CN209029438U - A kind of lithium-ion-power cell with thermal runaway control function - Google Patents

A kind of lithium-ion-power cell with thermal runaway control function Download PDF

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Publication number
CN209029438U
CN209029438U CN201821691795.5U CN201821691795U CN209029438U CN 209029438 U CN209029438 U CN 209029438U CN 201821691795 U CN201821691795 U CN 201821691795U CN 209029438 U CN209029438 U CN 209029438U
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China
Prior art keywords
conductive plate
battery
lithium
ion
thermal runaway
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Expired - Fee Related
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CN201821691795.5U
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Chinese (zh)
Inventor
张自惠
潘楠
张峰
任玉龙
曹文成
乔敏
杨凤玉
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TIANJIN SINOPOLY NEW ENERGY TECHNOLOGY Co Ltd
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TIANJIN SINOPOLY NEW ENERGY TECHNOLOGY Co Ltd
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Priority to CN201821691795.5U priority Critical patent/CN209029438U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Secondary Cells (AREA)
  • Connection Of Batteries Or Terminals (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The utility model discloses a kind of lithium-ion-power cells with thermal runaway control function, including hollow battery case (3), are provided with battery packet (4) in the battery case (3);Left and right ends are respectively provided with positive terminal (1) and negative terminal (6) at the top of the battery packet (4);The outer surface of the battery packet (4) is provided with a thermal runaway occluding device (2);The thermal runaway occluding device (2) is connected with positive terminal (1) and negative terminal (6) respectively;The thermal runaway occluding device (2) is in contact with battery case (3), for transmitting the heat on battery case (3), and when temperature thereon rises to preset temperature value, so that battery short circuit occurs in the external of battery packet (4).The utility model is safe and reliable, can effectively avoid lithium-ion-power cell and internal short-circuit occurs, prevent it from safety accident occur since internal short-circuit occurs, guarantee the security performance of battery.

Description

A kind of lithium-ion-power cell with thermal runaway control function
Technical field
The utility model relates to battery technology fields, dynamic more particularly to a kind of lithium ion with thermal runaway control function Power battery.
Background technique
Currently, lithium ion battery has many advantages, such as that specific energy is high, has extended cycle life, not only on a portable electronic device such as Mobile phone, DV and laptop computer are used widely, and are widely used in electric car, electric bicycle And in terms of the large and medium-sized electrical equipment such as electric tool, therefore the security performance of lithium ion battery is required higher and higher.
New-energy automobile increasingly becomes the Strategic planning row of national governments as a kind of energy-saving and environment-friendly vehicles Industry.Safety problem in new-energy automobile popularization and application had both been related to the security of the lives and property of the people, was also related to new energy The sustainable and healthy development of source automobile industry.The safety of important component as new-energy automobile --- lithium-ion-power cell Property also obtained more and more attention, Ministry of Industry and Information has issued " electric motor coach safety specification " and has reinforced to electrokinetic cell system Safety test and supervision, wherein thermal runaway and thermal runaway extension embody lithium ion power electricity as important test item The comprehensive safety performance in pond.In the use process of lithium ion battery, machinery abuse (is squeezed, is punctured), electrical to abuse (overcharging), It is thermal runaway that above-mentioned several abuses, which are easiest to development,.
Heat transfer during thermal runaway is mainly thermally conductive, at present plastic housing power lithium-ion battery because shell wall it is thicker, lead Hot property is poor, and heat can not disperse very well, and battery temperature is caused to rise, and diaphragm melts, and positive and negative electrode directly contacts, and causes big rule Mould internal short-circuit, it is final to burn, or even explode, battery safety cannot be guaranteed.
For the prior art, it is that thermal insulation layer is set between adjacent battery mostly, can temporarily delays thermal runaway Triggering, but does not prevent the progress of hot transmitting, when the temperature of inside battery rises to a certain extent, can still cause on a large scale Internal short-circuit eventually leads to cells burst, or even the safety accident of battery explosion occurs, and fails fundamentally to solve battery thermal runaway The problem of.
Therefore, there is an urgent need to develop a kind of technologies out at present, internal short-circuit can occur to avoid lithium-ion-power cell, prevent Only there are the safety accidents such as burning, explosion since internal short-circuit occurs in lithium-ion-power cell, and lithium ion power electricity is effectively ensured The security performance in pond.
Utility model content
In view of this, the purpose of the utility model is to provide a kind of, the lithium ion power with thermal runaway control function is electric Pond, it is safe and reliable, it is possible to prevente effectively from internal short-circuit occurs for lithium-ion-power cell, prevent lithium-ion-power cell due to hair It gives birth to internal short-circuit and the safety accidents such as burning, explosion occurs, the security performance of lithium-ion-power cell is effectively ensured, be conducive to extensively Ground application, is of great practical significance.
For this purpose, the utility model provides a kind of lithium-ion-power cell with thermal runaway control function, including hollow Battery case, be provided with battery packet in the battery case;
Left and right ends are respectively provided with positive terminal and negative terminal at the top of the battery packet;
The outer surface of the battery packet is provided with a thermal runaway occluding device;
The thermal runaway occluding device is connected with positive terminal and negative terminal respectively;
The thermal runaway occluding device is in contact with battery case, for transmitting the heat on battery case, and works as it On temperature when rising to preset temperature value so that battery short circuit occurs in the external of battery packet.
Wherein, the front or the back side of the battery packet is arranged in the thermal runaway occluding device.
Wherein, the thermal runaway occluding device includes the first conductive plate and the second conductive plate, first conductive plate and the Fitting is provided with barrier film between two conductive plates;
First conductive plate and the second conductive plate are spaced apart by the barrier film completely;
First conductive plate is connected by positive wire with positive terminal;
Second conductive plate is connected by negative wire with negative terminal;
First conductive plate is in contact with battery case;
Second conductive plate is in contact with the outer surface of the battery packet.
Wherein, one end of the positive wire is mutually welded with the first conductive plate, the other end and anode of the positive wire Terminal mutually welds;
One end of the negative wire is mutually welded with the second conductive plate, the other end and the negative terminal phase of the negative wire Welding.
Wherein, the outside of first conductive plate and the second conductive plate is enclosed with packaging film.
Wherein, the packaging film is the protective bag made of polypropylene PP material.
Wherein, the barrier film is film made of the organic and inorganic materials using fusing point between 90~130 DEG C.
Wherein, the barrier film is polyethylene PE film or vinyl-vinyl acetate copolymer eva film.
Wherein, the barrier film with a thickness of 10~50 μm.
Wherein, first conductive plate is copper sheet, with a thickness of 0.01~1mm;
Second conductive plate is aluminium sheet, with a thickness of 0.01~1mm.
By the above technical solution provided by the utility model as it can be seen that compared with prior art, the utility model provides A kind of lithium-ion-power cell with thermal runaway control function, it is safe and reliable, it is possible to prevente effectively from lithium-ion-power cell Internal short-circuit occurs, prevents lithium-ion-power cell from the safety accidents such as burning, explosion occur since internal short-circuit occurs, is effectively ensured The security performance of lithium-ion-power cell is conducive to widely apply, be of great practical significance.
Detailed description of the invention
Fig. 1 is a kind of structural representation of the lithium-ion-power cell with thermal runaway control function provided by the utility model Figure;
Fig. 2 is thermal runaway resistance in a kind of lithium-ion-power cell with thermal runaway control function provided by the utility model The structure schematic diagram of disconnected device;
Fig. 3 is thermal runaway resistance in a kind of lithium-ion-power cell with thermal runaway control function provided by the utility model Disconnected device along vertical direction the schematic diagram of the section structure;
In figure, 1, positive terminal, 2, thermal runaway occluding device, 3, battery case, 4, battery packet, 5, battery cover board, 6, Negative terminal;
21, positive wire, 22, negative wire, 23, packaging film, the 24, first conductive plate, 25, barrier film, 26, second is conductive Plate.
Specific embodiment
In order to make those skilled in the art better understand the scheme of the utility model, with reference to the accompanying drawing and embodiment The utility model is described in further detail.
Referring to Fig. 1 to Fig. 3, the utility model provides a kind of lithium-ion-power cell with thermal runaway control function, Applied to the security protection to lithium-ion-power cell, including hollow battery case 3, electricity is provided in the battery case 3 Chi Xin packet 4;
The 4 top left and right ends of battery packet are respectively provided with positive terminal 1 and negative terminal 6;
The outer surface (being not limited to front shown in FIG. 1) of the battery packet 4 is provided with a thermal runaway occluding device 2;
The thermal runaway occluding device 2 is connected with positive terminal 1 and negative terminal 6 respectively;
The thermal runaway occluding device 2 is in contact with battery case 3, for transmitting the heat on battery case 3, and works as When temperature (temperature of barrier film specially therein) thereon rises to preset temperature value, so that in the outside of battery packet 4 Battery short circuit occurs, i.e. generation battery external short circuit, the blocking of shape battery pair thermal runaway process.
In the present invention, in specific implementation, the top heat-sealing of the battery case 3 has a battery cover board 5;
The top of the positive terminal 1 and negative terminal 6 is exposed to the top of battery cover board 5.
In the present invention, in specific implementation, the thermal runaway occluding device 2 is preferably arranged on the battery packet Heat transfer is better achieved to increase the contact area between battery case 3 in 4 front or the back side.
In the present invention, in specific implementation, the thermal runaway occluding device 2 includes that the first conductive plate 24 and second is led Battery plate 26, fitting is provided with barrier film 25 between first conductive plate 24 and the second conductive plate 26;
First conductive plate 24 and the second conductive plate 26 are spaced apart by the barrier film 25 completely, so that the two does not occur Contact;
First conductive plate 24 is connected by positive wire 21 with positive terminal 1;
Second conductive plate 26 is connected by negative wire 22 with negative terminal 6;
First conductive plate 24 is in contact with battery case 3;
Second conductive plate 26 is in contact with the outer surface of the battery packet 4.
It should be noted that the temperature of battery case 3 rises, and the first conductive plate 24 can have when single battery is heated Heat on effect ground transmitting battery case 3 is into barrier film 25, so that barrier film 25 is blocked since heating temperature is increased reaching When the fusing point of film 25, barrier film 25 is melted, so that the first conductive plate 24 and the second conductive plate 26 occur directly to contact, thus conductive Connection, so that positive terminal 1 is mutually conductively connected with negative terminal 6, battery short circuit occurs for external in battery packet 4.
It should also be noted that, the second conductive plate 26 can play conductive, thermally conductive effect, it can guarantee that barrier film 25 can It is heated up with reliably absorbing heat, melts play a role in time.
In specific implementation, one end and 24 phase of the first conductive plate of the positive wire 21 are welded, the positive wire 21 The other end is mutually welded with positive terminal;
One end of the negative wire 22 is welded with 26 phase of the second conductive plate, the other end and cathode of the negative wire 22 The welding of 6 phase of terminal.
In specific implementation, the outside of first conductive plate 24 and the second conductive plate 26 is enclosed with packaging film 23.
In the present invention, in specific implementation, the lithium-ion-power cell is preferably rectangular cell, preferably plastic housing lithium Ion battery is also applicable on other batteries certainly, and the thickness of the battery case 3 is preferably 3.5~8mm.
In specific implementation, the packaging film 23 be preferably using polypropylene PP material production protective bag, fusing point be 150~ 180 DEG C, thickness is preferably 0.1~0.5mm.
In specific implementation, the barrier film 25 is preferably polyethylene PE film or vinyl-vinyl acetate copolymer Eva film, or using film made of other organic and inorganic materials (fusing point is between 90~130 DEG C), wherein it is described poly- The fusing point of ethylene PE film is 100~130 DEG C, and the fusing point of vinyl-vinyl acetate copolymer eva film is 90~100 DEG C.
In specific implementation, the thickness of the barrier film 25 is preferably 10~50 μm.
In specific implementation, first conductive plate 24 is preferably copper sheet, further preferably using copper made of red copper T2 Plate, thickness are preferably 0.01~1mm, can be multilayer or single layer.
In specific implementation, second conductive plate 26 is preferably aluminium sheet, and further preferably 1060 aluminium sheets, thickness is preferred It can be multilayer or single layer for 0.01~1mm.
It should be noted that for the utility model, belong to lithium ion battery power safety technical field, institute its in lithium The internal positive of ion battery, one in parallel of cathode both ends are by packaging film, the first conductive plate (such as copper sheet), barrier film, the The thermal runaway occluding device of two conductive plates (such as aluminium sheet) and packaging film composition.Therefore, when the heat of lithium ion battery power battery is lost After control triggering, barrier film, which will be shunk, even melts, so that the first conductive plate (such as copper sheet) and the second conductive plate (such as aluminium sheet) Directly contact is conductive, to cause the external short circuit of battery, the not internal uncontrollable short circuit of this short circuit passes through design Circuit realize short circuit, therefore, the utility model can effectively discharge the energy of battery storage in time, avoid due to occur Thermal runaway caused by uncontrollable chemical reaction.
It for the utility model, burns except avoiding causing, or even explosion is outer, also effectively prevents because of uncontrollable chemical reaction The release of poisonous and harmful substances caused by and reduces or avoids environmental pollution.
Based on above technical scheme it is found that for lithium-ion-power cell provided by the utility model, design science is closed Reason, meets scientific law, and working principle is safe and reliable, operates easy, can be effectively blocked the generation of thermal runaway, guarantee lithium from The safety of sub- power battery.
For the utility model, the barrier film in the structure can be replaced according to the usage of battery, to meet peace The needs of the battery of different temperatures requirement are entirely used, it is at low cost.
For the lithium-ion-power cell provided by the utility model with thermal runaway control function, assembled in production When, firstly, increasing a thermal runaway occluding device 2 inside the battery case of single battery, in the thermal runaway occluding device 2 In, the welding of positive terminal 1 of 21 one end of positive wire and single battery is connected, and the other end and the second conductive plate (such as aluminium sheet) 26 weld It connects and is connected, and the welding of the negative terminal 2 of one end of negative wire 22 and single battery is connected, the other end and the first conductive plate 24 (such as copper sheets) welding is connected, and barrier film 25 is put in the second conductive plate (such as aluminium sheet) 26 and the first conductive plate 24 (such as copper sheet) Between fitting it is close;
Then, it is put in packaging film 23, the fusing point of barrier film 25 is 90~130 DEG C, and packaging film 23 protects battery packet 4 Diaphragm not pierced through by external force;
Then, thermal runaway occluding device 2 and battery packet 4 are put into battery case 3 simultaneously;
Finally, battery cover board 5 is heat sealed on battery case 3.
When single battery is heated, 3 temperature of battery case rises, and by heat transfer, the first conductive plate 24 is heated, works as temperature When reaching 90~130 DEG C, barrier film 25 is melted, and the first conductive plate 24 (such as copper sheet) and the second conductive plate (such as aluminium sheet) 26 occur It directly contacts, to cause the external short circuit of battery, therefore, battery can effectively be avoided to cause burning, quick-fried because internal short-circuit occurs Fried safety accident.Therefore, the utility model can effectively discharge the energy of battery storage in time, avoid due to occurring not Thermal runaway caused by controllable chemical reaction.
By examining.For general common existing lithium-ion-power cell, when carrying out thermal runaway test, temperature is most 600 DEG C of promotion or more, it will vigorous combustion;And for the utility model, after increasing thermal runaway occluding device, battery cell When carrying out thermal runaway test, the external short circuit of battery can be caused, by the circuit of design so as to effectively by battery The energy of storage discharges in time, avoids thermal runaway caused by since uncontrollable chemical reaction occurs, for the utility model, It can sufficiently meet the requirement that thermal runaway is tested in Ministry of Industry and Information " electric motor coach safety specification ".
Compared with prior art, the utility model has the following characteristics that
1, the utility model can effectively block thermal runaway, guarantee the safety of lithium-ion-power cell.
2, the utility model only needs in the production process that special thermal runaway occluding device in parallel, production process are simply easy It goes, is safe and reliable, it is at low cost.
3, the utility model is not limited to the shape of battery case, size, the plastic housing lithium ion power suitable for any shape Battery or other batteries can be the battery applied to any one outside heating conduction difference, can significantly improve applied The safety of new-energy automobile.
In conclusion compared with prior art, a kind of lithium with thermal runaway control function provided by the utility model Ion battery, it is safe and reliable, it is possible to prevente effectively from internal short-circuit occurs for lithium-ion-power cell, prevent lithium ion power There are the safety accidents such as burning, explosion since internal short-circuit occurs in battery, and the security performance of lithium-ion-power cell is effectively ensured, Be conducive to widely apply, be of great practical significance.
The above is only the preferred embodiment of the utility model, it is noted that for the common skill of the art For art personnel, without departing from the principle of this utility model, several improvements and modifications can also be made, these improve and Retouching also should be regarded as the protection scope of the utility model.

Claims (10)

1. a kind of lithium-ion-power cell with thermal runaway control function, which is characterized in that including hollow battery case (3), battery packet (4) are provided in the battery case (3);
Left and right ends are respectively provided with positive terminal (1) and negative terminal (6) at the top of the battery packet (4);
The outer surface of the battery packet (4) is provided with a thermal runaway occluding device (2);
The thermal runaway occluding device (2) is connected with positive terminal (1) and negative terminal (6) respectively;
The thermal runaway occluding device (2) is in contact with battery case (3), for transmitting the heat on battery case (3), and When temperature thereon rises to preset temperature value, so that battery short circuit occurs in the external of battery packet (4).
2. lithium-ion-power cell as described in claim 1, which is characterized in that thermal runaway occluding device (2) setting exists The front or the back side of the battery packet (4).
3. lithium-ion-power cell as described in claim 1, which is characterized in that the thermal runaway occluding device (2) includes the One conductive plate (24) and the second conductive plate (26) are bonded between first conductive plate (24) and the second conductive plate (26) and are provided with Barrier film (25);
First conductive plate (24) and the second conductive plate (26) are spaced apart by the barrier film (25) completely;
First conductive plate (24) is connected by positive wire (21) with positive terminal (1);
Second conductive plate (26) is connected by negative wire (22) with negative terminal (6);
First conductive plate (24) is in contact with battery case (3);
Second conductive plate (26) is in contact with the outer surface of the battery packet (4).
4. lithium-ion-power cell as claimed in claim 3, which is characterized in that one end and first of the positive wire (21) Conductive plate (24) mutually welds, and the other end of the positive wire (21) is mutually welded with positive terminal;
One end of the negative wire (22) is mutually welded with the second conductive plate (26), the other end of the negative wire (22) and negative Extreme son (6) is mutually welded.
5. lithium-ion-power cell as claimed in claim 3, which is characterized in that first conductive plate (24) and the second conduction The outside of plate (26) is enclosed with packaging film (23).
6. lithium-ion-power cell as claimed in claim 5, which is characterized in that the packaging film (23) is using polypropylene PP The protective bag of material production.
7. lithium-ion-power cell as claimed in claim 3, which is characterized in that the barrier film (25) is using fusing point 90 Film made of organic and inorganic materials between~130 DEG C.
8. lithium-ion-power cell as claimed in claim 3, which is characterized in that the barrier film (25) is that polythene PE is thin Film or vinyl-vinyl acetate copolymer eva film.
9. lithium-ion-power cell as claimed in claim 8, which is characterized in that the barrier film (25) with a thickness of 10~50 μm。
10. the lithium-ion-power cell as described in any one of claim 3 to 9, which is characterized in that first conductive plate It (24) is copper sheet, with a thickness of 0.01~1mm;
Second conductive plate (26) is aluminium sheet, with a thickness of 0.01~1mm.
CN201821691795.5U 2018-10-18 2018-10-18 A kind of lithium-ion-power cell with thermal runaway control function Expired - Fee Related CN209029438U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109037544A (en) * 2018-10-18 2018-12-18 天津中聚新能源科技有限公司 A kind of lithium-ion-power cell with thermal runaway control function
CN110931660A (en) * 2019-11-12 2020-03-27 浙江锋锂新能源科技有限公司 A protection architecture and soft packet of battery for soft packet of battery
CN111490223A (en) * 2020-04-01 2020-08-04 北京理工大学 Method and device for inducing short circuit in power battery by magnetic heat
CN114175353A (en) * 2020-03-19 2022-03-11 广州汽车集团股份有限公司 Method and device for preventing thermal runaway of battery and battery system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109037544A (en) * 2018-10-18 2018-12-18 天津中聚新能源科技有限公司 A kind of lithium-ion-power cell with thermal runaway control function
CN110931660A (en) * 2019-11-12 2020-03-27 浙江锋锂新能源科技有限公司 A protection architecture and soft packet of battery for soft packet of battery
CN114175353A (en) * 2020-03-19 2022-03-11 广州汽车集团股份有限公司 Method and device for preventing thermal runaway of battery and battery system
CN111490223A (en) * 2020-04-01 2020-08-04 北京理工大学 Method and device for inducing short circuit in power battery by magnetic heat

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