CN209210893U - A kind of device extracting noble metal from dead catalyst - Google Patents

A kind of device extracting noble metal from dead catalyst Download PDF

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Publication number
CN209210893U
CN209210893U CN201821773336.1U CN201821773336U CN209210893U CN 209210893 U CN209210893 U CN 209210893U CN 201821773336 U CN201821773336 U CN 201821773336U CN 209210893 U CN209210893 U CN 209210893U
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acidleach
kettle
compartment
connecting tube
noble metal
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CN201821773336.1U
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Inventor
曹杰义
张燕
王立
周文茜
俞宏山
刘林
徐鹏
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Jinchuan Group Copper Gui Co ltd
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Jinchuan Group Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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Abstract

The utility model discloses a kind of from dead catalyst extracts the device of noble metal, belongs to precious metal hydrometallurgy field, solves the problems, such as that the existing extraction element rate of recovery is low.The utility model includes acidleach kettle, agitating paddle, vacuum pump, acid adding pipeline and discharge pipe, acidleach kettle top portion is equipped with feed opening, it further include fluid reservoir, air compressor and resin absorbing column group, fluid reservoir is full-closed structure, it is divided into left compartment and right compartment, it is connected between left compartment and right compartment by the second connecting tube, negative pressure filtration device is equipped in acidleach kettle, negative pressure filtration device is connected to left compartment, left upper compartment is connected with vacuum pump, left upper compartment is connected with air compressor, right upper compartment is equipped with ventilation pipe, right compartment is connected by the 5th connecting tube with resin absorbing column group, 5th connecting tube is equipped with peristaltic pump, resin absorbing column group is connected by return pipe with acidleach kettle, discharge pipe is located at acidleach bottom portion.The utility model can significantly improve the rate of recovery of noble metal.

Description

A kind of device extracting noble metal from dead catalyst
Technical field
The utility model belongs to precious metal hydrometallurgy field, and in particular to a kind of that noble metal is extracted from dead catalyst Device.
Background technique
Noble metal is widely used element in catalyst, mainly includes the elements such as Au Ag Pt Pd, rhodium, iridium, because its High value and rare attribute need to recycle noble metal therein after catalyst reaches service life failure.Useless catalysis The recovery method of agent is broadly divided into pyrogenic process and wet process two major classes, and pyrogenic process mainly includes melting concentration method, pyrogenic process chloridising and burning Method, wet process are then broadly divided into carrier dissolution method, active component dissolution method and complete molten method.
Current dead catalyst difficult to deal with is mainly with SiO2, α-Al2O3Or the mixture of the two is the automobile of matrix Tail-gas catalyst and petroleum catalyst.Pyrogenic process recycling dead catalyst has the advantages of high income, but pollute it is larger, and process route compared with Wet process is complicated, needs the higher production equipment of cost.Carrier dissolution method in wet process has metal recovery rate height, at low cost etc. excellent Point, but there are solution carrier ion concentration is higher, it is separated by solid-liquid separation difficult problem.Active component dissolution method in wet process is general Refer to the method for adding noble metal in the solution system catalyst-solvent of hydrochloric acid using one or more of oxidants, it will be expensive in acidleach kettle Metal leaches, and filter cloth is arranged in liquid storage pot bottom, filters leached mud, method reagent consumption is few, and cost recovery is low, but in leached mud Bullion content it is still higher, reach ignorable degree, noble metal leaching rate is generally below 95%.
Utility model content
The purpose of the utility model is to provide a kind of from dead catalyst extracts the device of noble metal, to solve existing extraction The device rate of recovery is low, is separated by solid-liquid separation difficult problem.
The technical solution of the utility model is: a kind of device extracting noble metal from dead catalyst, including acidleach kettle, stirs Paddle, vacuum pump, acid adding pipeline and discharge pipe are mixed, acidleach kettle top portion is equipped with feed opening, and acid adding pipeline is located at acidleach kettle top portion, stirs It mixes paddle and is located at acidleach kettle lower part, agitating paddle top is connected with stirring motor, further includes fluid reservoir, air compressor and resin adsorption Column group, fluid reservoir are full-closed structure, are divided into left compartment and right compartment, pass through the second connecting tube between left compartment and right compartment It is connected, the second connecting tube is equipped with compartment valve, and negative pressure filtration device is equipped in acidleach kettle, and negative pressure filtration device passes through first Connecting tube is connected to left compartment, and the first connecting tube is equipped with Filter valve, and left upper compartment passes through third connecting tube and vacuum pump Be connected, left upper compartment is connected by the 4th connecting tube with air compressor, the 4th connecting tube equipped with compressor valve, the right side every Room top is equipped with ventilation pipe, and right compartment is connected by the 5th connecting tube with resin absorbing column group, and the 5th connecting tube is equipped with compacted Dynamic pump, resin absorbing column group are connected by return pipe with acidleach kettle, and resin absorbing column group is made of resin absorbing column, discharge pipe Positioned at acidleach bottom portion.
Resin absorbing column is 2~5 and is connected in series as a further improvement of the utility model,.
It as a further improvement of the utility model, further include sampling pipe, sampling pipe is connected with the second connecting tube, Sampling pipe is equipped with sample cock.Detection can be sampled by sampling pipe during system circulation, your gold detected When category content reaches specified value, it can stop extracting circulation.
Water vapour collet is equipped with outside acidleach kettle as a further improvement of the utility model,.Pass through water vapour collet For the heating of acidleach kettle, leaching efficiency is improved.
Negative pressure filtration device is located at acidleach kettle middle part or top as a further improvement of the utility model, to reduce leaching It slags tap and is gathered on negative pressure filtration device.
Open Side Down for negative pressure filtration device as a further improvement of the utility model, can hinder on negative pressure filtration device The formation of filter cake.
It is equipped with enamel layer in acidleach kettle inner surface as a further improvement of the utility model, enamel layer is resistant to strong acid corruption Erosion.
It is equipped with temperature measuring device, in acidleach kettle as a further improvement of the utility model, convenient for grasping acidleach kettle Interior temperature.
The utility model devises circulation extraction system for the active component dissolution method in wet process, and leachate passes through negative Press filtering device enters fluid reservoir, then is pumped into resin absorbing column by peristaltic pump, and the noble metal in leachate is by after resin adsorption It is imported into the leaching that acidleach kettle continues to participate in dead catalyst again, so recycles, improves the leaching rate of noble metal.
Fluid reservoir is divided into left compartment and right compartment by the utility model, and left compartment is filtered, and right compartment is resin suction Attached column provides filtrate, between each other without influence.
The beneficial effects of the utility model are:
1. the utility model can carry out circulation extraction, after leachate is continuously adsorbed by resin absorbing column, your gold therein Belong to concentration constantly to decline in the dynamic equilibrium leached and adsorbed, the direction that the chemical reaction in acidleach kettle is leached towards noble metal It carries out, the rate of recovery of noble metal significantly improves;
2. the utility model is separated by solid-liquid separation simply, the utility model uses the filter method of anti-gravity, and negative pressure filtration is filled It sets and is upside down in acidleach kettle, filtering while hinders the formation of filter cake, keeps constant filter efficiency;
3. the utility model reagent consumption is small, at low cost, pickle liquor is recycled, after leaching whole noble metals, only Consume a small amount of reagent;
4. the utility model generates, waste liquid is few, and environmental protection is at low cost, while improving the rate of recovery, greatly reduces waste liquid amount, Residual waste solution even can be used for handling lower batch catalyst, and circulation is used for multiple times.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of existing extraction element;
Fig. 2 is the structural schematic diagram of the utility model.
In figure, 1- stirring motor;The first connecting tube of 2-;3- negative pressure filtration device;4- sampling pipe;5- agitating paddle;6- acid Soak kettle;7- vacuum pump;8- fluid reservoir;The left compartment of 81-;The right compartment of 82-;9- peristaltic pump;10- resin absorbing column group;11- reflux Pipe;12- air compressor;13- compressor valve;14- is connected to valve;15- compartment valve;16- sample cock;17- acid adding pipe Road;18- acid adding valve;19- discharge valve;20- feed opening;The second connecting tube of 21-;22- Filter valve;23- third connecting tube; The 4th connecting tube of 24-;25- ventilation pipe;The 5th connecting tube of 26-;27- water vapour collet;28- resin absorbing column;29- discharge nozzle Road;30- communicating pipe;31- lautertuns;32- air inlet pipe;33- air intake valve.
Specific embodiment
Below in conjunction with attached drawing, the present invention will be further described in detail.
As shown in Figure 1, existing extraction element includes acidleach kettle 6, agitating paddle 5, vacuum pump 7, acid adding pipeline 17, discharge pipe 29, communicating pipe 30, lautertuns 31 and air inlet pipe 32, feed opening 20 is equipped at the top of acidleach kettle 6, and acid adding pipeline 17 is located at acidleach kettle 6 Top, acid adding pipeline 17 are equipped with acid adding valve 18, and agitating paddle 5 is located at 6 lower part of acidleach kettle, and 5 top of agitating paddle is connected with stirring Motor 1, communicating pipe 30 one end be connected to 6 bottom of acidleach kettle, the other end leads to the top of lautertuns 31, communicating pipe 30 be equipped with connection Valve 14 is equipped with filter cloth above lautertuns 31, and vacuum pump 7 and air inlet pipe 32 are located in the filtering groove sidewall below filter cloth, air inlet Pipe 32 is equipped with air intake valve 33, and discharge pipe 29 is located at 31 bottom of lautertuns, and discharge pipe 29 is equipped with discharge valve 19.Acid It soaks and is equipped with water vapour collet 27 outside kettle 6.
Dead catalyst after agitated leaching, by flowing to the filter cloth of 31 top of lautertuns communicating pipe 30, is opened in acidleach kettle 6 Vacuum pump 7 is opened, leachate reaches 31 bottom of lautertuns by filtering, closes vacuum pump 7, opens air intake valve 33 and carrys out Balance Air Pressure, leachate after filtering are discharged by discharge pipe 29.
Existing extraction element is only to use 1-2 dissolution, your gold carried out to spent catalyst for oxidant+hydrochloric acid method The leaching velocity of category finally tends towards stability after parabola is presented and rises with regard to rapid decrease, and the leaching of noble metal progressivelyes reach pole Limit, extending extraction time cannot continue to improve leaching rate, simultaneously because powder particle is tiny, filtration washing is difficult, further increase The residual quantity of noble metal in leached mud.
The utility model as shown in Fig. 2, it is a kind of from dead catalyst extract noble metal device, including acidleach kettle 6, stirring Paddle 5, vacuum pump 7, acid adding pipeline 17 and discharge pipe 29, feed opening 20 is equipped at the top of acidleach kettle 6, and acid adding pipeline 17 is located at acidleach 6 top of kettle, acid adding pipeline 17 are equipped with acid adding valve 18, and agitating paddle 5 is located at 6 lower part of acidleach kettle, and 5 top of agitating paddle, which is connected with, to be stirred Motor 1 is mixed, it further includes fluid reservoir 8, air compressor 12 and resin absorbing column group that discharge pipe 29, which is equipped with discharge valve 19, 10, fluid reservoir 8 is full-closed structure, is divided into left compartment 81 and right compartment 82, by the between left compartment 81 and right compartment 82 Two connecting tubes 21 are connected, and the second connecting tube 21 is equipped with compartment valve 15, are equipped with negative pressure filtration device 3, negative pressure in acidleach kettle 6 Filter device 3 is connected to by the first connecting tube 2 with left compartment 81, and the first connecting tube 2 is equipped with Filter valve 22, on left compartment 81 Portion is connected by third connecting tube 23 with vacuum pump 7, and left 81 top of compartment passes through the 4th connecting tube 24 and 12 phase of air compressor Even, the 4th connecting tube 24 is equipped with compressor valve 13, and right 82 top of compartment is equipped with ventilation pipe 25, and right compartment 82 passes through the 5th Connecting tube 26 is connected with 10 groups of resin absorbing column, and the 5th connecting tube 26 is equipped with peristaltic pump 9, and resin absorbing column group 10 passes through reflux Pipe 11 is connected with acidleach kettle 6, and resin absorbing column group 10 is made of resin absorbing column 28, and discharge pipe 29 is located at 6 bottom of acidleach kettle.
Resin absorbing column 28 is 2~5 and is connected in series, to enhance adsorption effect.It can be according to resin in practical operation The concentration of noble metal determines the quantity of resin absorbing column 28 in type, load capacity and liquid.
It further include sampling pipe 4, the sampling pipe 4 is connected with the second connecting tube 21, and sampling pipe 4 is equipped with sampling Valve 16.
Water vapour collet 27 is equipped with outside acidleach kettle 6.
Negative pressure filtration device 3 is located at 6 middle part of acidleach kettle or top.
Open Side Down for negative pressure filtration device 3.
Enamel layer is equipped in 6 inner surface of acidleach kettle.
Temperature measuring device is equipped in acidleach kettle 6.
The application method of the utility model is as follows:
Before use, all valves are all in closed state.By dead catalyst through ball-milling treatment be superfines.From feed opening 20 are added the dead catalyst of milled, open acid adding valve 18, the acid solution prepared is added into acidleach kettle 6 through acid adding pipeline 17, makes Negative pressure filtration device 3 is located at liquid level hereinafter, being then shut off acid adding valve 18.Stirring motor 1 is opened, agitating paddle 5 carries out low speed and stirs It mixes, and is heated by water vapour collet 27, when temperature of charge in acidleach kettle 6 is increased to about 80 degree, open 7 He of vacuum pump Filter valve 22, the pressure in left compartment 81 reduce, and the pickle liquor containing noble metal is filtered by negative pressure filtration device 3 to left compartment In 81, when the acid solution liquid level in acidleach kettle 6 is lower than negative pressure filtration device 3, suitable acid can be added again through acid adding pipeline 17 Liquid.When reaching in left compartment 81 compared with high liquid level, vacuum pump 7 and Filter valve 22 are closed, opening compartment valve 15 makes left compartment 81 Be connected to right compartment 82, at this time since the pressure in left compartment 81 reduces, the liquid in left compartment 81 be unable to the automatic stream right side every Room 82, therefore need to open compressor valve 13, compartment 81 is pressurized air compressor 12 to the left, and the acidleach containing noble metal is hydraulic Compartment 82 to the right are then shut off air compressor 12 and compartment valve 15.At this point, vacuum pump 7 and Filter valve can be again turned on 22 are filtered;Peristaltic pump 9 is opened simultaneously, peristaltic pump 9 connects the pickle liquor containing noble metal in right compartment 82 by the 5th Adapter tube 26 is pumped into resin absorbing column group 10, and by after resin adsorption, pickle liquor is back in acidleach kettle 6 noble metal by return pipe 11 Continue to participate in Leach reaction.Pickle liquor recycles in systems, can be sampled by sampling pipe 4, and detects expensive in pickle liquor The concentration of metal when precious metal concentration drops to 0.0005g/L, can stop recycling, and close above-mentioned each valve and each device.Then Discharge valve 19 is opened, the material in acidleach kettle 6 is discharged by discharge pipe 29.
Open Side Down for negative pressure filtration device 3, and filtering while hinders the formation of filter cake, keeps constant filter efficiency. When the filter cloth surface being immersed in acid solution, which forms filter cake, influences the rate of filtration, filter cloth surface can be filtered by air compressor 12 Cake is purged, filter cake, that is, tear-away.
Due to using lower speed of agitator, the catalyst granules in acidleach kettle 6 is largely affected by gravity, and is in kettle Ti Zhong lower layer will not influence the rate of filtration of negative pressure filtration device 3, and the precious metal ion in pickle liquor can sufficiently be diffused into liquid In, precious metal ion concentration is substantially uniform.
Using the utility model device, the average diameter of spent catalyst particles should be milled to 10 microns hereinafter, noble metal contains Amount should not exceed 3%, and it is 10:1 that the liquid in leaching kettle, which consolidates mass ratio, and acid solution can be according to catalyst type, bullion content, absorption The characteristics of resin and flexible choice after the middle absorption resin saturation of resin absorbing column 28, can be replaced as needed.

Claims (8)

1. it is a kind of from dead catalyst extract noble metal device, including acidleach kettle, agitating paddle, vacuum pump, acid adding pipeline and go out Pipe material, acidleach kettle top portion are equipped with feed opening, and acid adding pipeline is located at acidleach kettle top portion, and agitating paddle is located at acidleach kettle lower part, stirring Paddle top is connected with stirring motor, it is characterised in that: further includes fluid reservoir (8), air compressor (12) and resin absorbing column group (10), the fluid reservoir (8) is full-closed structure, is divided into left compartment (81) and right compartment (82), left compartment (81) and the right side every It is connected between room (82) by the second connecting tube (21), the second connecting tube (21) is equipped with compartment valve (15), acidleach kettle (6) Interior to be equipped with negative pressure filtration device (3), negative pressure filtration device (3) is connected to by the first connecting tube (2) with left compartment (81), and first connects It takes over (2) and is equipped with Filter valve (22), left compartment (81) top is connected by third connecting tube (23) with vacuum pump (7), left Compartment (81) top is connected by the 4th connecting tube (24) with air compressor (12), and the 4th connecting tube (24) is equipped with compressor Valve (13), right compartment (82) top are equipped with ventilation pipe (25), and right compartment (82) is inhaled by the 5th connecting tube (26) and resin Attached column group (10) be connected, the 5th connecting tube (26) be equipped with peristaltic pump (9), resin absorbing column group (10) by return pipe (11) with Acidleach kettle (6) is connected, and resin absorbing column group (10) is made of resin absorbing column (28), and discharge pipe (29) is located at acidleach kettle (6) Bottom.
2. a kind of device for extracting noble metal from dead catalyst according to claim 1, it is characterised in that: the resin Adsorption column (28) is 2~5 and is connected in series.
3. a kind of device for extracting noble metal from dead catalyst according to claim 1 or 2, it is characterised in that: also wrap It includes sampling pipe (4), the sampling pipe (4) is connected with the second connecting tube (21), and sampling pipe (4) is equipped with sample cock (16).
4. a kind of device for extracting noble metal from dead catalyst according to claim 3, it is characterised in that: in acidleach kettle (6) external to be equipped with water vapour collet (27).
5. a kind of device for extracting noble metal from dead catalyst according to claim 4, it is characterised in that: the negative pressure Filter device (3) is located in the middle part of acidleach kettle (6) or top.
6. a kind of device for extracting noble metal from dead catalyst according to claim 5, it is characterised in that: the negative pressure Open Side Down for filter device (3).
7. a kind of device for extracting noble metal from dead catalyst according to claim 6, it is characterised in that: in acidleach kettle (6) inner surface is equipped with enamel layer.
8. a kind of device for extracting noble metal from dead catalyst according to claim 7, it is characterised in that: in acidleach kettle (6) temperature measuring device is equipped in.
CN201821773336.1U 2018-10-30 2018-10-30 A kind of device extracting noble metal from dead catalyst Active CN209210893U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111940402A (en) * 2020-08-03 2020-11-17 珠海格力绿色再生资源有限公司 Filtering and collecting device
CN114959275A (en) * 2022-06-20 2022-08-30 合肥神舟催化净化器股份有限公司 Metal purification device in automobile exhaust catalyst

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111940402A (en) * 2020-08-03 2020-11-17 珠海格力绿色再生资源有限公司 Filtering and collecting device
CN114959275A (en) * 2022-06-20 2022-08-30 合肥神舟催化净化器股份有限公司 Metal purification device in automobile exhaust catalyst

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Effective date of registration: 20240319

Address after: 737199 No. 2 Jianshe Road, Jinchuan District, Jinchang City, Gansu Province (east of Beijing Road, west of Heya Road, south of Guiyang Road)

Patentee after: Jinchuan Group Copper Gui Co.,Ltd.

Country or region after: Zhong Guo

Address before: 737103 No. 98, Jinchuan Road, Jinchang, Gansu

Patentee before: JINCHUAN GROUP Co.,Ltd.

Country or region before: Zhong Guo

TR01 Transfer of patent right