CN209039254U - A kind of Zero discharging system of suitable industrial circulating water - Google Patents
A kind of Zero discharging system of suitable industrial circulating water Download PDFInfo
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- CN209039254U CN209039254U CN201820656903.9U CN201820656903U CN209039254U CN 209039254 U CN209039254 U CN 209039254U CN 201820656903 U CN201820656903 U CN 201820656903U CN 209039254 U CN209039254 U CN 209039254U
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Abstract
The utility model relates to a kind of Zero discharging systems of suitable industrial circulating water, are separated into recirculated water (2) and sewerage (3) after entering other filter unit (10) processing of electrolysis from extraction system recirculated water (1) in circulation;Wherein, recirculated water (2) returns in the circulatory system, and sewerage (3) is handled into precipitation unit (11);Sewerage (3) is separated into clear liquid (4) and sludge (6) after handling by precipitation unit, clear liquid (4) enters in filter element;Clear liquid (4) is separated into filtrate (5) and filter residue after entering filter element (12) processing, and filtrate (5) enters in desalination unit (13), and sludge filter residue (6) is used as fixed-end forces;Filtrate (5) is separated into desalination water after desalination unit (13) are handled and returns to circulation, and concentrated water enters evaporation element.The utility model, which is reduced, even removes various antisludging agents, corrosion inhibiter, fungicide of recirculated water etc. from, thus investment reduction cost.
Description
Technical field
The utility model relates to a kind of sewage disposal systems, more particularly, to a kind of zero-emission system of suitable industrial circulating water
System.
Background technique
Mankind's daily life be unable to do without water, and industrial production similarly be unable to do without water.Water consumption is also got over the development of industry
Come bigger, China is water resource critical shortage and the country that is unevenly distributed, and the effective use of water resource directly affects social economy
Development, therefore rationally and water conservation have become a critical issue.
Industrial water mainly includes boiler feed water, Municipal Sewage for Circulating, process water, water for cleaning etc..It wherein recycles cold
But water is to use water sport, and in industries such as petrochemical industry, steel, metallurgy, recirculated cooling water accounts for the 50%-90% of enterprise water use, special
It is not that 90 or more percent is accounted for as the Municipal Sewage for Circulating in thermal power plant.Since recirculating cooling water system is in continuous work mistake
A large amount of evaporations, free-and-easy etc. occur for Cheng Zhonghui, it is necessary to constantly to circulatory system moisturizing, so as to cause objects various in circulation
Matter is continuously increased concentration, wherein just including fouling tendency and corrosive ion calcium ion, magnesium ion, sulfate ion, carbonate
Ion, chloride ion, iron ion etc., these ions reach a certain concentration will the fouling in equipment and pipeline, while can corrode and set
Standby and pipeline.According to national standards, when the total content of chloride ion in recirculated water and sulfate ion is greater than 1100mg/1, circulation
System needs to carry out sewage treatment, and water amount of blowdown is big and belongs to industrial wastewater, need to handle it is up to standard after could discharge.
In line with water conservation and high-efficient water use principle, the generation of fouling and corrosion is all prevented with adding method thereof at this stage,
To improve cycles of concentration.The cycles of concentration of recirculated water be the recirculated cooling water salt content with its supplement water salt content it
Than.Cycles of concentration is improved, the dosage that can reduce supplement water can also reduce blowdown flow rate to save water resource, to reduce
Harm of the treating capacity and reduction of sewage to bad border.But the various medicaments being added are in the cost for increasing operation while having brought into new
Pollution factor, such as ammonia nitrogen, phosphorus etc..
The processing of circulating sewage at this stage is generally Alternative combination, including chemical precipitation tenderizer, filtration method, film point
From method, bioanalysis etc..After circulating sewage enters precipitation unit, flocculant etc. need to be added to precipitation unit and carry out coagulating sedimentation,
Most turbidity and suspended matter are removed, the sludge of precipitating can send processing outside.Large-scale recirculating cooling water system is generally used with stone
Sand or anthracite are filter tank by the gravity valveless of filtrate, and filtering velocity can only be controlled in 10m/h hereinafter, and the suspended matter of cooling water
Concentration can only be controlled in 10mg/L hereinafter, the increase of blowdown flow rate causes infrastructure investment to increase.The water outlet of precipitation unit enters filtering
Unit, generally successively into PCF filter, self-cleaning filter and ultrafilter excessively, the same Treatment of Sludge of filter residue.Filtrate due to
There is the presence of ammonia nitrogen and phosphorus etc., need to just can enter reverse osmosis Deng desalinations unit after biochemical treatment.Hyperfiltration can be effective
The harmful components such as hardness, microorganism in cooling water are removed, there is a higher salt rejection rate, the water rate of recovery can achieve 75%~
90%, the disadvantage is that requiring harshness to influent quality, and the pressure oscillation in operational process easily leads to film and is destroyed, the corrosion in water
Product and microorganism easily block pre-flock device and reverse osmosis membrane, pollution, and frequent cleaning increases operating cost and disposable
Input cost is higher.Desalination unit desalination water can directly return to circulation, and concentrated water can enter evaporation element and handle.
As shown in Figure 1, the treatment process of conventional recycle sewerage are as follows: circulation needs to add scale inhibition into recirculated water
Agent, fungicide and corrosion inhibiter.System sewerage in circulation is introduced into precipitation unit 11 and flocculant is added except big
Partial turbidity and suspended matter, the sludge of precipitating send processing outside.The clear liquid that precipitation unit 11 exports enters filter element 12, filters
Filter residue also sends processing outside afterwards.The filtrate that filter element 12 exports enters biochemical unit 13 for removing ammonia nitrogen and phosphonium ion.It is biochemical
The treatment fluid that unit 13 exports enters desalination unit 14, and the desalination water that desalination unit 14 generates returns in circulation again
Secondary utilization, the concentrated water that desalination unit 14 generates can enter evaporation element and handle.
Utility model content
The technical issues of the utility model devises a kind of Zero discharging system of suitable industrial circulating water, solves is existing
It needs to add various medicaments in water circulation system and uses biochemical unit, need to carry out a large amount of moisturizing and blowdown etc..
In order to solve above-mentioned technical problem, the utility model uses following scheme:
A kind of Zero discharging system of suitable industrial circulating water, including circulation, other filter unit (10) of electrolysis, precipitating list
First (11), filter element (12), desalination unit (13) and evaporation element (14), it is characterised in that:
Recirculated water is separated into after entering other filter unit (10) processing of electrolysis from extraction system recirculated water (1) in circulation
(2) and sewerage (3);Wherein, the recirculated water (2) returns in the circulatory system, and the sewerage (3) enters precipitation unit (11)
Processing;The sewerage (3) is separated into clear liquid (4) and sludge (6) after handling by the precipitation unit (11), clear liquid (4) into
Enter in filter element (12);The clear liquid (4) is separated into filtrate (5) and filter residue (6) after entering the filter element (12) processing,
Filtrate (5) enters in desalination unit (13), and sludge filter residue (6) is used as fixed-end forces;The filtrate (5) through desalination unit (13) at
It is separated into desalination water (7) after reason and returns to the circulation, concentrated water (8) enters evaporation element (14).
Further, it is 5%-10% that extraction system recirculated water (1), which accounts for the water ratio in entire circulation,.
Further, other filter unit (10) of electrolysis filters device for electrolysis is other.
Further, the filter element (12) is PCF filter, self-cleaning filter or ultrafilter.
Further, the desalination unit (13) includes demineralizer and/or the evaporation element (14) includes vaporising device.
A kind of Zero emission method of suitable industrial circulating water, comprising the following steps:
Step 1 is separated into after entering other filter unit (10) processing of electrolysis from extraction system recirculated water (1) in circulation
Recirculated water (2) and sewerage (3);Wherein, the recirculated water (2) returns in the circulatory system, and it is single that the sewerage (3) enters precipitating
First (11) processing;
Step 2, the sewerage (3) are separated into clear liquid (4) and sludge (6) after handling by the precipitation unit (11),
Clear liquid (4) enters in filter element (12);
Step 3, the clear liquid (4) are separated into filtrate (5) and filter residue (6) after entering the filter element (12) processing, filter
Liquid (5) enters in desalination unit (13), and sludge filter residue (6) is used as fixed-end forces;
Step 4, the filtrate (5) are separated into desalination water (7) after desalination unit (13) are handled and return to the circulating water
System, concentrated water (8) enter evaporation element (14).
This is suitble to the Zero discharging system of industrial circulating water to have the advantages that compared with traditional handicraft
(1) the utility model can reduce rate of water make-up and blowdown flow rate, this is the important prerequisite condition of zero-emission.Traditional handicraft
For the cycles of concentration of recirculated water in 2-4, being electrolysed other filter unit ESF can be improved cycles of concentration to 4-6, even higher, reduction moisturizing
While amount, blowdown flow rate can be greatly reduced, generally when cycles of concentration is increased to 5 from 3, rate of water make-up about 20% can be saved, is reduced
Blowdown flow rate about 50%, so as to reduce half group technology cost of investment, while operating cost is also accordingly reduced.
(2) the utility model can make the substance of easy fouling in the circulatory system filter preparatory fouling in unit ESF by electrolysis, have
Effect prevents the fouling in the circulatory system, to reduce the addition for even removing various medicaments from.Half recirculated water can remove resistance from substantially
Dirty agent, is only added corrosion inhibiter when chloride ion is excessively high, to reduce stabilizing water quality while operating cost;
(3) the utility model electrolysis other filter unit ESF exempts from medicament function, eliminates bringing into for ammonia nitrogen phosphorus etc. in medicament,
So as to save the biochemical unit in traditional handicraft, this also greatly reduces the investment of technique;
(4) it is electrolysed the hardness basicity of other filter unit ESF 60% or more the circulatory system of removal in the utility model, stablizes water
Matter provides good processing environment for subsequent technique, provides strong guarantee to the service life for extending entire technique;
(5) ESF unit can provide the effective sterilizing object such as chlorine, oxyradical, hydrogen peroxide in the utility model
Matter can prevent biological pollution and microbial growth, this also provides advantageous treatment conditions for subsequent technique;
(6) ESF unit occupied area is few in the utility model, easy for installation, and original process system can be added without making
At any adverse effect;
Detailed description of the invention
Fig. 1: the treatment process schematic diagram of conventional recycle sewerage;
Fig. 2: the utility model is suitble to the box connection schematic diagram of the Zero discharging system of industrial circulating water.
Specific embodiment
Below with reference to Fig. 2, the utility model is described further:
As shown in Fig. 2, a kind of Zero discharging system of suitable industrial circulating water, including circulation, the other filter unit of electrolysis
10, precipitation unit 11, filter element 12, desalination unit 13 and evaporation element 14, extraction system recycles from circulation
Water 1, which enters after the other filter unit 10 of electrolysis is handled, is separated into recirculated water 2 and sewerage 3;Wherein, recirculated water 2 returns in the circulatory system,
Sewerage 3 enters precipitation unit 11 and handles;Sewerage 3 is separated into clear liquid 4 and sludge 6, clear liquid 4 after handling by precipitation unit 11
Into in filter element 12;Clear liquid 4, which enters after filter element 12 is handled, is separated into filtrate 5 and filter residue 6, and filtrate 5 enters desalination list
In member 13, sludge filter residue 6 is used as fixed-end forces;Filtrate 5 is separated into desalination water 7 after the processing of desalination unit 13 and returns to circulating water
System, concentrated water 8 enter evaporation element 14.
The utility model is mainly in circulation plus filter ESF (Electrolysis Side by electrolysis
Filtration), which will not generate any adverse effect to existing system, and land occupation is few, easy for installation.ESF device is taken out
It takes the recirculated water of internal circulating load about 5%-10% to enter ESF device, by related electrochemistry and chemical reaction, is easy fouling in water
Substance can the preparatory fouling on cathode, then the scale of precipitation is scraped off by scraper, be discharged circulation except, to protect
Demonstrate,prove non flouling behaviour in the circulatory system;Anode nearby generates chlorine, oxidizer free radicals, ozone and hydrogen peroxide simultaneously, and water supply mentions
Disinfection is obtained for fine, prevents biological pollution and microbial growth.
The utility model is mainly in circulation plus ESF device is filtered by electrolysis, filter ESF device will not by the electrolysis
Any adverse effect is generated to existing system, land occupation is few, easy for installation.The other filter ESF device of electrolysis extracts internal circulating load about 5%-
10% recirculated water enters the other filter ESF device of electrolysis, and by related electrochemistry and chemical reaction, the substance meeting of fouling is easy in water
Then the preparatory fouling on cathode scrapes off the scale of precipitation by scraper, be discharged except circulation, to guarantee to recycle
Non flouling behaviour in system;Anode nearby generates chlorine, oxidizer free radicals, ozone and hydrogen peroxide simultaneously, and water supply provides fine
Disinfection is obtained, biological pollution and microbial growth are prevented.
The sewerage of the other filter ESF device of electrolysis enters precipitation unit, and after natural sedimentation, clear liquid enters filter element, bottom
Sludge is mainly calcium carbonate magnesium hydroxide iron hydroxide etc..By filter element, filtrate enters desalting system, filter residue and above-mentioned dirt
Mud ingredient is suitable.After desalting system, fresh water can return to and follow bad water system, can also afforest with water etc., concentrated water can be direct
It is evaporated processing, to reach zero-emission purpose.
The other filter ESF of electrolysis the utility model has the advantages that
(1) it reduces and even removes various antisludging agents, corrosion inhibiter, fungicide of recirculated water etc. from, thus investment reduction cost.
(2) cycles of concentration of recirculated water is improved, the cycles of concentration of general recirculated cooling water is 2-4, and 4- can be improved in ESF
6, it is even higher, to reduce rate of water make-up and blowdown flow rate.
(3) easy to operate, and can automatic running, remove the manual operations such as dosing, blowdown from.
(4) it reduces or exempts from medicament, reduce the pollution to environment.
(5) occupied area is small, easy for installation.
(6) service life is long, and maintenance is simple.
Illustrative description has been carried out to the utility model above in conjunction with attached drawing, it is clear that the realization of the utility model not by
The limitation of aforesaid way, if the method concept of the utility model and the various improvement of technical solution progress are used, or without
It improves and the conception and technical scheme of the utility model is directly applied into other occasions, in the protection scope of the utility model
It is interior.
Claims (5)
1. a kind of Zero discharging system of suitable industrial circulating water, including circulation, other filter unit (10), precipitation unit of electrolysis
(11), filter element (12), desalination unit (13) and evaporation element (14), it is characterised in that:
Recirculated water (2) are separated into after entering other filter unit (10) processing of electrolysis from extraction system recirculated water (1) in circulation
With sewerage (3);Wherein, the recirculated water (2) returns in the circulatory system, and the sewerage (3) enters at precipitation unit (11)
Reason;The sewerage (3) is separated into clear liquid (4) and sludge filter residue (6), clear liquid (4) after handling by the precipitation unit (11)
Into in filter element (12);The clear liquid (4) is separated into filtrate (5) and sludge filtering after entering the filter element (12) processing
Slag (6), filtrate (5) enter in desalination unit (13), and sludge filter residue (6) is used as fixed-end forces;The filtrate (5) is through desalination unit
(13) it is separated into desalination water (7) after handling and returns to the circulation, concentrated water (8) enters evaporation element (14).
2. being suitble to the Zero discharging system of industrial circulating water according to claim 1, it is characterised in that: extraction system recirculated water
(1) the water ratio accounted in entire circulation is 5%-10%.
3. the Zero discharging system of suitable industrial circulating water according to claim 1 or claim 2, it is characterised in that: electrolysis is other to filter unit
(10) device is filtered for electrolysis is other.
4. being suitble to the Zero discharging system of industrial circulating water according to claim 1, it is characterised in that: the filter element (12)
For PCF filter, self-cleaning filter or ultrafilter.
5. being suitble to the Zero discharging system of industrial circulating water according to claim 1, it is characterised in that: the desalination unit (13)
It include vaporising device including demineralizer and/or the evaporation element (14).
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CN201820656903.9U CN209039254U (en) | 2018-05-04 | 2018-05-04 | A kind of Zero discharging system of suitable industrial circulating water |
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CN110436687A (en) * | 2018-05-04 | 2019-11-12 | 芜湖佳泽利环境资源科技有限公司北京分公司 | A kind of Zero discharging system and method for suitable industrial circulating water |
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CN110436687A (en) * | 2018-05-04 | 2019-11-12 | 芜湖佳泽利环境资源科技有限公司北京分公司 | A kind of Zero discharging system and method for suitable industrial circulating water |
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210423 Address after: 100176 402, unit 1, building 1, Guiyuan Nanli District, Yizhuang Town, Daxing District, Beijing Patentee after: Guo Hongfei Address before: 3b01, 3 / F, building 7, yard 29, Jinghai 2nd Road, Beijing Economic and Technological Development Zone, Beijing Patentee before: WUHU JIAZELI ENVIRONMENTAL RESOURCES TECHNOLOGY Co.,Ltd. BEIJING BRANCH |
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TR01 | Transfer of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190628 |
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CF01 | Termination of patent right due to non-payment of annual fee |