CN209206021U - A kind of stabilisation curing process system of incineration of refuse flyash - Google Patents

A kind of stabilisation curing process system of incineration of refuse flyash Download PDF

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CN209206021U
CN209206021U CN201821995880.0U CN201821995880U CN209206021U CN 209206021 U CN209206021 U CN 209206021U CN 201821995880 U CN201821995880 U CN 201821995880U CN 209206021 U CN209206021 U CN 209206021U
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flying dust
unit
cement
chelating agent
metering units
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易新建
李静
周斌
邵煜锟
魏来
石燕
何宇宁
杨流
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YONKER ENVIRONMENTAL PROTECTION CO Ltd
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YONKER ENVIRONMENTAL PROTECTION CO Ltd
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Abstract

The utility model relates to a kind of stabilisation curing process systems of incineration of refuse flyash, including flying dust metering units, cement-weighting unit, chelating agent metering units, detection addition control unit, unit is stabilized, the flying dust metering units, cement-weighting unit, chelating agent metering units are connected to stabilisation unit;The detection addition control unit includes online detection module and control module.The utility model uses on-line checking module, can each element content in real-time detection every batch of flying dust, the accurate physicochemical property for grasping every batch of flying dust is conducive to the stabilisation curing process for instructing flying dust;In addition, carrying out the accurate adjustment control of cement, chelating agent additive amount for the physicochemical property of every batch of flying dust, the cured treatment effect of stabilizing fly ashization can be greatly improved, it is advantageously ensured that meeting environmental protection standard requirement after flying dust processing.

Description

A kind of stabilisation curing process system of incineration of refuse flyash
Technical field
The utility model belongs to field of environment engineering technology, is related to a kind of stabilisation curing process system of incineration of refuse flyash System.
Background technique
Counted according in July, 2018, the garbage incinerating power plant that has put into operation of the whole nation reaches 359, year garbage treatment quantity More than 1.05 hundred million tons, the yield of incineration of refuse flyash has reached 3,200,000 tons, and according to national policy, standard criterion, waste incineration Flying dust belongs to hazardous waste, and need to carry out stabilizing after curing process reaches relevant criterion can fill out into household refuse landfill sites subregion It buries.But since landfill facility digestion capability is insufficient, specification cost of disposal is high, enterprise operation thinks little of, supervises seriously disconnection etc. Reason becomes waste incineration facility fortune so that the illegal phenomenon such as incineration of refuse flyash disposition lack of standardization, any violation discharge is more Capable weak link.But the physicochemical property of incineration of refuse flyash is influenced by location, Various Seasonal etc., difference is big, fluctuates Property it is strong, if being handled in such a way that the chelating agent adding proportion that generallys use at present is fixed, first is that containing in fly-ash heavy metal The waste that will lead to flying dust processing chelating agent when measuring lower, increases processing cost, second is that will when fly-ash heavy metal content is higher Cause flying dust processing that relevant standard is not achieved, causes adverse effect to environment.Existing fly-ash heavy metal detection method is main Including atomic absorption spectrography (AAS) (AAS), atomic emission spectrometry (AES), atomic fluorescence spectrometry (AFS), inductive coupling etc. from Daughter mass spectrum (ICP-MS), UV-VIS spectrophotometry (UV-Vis) etc..Such methods detect heavy metal in the lab and contain Amount has played important function, measuring accuracy with higher, but needs complicated sample pretreatment process, sampling-sample preparation-inspection The survey overall process period is longer, cannot achieve the quick in situ measurement at operation scene.And X fluorescence spectrometer (XRF), induced with laser etc. Emission spectrometer (LIBS) is detected in related fieldss such as power plant's raw coal, flying dust and environmental protection for the real-time online of element.
Patent CN201810067499.6 discloses a kind of using various heavy content in XRF instrument quantitative measurement flying dust Method;Patent CN108246770A discloses a kind of use of stabilizing fly ash chelating agent dosing system based on XRF detection Method is measured in real time every batch of flying dust Pb total amount using XRF, is divided into five class of A1-A5 according to flying dust Pb total amount, It determines five grades of M1-M5 different chelating agent adding proportions, is compared by logic and realize stabilizing fly ash curing process chelating agent Fining adds, but does not account for influence to stabilizing fly ash treatment effect of other elements such as Cd, Ca, Zn in flying dust, do not have Relevant function model is established, there are biggish limitations for instructing chelating agent adding proportion;Application number CN106862235A Utility model patent disclose a kind of on-line checking heavy metal solid waste method for innocent treatment, but the patent cannot be straight Connect monitoring solid in content of beary metal, after being extracted monitor aqueous phase solution in heavy metal ion content, need into The complicated water logging of row or acidleach pre-treating technology, and be not implemented and automatically control.
Utility model content
In view of the deficiencies of the prior art, the utility model provides a kind of stabilisation curing process system of incineration of refuse flyash System, one of its goals is to meet different regions, Various Seasonal, physicochemical property significant difference incineration of refuse flyash accurate place Reason.
In order to solve the above-mentioned technical problem, the technical solution of the utility model is as follows:
A kind of stabilisation curing process system of incineration of refuse flyash, including flying dust metering units, cement-weighting unit, chela Mixture metering units, stabilize unit, the flying dust metering units, cement-weighting unit, chelating agent at detection addition control unit Metering units are connected to stabilisation unit;
Control unit is added in the detection
On-line checking module, for detecting in flying dust metering units each contents of heavy metal elements in incineration of refuse flyash;With
Control module, the data-signal for receiving and processing on-line checking module and flying dust metering units transmit, then root According to data processed result control cement-weighting unit, chelating agent metering units, to unit is stabilized, according to target additive amount is quantitative respectively Administration.
On-line checking module can with real-time online detect flying dust in calcium (Ca), cadmium (Cd), lead (Pb), nickel (Ni), copper (Cu), The content of the elements such as zinc (Zn), chromium (Cr), barium (Ba), arsenic (As), mercury (Hg);Generally, the detection range of each element, calcium (Ca) It is 1 × 104~40 × 104Mg/kg, cadmium (Cd) are 50~1000mg/kg, lead (Pb) is 50~5000mg/kg, and nickel (Ni) is 50 ~5000mg/kg, copper (Cu) are 50~5000mg/kg, zinc (Zn) is 50~10000mg/kg, chromium (Cr) is 50~5000mg/ Kg, barium (Ba) are 50~5000mg/kg, arsenic (As) is 50~1000mg/kg, mercury (Hg) is 50~1000mg/kg;Further Ground, the detection error of each element are not more than 20%, and the period detected every time is 30~60 seconds.Control module receives and processes online Data-signal that detection module and flying dust metering units transmit (including each contents of heavy metal elements data and to be processed fly in flying dust The qualitative data of ash), controlling cement-weighting unit further according to data processed result, according to target additive amount is quantitative to unit is stabilized Add cement, and control chelating agent metering units to stabilize unit according to target additive amount quantitatively add chelating agent, to flying dust reality Now precisely processing, advantageously reduces processing cost, and guarantee treatment effect.
Further, as Ca content C in handled incineration of refuse flyashCaWhen > 12wt%, the leaching concentration L of i elementi =a × CCa+b×Ci+ c, target additive amount P=m × (∑ L of chelating agenti)n, the target additive amount of cement is 0, wherein a, b, c, M, the value range of n is respectively 0.5~0.7,0~0.01, -6~-0.1,0.013~0.024,0.20~0.38;When handled Incineration of refuse flyash in Ca content CCaWhen < 12wt%, the leaching concentration of i element is Li=e × CCa+f×Ci+ g, chelating agent Target additive amount P=s × (∑ Li)t, the target additive amount P of cementc=2 × (12-CCa) %, i be selected from Cd, Pb, Ni, Cu, Zn, Cr, Ba, As, Hg, wherein the value range of e, f, g, s, t be respectively -0.3~-0.5,0.003~0.01, -6~20,0.01~ 0.025,0.20~0.40;CiFor the content of i element in handled incineration of refuse flyash, ∑ Li=LPb+LCd+LNi+LCu+LZn+ LCr+LBa+LAs+LHg
Optionally, the chelating agent is dimethyl amine organic sulfur chelating agent;Optionally, the cement is normal silicate class Cement meets GB175-2007.Above-mentioned function model can be embedded in control module, be calculated in conjunction with flying dust qualitative data to be processed Chelating agent, the cement, technique water quality that respective batch stabilizing fly ashization is added needed for solidifying.
Further, the flying dust metering units include the flying dust warehouse, screw(-type) feeder and flying dust quality being sequentially communicated Measuring chute, the discharge port in flying dust mass metrology storehouse are connected to unit is stabilized, and the on-line checking module is set to screw feeder Between machine and flying dust mass metrology storehouse, flying dust mass metrology storehouse passes the flying dust qualitative data added in stabilisation unit It is defeated by control module, optionally, the control section in flying dust mass metrology storehouse communicates to connect or is electrically connected with control module.
The processing in batches of incineration of refuse flyash can be realized by flying dust mass metrology storehouse, it is preferable that every batch of is to be processed The quality of incineration of refuse flyash is 800-1000ka.In addition, flying dust mass metrology storehouse can directly stabilize investment in unit The qualitative data of incineration of refuse flyash is transferred to control module, and control module combines this data, can obtain specific required cement The data of amount, chelating dosage.
Further, the on-line checking module includes detecting instrument, and the detecting instrument is X fluorescence spectrometer (XRF) Or Laser induced plasma spectroscopy instrument (LIBS).
Further, the cement-weighting unit includes the cement storage bin being sequentially communicated and cement quality measuring chute, described The discharge port of cement quality measuring chute is connected to unit is stabilized, and the cement quality measuring chute receives the water that control module issues Mud adds instruction and adds cement to unit is stabilized by the instruction, optionally, the control section of the cement quality measuring chute It communicates to connect or is electrically connected with control module.Cement quality measuring chute can receive the cement target additive amount number of control module output It is believed that number, cement is quantitatively added by this.
Further, the chelating agent metering units include chelating agent storage tank, meter and the solution measures being sequentially communicated Tank, the liquid outlet of the solution measures tank are connected to unit is stabilized, and meter receives the chelating agent that control module issues and adds Instruct and add chelating agent to solution measures tank by the instruction, optionally, the control section of meter and control module communication link It connects or is electrically connected;It further include the process water feeder being connected to solution measures tank, technique water controller receives control module and issues Process water add instruct and add process water to solution measures tank by the instruction, optionally, the control of the process water feeder System part communicates to connect or is electrically connected with control module.Solution measures tank is mainly used for the mixing of chelating agent and process water;Metering Device receives the chelating agent target additive amount data-signal of the processing of the control module output part incineration of refuse flyash, quantitatively adds Chelating agent.Process water target needed for the control section of process water feeder receives the processing of the control module output batch flying dust Additive amount data, quantitative adding technology water.
Further, the meter is flow measurement pump;The process water feeder is technique Water flow control valve.
Further, it is equipped with pump between the solution measures tank and stabilisation unit, facilitates the addition of chelating agent solution.
Further, the unit that stabilizes includes the stabilizing fly ashization solidification kneading machine and flying dust jumbo bag packet being sequentially communicated Installation.
Generally, the additive amount of chelating agent is the 0.1-10% of incineration of refuse flyash quality to be processed, process water additive amount For the 35-45% of incineration of refuse flyash quality to be processed.
Conceived based on same utility model, the utility model also provides a kind of stabilisation curing process of incineration of refuse flyash Method is carried out using processing system as described above, is included the following steps:
Ca content C in S1, detection incineration of refuse flyash to be processedCaWith other each contents of heavy metal elements Ci, wherein i choosing From Cd, Pb, Ni, Cu, Zn, Cr, Ba, As, Hg;
S2, work as CCaWhen > 12wt%, the target additive amount P for obtaining chelating agent is calculated according to the following formula,
The leaching concentration L of i elementi=a × CCa+b×Ci+ c, P=m × (∑ Li)n
Work as CCaWhen < 12wt%, the target for calculating the target additive amount P and cement that obtain chelating agent according to the following formula adds Dosage Pc,
The leaching concentration of i element is Li=e × CCa+f×Ci+ g, P=s × (∑ Li)t, Pc=2 × (12-CCa) %;
Wherein, ∑ Li=LPb+LCd+LNi+LCu+LZn+LCr+LBa+LAs+LHg, a, b, c, e, f, g, m, n, s, t are constant;
S3, the calculated result according to S2 add chelating agent, cement into incineration of refuse flyash to be processed, are stabilized Processing.
Compared with prior art, the beneficial effects of the utility model are as follows:
(1) use on-line checking module, can each element content in real-time detection every batch of flying dust, accurate grasp The physicochemical property of every batch of flying dust is conducive to the stabilisation curing process for instructing flying dust, realizes accurate, efficient process.
(2) the polynomial function model of reflection flying dust each element content and its toxicity leaching concentration relationship, reflection are established The power exponential function model of flying dust each element Leaching concentration and cement, chelating agent adding proportion relationship, can adapt to difference The variation in area, Various Seasonal incineration of refuse flyash physicochemical property, precisely adjustment controls the additive amount of chelating agent, cement, favorably In reduction stabilizing fly ash curing process cost.
(3) the accurate adjustment control of cement, chelating agent additive amount, Neng Gou great are carried out for the physicochemical property of every batch of flying dust Width improves the cured treatment effect of stabilizing fly ashization, it is advantageously ensured that meeting environmental protection standard requirement after flying dust processing.
Detailed description of the invention
Fig. 1 is the building-block of logic of the processing system of the utility model the first embodiment.
Fig. 2 is the flow direction of material and control structure schematic diagram of the processing system of the utility model the first embodiment.
Specific embodiment
The utility model is further described with reference to embodiments: applying processing system described in the utility model High lead cadmium content incineration of refuse flyash is handled, the Leaching concentration of lead cadmium in flying dust can be significantly reduced, reaches project institute really Fixed management goal requirement.
Embodiment 1
A kind of stabilisation curing process system of incineration of refuse flyash, including flying dust metering units 100, cement-weighting unit 200, chelating agent metering units 300, detection addition control unit 400, stabilisation unit 500, the flying dust metering units 100, Cement-weighting unit 200, chelating agent metering units 300 are connected to stabilisation unit 500;
Control unit 400 is added in the detection
On-line checking module 401, for detecting in flying dust metering units each contents of heavy metal elements in incineration of refuse flyash; With
Control module (402) uses Siemens S7-300 PLC control cabinet, for receiving and processing on-line checking module and flying The data-signal that grey metering units transmit, further according to data processed result control cement-weighting unit, chelating agent metering units point Not to stabilizing unit according to target additive amount dosed administration.
The flying dust metering units 100 include flying dust warehouse 101, screw(-type) feeder 102 and the flying dust quality being sequentially communicated Measuring chute 103 (is equipped with the Weighing module WMS1501C- of Meiteler-Toliduo's production LX), the discharge port in flying dust mass metrology storehouse 103 is connected to unit 500 is stabilized, and the on-line checking module 401 is set to spiral shell Revolve between batcher and flying dust mass metrology storehouse, the control section in flying dust mass metrology storehouse and control module communicate to connect or Electrical connection.
The on-line checking module 401 includes detecting instrument, and the detecting instrument is Laser induced plasma spectroscopy instrument. The cement-weighting unit 200 includes that the cement storage bin 201 being sequentially communicated and cement quality measuring chute 202 (are equipped with plum Teller- Hold in the palm the Weighing module WMS402C-LX of benefit (Changzhou) Weight Equipment System Co., Ltd production)), the cement quality measuring chute Discharge port be connected to unit is stabilized, the control section of the cement quality measuring chute and control module communication connection or be electrically connected It connects.The chelating agent metering units 300 include the chelating agent storage tank 301 being sequentially communicated, the production of Changzhou Xin Wang finite instrument company Teletransmission type electromagnetic type meter 302 and solution measures tank 304, the liquid outlet of the solution measures tank are connected to unit is stabilized, The control section of meter communicates to connect or is electrically connected with control module;It further include the process water supply being connected to solution measures tank The control section of device 303, the process water feeder communicates to connect or is electrically connected with control module.The solution measures tank 304 And it stabilizes and is equipped with pump 305 between unit.The unit that stabilizes includes that Zhuhai Shi Gaoma mechanical equipment for being sequentially communicated is limited The stabilizing fly ashization of company's production solidifies the flying dust jumbo bag packing machine of kneading machine 501 and the production of Zhong Kekezheng Automation Engineering Company 502。
It is stabilized by incineration of refuse flyash described in the utility model and solidifies accurate efficient process system, Hengyang rubbish is sent out Flying ash in electric power plant is handled.The flying dust amount that flying dust metering units 100 control every batch of processing is 1000kg, and flying dust is given by spiral Material machine 102 enters flying dust mass metrology storehouse 103 from flying dust warehouse 101, solid subsequently into the stabilizing fly ashization for stabilizing unit 500 Change in kneading machine 501, is packaged after processing by flying dust jumbo bag packing machine 502, guarantees the uniformity of flying dust.On-line measuring device peace Between batcher and measuring chute.
Laser induced plasma spectroscopy instrument (LIBS) detection is used to obtain the calcium content of first batch flying dust as 16.0%, Lead content is 1165mg/kg and other content of beary metal data.The calcium content data that on-line checking module 202 obtains are automatic The control module 402 of input detection addition control unit 400, since calcium content is higher than 12%, calculated result cement dosage is 0, the control section of the cement quality measuring chute 202 in cement-weighting unit 200 receives instruction and does not add cement.Calcium content and lead Content data automatically enters the control module of detection addition control unit 400, according to the Leaching of Heavy Metals concentration in control module Calculating formula Li=0.511 × CCa+0.00087×Ci- 6, wherein LiFor heavy metal leaching concentration (mg/L), CCaFor calcium content (mg/kg), CiFor content of beary metal (mg/kg).Be calculated Pb leaching concentration be 3.19mg/L, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg are to be not detected, and are -0.59%~4.7% with actually detected error range.The data automatically enter computation model∑LiFor the sum of Pb, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg heavy metal concentration, the batch is calculated Medicament adding proportion be the 2.50% of flying dust to be processed, process water adding proportion is 40% (fixed adding proportion).The data Chelating agent metering units 300 are automatically entered, meter 302 receives the data of medicament ratio 2.5%, according to flying dust quality to be processed 1000kg, calculating decentralization to the pharmacy quality for stabilizing unit 500 is 25kg, and process water feeder 303 receives process water addition The data of ratio 40%, then transferring to the technique water quality for stabilizing unit 500 is 400kg.Fly after final stabilization processes For ash after maintenance 2-3 days, the leaching concentration detection of Pb is below " household refuse landfill sites contamination control standard " GB16889- 2008 standard limited value 0.25mg/L.Illustrate to can effectively ensure that treated using Online Processing System fly-ash heavy metal concentration Leaching concentration is up to standard.
After the accurate efficient process system of the solidification is run one month, calcium content and lead content change, and detect resulting Calcium content is respectively 12.5%, and detecting resulting lead content is respectively 909mg/kg.Calcium content data automatically enter detection addition The cement adding proportion calculation control module of control unit 400, since calcium content is higher than 12%, calculated result cement dosage is 0, the cement-weighting storehouse in cement-weighting unit 200 receives instruction and does not add cement.Calcium content and lead content data automatically enter The medicament adding proportion calculation control module of detection addition control unit 400, according to the Leaching of Heavy Metals concentration in control system Calculating formula Li=0.511 × CCa+0.00087×Ci- 6, wherein LiFor heavy metal leaching concentration (mg/L), CCaFor calcium content (mg/kg), CiFor content of beary metal (mg/kg).Be calculated Pb leaching concentration be 1.18mg/L, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg are to be not detected, and are -0.67%~5.2% with actually detected error range.The data automatically enter computation model∑LiFor the sum of Pb, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg heavy metal concentration, the batch is calculated Medicament adding proportion be 1.8%, process water adding proportion be 40%.The data automatically enter chelating agent metering units 300, meter 302 control section of measuring device receives the data that medicament ratio is 1.8%, according to flying dust quality 1000kg to be processed, calculates decentralization extremely The pharmacy quality for stabilizing unit 500 is 18kg, and the control section of process water feeder 303 receives process water adding proportion 40% Data, then transfer to stabilize unit 500 technique water quality be 400kg.Flying dust after final stabilization processes is by supporting For shield after 2-3 days, the leaching concentration detection of Pb is below the mark of " household refuse landfill sites contamination control standard " GB16889-2008 Quasi- limit value 0.25mg/L.Illustrate using system can real-time online regulation stabilizer adding proportion, guarantee treated flying dust weight Metal concentration leaching concentration is up to standard, and can save cost.
Table 1Pb element on-line checking and processing situation up to standard
Embodiment 2:
It is stabilized by incineration of refuse flyash described in the utility model and solidifies accurate efficient process system, to Shanghai rubbish Power plant flying dust is handled.The flying dust amount that flying dust metering units 100 control every batch of processing is 1000kg, and flying dust passes through spiral Batcher enters stabilisation solidification stirring system, guarantees the uniformity of flying dust.On-line measuring device is mounted on batcher and metering Between storehouse.
The calcium, lead and cadmium content point of first batch flying dust are obtained using Laser induced plasma spectroscopy instrument (LIBS) detection Not Wei 10.8%, 2191mg/kg, 260mg/kg and other content of beary metal data.Calcium content data automatically enter detection and add The cement adding proportion calculation control module for adding control unit 400, since calcium content is lower than 12%, according to model Pc=2 × (12-CCa) %, cement additive amount is 2.4%.Cement-weighting unit 200 receives instruction and is kneaded to the solidification for stabilizing unit 500 2.4% cement is added in machine.Calcium content and lead content data automatically enter the medicament addition ratio of detection addition control unit 400 Example calculation control module, according to the calculating formula L of the Leaching of Heavy Metals concentration in control systemi=-0.06 × CCa+0.005×Ci+ 0.52, it is 10.83mg/L that Pb leaching concentration, which is calculated, according to the calculating formula L of the Cd leaching concentration in control uniti=- 0.416×CCa+0.037×Ci- 0.11, it is 5.02mg/L that Cd leaching concentration, which is calculated, other Leaching of Heavy Metals concentration do not surpass Mark.It is -12.3%~13.0% with actually detected error range.The data series automatically enter computation model Pi=0.0127 × ∑Li 0.3985, ∑ LiFor the sum of Pb, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg heavy metal concentration, the medicament addition of the batch is calculated Ratio is 3.8%, and process water adding proportion is 40%.The data automatically enter chelating agent metering units 300, the control of meter Part receives the data of medicament ratio 3.8%, and calculating decentralization to the pharmacy quality for stabilizing unit 500 is 38kg, and process water supplies The data of process water adding proportion 40% are received to the control section of device, then are transferred to the technique water quality for stabilizing unit 500 For 400kg.For flying dust after final stabilization processes after maintenance 2-3 days, the leaching concentration detection of Pb is below " house refuse Landfill yard contamination control standard " GB16889-2008 standard limited value 0.25mg/L.Illustrate can have using Online Processing System Effect guarantees that the leaching of treated fly-ash heavy metal concentration reaches standard.
After running a period of time, the constituent content in flying dust changes.Using Laser induced plasma spectroscopy instrument (LIBS) it is respectively 7.1%, 2973.5mg/kg, 200mg/kg and other huge sum of moneys that detection, which obtains the calcium, lead and cadmium content of flying dust, Belong to content data.Calcium content data automatically enter the cement adding proportion calculation control module of detection addition control unit 400, by It is lower than 12% in calcium content, according to model Pc=2 × (12-CCa) %, cement additive amount is 9.8wt%.Cement-weighting unit 200 It receives instruction and adds the cement of 9.8wt% in kneading machine to solidifying for unit 500 is stabilized.Calcium content and lead content data are automatic Input detection addition control unit 400, control module is according to the calculating formula L of Pb leaching concentrationi=-0.06 × CCa+0.005×Ci + 0.52, it is 14.96mg/L that Pb leaching concentration, which is calculated, according to the calculating formula L of Cd leaching concentrationi=-0.416 × CCa+ 0.037×Ci- 0.11, it is 4.34mg/L that Cd leaching concentration, which is calculated, other Leaching of Heavy Metals concentration are not exceeded.With practical inspection Surveying error range is -11.5%~13.5%.The data series automatically enter computation model Pi=0.0127 × ∑ Li 0.3985, ∑ LiFor the sum of Pb, Cd, As, Ba, Cr, Cu, Ni, Zn, Hg heavy metal concentration, the medicament adding proportion for calculating the batch is 4.13%, process water adding proportion is 40%.The data automatically enter chelating agent metering units 300, the control unit of meter 302 Tap receives the data of medicament ratio 4.13%, and calculating decentralization to the pharmacy quality for stabilizing unit 500 is 41.3kg, and process water supplies The data of process water adding proportion 40% are received to device, then transferring to the technique water quality for stabilizing unit 500 is 400kg.Most For flying dust after whole stabilization processes after maintenance 2-3 days, the leaching concentration detection of Pb and Cd are below " household refuse landfill sites Contamination control standard " GB16889-2008 standard limited value 0.25mg/L, 0.15mg/L.Illustrate first in flying dust using the system Element when changing can real-time monitoring medicament and cement adding proportion, being effectively ensured that treated, fly-ash heavy metal concentration leaches It is up to standard.
The accurate efficient process system treatment effect of table 2
Flying dust metering units are controlled per a batch of flying dust about 800-1000kg, and blender continuous work, Weighing system waits for After preceding a batch flying dust stirring, discharging second batch flying dust to blender, while being discharged into chelating agent or cement.When on-line checking mould When the continuous two batches flying dust Ca and As, Ba, Cr, Cu, Ni, Zn, Hg content that block measures do not have significant change, detection addition control is single Member continues set chelating agent proportion, when significant change occur in continuous two batches flying dust Ca and As, Ba, Cr, Cu, Ni, Zn, Hg content When, logical operation of the data through computer software after the variation that detection addition control unit is measured according to on-line checking module is real When adjustment chelating agent proportion, guarantee that flying dust processing is up to standard while can also save processing cost.
To sum up, the processing system of the utility model can adapt to different regions, Various Seasonal, physicochemical property significant difference The processing requirement of incineration of refuse flyash realizes efficient, the accurate processing of incineration of refuse flyash.
The content that above-described embodiment illustrates should be understood as that these embodiments are only used for being illustrated more clearly that the utility model, Rather than limitation the scope of the utility model, after having read the utility model, those skilled in the art are practical new to this The modification of the various equivalent forms of type each falls within the application range as defined in the appended claims.

Claims (7)

1. a kind of stabilisation curing process system of incineration of refuse flyash, which is characterized in that including flying dust metering units (100), Cement-weighting unit (200), detection addition control unit (400), stabilizes unit (500) at chelating agent metering units (300), The flying dust metering units (100), cement-weighting unit (200), chelating agent metering units (300) with stabilize unit (500) it is connected to;
Control unit (400) are added in the detection
On-line checking module (401), for detecting in flying dust metering units each contents of heavy metal elements in incineration of refuse flyash;With
Control module (402), the data-signal for receiving and processing on-line checking module and flying dust metering units transmit, then root According to data processed result control cement-weighting unit, chelating agent metering units, to unit is stabilized, according to target additive amount is quantitative respectively Administration.
2. processing system according to claim 1, which is characterized in that the flying dust metering units (100) include successively connecting Logical flying dust warehouse (101), screw(-type) feeder (102) and flying dust mass metrology storehouse (103), flying dust mass metrology storehouse (103) Discharge port is connected to unit (500) are stabilized, and the on-line checking module (401) includes detecting instrument, and the detecting instrument is set It is placed between screw(-type) feeder and flying dust mass metrology storehouse, flying dust mass metrology storehouse, which will add in stabilisation unit, to fly Grey qualitative data is transferred to control module.
3. processing system according to claim 2, which is characterized in that the detecting instrument is X fluorescence spectrometer or laser Induced plasma spectrometer.
4. processing system according to claim 1, which is characterized in that the cement-weighting unit (200) includes successively connecting Logical cement storage bin (201) and cement quality measuring chute (202), the discharge port and stabilisation unit of the cement quality measuring chute Connection, the cement quality measuring chute receive the cement that control module issues and add instruction and throw by the instruction to unit is stabilized Add cement.
5. processing system according to claim 1, which is characterized in that the chelating agent metering units (300) include successively Chelating agent storage tank (301), meter (302) and the solution measures tank (304) of connection, the liquid outlet of the solution measures tank and steady Surely change unit connection, meter receives the chelating agent that control module issues and adds instruction and add by the instruction to solution measures tank Chelating agent;It further include the process water feeder (303) being connected to solution measures tank, technique water controller receives control module and issues Process water add instruct and add process water to solution measures tank by the instruction.
6. processing system according to claim 5, which is characterized in that the solution measures tank (304) and stabilisation unit Between be equipped with pump (305).
7. processing system according to claim 1-6, which is characterized in that the stabilisation unit includes successively connecting Logical stabilizing fly ashization solidification kneading machine (501) and flying dust jumbo bag packing machine (502).
CN201821995880.0U 2018-11-30 2018-11-30 A kind of stabilisation curing process system of incineration of refuse flyash Active CN209206021U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109277402A (en) * 2018-11-30 2019-01-29 永清环保股份有限公司 A kind of the stabilisation curing process system and processing method of incineration of refuse flyash
CN113843255A (en) * 2021-09-13 2021-12-28 生态环境部华南环境科学研究所 Sectional type stabilization treatment method and system for household garbage incineration fly ash
CN115120924A (en) * 2022-06-28 2022-09-30 重庆新离子环境科技有限公司 Intelligent preparation system for household garbage incineration fly ash chelating agent

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109277402A (en) * 2018-11-30 2019-01-29 永清环保股份有限公司 A kind of the stabilisation curing process system and processing method of incineration of refuse flyash
CN109277402B (en) * 2018-11-30 2023-11-07 永清环保股份有限公司 Stabilization and solidification treatment system and treatment method for waste incineration fly ash
CN113843255A (en) * 2021-09-13 2021-12-28 生态环境部华南环境科学研究所 Sectional type stabilization treatment method and system for household garbage incineration fly ash
CN113843255B (en) * 2021-09-13 2023-10-27 生态环境部华南环境科学研究所 Sectional type stabilization treatment method and system for household garbage incineration fly ash
CN115120924A (en) * 2022-06-28 2022-09-30 重庆新离子环境科技有限公司 Intelligent preparation system for household garbage incineration fly ash chelating agent
CN115120924B (en) * 2022-06-28 2023-11-10 重庆新离子环境科技有限公司 Intelligent preparation system for household garbage incineration fly ash chelating agent

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