CN208738350U - A kind of waste lead storage battery electrolyte collection system - Google Patents

A kind of waste lead storage battery electrolyte collection system Download PDF

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Publication number
CN208738350U
CN208738350U CN201821475249.8U CN201821475249U CN208738350U CN 208738350 U CN208738350 U CN 208738350U CN 201821475249 U CN201821475249 U CN 201821475249U CN 208738350 U CN208738350 U CN 208738350U
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China
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storage tank
electrolyte
storage battery
sieve apparatus
tank
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CN201821475249.8U
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李培文
张行祥
梅立寿
孔庆波
舒绍明
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HUBEI CHUKAI CO Ltd
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HUBEI CHUKAI CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/84Recycling of batteries or fuel cells

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  • Secondary Cells (AREA)

Abstract

A kind of waste lead storage battery electrolyte collection system, it is cheated including waste lead storage battery, communicated device cheats the crusher being connected with waste lead storage battery, vibrate sieve apparatus, lead mud tank, filter press, storage tank I, micro-filtrate membrane filtration equipment, electrolyte storage tank, cracking and sorting system, for storing up the storage tank II of pure water, it vibrates corresponding with discharge hole of crusher above sieve apparatus, it is connected below vibration sieve apparatus with mud inlet above lead mud tank, it vibrates sieve apparatus side and connects cracking and sorting system, lead mud tank mud mouth is connected with filter press, filter press is connected with storage tank I, one discharge port of storage tank I is connected through valve I with acidproof pump inlet, acidproof pump discharge is connect with the spray head on vibration sieve apparatus, another discharge port of storage tank I is connected through micro-filtrate membrane filtration equipment with electrolyte storage tank feed inlet, acidproof pump inlet is also connected through valve II with storage tank II.Metal impurities in waste electrolyte can be reduced using the utility model, and increase efficiency, and be avoided that the introducing of difficult chlorine impurity.

Description

A kind of waste lead storage battery electrolyte collection system
Technical field
The utility model belongs to lead-acid accumulator recycling field, in particular to a kind of waste lead storage battery electrolyte Collection system can be used for the collection of old and useless battery electrolyte.
Background technique
According to statistics, the annual lead-acid accumulator yield in China reaches millions of tons, is crushed waste electrolyte caused by recycling Lead-acid accumulator gross weight 20% or so is accounted for, accounting is big, and waste and old lead acid accumulator contain in broken generated waste electrolyte 0.16% or so metal impurities, intractable chlorine impurity increase since impurity is excessively high so as to cause processing difficulty, processing cost Add, wherein chlorine impurity is even more the problem that current waste electrolyte recycles.
Therefore, it is necessary to a kind of waste lead storage battery electrolyte collection system is designed, the useless electricity for generating Battery recycling It solves liquid impurity to reduce, and avoids bringing into for chlorine impurity.
Utility model content
Against the above technical problems, the purpose of this utility model is to provide economic and environmental protection waste lead storage battery electrolysis Liquid collection system can reduce metal impurities in waste electrolyte using the utility model, reduce the processing cost of waste electrolyte, and increase Add efficiency, and be avoided that the introducing of difficult chlorine impurity, to solve the problems, such as waste electrolyte recycling.
In order to achieve the above objectives, the utility model provides the following technical solutions: including waste lead storage battery hole, communicated dress Set with waste lead storage battery hole be connected crusher, vibrate sieve apparatus, lead mud tank, filter press, storage tank I, micro-filtrate membrane filtration equipment, Electrolyte storage tank, cracking and sorting system, the storage tank II for storing up pure water, vibration sieve apparatus top are opposite with discharge hole of crusher It answers, is connected below vibration sieve apparatus with mud inlet above lead mud tank, vibration sieve apparatus side connects cracking and sorting system, lead mud tank Mud mouth is connected with filter press, and filter press is connected with storage tank I, and a discharge port of storage tank I is connected through valve I with acidproof pump inlet, Acidproof pump discharge is connect with the spray head on vibration sieve apparatus, and another discharge port of storage tank I is through micro-filtrate membrane filtration equipment and electrolyte Reservoir inlet is connected, and acidproof pump inlet is also connected through valve II with storage tank II.
The transmission device is conveyer belt.
The spray head is loaded on the two sides of vibrating screen equipment.
The pipeline I that the crusher, vibration sieve apparatus, spray head, acidproof pump discharge are connected with spray head, lead mud tank 6 and electrolysis Liquid contact portion material is all made of 316L steel.
Pipeline II, micro-filtrate membrane filtration equipment and the electrolyte contacts portion that I discharge port of storage tank is connected with acidproof pump inlet Point material is all made of PVC plastic.
The storage tank I, storage tank II, electrolyte storage tank material are pp material.
The cracking and sorting system is connected with vibration sieve apparatus by helical feed, cracking and sorting system feeding mouth and vibration The outlet of sieve apparatus oversize is connected.
The utility model can make electrolyte in shattering process compared with existing waste lead storage battery electrolyte collects measure It collects, by controlling crushing system impurity introduction point, to significantly reduce electrolyte impurity content, can more accomplish The introducing for avoiding chloride ion impurities, since current waste electrolyte recycles.By crushing system to waste lead storage battery removal process The electrolyte of generation is collected, and can avoid the introducing of chlorine impurity, and chlorine impurity is the difficult point of waste electrolyte recycling at present, due to control The introducing of chlorine impurity has been made, waste electrolyte recycling has fundamentally been solved the problems, such as, becomes the recycling and reusing of waste electrolyte May, so that needing neutralisation treatment waste electrolyte originally, the mode that distillation or film recycling can be used recycles waste electrolyte It recycles, not only reduces processing cost, so that electrolyte neutralize and is recycled, lead is made to store the circular economy of industry to being pushed forward It is dynamic.Waste electrolyte is collected using crushing system, compared to the method that tradition is collected from battery hole, mechanization degree is high, makes It obtains continuous production and collects waste electrolyte implementation easier to control, and reduce the risk of refuse battery hole antiseep.
Detailed description of the invention
Fig. 1 is the waste electrolyte collection system of the utility model;
In figure, 0- waste lead storage battery hole, 1- conveyer belt, 2- crusher, 3- vibration sieve apparatus, 4- spray head, broken point of 5- Select system, 6- lead mud tank, 7- acid-proof pump, 8- filter press, 9- storage tank I, 10- micro-filtrate membrane filtration equipment, 11- electrolyte storage tank, 12- storage tank II, 13- valve I, 14- valve II.
Specific embodiment
Below in conjunction with the utility model embodiment and Fig. 1, the technical scheme in the embodiment of the utility model is carried out clear Chu is fully described by, it is clear that the described embodiments are only a part of the embodiments of the utility model, rather than whole realities Apply example.Based on the embodiments of the present invention, those of ordinary skill in the art institute without making creative work The every other embodiment obtained, fall within the protection scope of the utility model.
It is used with waste and old lead acid accumulator as experimental test.
Waste lead storage battery hole 0 is connected by conveyer belt 1 with crusher 2, and 3 top of vibration sieve apparatus is opposite with crusher 2 It answers, vibrate that the lower section of sieve apparatus 3 is connected with lead mud tank 6,6 mud mouth of lead mud tank is connected with filter press 8, filter press 8 and I 9 phase of storage tank Even, I 91 discharge port of storage tank is connected with 10 feed inlet of micro-filtrate membrane filtration equipment, and 10 discharge port of membrane filtration equipment and electrolyte store up 11 feed inlet of tank is connected, and vibration 3 upper nozzle 4 of sieve apparatus is connected with the outlet of acid-proof pump 7, and 7 import of acid-proof pump is through valve I and storage tank I 9 Another discharge port is connected, and 7 import of acid-proof pump is also connect through valve II 14 with storage tank II 12.
Using waste lead storage battery electrolyte collection system recycling waste electrolyte method specifically includes the following steps:
(1) lead-acid accumulator is broken to crusher 2 by belt-conveying 1 in waste lead storage battery hole 0;
(2) broken battery each component is each fallen in vibration sieve apparatus 3 on vibrating screen, sieved by vibration sieve apparatus, It rinses, the lead grid, plastics, partition on sieve, which enter, is crushed subsystem 5, and the lead mud of electrolyte and flushing is each fallen within below vibrating screen In lead mud tank 6;
(3) lead mud, electrolyte are separated by 8 filters pressing of filter press in lead mud tank 6;
(4) it is entered in storage tank I 9 through the filtered electrolyte of filter press 8, storage tank I 9 stores electrolyte a part through resistance to Acid is pumped into spray head 4, rinses the use of lead mud for vibrating sieve apparatus 3, another part again can through the removal of micro-filtrate membrane filtration equipment 10 Solubility impurity is stored in electrolyte storage tank;
The pure water pair shut down for a long time, to avoid corrosion of the electrolyte to equipment, therefore need to empty, and stored with storage tank II 12 It is cleaned with the equipment of electrolyte contacts, emptying, cleaning step are as follows:
Valve I 13 is closed, stops conveyer belt 1, spray head 4 rinses, other equipment normal operations, until lead mud in lead mud tank 6 It empties, is then turned on valve II 14, after opening the flushing half an hour of spray head 4, close valve II 14, again empty lead mud tank 6, tie Beam.
Experimental analysis:
The electrolyte collected to electrolyte collection system in embodiment detects, and examines with the electrolyte that the prior art is collected Result statistics is surveyed to compare in table 1.
Each impurity content table of comparisons in the electrolyte that 1 prior art of table and the utility model are collected
As can be seen from Table 1: at collection system and collection method of the waste lead accumulator electrolyte by embodiment offer After reason, each impurity has apparent reduction, and wherein chlorine impurity has met battery acid requirement, only need to be to metal impurities at Reason.
The utility model avoids waste electrolyte recycling again compared with existing lead-acid accumulator collects electrolyte measure Using the introducing of difficult chlorine impurity, so that waste electrolyte recycling and reusing becomes possible, lead storage battery industry has been pushed The construction of circular economy.
Finally, above embodiments are only to illustrate the technical solution of waste lead storage battery electrolyte collection system rather than limit System, although through the foregoing embodiment to waste lead storage battery electrolyte collection system, collection method, carried out detailed retouch It states, however, those skilled in the art should understand that, various changes can be made to it in the form and details, without inclined From the utility model claims book limited range.

Claims (7)

1. a kind of waste lead storage battery electrolyte collection system, it is characterised in that: including waste lead storage battery hole (0), communicated Device cheats crusher (2), vibration sieve apparatus (3), lead mud tank (6), filter press (8), storage tank that (0) is connected with waste lead storage battery I (9), micro-filtrate membrane filtration equipment (10), electrolyte storage tank (11), cracking and sorting system (5), the storage tank II for storing up pure water (12), corresponding with crusher (2) discharge port above vibration sieve apparatus (3), below vibration sieve apparatus (3) and on lead mud tank (6) Square mud inlet is connected, vibration sieve apparatus (3) side connection cracking and sorting system (5), lead mud tank (6) mud mouth and filter press (8) It is connected, filter press (8) is connected with storage tank I (9), and a discharge port of storage tank I (9) is through valve I (13) and acid-proof pump (7) import phase Even, acid-proof pump (7) outlet is connect with the spray head (4) in vibration sieve apparatus (3), and another discharge port of storage tank I (9) is through microfiltration membranes mistake Filter equipment (10) is connected with electrolyte storage tank (11) feed inlet, and acid-proof pump (7) import is also through valve II (14) and storage tank II (12) It is connected.
2. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: the transmission dress It is set to conveyer belt (1).
3. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: the spray head (4) two sides loaded on vibration sieve apparatus (3).
4. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: the crusher (2), vibration sieve apparatus (3), spray head (4), acid-proof pump (7) export the pipeline I being connected with spray head (4), lead mud tank (6) and electrolyte Contact portion material is all made of 316L steel.
5. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: the storage tank I (9) pipeline II, micro-filtrate membrane filtration equipment and the electrolyte contacts part material that discharge port is connected with acid-proof pump (7) import are all made of PVC plastic.
6. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: the storage tank I (9), storage tank II (12), electrolyte storage tank (11) material are pp material.
7. a kind of waste lead storage battery electrolyte collection system according to claim 1, it is characterised in that: described broken point System (5) is selected to be connected with vibration sieve apparatus (3) by helical feed.
CN201821475249.8U 2018-09-10 2018-09-10 A kind of waste lead storage battery electrolyte collection system Active CN208738350U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110586613A (en) * 2019-08-29 2019-12-20 浙江浙矿重工股份有限公司 Waste battery crushing and sorting method capable of directly recycling waste electrolyte
WO2023179191A1 (en) * 2022-03-22 2023-09-28 宁德时代新能源科技股份有限公司 Standing device

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110586613A (en) * 2019-08-29 2019-12-20 浙江浙矿重工股份有限公司 Waste battery crushing and sorting method capable of directly recycling waste electrolyte
WO2021036918A1 (en) * 2019-08-29 2021-03-04 浙江浙矿重工股份有限公司 Waste battery crushing and sorting method for direct recycling of waste electrolyte
WO2023179191A1 (en) * 2022-03-22 2023-09-28 宁德时代新能源科技股份有限公司 Standing device

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