation blower, 1 gas outlet of hot air circulation blower and 3 air inlet of heater Mouth connection, 3 gas outlet of heater are connect with hot-wind inlet 17, and hot wind is in hot air circulation blower 1, heater 3,17 and of hot-wind inlet Circulation is formed between hot-blast outlet 18, and the hot wind of outflow bringing-up section 22 is recycled, is saved energy consumption.
It parses gas vent 26 in the present embodiment to connect by parsing gas pipeline with resource utilization device, utilization of resources dress It sets connection to recycle the SO2 and SO3 etc. that parse in gas, production sulfuric acid, sulphur etc. have the product of higher utility value, realize Resource utilization in flue gas after pollutant removing.
The first shut-off valve 5 and the second shut-off valve 6 are successively arranged along gas flow direction on parsing gas pipeline.Parse gas Pipeline is connected with compressed air pipe, compressed air pipe and parsing gas pipeline between the first shut-off valve and the second shut-off valve Between be equipped with third shut-off valve 7.It parses gas pipeline position between the second shut-off valve 7 and resource utilization device and passes through outer comb Road is connect with chimney, and outer discharge pipe is equipped with the 4th shut-off valve 4.
24 lower part of cooling section is equipped with cold air inlet 19 in the present embodiment, and top is equipped with cold wind outlet 20, at cold air inlet 19 Equipped with cooling blower 8.
When regenerator is run, carbon base catalyst enters regenerator from charge section 21, is equipped in the middle part of charge section along horizontal cross-section Partition, partition are equipped with blanking port, enter charge section bottom through blanking port 20, carbon base catalyst can be made even into bringing-up section 22, it will not be accumulated in 22 inlet of bringing-up section, facilitate being evenly heated for carbon base catalyst, carbon base catalyst enters heating tube 22 And walk tube side 10(heating tube) in heating, the shell side 13 of the heated pipe of the hot wind that hot-wind inlet 17 is passed through, and to the charcoal for walking tube side Base catalyst is heated, and is then flowed out through hot-blast outlet 18, and hot wind is not contacted with carbon base catalyst in heating process, reduces charcoal Pollution, corrosion of base catalyst etc.;Segregation section 23 is fallen into after carbon base catalyst heating and parses the gases such as SO2, enters back into cooling The tube side (cooling tube) of section 24 is cooling, and the cold wind that cold air inlet 19 is passed through enters the shell side 13 of cooling section, to carbon base catalyst into Row cooling, after from 20 discharge of cold wind outlet, enter unloading part 25 after carbon base catalyst is cooling.
It is symmetrically arranged with the first nitrogen inlet 15 in 21 two sides of charge section in the present embodiment, the first nitrogen inlet 15 is located at partition Lower section is equipped with the 5th shut-off valve 9 at the first nitrogen inlet.25 two sides of unloading part are symmetrically arranged with the second nitrogen inlet 16, the second nitrogen The 6th shut-off valve 14 is equipped at gas entrance 16.
The nitrogen that the first, second nitrogen inlet is passed through when regenerator is run can be used as delivery gas and carbon base catalyst enters Tube side (heating tube and cooling tube) guarantees that carbon base catalyst is in positive pressure oxygen-free environment, and the solution that will be parsed in heating process Gassing body is transported to resource utilization device.The nitrogen being passed through may further be used to maintain necessary positive pressure in reactor, prevent all Air caused by factor enters regenerator, guarantees that carbon base catalyst is in oxygen-free environment.
To prevent parsing residual gas from corroding regenerator when the regenerator of the present embodiment, grasped using the shutdown of following steps Make:
Step 1: closing heater 3, no longer offer heat source heats carbon base catalyst, and hot air circulation blower 1 is normally transported It goes, the conveying of carbon base catalyst operates normally in regenerator;
Step 2: when the detection temperature of the first thermometer 2 is lower than 350 DEG C, and the second temperature meter of regenerator segregation section 23 When 12 detection temperature are lower than 150 DEG C, hot air circulation blower 1 is closed, is stopped to regenerator air blast;
Step 3: closing the 6th shut-off valve 14, stop injecting nitrogen to regenerator cooling section 24;
Step 4: closing the 5th shut-off valve 9, stop injecting nitrogen to regenerator bringing-up section 22;
Step 5: stopping the operation of resource utilization device;
Step 6: opening the 4th shut-off valve 4 on outer discharge pipe, the first shut-off valve 5 on parsing gas pipeline is closed, every Exhausted regenerator and external connection;
Step 7: the second shut-off valve 6 is closed, isolation resource utilization device and external connection;
Step 8: opening third shut-off valve 7, pipeline inside is blown by compressed air pipe injecting compressed air It sweeps, remaining parsing gas is discharged from chimney.
Step 9: stopping the transport of carbon base catalyst.
The parsing gas of the regenerator discharge of the present embodiment is not provided with blower, will parse gas using the pressure of nitrogen and convey To resource utilization unit, simplifies system, investment reduction and reduce maintenance cost.Regenerator is in positive pressure environment, is compared to Subnormal ambient is easier to realize the oxygen-free environment still adhered in regenerator, air can be prevented from carbon base catalyst feed inlet and discharge Mouthful enter regenerator, can further prevent outside air from entering from because of gap caused by the factors such as manufacturing quality and construction quality Regenerator.
The utility model can have various suitable changes and variation, within the spirit and principle of the utility model institute Any modification, equivalent substitution, improvement and etc. of work, should be included within the scope of protection of this utility model.

Claims (9)

1. a kind of regenerator shuts down anti-corrosion system, it is characterised in that: be divided into charging inside the regenerator from top to bottom Section, bringing-up section, segregation section, cooling section and unloading part;Heating tube, the heating tube upper and lower ends point are equipped with inside the bringing-up section Be not connected to charge section and segregation section, be equipped with cooling tube in cooling section, cooling tube upper and lower ends respectively with segregation section and unloading part Connection;The heating pars infrasegmentalis is equipped with hot-wind inlet, and top is equipped with hot-blast outlet, is equipped with the first thermometer, institute at hot-wind inlet It states segregation section side and is equipped with parsing gas vent, be equipped with second temperature meter inside segregation section.
2. regenerator shuts down anti-corrosion system according to claim 1, it is characterised in that: the hot-blast outlet and hot air circulation Fan air inlet connection, hot air circulation blower gas outlet are connect with heater air inlet, and heater air outlet and hot-wind inlet connect It connects.
3. regenerator shuts down anti-corrosion system according to claim 2, it is characterised in that: the parsing gas vent passes through solution Analysis gas pipeline is connect with resource utilization device, is successively arranged the first shutdown along gas flow direction on the parsing gas pipeline Valve and the second shut-off valve.
4. regenerator shuts down anti-corrosion system according to claim 3, it is characterised in that: the parsing gas pipeline is first It is connected with compressed air pipe between shut-off valve and the second shut-off valve, the is equipped between compressed air pipe and parsing gas pipeline Three shut-off valves.
5. regenerator shuts down anti-corrosion system according to claim 4, it is characterised in that: the parsing gas pipeline is second Position is connect by outer discharge pipe with chimney between shut-off valve and resource utilization device, and the outer discharge pipe is equipped with the 4th shutdown Valve.
6. regenerator shuts down anti-corrosion system according to claim 1, it is characterised in that: the cooling pars infrasegmentalis is equipped with cold wind Entrance, top are exported equipped with cold wind, and cooling blower is equipped at cold air inlet.
7. regenerator shuts down anti-corrosion system according to claim 1, it is characterised in that: cut in the middle part of the charge section along level Face is equipped with partition, and the partition is equipped with blanking port.
8. regenerator shuts down anti-corrosion system according to claim 7, it is characterised in that: the charge section two sides are symmetrically arranged with First nitrogen inlet, first nitrogen inlet are located at below partition, and the 5th shut-off valve is equipped at the first nitrogen inlet.
9. regenerator shuts down anti-corrosion system according to claim 8, it is characterised in that: the unloading part two sides are symmetrically arranged with Second nitrogen inlet is equipped with the 6th shut-off valve at the second nitrogen inlet.
CN201821986676.2U 2018-11-29 2018-11-29 A kind of regenerator shutdown anti-corrosion system Active CN209271194U (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109289515A (en) * 2018-11-29 2019-02-01 国电环境保护研究院有限公司 A kind of regenerator shuts down anti-corrosion system and shutdown operation method
CN112957806A (en) * 2021-02-09 2021-06-15 深圳中广核工程设计有限公司 Bottom cleaning system and bottom cleaning method for inward-in and outward-out drum-shaped filter screen

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109289515A (en) * 2018-11-29 2019-02-01 国电环境保护研究院有限公司 A kind of regenerator shuts down anti-corrosion system and shutdown operation method
CN109289515B (en) * 2018-11-29 2024-01-19 国电环境保护研究院有限公司 Shutdown anti-corrosion system and shutdown operation method for regeneration tower
CN112957806A (en) * 2021-02-09 2021-06-15 深圳中广核工程设计有限公司 Bottom cleaning system and bottom cleaning method for inward-in and outward-out drum-shaped filter screen

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