CN209076651U - Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol - Google Patents

Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol Download PDF

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Publication number
CN209076651U
CN209076651U CN201821752336.3U CN201821752336U CN209076651U CN 209076651 U CN209076651 U CN 209076651U CN 201821752336 U CN201821752336 U CN 201821752336U CN 209076651 U CN209076651 U CN 209076651U
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carbinol
methanol
layer
hydrogen production
production units
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陈杰平
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Zhejiang Hydrogen Valley New Energy Automobile Co Ltd
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Zhejiang Hydrogen Valley New Energy Automobile Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • Y02P20/133Renewable energy sources, e.g. sunlight

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Abstract

The utility model belongs to Technology for Production Hydrogen from Methanol field more particularly to a kind of methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol.The utility model, including jacket reactor, the jacket reactor includes the internal reaction kettle ontology with reaction chamber, the reaction kettle body outer surface is equipped with chuck layer, the chuck layer upper section is equipped with conduction oil outlet, lower section is equipped with heat conducting oil inlet, there is discharge port on the jacket reactor, bottom has baiting valve, it further include the feed pipe that one end penetrated through this body sidewall of reaction kettle and was connected to reaction chamber, the feed pipe outer surface is equipped with one layer of magnetic clad, and reaction kettle body internal surface has one layer of enamel layer.The utility model reaction kettle body internal surface has one layer of enamel layer, and one layer of magnetic clad is equipped in feed pipe outer surface, it can prevent in this way containing iron, cobalt and nickel in reaction system, therefore the generation of methane byproduct can be prevented, to improve the conversion ratio of hydrogen.

Description

Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol
Technical field
The utility model belongs to Technology for Production Hydrogen from Methanol field, more particularly to a kind of applied to solar powered auxiliary methanol system The methanol decomposition reactor of hydrogen production device.
Background technique
In existing hydrogen from methyl alcohol technique, in fill process, raw material is after being evaporated to gas by pipeline to anti- It answers in device, may make to be mixed with the impurity such as iron, cobalt, nickel in raw material in this way in preprocessing process, be generated after leading to methanol decomposition More methane gas, so that hydrogen conversion reduces.
For example, Chinese utility model patent discloses a kind of hydrogen production units by carbinol [application number: 201720057475.3], should Utility model patent includes reaction kettle and chassis, and the upper side of the chassis is fixed by being mounted on the fixing seat above chassis There is hold-up tank, the interior bottom portion of the hold-up tank is equipped with liquid level sensor, and the top of the solenoid valve is connected with feed pipe, institute It states burner to connect with feed pipe, reaction kettle and hold-up tank respectively by pipeline, the top that the reaction kettle is mounted on chassis is another The side of side, the drawing liquid pump is connect by pipeline with hold-up tank, and the other side is connect by pipeline with reaction kettle, the reaction Lower position in kettle front surface close to observation window is equipped with control panel, and the rear of reaction kettle is provided with pressure-variable adsorption Device, the reaction kettle right side are equipped with tail gas buffer, the reaction kettle and transformation at the front position of pressure swing adsorber Absorber is connected by pipeline, while pipeline middle position is equipped with condenser, and the lower end of the condenser is connected with condensation Liquid pipe, and the other end of condensate line is connect with feed pipe, the tail gas buffer by pipeline respectively with pressure swing adsorber, Burner connection, the pressure swing adsorber is internally provided with adsorbent, and the right end of pressure swing adsorber is connected with hydrogen outlet, Gas flowmeter, the solenoid valve, gas stream are installed at the right positions of pressure swing adsorber above the hydrogen outlet Meter, drawing liquid pump, burner and liquid level sensor are electrically connected with control panel.
Reaction kettle in the utility model patent is reaction kettle commonly used in the prior art, and is directed to the cracking reaction Special structure design is carried out, therefore still there is above-mentioned problem.
Utility model content
The purpose of this utility model is in view of the above-mentioned problems, providing a kind of applied to solar powered auxiliary hydrogen from methyl alcohol dress The methanol decomposition reactor set.
In order to achieve the above objectives, the utility model uses following technical proposal:
A kind of methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol, including jacket reactor, The jacket reactor includes the internal reaction kettle ontology with reaction chamber, and the reaction kettle body outer surface is equipped with collet Layer, the chuck layer upper section are equipped with conduction oil outlet, and lower section is equipped with heat conducting oil inlet, has discharging on the jacket reactor Mouthful, it further includes the feed pipe that one end penetrated through this body sidewall of reaction kettle and was connected to reaction chamber, institute that bottom, which has baiting valve, Feed pipe outer surface is stated equipped with one layer of magnetic clad, reaction kettle body internal surface has one layer of enamel layer.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the reaction chamber Room is also communicated with vacuum source and inert gas source, and a control is respectively equipped between vacuum source and inert gas source and jacket reactor Valve processed.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the collet is anti- Answer and be additionally provided with the triple valve that one end is connected with reaction chamber on kettle, remaining both ends of the triple valve respectively with vacuum source and lazy Property gas source connection.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the feed pipe Road is communicated with methanol evaporator and/or deionized water evaporator far from one end of reaction chamber, and methanol tank passes through the first conveying Pump is connected to methanol evaporator, and deionized water storage tank is connected to by the second delivery pump with deionized water evaporator, and the collet is anti- Answer kettle top portion that there is the catalyst addition tube being connected with reaction chamber, catalyst storage bottle is detachably connected on catalyst addition tube On, it further include aftertreatment assembly and heat-conducting oil pipes, the aftertreatment assembly is connected to discharge port, the both ends point of the heat-conducting oil pipes It is not connected to conduction oil outlet and heat conducting oil inlet, solar heater is arranged on heat-conducting oil pipes.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the solar energy Heater includes the solar panel, voltage-stablizer and electric heating coil being sequentially connected electrically, and the electric heating coil is located at heat-conducting oil heating case Interior, heat-conducting oil heating case is connected on heat-conducting oil pipes.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the electric heating coil Also it is electrically connected by spare electric wire with external power supply.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the conduction oil Heater box bottom is additionally provided with the stirring rotator that opposite heat-conducting oil heating case rotational motion can occur.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, methanol evaporator Pressure gauge is equipped with on deionized water evaporator.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the post-processing Component includes the condenser being sequentially communicated, hydrogen adsorption device and exhaust gas warehouse, and the condenser is anti-by discharge port and collet Kettle is answered to be connected to.
It is applied in the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol in above-mentioned, the hydrogen is inhaled Attaching is set to pressure swing adsorber.
Compared with prior art, utility model has the advantages that
1, the utility model reaction kettle body internal surface has one layer of enamel layer, and is equipped with one in feed pipe outer surface The magnetic clad of layer, can prevent in this way containing iron, cobalt and nickel in reaction system, therefore can prevent the generation of methane byproduct, To improve the conversion ratio of hydrogen.
2, the utility model provides Initial energy source using solar power generation for methanol decomposition hydrogen manufacturing, reduces the whole energy Consumption, to reduce production cost accordingly.
3, the utility model removes the air in jacket reactor using vacuum source and inert gas source cooperation, therefore can prevent Reaction generates oxidation impurities, to improve the conversion ratio of hydrogen.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model;
Fig. 2 is the structural schematic diagram of hydrogen production units by carbinol;
Fig. 3 is the structural schematic diagram of solar heater;
Fig. 4 is the structural schematic diagram of heater box;
In figure: methanol tank 1, deionized water storage tank 2, the first delivery pump 3, methanol evaporator 4, the second delivery pump 5, go from Sub- water evaporimeter 6, jacket reactor 7, catalyst storage bottle 8, discharge port 9, aftertreatment assembly 10, heat-conducting oil pipes 11, solar energy add Hot device 12, solar panel 13, voltage-stablizer 14, electric heating coil 15, heat-conducting oil heating case 16, spare electric wire 17, stirring rotator 18, Feed pipe 19, magnetic clad 20, pressure gauge 21, vacuum source 22, inert gas source 23, control valve 24, condenser 25, hydrogen Aspiration adsorption device 26, exhaust gas warehouse 27, reaction kettle ontology 71, reaction chamber 72, chuck layer 73, conduction oil outlet 74, conduction oil Entrance 75, baiting valve 76, enamel layer 77, catalyst addition tube 78, triple valve 79.
Specific embodiment
The utility model is described in more detail with reference to the accompanying drawings and detailed description.
As shown in Figure 1, a kind of methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol, including folder Reaction kettle 7 is covered, the jacket reactor 7 includes the internal reaction kettle ontology 71 with reaction chamber 72, the reaction kettle ontology 71 outer surfaces are equipped with chuck layer 73, and 73 upper section of chuck layer is equipped with conduction oil outlet 74, and lower section is equipped with heat conducting oil inlet 75, institute Stating has discharge port 9 on jacket reactor 7, bottom has baiting valve 76, has at the top of the jacket reactor 7 and reaction chamber 72 catalyst addition tubes 78 being connected, catalyst storage bottle 8 are detachably connected in catalyst addition tube 78, further include that one end is passed through The feed pipe 19 for passing through 71 side wall of reaction kettle ontology and being connected to reaction chamber 72,19 outer surface of feed pipe are equipped with one The magnetic clad 20 of layer, 71 inner surface of reaction kettle ontology have one layer of enamel layer 77.
The utility model, in use, methanol gas and deionized are equipped with one layer of magnetic clad by outer surface 20 feed pipe 19 enters in reaction chamber 72, and the catalyst in catalyst storage bottle 8 is added to reaction chamber 72, conduction oil Chuck layer 73 is flowed into from heat conducting oil inlet 75, then flows out chuck layer 73 from conduction oil outlet 74, thus in reaction chamber 72 Gaseous methanol and gaseous state deionized water are heated, so that methanol decomposition, the mixed gas after reaction is discharged by discharge port 9, Condensate liquid and catalyst can be discharged from baiting valve 76, therefore the utility model is equipped with one layer of enamel layer in 71 inner surface of reaction kettle ontology 77, and it is equipped with one layer of magnetic clad 20 in 19 outer surface of feed pipe, it can prevent to contain iron, cobalt in reaction system in this way And nickel, therefore the generation of methane byproduct can be prevented, to improve the conversion ratio of hydrogen.
Referring to figs. 1 and 2, the reaction chamber 72 is also communicated with vacuum source 22 and inert gas source 23, vacuum source A control valve 24 is respectively equipped between 22 and inert gas source 23 and jacket reactor 7, wherein inert gas source 23 provides Inert gas can be argon gas, be also possible to helium, in this way using vacuum source 22 and inert gas source 23 cooperation remove folder The air (mainly oxygen) in reaction kettle 7 is covered, therefore can prevent reaction from generating oxidation impurities, to improve the conversion ratio of hydrogen.
Preferably, it is additionally provided with the triple valve 79 that one end is connected with reaction chamber 72 on the jacket reactor 7, described three Remaining both ends of port valve 79 are connected to vacuum source 22 and inert gas source 23 respectively, and triple valve 79, which can facilitate, removes reaction chamber 72 The operation of interior air.
Referring to figs. 1 and 2, the feed pipe 19 is communicated with methanol evaporator 4 far from one end of reaction chamber 72 And/or deionized water evaporator 6, methanol tank 1 are connected to by the first delivery pump 3 with methanol evaporator 4, deionized water storage tank 2 It is connected to by the second delivery pump 5 with deionized water evaporator 6, further includes aftertreatment assembly 10 and heat-conducting oil pipes 11, locate after described Reason component 10 is connected to discharge port 9, and the both ends of the heat-conducting oil pipes 11 connect with conduction oil outlet 74 and heat conducting oil inlet 75 respectively Logical, solar heater 12 is arranged on heat-conducting oil pipes 11.
In use, the deionized water in methanol and deionized water storage tank 2 in methanol tank 1 passes through the first delivery pump respectively 3 and second delivery pump 5 be delivered to methanol evaporator 4 and water evaporimeter 6, gaseous state is evaporated to by liquid, gaseous methanol and gaseous state are gone Ionized water is entered in jacket reactor 7 by feed pipe 19, and the catalyst in catalyst storage bottle 8 is added to jacket reactor 7 In, the high temperature heat conductive oil heated in heat-conducting oil pipes 11 through solar heater 12 enters from the bottom of 7 chuck layer of jacket reactor, From top flow out, and in jacket reactor 7 gaseous methanol and gaseous state deionized water heat so that jacket reactor 7 Interior methanol decomposition, the post-treated post-processing of component 10 of mixed gas after the reaction was completed obtains hydrogen, therefore the utility model utilizes Solar heater 12 provides Initial energy source for methanol decomposition hydrogen manufacturing, reduces whole energy consumption, to reduce accordingly Production cost.
Preferably, it is equipped with pressure gauge 21 on methanol evaporator 4 and deionized water evaporator 6, can preferably controlled in this way The partial pressure of gaseous methanol and gaseous state deionized water in jacket reactor 7, to guarantee the conversion ratio of reaction.
Specifically, the aftertreatment assembly 10 includes condenser 25, hydrogen adsorption device 26 and the exhaust gas being sequentially communicated Warehouse 27, the condenser 25 are connected to by discharge port 9 with jacket reactor 7.
When post-processing, deionized and methanol vapor in mixed gas are condensed into liquid in condenser 25 and are removed It going, the hydrogen in remaining hydrogen-rich gas is adsorbed in hydrogen adsorption device 26, and remainder of exhaust gas is transferred to exhaust gas warehouse 27, In, hydrogen adsorption device 26 can be pressure swing adsorber, it is adsorbed from hydrogen rich stream using pressure swing adsorption method and purifying hydrogen of hydrogen, The hydrogen purification pressure-swing absorption apparatus provided in Chinese utility model patent application No. is 201521056228.9 is provided.
In conjunction with shown in Fig. 3 and Fig. 4, the solar heater 12 includes the solar panel 13 being sequentially connected electrically, steady Depressor 14 and electric heating coil 15, the electric heating coil 15 are located in heat-conducting oil heating case 16, and heat-conducting oil heating case 16 is connected in conduction oil On pipe 11, solar energy is changed into electric energy by solar panel 13, and by 14 electric heating electric heating coil 15 of voltage-stablizer, makes electric heating coil 15 pairs of conduction oils for flowing through heat-conducting oil heating case 16 carry out heat temperature raising.
Preferably, the electric heating coil 15 is also electrically connected by spare electric wire 17 with external power supply, in this way in solar battery It powers in the case where 13 electricity shortage of plate using external power supply, to guarantee the stability of device work.
Preferably, 16 bottom of heat-conducting oil heating case, which is additionally provided with, can occur opposite 16 rotational motion of heat-conducting oil heating case Stirring rotator 18 can improve the uniformity of the thermally conductive oil temperature in heat-conducting oil heating case 16 in this way.
The working principle of the utility model is: in use, being gone in methanol and deionized water storage tank 2 in methanol tank 1 Ionized water passes through the first delivery pump 3 respectively and the second delivery pump 5 is delivered to methanol evaporator 4 and water evaporimeter 6, is evaporated by liquid For gaseous state, gas pressure intensity therein is monitored using pressure gauge 21, removes dereaction using vacuum source 22 and the cooperation of inert gas source 23 Air in chamber 72, methanol gas and deionized are equipped with the feed pipe of one layer of magnetic clad 20 by outer surface 19 enter in reaction chamber 72, and the catalyst in catalyst storage bottle 8 is added to reaction chamber 72, through thermally conductive in heat-conducting oil pipes 11 The high temperature heat conductive oil that electric heating coil 15 in oily heater box 16 heats flows into chuck layer 73 from heat conducting oil inlet 75, then goes out from conduction oil Mouthfuls 74 flow out chuck layers 73, thus in reaction chamber 72 gaseous methanol and gaseous state deionized water heat so that methanol Cracking, the mixed gas after reaction are discharged by discharge port 9, and deionized and methanol vapor therein are in condenser 25 It is condensed into liquid to be removed, the hydrogen in remaining hydrogen-rich gas is adsorbed in hydrogen adsorption device 26, remainder of exhaust gas transfer To exhaust gas warehouse 27, the catalyst of the condensate liquid and addition that generate in reaction process can be discharged from baiting valve 76, therefore this is practical new Type is equipped with one layer of enamel layer 77 in 71 inner surface of reaction kettle ontology, and is equipped with one layer of magnetic cladding in 19 outer surface of feed pipe Layer 20 can prevent in this way containing iron, cobalt and nickel in reaction system, therefore can prevent the generation of methane byproduct, to improve The conversion ratio of hydrogen.
The specific embodiments described herein are merely examples of the spirit of the present invention.The utility model institute Belonging to those skilled in the art can make various modifications or additions to the described embodiments or using similar Mode substitute, but without departing from the spirit of the present application or beyond the scope of the appended claims.
Although be used more herein methanol tank 1, deionized water storage tank 2, the first delivery pump 3, methanol evaporator 4, It is second delivery pump 5, deionized water evaporator 6, jacket reactor 7, catalyst storage bottle 8, discharge port 9, aftertreatment assembly 10, thermally conductive Oil pipe 11, solar heater 12, solar panel 13, voltage-stablizer 14, electric heating coil 15, heat-conducting oil heating case 16, standby electricity Line 17, stirring rotator 18, feed pipe 19, magnetic clad 20, pressure gauge 21, vacuum source 22, inert gas source 23, control valve It is door 24, condenser 25, hydrogen adsorption device 26, exhaust gas warehouse 27, reaction kettle ontology 71, reaction chamber 72, chuck layer 73, thermally conductive The terms such as oil export 74, heat conducting oil inlet 75, baiting valve 76, enamel layer 77, catalyst addition tube 78, triple valve 79, but not It rules out the possibility of using other terms.The use of these items is only for be more convenient to describe and explain the utility model Essence;It is contrary to the spirit of the present invention to interpret them as any one of the additional limitations.

Claims (10)

1. a kind of methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol, including jacket reactor (7), It is characterized by: the jacket reactor (7) includes the internal reaction kettle ontology (71) with reaction chamber (72), the reaction Kettle ontology (71) outer surface is equipped with chuck layer (73), and chuck layer (73) upper section is equipped with conduction oil outlet (74), and lower section is equipped with Heat conducting oil inlet (75) has discharge port (9) on the jacket reactor (7), and bottom has baiting valve (76), and the collet is anti- Answering has the catalyst addition tube (78) being connected with reaction chamber (72) at the top of kettle (7), catalyst storage bottle (8) is detachably connected It further include that one end penetrated through reaction kettle ontology (71) side wall and was connected to reaction chamber (72) on catalyst addition tube (78) Feed pipe (19), feed pipe (19) outer surface are equipped with one layer of magnetic clad (20), reaction kettle ontology (71) interior table Face has one layer of enamel layer (77).
2. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as described in claim 1, it is special Sign is: the reaction chamber (72) is also communicated with vacuum source (22) and inert gas source (23), vacuum source (22) and indifferent gas A control valve (24) is respectively equipped between body source (23) and jacket reactor (7).
3. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 2, it is special Sign is: the triple valve (79) that one end is connected with reaction chamber (72), the threeway are additionally provided on the jacket reactor (7) Remaining both ends of valve (79) are connected to vacuum source (22) and inert gas source (23) respectively.
4. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as described in claim 1, it is special Sign is: the feed pipe (19) is communicated with methanol evaporator (4) and/or deionized water far from the one end of reaction chamber (72) Evaporator (6), methanol tank (1) are connected to by the first delivery pump (3) with methanol evaporator (4), and deionized water storage tank (2) passes through Second delivery pump (5) is connected to deionized water evaporator (6), further includes aftertreatment assembly (10) and heat-conducting oil pipes (11), described Aftertreatment assembly (10) is connected to discharge port (9), the both ends of the heat-conducting oil pipes (11) respectively with conduction oil outlet (74) and lead Hot oil entrance (75) connection, solar heater (12) are arranged on heat-conducting oil pipes (11).
5. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 4, it is special Sign is: the solar heater (12) includes the solar panel (13), voltage-stablizer (14) and electric heating being sequentially connected electrically It encloses (15), the electric heating coil (15) is located in heat-conducting oil heating case (16), and heat-conducting oil heating case (16) is connected in heat-conducting oil pipes (11) on.
6. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 5, it is special Sign is: the electric heating coil (15) is also electrically connected by spare electric wire (17) with external power supply.
7. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 5, it is special Sign is: heat-conducting oil heating case (16) bottom is additionally provided with the stirring that opposite heat-conducting oil heating case (16) rotational motion can occur Rotor (18).
8. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 4, it is special Sign is: being equipped with pressure gauge (21) on methanol evaporator (4) and deionized water evaporator (6).
9. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 4, it is special Sign is: the aftertreatment assembly (10) includes the condenser (25), hydrogen adsorption device (26) and exhaust gas warehouse being sequentially communicated (27), the condenser (25) is connected to by discharge port (9) with jacket reactor (7).
10. it is applied to the methanol decomposition reactor of solar powered auxiliary hydrogen production units by carbinol as claimed in claim 9, it is special Sign is: the hydrogen adsorption device (26) is pressure swing adsorber.
CN201821752336.3U 2018-10-26 2018-10-26 Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol Active CN209076651U (en)

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CN201821752336.3U CN209076651U (en) 2018-10-26 2018-10-26 Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109126639A (en) * 2018-10-26 2019-01-04 浙江氢谷新能源汽车有限公司 Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109126639A (en) * 2018-10-26 2019-01-04 浙江氢谷新能源汽车有限公司 Methanol decomposition reactor applied to solar powered auxiliary hydrogen production units by carbinol
CN109126639B (en) * 2018-10-26 2024-03-15 浙江氢谷新能源汽车有限公司 Methanol cracking reactor applied to solar power supply auxiliary methanol hydrogen production device

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