Sodium chlorate electrolysis production system
Technical field:
The utility model relates to sodium chlorate to be electrolysed field, and in particular to a kind of sodium chlorate electrolysis production system.
Background technique:
The chemical formula of sodium chlorate is NaClO3, relative molecular mass 106.44.There is strong oxidation in an acidic solution,
300 DEG C or more can decomposite oxygen.Sodium chlorate is unstable, mixed with phosphorus, sulphur and organic matter when being impacted easily occur burning and
Explosion, easy moisture absorption agglomeration.Sodium chlorate is widely used, industrially mainly for the manufacture of chlorine dioxide, sodium chlorite, perchlorate and
Other chlorates;In medical industry for manufacturing medicinal zinc oxide, disulfide group sodium succinate;It is advanced for manufacturing in pigment industry
Zinc oxide;Agriculturally it is used as herbicide, also can be used as the mordant and oxidant of printing and dyeing industry and inorganic industrial.
Currently, mainly by electrolytic chlorination sodium solution be made sodium chlorate, current electrolysis system include electrolysis reactor,
Electrolyte surge tank and de- hypochlorous acid reactor tank, the inlet of electrolysis reactor is connected with sodium chloride solution conveyance conduit, in chlorine
Change the direction on sodium solution conveyance conduit from liquid feeding end to outlet end and is successively arranged dilute hydrochloric acid conveyance conduit, variable-frequency delivery pump, pH
Sensor, cooler are equipped with manual modulation valve on dilute hydrochloric acid conveyance conduit, have the following problems in electrolytic process: 1, electric
It solves the electrolyte pH in reactor to need 6.6 or so, otherwise can generate excessive byproduct not only and influence electrolysis effectiveness can also increase
Big a possibility that generating explosive gas, therefore need to be mixed into dilute hydrochloric acid into sodium chloride solution before electrolytic chlorination sodium solution
PH adjusting is carried out, dilute hydrochloric acid flow valve is manual modulation valve, and the degree of regulation manually adjusted is lower, so that sodium chloride and dilute hydrochloric acid
Mixed solution pH it is unstable, and adjust personnel and to observe pH sensor always and be adjusted, large labor intensity;2, pH is sensed
Device is close to dilute hydrochloric acid conveyance conduit outlet end, sodium chloride solution and dilute hydrochloric acid undercompounding, pH measurement inaccuracy;And it closes on
Electrolyte delivery pump outlet end, liquid flow velocity is fast, be easy to cause pH sensor degradation.
Utility model content:
The purpose of this utility model is to provide a kind of high degree of automation, electrolyte pH adjusts accurately sodium chlorate and is electrolysed
Production system.
The utility model is implemented by following technical solution: sodium chlorate electrolysis production system comprising pH regulating system, electrolysis
Reactor, electrolyte surge tank and de- hypochlorous acid reactor tank,
Race way and product zone are divided by weir divider inside the electrolyte surge tank, the weir divider top is set
There is overflow port, the mixed liquor pipe road outlet end of the pH regulating system is connect with the inlet of the electrolysis reactor, described
The liquid outlet of electrolysis reactor is connect with the product inlet of the race way by electrolyte pipeline, the race way bottom
Circulation liquid outlet is connected to by first circulation pipeline with the sodium chloride solution conveyance conduit of variable-frequency delivery pump liquid feeding side;The product
The product liquid outlet in area is connect with the inlet of the de- hypochlorous acid reactor tank by de- hypochlorous acid pipeline, and the de- hypochlorous acid is anti-
The liquid outlet of tank is answered to be connected with product pipeline, the product pipeline passes through the circulation feed liquor of second circulation pipeline and the product zone
Mouth connection is equipped with circulation electrically-controlled valve, in the second circulation pipeline liquid feeding end to the product on the second circulation pipeline
The product pipeline between pipeline outlet end is equipped with the automatically controlled flow valve of product;
The pH regulating system includes the sodium chloride solution conveyance conduit, is set on the sodium chloride solution conveyance conduit
There is dilute hydrochloric acid conveyance conduit, the outlet end of the sodium chloride solution conveyance conduit is connected with the variable-frequency delivery pump, the frequency conversion
The outlet end of delivery pump is connected with the mixed solution pipeline, and cooler is equipped on the mixed solution pipeline, described mixed
It closes and is equipped with pH sensor on solution line at outlet end;On the dilute hydrochloric acid conveyance conduit from liquid feeding end to outlet end according to
It is secondary to be equipped with defective valves, first flowmeter and the automatically controlled flow valve of dilute hydrochloric acid;
It further includes PLC controller, the first flowmeter, the pH sensor signal output end respectively with it is described
The signal input part of PLC controller connects, the signal output end of the PLC controller respectively with the automatically controlled flow of the dilute hydrochloric acid
The signal input part connection of valve, the circulation electrically-controlled valve.
Further, the dilute hydrochloric acid conveyance conduit liquid feeding end to the dilute hydrochloric acid between the first flowmeter conveys
Pipeline is connect by backup line with the dilute hydrochloric acid inlet of the race way, along liquid feeding end to liquid out on the backup line
The direction at end is equipped with dilute hydrochloric acid hand control valve and second flowmeter, and the mixed solution in electrolysis reactor inlet side is defeated
It send pipeline to be equipped with probe tube, sampling valve is equipped on the probe tube.
Further, cooling water electrically-controlled valve is equipped on the coolant intake pipe road of the cooler, it is anti-in the electrolysis
The mixed solution conveyance conduit of device inlet side is answered to be equipped with temperature sensor, the signal output end of the temperature sensor
It is connect with the signal input part of the PLC controller, the signal output end of the PLC controller and the cooling water electrically-controlled valve
Signal input part connection.
Further, to be successively arranged de- hypochlorous acid along the direction of liquid feeding end to outlet end on the de- hypochlorous acid pipeline defeated
Send pump and the automatically controlled flow valve of de- hypochlorous acid;The de- hypochlorous acid reactor tank liquid outlet to the second circulation pipeline liquid feeding end
Between the product pipeline be equipped with product delivery pump.
Further, the product inlet is higher than the overflow port.
Further, crystalline mother solution entrance is equipped at the top of the race way.
The advantages of the utility model: 1, the automatically controlled flow valve of dilute hydrochloric acid, pH sensor are connect with PLC controller signal respectively,
It is automatically adjusted, realize real-time monitoring and adjusted to dilute hydrochloric acid additional amount according to the pH of mixed solution, improve degree of regulation
And reduce the labor intensity of staff;2, the entrance side of electrolysis reactor is arranged in pH sensor, defeated far from dilute hydrochloric acid
Pipeline outlet end is sent, pH is measured after sodium chloride solution and dilute hydrochloric acid are sufficiently mixed, improves the accuracy of measurement result;And
PH sensor distance variable-frequency delivery pump farther out, avoids high-velocity fluid and washes away damage to pH sensor.
Detailed description of the invention:
In order to illustrate the embodiment of the utility model or the technical proposal in the existing technology more clearly, below will be to embodiment
Or attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only
It is some embodiments of the utility model, for those of ordinary skill in the art, in the premise not made the creative labor
Under, it is also possible to obtain other drawings based on these drawings.
Fig. 1 is the system connection schematic diagram of the utility model;
Fig. 2 is the control schematic diagram of PLC controller.
Sodium chloride solution conveyance conduit 1, dilute hydrochloric acid conveyance conduit 2, variable-frequency delivery pump 3, cooler 4, pH sensor 5, electricity
Reactor 6 is solved, electrolyte surge tank 7 takes off hypochlorous acid reactor tank 8, product pipeline 9, and second circulation pipeline 10 recycles electrically-controlled valve
11, first circulation pipeline 12, first flowmeter 13, the automatically controlled flow valve 14 of dilute hydrochloric acid, de- hypochlorous acid delivery pump 15, de- hypochlorous acid electricity
Control flow valve 16, product delivery pump 17, the automatically controlled flow valve 18 of product, PLC controller 19, backup line 20, dilute hydrochloric acid hand control valve
21, second flowmeter 22, probe tube 23, cooling water electrically-controlled valve 24, temperature sensor 25.
Specific embodiment:
The following will be combined with the drawings in the embodiments of the present invention, carries out the technical scheme in the embodiment of the utility model
Clearly and completely describe, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole
Embodiment.Based on the embodiments of the present invention, those of ordinary skill in the art are without making creative work
Every other embodiment obtained, fall within the protection scope of the utility model.
Embodiment 1:
As shown in Figs. 1-2, sodium chlorate electrolysis production system comprising pH regulating system, electrolysis reactor 6, electrolyte are slow
Tank 7 and de- hypochlorous acid reactor tank 8 are rushed,
Race way and product zone are divided by weir divider inside electrolyte surge tank 7, weir divider top is equipped with overflow
Mouthful, the mixed liquor pipe road outlet end of pH regulating system is connect with the inlet of electrolysis reactor 6, and electrolysis reactor 6 goes out liquid
Mouth is connect with the product inlet of race way by electrolyte pipeline, and product inlet is higher than overflow port, and race way bottom is followed
Ring liquid outlet is connected to by first circulation pipeline 12 with the sodium chloride solution conveyance conduit 1 of 3 liquid feeding side of variable-frequency delivery pump, is being recycled
Crystalline mother solution entrance is equipped at the top of area;The product liquid outlet of product zone and the inlet of de- hypochlorous acid reactor tank 8 pass through de- chlorine
The connection of acid tube road is successively arranged de- hypochlorous acid delivery pump 15 along the direction of liquid feeding end to outlet end on de- hypochlorous acid pipeline and takes off
The automatically controlled flow valve 16 of hypochlorous acid;The liquid outlet of de- hypochlorous acid reactor tank 8 is connected with product pipeline 9, and product pipeline 9 is followed by second
Endless tube road 10 is connect with the circulation inlet of product zone, and circulation electrically-controlled valve 11 is equipped on second circulation pipeline 10, is followed second
10 liquid feeding end of endless tube road to the product pipeline 9 between 9 outlet end of product pipeline is equipped with the automatically controlled flow valve 18 of product;In de- chlorine
The liquid outlet of sour reactor tank 8 to the product pipeline 9 between 10 liquid feeding end of second circulation pipeline is equipped with product delivery pump 17.
PH regulating system includes sodium chloride solution conveyance conduit 1, and it is defeated that dilute hydrochloric acid is equipped on sodium chloride solution conveyance conduit 1
Pipeline 2 is sent, the outlet end of sodium chloride solution conveyance conduit 1 is connected with variable-frequency delivery pump 3, the outlet end connection of variable-frequency delivery pump 3
There is mixed solution pipeline, cooler 4 is equipped on mixed solution pipeline, is equipped with pH at outlet end on mixed solution pipeline
Sensor 5;Defective valves, first flowmeter 13 and dilute salt are successively arranged from liquid feeding end to outlet end on dilute hydrochloric acid conveyance conduit 2
The automatically controlled flow valve 14 of acid;The entrance side of electrolysis reactor 6 is arranged in pH sensor 5, separate 2 outlet end of dilute hydrochloric acid conveyance conduit,
PH is measured after sodium chloride solution and dilute hydrochloric acid are sufficiently mixed, improves the accuracy of measurement result;And 5 distance of pH sensor
Variable-frequency delivery pump 3 farther out, avoids high-velocity fluid and washes away damage to pH sensor 5.
It further includes PLC controller 19, first flowmeter 13, pH sensor 5 signal output end respectively with PLC controller
19 signal input part connection, the signal output end of PLC controller 19 respectively with the automatically controlled flow valve 14 of dilute hydrochloric acid, circulation electrically-controlled valve
11 signal input part connection.The automatically controlled flow valve 14 of dilute hydrochloric acid, pH sensor 5 are connect with 19 signal of PLC controller respectively, according to
The pH of mixed solution automatically adjusts to dilute hydrochloric acid additional amount, realize real-time monitoring and adjust, improve degree of regulation and
Reduce the labor intensity of staff.
2 liquid feeding end of dilute hydrochloric acid conveyance conduit to the dilute hydrochloric acid conveyance conduit 2 between first flowmeter 13 passes through backup line
20 connect with the dilute hydrochloric acid inlet of race way, are equipped with dilute hydrochloric acid hand along the direction of liquid feeding end to outlet end on backup line 20
Valve 21 and second flowmeter 22 are controlled, probe tube 23 is equipped on the mixed solution conveyance conduit of 6 inlet side of electrolysis reactor,
Probe tube 23 is equipped with sampling valve.
Cooling water electrically-controlled valve 24 is equipped on the coolant intake pipe road of cooler 4, in 6 inlet side of electrolysis reactor
Mixed solution conveyance conduit is equipped with temperature sensor 25, the signal output end of temperature sensor 25 and the letter of PLC controller 19
The connection of number input terminal, the signal output end of PLC controller 19 are connect with the signal input part of cooling water electrically-controlled valve 24.
Working principle:
Sodium chlorate electrolysis production process the following steps are included:
1, the adjusting of pH and temperature are carried out before output of products to electrolyte:
The automatically controlled flow valve 18 of product is closed, circulation electrically-controlled valve 11 is opened, after electrolysis reactor 6 is driven, electrolyte is made first to exist
It is recycled between electrolysis reactor 6, electrolyte surge tank 7 and de- hypochlorous acid reactor tank 8, without output of products, to electrolyte
PH and temperature are adjusted.
Dilute hydrochloric acid enters the end of sodium chloride solution conveyance conduit 1 by dilute hydrochloric acid conveyance conduit 2, mixed with sodium chloride solution
It is conveyed by variable-frequency delivery pump 3 into cooler 4 after conjunction and carries out temperature adjustment, the mixed solution after temperature adjustment reaches sodium chloride solution delivery pipe
The end in road 1, pH sensor 5 detects the pH of mixed solution, and measured value is transferred to PLC controller 19, temperature sensor
25 detect the temperature value of mixed solution, and measured value is transferred to PLC controller 19;It is set when pH is greater than in PLC controller 19
When fixed maximum value 6.0, PLC controller 19 tunes up signal to automatically controlled 14 transmitted traffic of flow valve of dilute hydrochloric acid, when pH is controlled less than PLC
When the minimum value 5.8 set in device 19 processed, PLC controller 19 turns signal down to automatically controlled 14 transmitted traffic of flow valve of dilute hydrochloric acid, the
The flow value of dilute hydrochloric acid is conveyed to PLC controller 19 by flow meters 13, and the addition of dilute hydrochloric acid is monitored convenient for PLC controller 19
Amount, judges the regulated quantity of the automatically controlled flow valve 14 of dilute hydrochloric acid;When temperature value is greater than the maximum value set in PLC controller 19, PLC
Controller 19 tunes up signal to 24 transmitted traffic of cooling water electrically-controlled valve, when temperature value is less than the minimum set in PLC controller 19
When value, PLC controller 19 turns signal down to 24 transmitted traffic of cooling water electrically-controlled valve.Mixed solution is from sodium chloride solution conveyance conduit
After 1 discharge, cell reaction is carried out into electrolysis reactor 6, the electrolyte after reaction enters the race way of electrolyte surge tank 7,
Product density after electrolysis is less than the electrolyte not being electrolysed, therefore product overflow of the product in the top of race way, race way
To the product zone of electrolyte surge tank 7, de- hypochlorous acid reactor tank 8 is entered back into, product zone is finally recycled back to;It is not electric in race way
It is again introduced into sodium chloride solution conveyance conduit 1 after the electrolyte discharge of solution and the mixed solution of 3 arrival end of variable-frequency delivery pump carries out
Mixing repeats above-mentioned temperature and adjusts and pH adjusting.
2, the pH of electrolyte and temperature, which meet after electrolysis requires, carries out output of products:
After the pH and temperature of electrolyte, which meet electrolysis, to be required, the automatically controlled flow valve 18 of product is opened, closes circulation electrically-controlled valve
11, carry out output of products.The aperture that the automatically controlled flow valve 18 of product is adjusted by product consumption, to control output of products amount.
At this point, the electrolyte in the race way of electrolyte surge tank 7 produces after mixing with the crystalline mother solution that subsequent product processing equipment returns
Product overflow to product zone by the overflow port on weir divider top, into de- hypochlorous acid reactor tank 8 in carry out de- hypochlorous acid reaction
Then subsequent product processing equipment is discharged by product channels 9, the electrolyte and crystalline mother solution that lower part is not electrolysed pass through the
One circulating line 12 is mixed with dilute hydrochloric acid and sodium chloride solution into sodium chloride solution conveyance conduit 1, temperature adjustment, adjusts pH, most
Enter electrolysis reactor 6 afterwards and carry out cell reaction, the electrolyte after cell reaction enters race way and the knot of electrolyte surge tank 7
After brilliant mother liquor mixing, a part is used as output of products, and a part mixes with dilute hydrochloric acid and sodium chloride solution, continues to be electrolysed.
3, when pH sensor or the automatically controlled flow valve of dilute hydrochloric acid break down, the pH of electrolyte is adjusted:
When pH sensor 5 or the automatically controlled flow valve 14 of dilute hydrochloric acid break down, when can not carry out the automatic monitoring and regulation of pH, close
It closes defective valves and opens dilute hydrochloric acid hand control valve 21, switching dilute hydrochloric acid is added channel, enables backup line 20, dilute hydrochloric acid directly adds at this time
The race way for entering electrolyte surge tank 7 is mixed with the electrolyte in race way, expands blending space, so that dilute hydrochloric acid
It is more fully mixed with electrolyte;It is sampled in the outlet end of sodium chloride solution conveyance conduit 1 by probe tube 23, to sample
PH value artificial detection is carried out, and manually adjusts dilute hydrochloric acid hand control valve 21 according to testing result.
The above is only the preferred embodiment of the utility model only, is not intended to limit the utility model, all at this
Within the spirit and principle of utility model, any modification, equivalent replacement, improvement and so on should be included in the utility model
Protection scope within.