CN209102611U - A kind of formaldehyde examination probe - Google Patents

A kind of formaldehyde examination probe Download PDF

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Publication number
CN209102611U
CN209102611U CN201821922066.6U CN201821922066U CN209102611U CN 209102611 U CN209102611 U CN 209102611U CN 201821922066 U CN201821922066 U CN 201821922066U CN 209102611 U CN209102611 U CN 209102611U
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CN
China
Prior art keywords
formaldehyde
probe
probe body
column
sensing element
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Expired - Fee Related
Application number
CN201821922066.6U
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Chinese (zh)
Inventor
关荣锋
王新霖
陈中
赵森
江楠
谭思钰
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Yangcheng Institute of Technology
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Yangcheng Institute of Technology
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Priority to CN201821922066.6U priority Critical patent/CN209102611U/en
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Publication of CN209102611U publication Critical patent/CN209102611U/en
Expired - Fee Related legal-status Critical Current
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  • Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The utility model provides a kind of formaldehyde examination probe, including probe body, upper cover, incidental optical fibre connectors, the output optical fiber connector, air inlet column, outgassing column and formaldehyde sensing element, probe body is box like structure, the upper opening of the probe body, the leading flank of probe body, trailing flank, left side and right side are respectively fitted with air inlet column, outgassing column, the output optical fiber connector and incidental optical fibre connectors, formaldehyde sensing element is mounted in probe body by the guide groove in probe body, probe body is divided into left and right two chambers, pilot hole and shading cover are provided on upper lid, facilitate the installation and replacement of formaldehyde sensing element, outgassing column end is provided with micropump, convenient for forming negative pressure in probe body, enhance circulation of the gas to be detected in probe body, make to detect more accurate, it is provided by the utility model The development of technical solution PARA FORMALDEHYDE PRILLS(91,95) detection technique has important meaning.

Description

A kind of formaldehyde examination probe
Technical field
The utility model belongs to environmental monitoring technology field, and in particular to a kind of formaldehyde examination probe.
Background technique
Formaldehyde is a kind of colourless, with strong excitatory smell gas, is dialled since its chemical property is living, production technology letter Single, raw material supply abundance is a kind of important industrial chemicals, is all widely used at many aspects.Formaldehyde is widely used in Building, furniture etc., in numerous indoor pollutants, as most important indoor decoration pollution object, the harm pole of formaldehyde It is serious.Formaldehyde has certain toxicity, the aerial formaldehyde of exposure, and eyes and upper respiratory tract system to people have strong Stimulation.For the concentration of indoor formaldehyde about in the range of 0.00l-1ppm, the World Health Organization suggests that indoor formaldehyde is dense Degree control, when concentration of formaldehyde is more than 0.1ppm, will cause certain danger within 0.08ppm to the health of human body Evil.Exceeded formaldehyde to human body have a variety of harm, can cause cancer, to respiratory system, smell, eyesight, lung, liver function, And skin is all harmful, moreover it is possible to benumb nervous system, cause hypoimmunity etc.;In addition to this, formaldehyde is to a certain extent It also will increase the probability of cases with leukemia, especially suffer from the probability of myeloid leukemia, therefore the detection of PARA FORMALDEHYDE PRILLS(91,95) is most important.
Existing formaldehyde examination device generally uses the detection of group of the lanthanides sensor progress formaldehyde, in general group of the lanthanides sensor In, most of to be all based on single-shot and penetrate luminous quenching, they usually will receive the influence of environment, such as fluctuate source strength, sensing Device concentration, gas insufficient contact to be detected etc., this will lead to the inaccuracy of detection.
Accordingly, it is desirable to provide a kind of for the above-mentioned prior art is insufficient there is highly sensitive formaldehyde examination to pop one's head in.
Utility model content
The purpose of this utility model is to provide a kind of formaldehyde examination probe at least solve current formaldehyde examination probe by The problems such as environment is affected, detection sensitivity is low.
To achieve the goals above, the utility model provides the following technical solutions:
A kind of formaldehyde examination probe, comprising:
Probe body, the probe body be box like structure, the upper opening of the probe body, the probe body Leading flank, trailing flank, left side and right side are provided with mounting hole;
Upper cover, the upper cover are close contact at the upper opening of the probe body, form closed structure;
Incidental optical fibre connectors, the incidental optical fibre connectors are assemblied in the mounting hole of the right side of the probe body It is interior;
The output optical fiber connector, the output optical fiber connector device fit over the mounting hole of the left side of the probe body It is interior;
Air inlet column, in the mounting hole for the leading flank that the air inlet column is assemblied in the probe body;
Outgassing column, the outgassing column are assemblied in the mounting hole of the trailing flank of the probe body;
Formaldehyde sensing element, the formaldehyde sensing element are located in the probe body, and formaldehyde sensing element will pop one's head in this Body is divided into left and right two chambers, and formaldehyde sensing element includes glass backing plate and the formaldehyde sensitive thin film that is attached on glass backing plate.
Formaldehyde examination probe as described above, it is preferable that the upper cover includes cover board and shading cover, is provided on the cover board Pilot hole is conveniently replaceable formaldehyde sensing element, the top of the pilot hole of the shading cover installation on the cover board.
Formaldehyde examination probe as described above, it is preferable that the end of the outgassing column is provided with micropump, convenient for promoting probe Intrinsic gas circulation.
Formaldehyde examination probe as described above, it is preferable that the formaldehyde sensing element is located at close to the output optical fiber connector one In the probe body of side.
Formaldehyde examination probe as described above, it is preferable that the formaldehyde sensitive thin film is located at the right side of the glass backing plate.
Formaldehyde examination probe as described above, it is preferable that the formaldehyde examination probe further includes pedestal, and the pedestal is located at institute The lower section for stating probe body, for carrying probe body.
Formaldehyde examination probe as described above, it is preferable that the pedestal is disc platform, and the bottom surface of the probe body fills Fit over the upper surface of the pedestal.
Formaldehyde examination probe as described above, it is preferable that the pilot hole through upper bottom surface is provided on the pedestal, it is described Pedestal is mounted in formaldehyde examination system by pilot hole.
Formaldehyde examination probe as described above, it is preferable that the air inlet column be it is cylindric, set at the axis of the air inlet column It is equipped with air inlet.
Formaldehyde examination probe as described above, it is preferable that the outgassing column be it is cylindric, set at the axis of the outgassing column It is equipped with gas outlet.
Compared with the immediate prior art, technical solution provided by the utility model has following excellent effect:
Formaldehyde examination probe provided by the utility model, using the formaldehyde sensing element for being attached with formaldehyde sensitive thin film, benefit The formaldehyde sensing probe formed with Optochemical sensor principle, utilizes its formaldehyde sensitive thin film and the formaldehyde phase in detected air The change of spectral intensity caused by interaction detects content of formaldehyde, cheap, and it is excellent to have that selectivity is good, sensitivity is high etc. Point, using fiber optic conduction light, transmission speed is fast, strong antijamming capability, using micropump, increases the flowing of gas to be detected Property, keep detection more accurate, pilot hole is arranged in cover board, cooperates the use of shading cover, facilitate the installation of formaldehyde sensing element with more It changes.The development of PARA FORMALDEHYDE PRILLS(91,95) detection technique has important meaning.
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide a further understanding of the present invention, this is practical Novel illustrative embodiments and their description are not constituteed improper limits to the present invention for explaining the utility model.
Wherein:
Fig. 1 is the explosive view that the formaldehyde examination of the utility model embodiment is popped one's head in;
Fig. 2 is the structural schematic diagram of the formaldehyde sensing element of the utility model embodiment;
Fig. 3 is the explosive view that the formaldehyde examination of the utility model embodiment 2 is popped one's head in;
Fig. 4 is the explosive view that the formaldehyde examination of the utility model embodiment 3 is popped one's head in.
In figure: 1, probe body;2, cover board;3, shading cover;4, incidental optical fibre connectors;5, the output optical fiber connector;6, Air inlet column;7, outgassing column;8, micropump;9, formaldehyde sensing element;91, glass backing plate;92, formaldehyde sensitive thin film;10, pedestal.
Specific embodiment
The utility model will be described in detail below with reference to the accompanying drawings and embodiments.It should be noted that not conflicting In the case where, the features in the embodiments and the embodiments of the present application can be combined with each other.
In the description of the present invention, term " longitudinal direction ", " transverse direction ", "upper", "lower", "front", "rear", "left", "right", The orientation or positional relationship of the instructions such as "vertical", "horizontal", "top", "bottom" is to be based on the orientation or positional relationship shown in the drawings, It is merely for convenience of description the utility model rather than requires the utility model that must be constructed and operated in a specific orientation, therefore It should not be understood as limiting the present invention.Term used in the utility model " connected ", " connection " shall be understood in a broad sense, For example, it may be being fixedly connected, may be a detachable connection;It can be directly connected, it can also be indirect by intermediate member It is connected, for the ordinary skill in the art, can understands the concrete meaning of above-mentioned term as the case may be.
Embodiment 1
Specific embodiment according to the present utility model, as depicted in figs. 1 and 2, formaldehyde examination probe includes:
Probe body 1, probe body 1 be box like structure, the upper opening of probe body 1, the leading flank of probe body 1, Trailing flank, left side and right side are provided with mounting hole.
Upper cover, upper cover are close contact in the opening on 1 top of probe body, form closed structure;Upper cover includes cover board 2 and shading Lid 3 is provided with pilot hole on cover board 2, is conveniently replaceable formaldehyde sensing element 9, and shading cover 3 is mounted on the upper of pilot hole on cover board 2 Side.
Incidental optical fibre connectors 4, incidental optical fibre connectors 4 are assemblied in the mounting hole of the right side of probe body 1, are convenient for Incident ray is conducted to formaldehyde examination and is popped one's head in.
The output optical fiber connector 5, the output optical fiber connector 5 are assemblied in the mounting hole of the left side of probe body 1, are convenient for Light conduction after reacted in probe body 1 is gone out into formaldehyde examination probe.
Air inlet column 6, air inlet column 6 are assemblied in the mounting hole of the leading flank of probe body 1, air inlet column 6 be it is cylindric, into It is provided with air inlet at the axis of air column 6, is provided with strainer in air inlet, the impurity such as sucking dust are avoided, to influence to detect As a result.
Outgassing column 7, outgassing column 7 are assemblied in the mounting hole of the trailing flank of probe body 1, outgassing column 7 be it is cylindric, go out Gas outlet is provided at the axis of air column 7, the end of outgassing column 7 is provided with micropump 8, and the entrance of micropump 8 connects gas outlet, The setting of micropump 8 makes formaldehyde examination probe and internal formation negative pressure, gas to be detected is promoted to enter probe originally from air inlet column 6 In body 1, promotes the gas circulation in probe body 1, make to detect more accurate.
Formaldehyde sensing element 9, formaldehyde sensing element 9 are located in probe body 1, and the forward and backward inner wall of probe body 1 is provided with Guide groove, formaldehyde sensing element 9 are inserted into the guide groove in probe body 1 by the pilot hole on cover board 2, make the sensitive member of formaldehyde Part 9 is put vertical vertically, and probe body 1 is divided for left and right two chambers;Formaldehyde sensing element 9 includes glass backing plate 91 and is attached to glass Formaldehyde sensitive thin film 92 on glass liner plate 91;In the embodiments of the present invention, formaldehyde sensitive thin film 92 is multiple using Eu-NDC Film is closed, which has double emission peaks;In general group of the lanthanides sensor, it is most of be all based on single-shot penetrate it is luminous sudden It goes out, they usually will receive the influence of environment, such as fluctuate source strength, sensor concentration etc..This will lead to the inaccuracy of detection;Tool There is 92 sensor of formaldehyde sensitive thin film of double emission peaks to provide a kind of self calibration mechanism, the hair for the more different centres of luminescence Luminous intensity, without any external reference.When exciting Eu-NDC laminated film with the light of wavelength 360nm, Eu-NDC THIN COMPOSITE Film can issue fluorescence, and for emission spectrum mainly there are three emission peak, launch wavelength is respectively 453nm, 590nm and 612nm, inspection The variation for surveying fluorescence intensity can get concentration of formaldehyde;With the increase of concentration of formaldehyde, emit at spectral emissions wavelength 612nm Fluorescence intensity is gradually reduced, and the fluorescence emitted at spectral emissions wavelength 453nm will gradually increase, and spectral emissions wavelength The ratio and concentration of formaldehyde of the fluorescence intensity emitted at the fluorescence intensity and spectral emissions wavelength 612nm emitted at 453nm are kept Good linear relationship can measure the concentration of formaldehyde using this rule;It is dense that the variation of fluorescence intensity can get formaldehyde Degree.Formaldehyde sensing element 9 is located at 1 inside left of probe body, close to 5 side of the output optical fiber connector, such sensitive thin film hair Fluorescence out is easier to be received optical fiber collection;Formaldehyde sensitive thin film 92 is located at the right side of glass backing plate 91, close to incident optical 4 side of connector.
Pedestal 10, pedestal 10 are disk platform, and for carrying probe body 1, the bottom surface of probe body 1 is assemblied in pedestal 10 Upper surface, pedestal 10 is provided with the pilot hole through upper bottom surface, convenient for by formaldehyde examination probe assembly in formaldehyde examination system In system.
The formaldehyde examination is popped one's head in when in use, and formaldehyde examination probe is put into environment to be detected, first by formaldehyde sensitivity Element 9 is inserted into the guide groove in probe body 1 by the pilot hole on cover board 2, covers shading cover 3, it is ensured that closed opaque; Then starting is mounted on the micropump 8 of outgassing column 7, recycles gas to be detected sufficiently in probe body 1, light passes through incidence In fiber optic conduction to probe body 1, in atmosphere to be detected, excitation formaldehyde sensing element 9 issues fluorescence, and fluorescence is by going out It penetrates fiber optic conduction and goes out formaldehyde examination probe, analyzed into next component.
Embodiment 2
In order to simplify the structure of formaldehyde examination probe, as shown in figure 3, distinguishing in the leading flank of probe body 1 and trailing flank Air inlet and air outlet are set, and micropump 8 is connected directly between at gas outlet, and which simplify the structures of formaldehyde examination probe, is made Production cost further decreases.Other implementation steps are same as Example 1, and details are not described herein.
Embodiment 3
In order to simplify the structure of formaldehyde examination probe, cost is reduced, as shown in figure 4, cover board 2 is tabular, is set on cover board 2 It is equipped with mounting hole corresponding with probe body 1, when replacing formaldehyde sensing element 9, removes cover board 2, by 9 edge of formaldehyde sensing element 1 inner sidewall of probe body guide groove be packed into, cover cover board 2, can be detected, which simplify formaldehyde examination probe Structure further decreases manufacturing cost.Other implementation steps are same as Example 1, and details are not described herein.
In conclusion formaldehyde examination probe provided by the utility model, quick using the formaldehyde for being attached with formaldehyde sensitive thin film Sensing unit, the formaldehyde sensing probe formed using Optochemical sensor principle, utilizes its formaldehyde sensitive thin film and detected air In the change of formaldehyde interaction caused spectral intensity detect content of formaldehyde, it is cheap, have selectivity good, clever The advantages that sensitivity is high, using fiber optic conduction light, transmission speed is fast, strong antijamming capability, visits formaldehyde examination using micropump Negative pressure is formed in head, increases the flowing of gas to be detected, keeps detection more accurate, and pilot hole is arranged in cover board, cooperates shading cover It uses, facilitates the installation and replacement of formaldehyde sensing element.The development of PARA FORMALDEHYDE PRILLS(91,95) detection system has important meaning.
The above is only the preferred embodiment of the present invention, is not intended to limit the utility model, for this field Technical staff for, various modifications and changes may be made to the present invention.Within the spirit and principle of the utility model, Any modification, equivalent replacement, improvement and so on should be included within the scope of protection of this utility model.

Claims (10)

1. a kind of formaldehyde examination probe, which is characterized in that the formaldehyde examination, which is popped one's head in, includes:
Probe body, the probe body are box like structure, the upper opening of the probe body, the front side of the probe body Face, trailing flank, left side and right side are provided with mounting hole;
Upper cover, the upper cover are close contact at the upper opening of the probe body, form closed structure;
Incidental optical fibre connectors, the incidental optical fibre connectors are assemblied in the mounting hole of the right side of the probe body;
The output optical fiber connector, in the mounting hole for the left side that the output optical fiber connector device fits over the probe body;
Air inlet column, in the mounting hole for the leading flank that the air inlet column is assemblied in the probe body;
Outgassing column, the outgassing column are assemblied in the mounting hole of the trailing flank of the probe body;
Formaldehyde sensing element, the formaldehyde sensing element are located in the probe body, and formaldehyde sensing element divides probe body For left and right two chambers, formaldehyde sensing element includes glass backing plate and the formaldehyde sensitive thin film that is attached on glass backing plate.
2. formaldehyde examination as described in claim 1 probe, which is characterized in that the upper cover includes cover board and shading cover, described It is provided with pilot hole on cover board, is conveniently replaceable formaldehyde sensing element, the top of the pilot hole of the shading cover installation on the cover board.
3. formaldehyde examination probe as described in claim 1, which is characterized in that the end of the outgassing column is provided with micropump, Convenient for promoting the gas circulation in probe body.
4. formaldehyde examination probe as described in claim 1, which is characterized in that the formaldehyde sensing element is located at close to emergent light In the probe body of fiber connector side.
5. formaldehyde examination probe as described in claim 1, which is characterized in that the formaldehyde sensitive thin film is located at the glass lined The right side of plate.
6. formaldehyde examination probe as described in claim 1, which is characterized in that the formaldehyde examination probe further includes pedestal, institute The lower section that pedestal is located at the probe body is stated, for carrying probe body.
7. formaldehyde examination probe as claimed in claim 6, which is characterized in that the pedestal is disc platform, the probe The bottom surface of ontology is assemblied in the upper surface of the pedestal.
8. formaldehyde examination probe as claimed in claim 7, which is characterized in that be provided on the pedestal through upper bottom surface Pilot hole, the pedestal are mounted in formaldehyde examination system by pilot hole.
9. formaldehyde examination as described in claim 1 probe, which is characterized in that the air inlet column be it is cylindric, in the air inlet Air inlet is provided at the axis of column.
10. formaldehyde examination as described in claim 1 probe, which is characterized in that the outgassing column be it is cylindric, in the outlet Gas outlet is provided at the axis of column.
CN201821922066.6U 2018-11-21 2018-11-21 A kind of formaldehyde examination probe Expired - Fee Related CN209102611U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821922066.6U CN209102611U (en) 2018-11-21 2018-11-21 A kind of formaldehyde examination probe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821922066.6U CN209102611U (en) 2018-11-21 2018-11-21 A kind of formaldehyde examination probe

Publications (1)

Publication Number Publication Date
CN209102611U true CN209102611U (en) 2019-07-12

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CN201821922066.6U Expired - Fee Related CN209102611U (en) 2018-11-21 2018-11-21 A kind of formaldehyde examination probe

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111707309A (en) * 2020-06-15 2020-09-25 岱特智能科技(昆山)有限公司 Laboratory environment detection device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111707309A (en) * 2020-06-15 2020-09-25 岱特智能科技(昆山)有限公司 Laboratory environment detection device

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Granted publication date: 20190712