CN208711431U - An electrostatic photocatalytic mercury removal and dust removal device - Google Patents

An electrostatic photocatalytic mercury removal and dust removal device Download PDF

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Publication number
CN208711431U
CN208711431U CN201821059632.5U CN201821059632U CN208711431U CN 208711431 U CN208711431 U CN 208711431U CN 201821059632 U CN201821059632 U CN 201821059632U CN 208711431 U CN208711431 U CN 208711431U
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China
Prior art keywords
dust
electrostatic
demercuration
flue gas
extraction unit
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Expired - Fee Related
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CN201821059632.5U
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Chinese (zh)
Inventor
吴江
关昱
朱良君
纪政
吴强
齐雪梅
曲晨昊
张会
李庆伟
凌杨
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Shanghai University of Electric Power
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Shanghai University of Electric Power
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Abstract

本实用新型涉及一种静电光催化脱汞除尘装置,包括壳体,壳体内设置电除尘区、催化脱汞区和净烟气室,净烟气室内设有喷淋设备,电除尘区内设有放电级以及吸附尘粒的集尘级,放电级和集尘级上设有振打机构,催化脱汞区内设有若干附有催化剂的催化板,催化板沿烟气流进方向平行布置,在相邻催化板之间的顶端设置LED光源,催化脱汞区末端设有后墙,后墙下端设有与净烟气室相通的开口,进入壳体的烟气依次经过电除尘区除尘、催化脱汞区脱汞以及喷淋设备冲刷后排出。与现有技术相比,本实用新型针对烟气中的粉尘颗粒、重金属汞进行有效脱除,实现除尘和脱汞一步完成,烟气在除尘器中以此经过除尘脱汞洗涤,实现对烟气的有效净化。

The utility model relates to an electrostatic photocatalytic mercury removal and dust removal device, which comprises a casing. An electrostatic dust removal area, a catalytic mercury removal area and a clean flue gas chamber are arranged in the casing. There are a discharge stage and a dust collection stage for adsorbing dust particles. The discharge stage and the dust collection stage are provided with a rapping mechanism. There are several catalytic plates with catalysts in the catalytic mercury removal area. The catalytic plates are arranged in parallel along the inflow direction of the flue gas. , An LED light source is arranged at the top between the adjacent catalytic plates, a rear wall is arranged at the end of the catalytic mercury removal zone, and an opening that communicates with the clean flue gas chamber is arranged at the lower end of the rear wall. , Mercury removal in the catalytic mercury removal zone and after flushing by the spray equipment. Compared with the prior art, the utility model effectively removes dust particles and heavy metal mercury in the flue gas, and realizes the dust removal and mercury removal in one step. Effective purification of air.

Description

A kind of electrostatic photocatalysis demercuration dust-extraction unit
Technical field
The utility model relates to Environmental-protecting dust-removing fields, and in particular to a kind of electrostatic photocatalysis demercuration dust-extraction unit.
Background technique
Currently, pillar of the thermoelectricity as China's power industry, rapid development in recent years cause to a certain degree environment Pollution, multiple pollutant becomes the important source of atmosphere pollution in coal steam-electric plant smoke.It is well known that mercury and mercuric compounds have Very strong bio-toxicity, wherein the toxicity of organomercurial compound is maximum.It is caused a disease the most seriously in mercury poisoning with methyl mercury.Methyl mercury The basic operation function that human body cell can be destroyed, influences the nervous function of human body, endangers neuronal cell and strong denaturation occurs, make The various pieces of central nervous system are by different degrees of damage.Harm in addition to mercury to human body, mercury also produce ecological environment Significant impact have been given birth to, pollution can have been generated to the ecological environment including big gas and water, soil, they are not degraded by biology, It precipitates, and is converted into human body more added with the organomercurial compound of lethality in human body, to be generated to human health straight It connects or indirectly endangers.
The mercury Main Morphology that atmosphere is diffused into combustion process has 3 kinds: nonvalent mercury, bivalent mercury and particulate Hg.Bivalent mercury It can be dissolved in water, therefore can effectively be removed by wet method fume desulfurizing system, particulate Hg can be captured by deduster, as electrostatic removes Dirt device or sack cleaner.However nonvalent mercury is both not soluble in water or is not easy to adsorb, and may exist 1-2 in an atmosphere, they It cannot be degraded by microorganisms, constantly be enriched in human body, and be converted into the metallo-organic compound of severe toxicity, it is strong to the body of the mankind Kang Zaocheng direct or indirect harm.
In the prior art, the mercury removal device of injection adsorbent is widely used, absorption disengaging is carried out to the mercury in flue gas, it is this Mode haves the defects that certain.Such as patent 201310425727.X, a kind of integrated device and method of dedusting demercuration, coal-fired pot Kiln gas is efficiently trapped through dust collection electric field compared with crude particle dust first, and it is solidifying to subsequently enter charged integral type coalescence electric field progress dust And thickening, activated carbon adsorption demercuration is sprayed into after integral type coalescence electric field, active carbon enters together after dust and demercuration after thickening Bag area later is captured down;Patent 201520207706.5 is a kind of to combine removing with heavy metal for boiler smoke particulate matter, The device includes electric precipitation area, heavy metal catalyzed oxidation area, several parts in sorbent injection area and bag-type dusting area.Edge in device Flue gas flows into direction and electric precipitation area is arranged first, efficiently to trap flue gas particles and particulate form heavy metal Hg, arsenic etc.;Then set It sets mercury catalytic oxidant fixed bed, realizes in flue gas nonvalent mercury to mercuric conversion;Sorbent injection area is set after fixed bed With heavy metals such as adsorbing and removing mercury arsenic;The active carbon and escape flying dust for adsorbing heavy metal enter a bag area and are captured down.Electric area's ash Unloading under bucket is original matter flyash, and unloading under bag area ash bucket is the active carbon and a small amount of flyash for adsorbing heavy metal, on a small quantity Outlet is largely recycled to pipeline and sprays into flue gas recirculation utilization again.On the one hand, it will be adsorbed by way of spraying adsorbent Agent is mixed into the dust of recycling, causes the pollution of dust, cannot achieve the secondary use of dust, wastes a large amount of resource;It is another Aspect, when carrying out demercuration processing to a large amount of flue gases of high concentration, existing mode needs small size a large amount of mercury removal agent, cause demercuration at This serious increase, affects the economic benefit of industry, and demercuration efficiency and demercuration quality are lower, is unable to satisfy and arranges mercury in flue gas The requirement for the higher standard put.Therefore, developmental research is new and effective, energy-saving and environment-friendly demercuration dedusting technology becomes Environmental-protecting dust-removing skill The task of top priority in art field.
Utility model content
The purpose of this utility model is exactly to provide a kind of electrostatic photocatalysis demercuration dust-extraction unit to solve the above-mentioned problems.
The purpose of this utility model is achieved through the following technical solutions:
A kind of electrostatic photocatalysis demercuration dust-extraction unit flows into direction along flue gas including hollow shell, in the shell according to Secondary setting electric precipitation area, catalysis demercuration area and neat stress room, equipped with sprinkling equipment in the neat stress room, in the electric precipitation area Dust grade equipped with several arrester stages for keeping grit charged and absorption grit, the arrester stage and dust grade are equipped with rapping machine Structure, several catalytic plates with catalyst are equipped in the catalysis demercuration area, and the catalytic plate flows into the parallel cloth in direction along flue gas It sets, LED light source is arranged in the top between adjacent catalyst plate, and the catalysis demercuration area end is equipped with rear wall, the lower end Hou Qiang Equipped with the opening communicated with neat stress room, into shell flue gas successively pass through the dedusting of electric precipitation area, catalysis demercuration area demercuration with And sprinkling equipment wash away after be discharged.
Further, the housing forward end is equipped with import end socket, and rear end is equipped with exhanst gas outlet, and the exhanst gas outlet position is high In the sprinkling equipment.
Further, the shell is equipped with ash bucket in the lower end in electric precipitation area.
Further, the ash bucket lower end is equipped with unloading valve.
Further, the catalytic plate is waveform plate, along flue gas flow direction stacked arrangement.
Further, preceding insulation board and rear insulation board is respectively set in the front and back end in the electric precipitation area, it is ensured that arrester stage Electric field will not be revealed.
Further, being equipped on the preceding insulation board and rear insulation board makes the uniform air-flow even distributor of smoke distribution.
Further, the vibration body includes the anode vibration body of superposed cathode rapping mechanism and lower part, The external chain making machine of cathode rapping mechanism or motor, the anode vibration body are fixed on housing bottom and are connect by metallic support Ground, vibration body guarantee dedusting efficient stable.
Further, the sprinkling equipment is set as multilayer, and the sprinkling equipment water source can be desulfurizing tower water, and according to need Demister is installed additional on sprinkling equipment top, element mercury is bivalent mercury in the flue gas through being catalyzed, and bivalent mercury enters spray with flue gas Equipment is washed away, by mercury removal, to realize flue gas ash removal demercuration integration.
Further, the photochemical catalyst on the catalytic plate is BiOiO3Photochemical catalyst.
Compared with prior art, the utility model using photocatalysis technology in flue gas dust particles, heavy metal Hg into Row effectively removing is avoided the disadvantage excessively high using dust pollution caused by injection adsorbent and investment, is urged using electrostatic light Change deduster, realizes that dedusting and one step of demercuration are completed, flue gas is washed with this by dedusting demercuration in deduster, is realized to flue gas Effective purification.
Specific advantage are as follows:
1, preceding insulation board and rear insulation board is respectively set in the front and back end in electric precipitation area, it is ensured that the electric field of arrester stage will not be let out Dew.
2, being equipped on preceding insulation board and rear insulation board makes the uniform air-flow even distributor of smoke distribution, it is ensured that flue gas is equal Uniform flow is dusted through electric precipitation area, guarantees that the dust particles in flue gas are efficiently collected.
3, arrester stage and dust grade are equipped with vibration body, can vibrate the particle of collection and fall off, exclude in time.
4, catalytic plate is waveform plate, along flue gas flow direction stacked arrangement, the surface area of increase and smoke contacts, while making cigarette Gas disturbs, and increase is reacted with catalyst.
5, using photocatalysis technology, 90% or more, and catalyst preparation side can reach to the removal efficiency of the heavy metals such as mercury Just, stability is strong, can repeatedly use in the case where not increasing excessively high cost, realizes the removing of mercury.
6, using spray equipment purifying smoke, the heavy metal to the molecule in flue gas and after catalysis realizes cleaning, and Flue-gas temperature is reduced simultaneously, is reduced the water of taking in desulfurizing tower, is mitigated plume phenomenon.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of utility model device;
Fig. 2 is schematic diagram of the A to catalysis demercuration area;
In figure: 1- import end socket;Insulation board before 2-;3- air-flow even distributor;4- cathode rapping mechanism;5- arrester stage;6- collection Dirt grade;Insulation board after 7-;8-LED light source;9- catalytic plate;Wall after 10-;11- neat stress room;12- exhanst gas outlet;13- spray is set It is standby;14- bottom beam;15- anode vibration body;16- unloading valve;17- ash bucket.
Specific embodiment
The utility model is described in detail in the following with reference to the drawings and specific embodiments.
Embodiment 1
A kind of novel electrostatic photocatalysis demercuration dust-extraction unit, as shown in Figure 1, including import end socket 1, ash bucket 17 makes to enter The uniform air-flow even distributor 3 of electric field smoke distribution, makes the arrester stage 5 that grit is charged, adsorbs the dust grade 6 of grit, with can be with The catalytic plate 9 of the catalyst of catalysis oxidation mercury, and the sprinkling equipment 13 of flue gas is washed away, cathode rapping mechanism 4 can outer chain Mechanical, electrical motivation equal power device, anode vibration body 15 are fixed on device bottom beam 14, and pass through the metallic support on bottom beam 14 Vibrator can be used in ground connection, vibration body.Insulation board 2 before flue gas is reached by import end socket 1, and it is real at air-flow even distributor 3 It is now uniformly distributed, to guarantee that efficiency of dust collection, preceding insulation board 2 play insulating effect, it is ensured that the electric field of arrester stage 5 will not be revealed, cigarette Gas passes through electric field, and grit enters catalytic plate region by charged removing, by rear insulation board 7 and air-flow even distributor, and rear insulation board 7 is protected Card electric field will not have an impact light-catalyzed reaction.
As shown in Fig. 2, catalytic plate 9 is the S template along flue gas flow direction stacked arrangement, to increase the surface with smoke contacts Product, while flue gas is disturbed, increase is reacted with catalyst, and the LED for being provided with stable exciting light is arranged in 9 top of catalytic plate Light source 8 makes photochemical catalyst that the nonvalent mercury in flue gas are oxidized to bivalent mercury under the irradiation of LED light source 8, while in deduster The reserved opening in top, guarantees the replaceable of catalytic plate.10 bottom end of wall is porous structure after catalytic plate 9, and flue gas is de- by photocatalysis Enter sprinkling equipment 13 from the bottom Hou Qiang after mercury, sprinkling equipment 13 is multi-layer spray, and flue gas is by washing away removal therein two Valence mercury simultaneously carries out further cleaning to remaining grit.
The above descriptions are merely preferred embodiments of the present invention, is not intended to limit the utility model, although ginseng The utility model is described in detail according to previous embodiment, it for those skilled in the art, still can be with It modifies the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, it is all Within the spirit and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in practical Within novel protection scope.

Claims (10)

1. a kind of electrostatic photocatalysis demercuration dust-extraction unit, including hollow shell, direction is flowed into along flue gas, in the shell successively Electric precipitation area, catalysis demercuration area and neat stress room are set, are equipped with sprinkling equipment in the neat stress room, which is characterized in that described Several arrester stages for keeping grit charged are equipped in electric precipitation area and adsorb the dust grade of grit, on the arrester stage and dust grade Equipped with vibration body, several catalytic plates with catalyst are equipped in the catalysis demercuration area, the catalytic plate is flowed into along flue gas LED light source is arranged in direction parallel arrangement, the top between adjacent catalyst plate, and the catalysis demercuration area end is equipped with rear wall, institute It states the lower end Hou Qiang and is equipped with the opening that communicates with neat stress room, successively to pass through the dedusting of electric precipitation area, catalysis de- into the flue gas of shell Mercury area demercuration and sprinkling equipment are discharged after washing away.
2. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the housing forward end is set There is import end socket, rear end is equipped with exhanst gas outlet, and the exhanst gas outlet position is higher than the sprinkling equipment.
3. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the shell is removed in electricity The lower end in dirt area is equipped with ash bucket.
4. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 3, which is characterized in that the ash bucket lower end is set There is unloading valve.
5. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the catalytic plate is wave Shape wave plate, along flue gas flow direction stacked arrangement.
6. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the electric precipitation area Preceding insulation board and rear insulation board is respectively set in front and back end.
7. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 6, which is characterized in that the preceding insulation board and Being equipped on insulation board afterwards makes the uniform air-flow even distributor of smoke distribution.
8. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the vibration body packet The anode vibration body of superposed cathode rapping mechanism and lower part, the external chain making machine of cathode rapping mechanism or motor are included, The anode vibration body is fixed on housing bottom and is grounded by metallic support.
9. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that the sprinkling equipment is set For multilayer, and demister is installed additional on sprinkling equipment top as needed.
10. a kind of electrostatic photocatalysis demercuration dust-extraction unit according to claim 1, which is characterized in that on the catalytic plate Photochemical catalyst be BiOiO3Photochemical catalyst.
CN201821059632.5U 2018-07-05 2018-07-05 An electrostatic photocatalytic mercury removal and dust removal device Expired - Fee Related CN208711431U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201821059632.5U CN208711431U (en) 2018-07-05 2018-07-05 An electrostatic photocatalytic mercury removal and dust removal device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201821059632.5U CN208711431U (en) 2018-07-05 2018-07-05 An electrostatic photocatalytic mercury removal and dust removal device

Publications (1)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108786454A (en) * 2018-07-05 2018-11-13 上海电力学院 A kind of electrostatic photocatalysis demercuration dust-extraction unit
CN114939342A (en) * 2022-06-07 2022-08-26 西安交通大学 Small-space air purification device based on corona discharge and use method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108786454A (en) * 2018-07-05 2018-11-13 上海电力学院 A kind of electrostatic photocatalysis demercuration dust-extraction unit
CN114939342A (en) * 2022-06-07 2022-08-26 西安交通大学 Small-space air purification device based on corona discharge and use method thereof

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Granted publication date: 20190409