CN208690433U - A kind of online desulfurizing device of lead-acid accumulator based on chaos - Google Patents
A kind of online desulfurizing device of lead-acid accumulator based on chaos Download PDFInfo
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- CN208690433U CN208690433U CN201721298201.XU CN201721298201U CN208690433U CN 208690433 U CN208690433 U CN 208690433U CN 201721298201 U CN201721298201 U CN 201721298201U CN 208690433 U CN208690433 U CN 208690433U
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- battery
- output end
- input terminal
- mode selector
- chaos
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- 239000002253 acid Substances 0.000 title claims abstract description 28
- 230000003009 desulfurizing effect Effects 0.000 title claims abstract description 15
- 238000001514 detection method Methods 0.000 claims abstract description 33
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 13
- 230000023556 desulfurization Effects 0.000 claims abstract description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 35
- 239000005864 Sulphur Substances 0.000 claims description 21
- 230000000739 chaotic effect Effects 0.000 abstract description 15
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 abstract description 10
- 238000002425 crystallisation Methods 0.000 abstract description 5
- 230000008025 crystallization Effects 0.000 abstract description 5
- 238000001228 spectrum Methods 0.000 abstract description 3
- 230000008439 repair process Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 17
- 229910052717 sulfur Inorganic materials 0.000 description 14
- 239000011593 sulfur Substances 0.000 description 14
- 238000012360 testing method Methods 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 230000005611 electricity Effects 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 238000004073 vulcanization Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 230000036461 convulsion Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000007926 Craterellus fallax Nutrition 0.000 description 1
- 240000007175 Datura inoxia Species 0.000 description 1
- 208000032953 Device battery issue Diseases 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 210000001367 artery Anatomy 0.000 description 1
- 230000005779 cell damage Effects 0.000 description 1
- 208000037887 cell injury Diseases 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009774 resonance method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Charge And Discharge Circuits For Batteries Or The Like (AREA)
- Secondary Cells (AREA)
Abstract
A kind of online desulfurizing device of lead-acid accumulator based on chaos, including battery further include chaos signal generator, mode selector and internal resistance detection device;Its connection type are as follows: the output end of chaos signal generator is connected to the input terminal of mode selector, the input terminal of mode selector is connect with the output end of internal resistance detection device, and the output end of mode selector is connected by single-pole double-throw switch (SPDT) with the input terminal of the input terminal of battery or internal resistance detection device;The output end of the input terminal connection charging equipment of the online desulfurization device;The output end of the desulfurization device is loaded into battery both ends;And the output end of battery is then connected with power rectifier cabinet and electrical equipment.The utility model utilizes chaos circuit, produces the wide spectrum chaotic signal with different frequency characteristic, has frequency signal similar in resonance frequency therewith for the crystallization of different size of lead sulfate.In this manner it is possible to improve the reparation speed of battery, reaches quickly, efficiently repair purpose.
Description
Technical field
The utility model relates to Lead-acid Battery Technology field, refers specifically to a kind of lead-acid accumulator based on chaos and remove online
Sulphur device.
Background technique
Since lead-acid accumulator has high cost performance, in communications and transportation, telecommunication power, the fields such as defence and military have
Widely apply.In fields such as telecommunication powers, the occupation rate of market of lead-acid accumulator has been even up to 95%.But in reality
A kind of hard and conductive undesirable coarse grain sulfuric acid can be gradually generated since improper use and maintenance are not good in, on negative plate
Lead.This lead sulfate conventional method charging is difficult to restore, and in charging, charge acceptance is very poor, a large amount of bubbings, this
Kind phenomenon is referred to as " irreversible lead sulfate salinization ", referred to as " vulcanization ".This makes that battery capacity reduction, shortening is caused to use the longevity
Life.To produce the huge wasting of resources and DC power system failure rate.Simultaneously as in the composition of lead-acid accumulator,
Electrolyte sulfuric acid accounts for total cell weight 16% or so, and leaded substance accounts for 70% of weight or more.These lead acid storage batteries scrapped
Pond environmental pollution is very harmful, and acid solution meeting contaminated soil and underground water can also cause blood lead to be poisoned people and animals.Because of heavy metal
The maximum feature of pollution is cannot to be degraded in nature, that is to say, that once water body or soil are contaminated, which will
Time of the lasting decades to upper a century.
Traditional lead-acid accumulator process for sulfur removal has 1. electricity current methods.2. negative pulse method.3. adding active agent method etc..At present
Having most effective lead-acid accumulator recovery technique is compound electrical pulse method, and this method is using the higher hamonic wave in charging pulse and greatly
Lead sulfate crystallization resonance method, in repair process eliminate battery vulcanization.This method is repaired when repairing to battery
It is multiple high-efficient, it is small to cell damage, make longer cell life, reduces user because replacing battery due to bring enormous expenditure, greatly
Alleviate pollution of the lead-acid accumulator to environment.
Crystal has resonance frequency after molecular structure determines, and this resonance frequency is related with the size of crystal.It is brilliant
The size of body is different, and resonance frequency is different.The characteristics of compound electrical pulse method is exactly to use high frequency positive negative pulse stuffing generator, to battery
It is continuous to generate height variable-frequency pulse.One can have the condition for dissolving big lead sulfate, the second is pulse-type disturbance, destroys big
The condition of lead sulfate continued growth.To reach quickly, efficient sulfur limitation effect.But the pulse harmonic frequency generated by this method
Rate is abundant not enough.In actual use, since the vulcanization situation of battery is different, the internal lead sulfate crystallite size generated
Varied, frequency caused by compound electrical pulse method is not able to satisfy sulphur removal demand, and sulfur removal effectiveness is high not enough.
Utility model content
The problem of the purpose of this utility model is for lead-acid accumulator sulfur removal technology proposes a kind of structure letter
It is single, it can complete quickly, efficient online desulfurizing device.
The technical solution adopted in the utility model is:
A kind of online desulfurizing device of lead-acid accumulator based on chaos, including battery, further include chaos signal generator,
Mode selector and internal resistance detection device;Its connection type are as follows: the output end of chaos signal generator is connected to mode selector
The input terminal of input terminal, mode selector is connect with the output end of internal resistance detection device, and the output end of mode selector passes through list
Double-pole double throw switch is connected with the input terminal of the input terminal of battery or internal resistance detection device;The input terminal of the online desulfurization device connects
Connect the output end of charging equipment;The output end of the desulfurization device is loaded into battery both ends;And the output end of battery then with electricity
Source rectifier cabinet is connected with electrical equipment.
A kind of online desulfurizing device of lead-acid accumulator based on chaos, if including dry battery, further include chaotic signal hair
Raw device, mode selector and several internal resistance detection devices;Its connection type are as follows: each output end of chaos signal generator is separately connected
To each input terminal of mode selector, each input terminal of mode selector connects with the output end of corresponding internal resistance detection device respectively
It connects;And each output end of mode selector by respective single-pole double-throw switch (SPDT) respectively with the input terminal of corresponding battery or right
The internal resistance detection device connection answered;The output end of the input terminal connection charging equipment of the online desulfurization device;The desulfurization device
Output end is loaded into battery both ends;And the output end of battery is then connected with power rectifier cabinet and electrical equipment.
The utility model utilizes chaos circuit, produces the wide spectrum chaotic signal with different frequency characteristic.Compared to
The restorative procedure of existing most effective compound electric pulse.The more horn of plenty of frequency signal caused by this method, for different size
Lead sulfate crystallization have frequency signal similar in resonance frequency therewith.In this manner it is possible to improve the reparation speed of battery, reach
To quick, purpose is efficiently repaired.
The utility model improves the service life of battery, avoids scrapping in advance for a large amount of batteries.It has saved big
The economic cost of amount reduces the failure rate as caused by accumulator property decline.
Since in the composition of lead-acid accumulator, electrolyte sulfuric acid accounts for total cell weight 16% or so, leaded substance accounts for weight
70% or more of amount.The lead-acid accumulator environmental pollution that these are scrapped is very harmful, acid solution meeting contaminated soil and underground water, also
Blood lead can be caused to be poisoned people and animals.The technology as involved in the utility model improves battery, so as to avoid
A large amount of batteries scrap brought problem of environmental pollution in advance.
Detailed description of the invention
Fig. 1 is the structural block diagram of the utility model embodiment 1;
Fig. 2 is the structural block diagram of the utility model embodiment 2;
Fig. 3 is the structural block diagram of the utility model embodiment 3;
Fig. 4 is the structural block diagram of the utility model embodiment 4;
Fig. 5 is the structural block diagram of the utility model embodiment 5;
Fig. 6 is that the utility model online mode realizes structural block diagram.
Specific embodiment
The utility model and its effect are further illustrated with reference to the accompanying drawing.
The realization principle of the utility model is: utilizing chaos circuit, the impulse wave with abundant frequency spectrum is generated, by this arteries and veins
It rushes wave and is applied to battery or battery pack both ends;So that different size of lead sulfate crystallization can obtain resonance therewith in battery
The close impulse wave of frequency;To smash and dissolve big lead sulfate crystallization, it is allowed to be dissolved in electrolyte, finally with charging
It carries out, resolves into lead ion and sulfate ion participates in reaction, to reach quickly, the purpose of efficient sulphur removal.And then improve electric power storage
The service life in pond avoids scrapping in advance for a large amount of batteries.A large amount of economic cost has been saved, has been reduced due to battery
Failure rate caused by performance declines.Meanwhile it also largely avoiding and largely scrapping environmental pollution caused by battery.
Based on the above principles, the utility model is further illustrated with following specific embodiments.
Embodiment 1, referring to Fig.1, a kind of online desulfurizing device of single lead-acid accumulator based on chaos is sent out by chaotic signal
Raw device, mode selector, internal resistance detection device and battery are constituted.The connection type of the device are as follows: chaos signal generator it is defeated
Outlet C1, C2 ..., Cn are connected respectively to the input terminal of mode selector, the input terminal of mode selector respectively with internal resistance detection
Output end F1, the F2 connection of device, the output end of mode selector by single-pole double-throw switch (SPDT) K1, K2 respectively with the input of battery
End phase is connect with the input terminal of internal resistance detection device.The output end of the input terminal connection charging equipment of the online desulfurization device;
The output end of the desulfurization device is loaded into battery both ends;And the output end of battery then with power rectifier cabinet and electrical equipment phase
Connection.
Above-mentioned battery is single battery or the battery pack that multiple battery strings unify.
Embodiment 2, referring to Fig. 2, a kind of online desulfurizing device of multiple lead-acid accumulators based on chaos is sent out by chaotic signal
Raw device, mode selector, if several internal resistance detection devices and dry battery group are constituted.The connection type of the device are as follows: chaotic signal
The output end C1, C2 ..., Cn of generator are connected respectively to each input terminal of mode selector, each input terminal of mode selector
Respectively with corresponding internal resistance detection device 1, internal resistance detection device 2 ..., the output end F1, F2 ..., F2n-1, F2n of internal resistance detection device n
It is connected.Each output end of mode selector by respective single-pole double-throw switch (SPDT) K1, K2 ..., K2n respectively with corresponding electric power storage
Pond 1, the input terminal phase of battery 2 ... battery n or with corresponding internal resistance detection device 1, internal resistance detection device 2, internal resistance detection device n
Connection.The output end of the input terminal connection charging equipment of the online desulfurization device;The output end of the desulfurization device is loaded into storage
Battery both ends;And the output end of battery is then connected with power rectifier cabinet and electrical equipment.
The battery pack that above-mentioned each battery still can be single battery or multiple battery strings unify.
The working principle of embodiment 1 and embodiment 2: in actual work, which carries out in two steps.Step 1: letter
Number choice phase.Mode selector selects different chaotic signal waveforms respectively, is loaded on battery, according to internal resistance detection
Result calculate sulfur removal effectiveness, select the best chaotic waves for the battery.Step 2: sulphur removal stage.Mode selector root
According to selected optimum waveform, sulphur removal is carried out to battery.
The utility model replaces original pulse signal to carry out chaos sulphur removal using chaotic signal, and according to internal resistance detection
As a result, carrying out sulphur removal using different chaotic signals for different batteries.
Embodiment 3, the online desulfurizing device of lead-acid accumulator based on Chua's chaotic circuit, such as Fig. 3 choose Cai Shi chaos electricity
Two output C1 and C2 on road access mode selector, remaining is the same as embodiment 1.In actual work, sulphur removal process is divided into two ranks
Section.In the first stage, single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector selects C1 waveform, to battery
The sulphur removal of a period of time is carried out, then, it is mixed to calculate the road according to testing result for single-pole double-throw switch (SPDT) selection access internal resistance detection device
Ignorant signal sulfur removal effectiveness;Then single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector select C2 waveform, carry out
The sulphur removal of same time, then single-pole double-throw switch (SPDT) selection access internal resistance detection device, calculates road chaos letter according to testing result
Number sulfur removal effectiveness.In second stage, mode selector according to testing result, selects the preferable chaotic signal of sulfur limitation effect to storage
Battery carries out sulphur removal.
Embodiment 4, the online desulfurizing device of lead-acid accumulator based on Jerk chaos circuit, such as Fig. 4 choose Jerk circuit
Three outputs C1, C2 and C3 access mode selector, remaining is the same as embodiment 1.In actual work, sulphur removal process is divided into two ranks
Section.In the first stage, single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector selects C1 waveform, to battery
The sulphur removal of a period of time is carried out, then, it is mixed to calculate the road according to testing result for single-pole double-throw switch (SPDT) selection access internal resistance detection device
Ignorant signal sulfur removal effectiveness;Single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector select C2 waveform, carry out identical
The sulphur removal of time, then single-pole double-throw switch (SPDT) selection access internal resistance detection device, calculates the road chaotic signal according to testing result
Sulfur removal effectiveness;Single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector select C3 waveform, carry out phase to battery
With the sulphur removal of time, in second stage, mode selector according to testing result, selects the preferable chaotic signal of sulfur limitation effect to storage
Battery carries out sulphur removal.
Embodiment 5, the online desulfurizing device of lead-acid accumulator based on Lorentz circuit, such as Fig. 5 choose Lorentz chaos electricity
Two output C1 and C2 on road access mode selector, remaining is the same as embodiment 1.In actual work, sulphur removal process is divided into two ranks
Section.In the first stage, single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector selects C1 waveform, to battery
The sulphur removal of a period of time is carried out, then, it is mixed to calculate the road according to testing result for single-pole double-throw switch (SPDT) selection access internal resistance detection device
Ignorant signal sulfur removal effectiveness;Then single-pole double-throw switch (SPDT) selection access battery or battery pack, mode selector select C2 waveform, carry out
The sulphur removal of same time, then single-pole double-throw switch (SPDT) selection access internal resistance detection device, calculates road chaos letter according to testing result
Number sulfur removal effectiveness.In second stage, mode selector according to testing result, selects the preferable chaotic signal of sulfur limitation effect to storage
Battery carries out sulphur removal.
Chaos circuit commonly used in the prior art is suitable for the utility model.
Claims (4)
1. a kind of online desulfurizing device of lead-acid accumulator based on chaos, including battery, it is characterised in that: further include chaos letter
Number generator, mode selector and internal resistance detection device;Its connection type are as follows: the output end of chaos signal generator is connected to waveform
The input terminal of the input terminal of selector, mode selector is connect with the output end of internal resistance detection device, and the output of mode selector
End is connected by single-pole double-throw switch (SPDT) with the input terminal of the input terminal of battery or internal resistance detection device;The online desulfurization device
The output end of input terminal connection charging equipment;The output end of the desulfurization device is loaded into battery both ends;And the output of battery
End is then connected with power rectifier cabinet and electrical equipment.
2. the online desulfurizing device of a kind of lead-acid accumulator based on chaos according to claim 1, it is characterised in that: described
Battery is single battery or the battery pack that multiple battery strings unify.
3. a kind of online desulfurizing device of lead-acid accumulator based on chaos, if including dry battery, it is characterised in that: further include mixing
Ignorant signal generator, mode selector and several internal resistance detection devices;Its connection type are as follows: each output end of chaos signal generator
It is connected respectively to each input terminal of mode selector, each input terminal of mode selector is defeated with corresponding internal resistance detection device respectively
Outlet connection;And each output end of mode selector by respective single-pole double-throw switch (SPDT) respectively with the input of corresponding battery
End or the connection of corresponding internal resistance detection device;The output end of the input terminal connection charging equipment of the online desulfurization device;The sulphur removal
The output end of equipment is loaded into battery both ends;And the output end of battery is then connected with power rectifier cabinet and electrical equipment.
4. the online desulfurizing device of a kind of lead-acid accumulator based on chaos according to claim 3, it is characterised in that: described
Battery is single battery or the battery pack that multiple battery strings unify.
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CN201721298201.XU CN208690433U (en) | 2017-10-10 | 2017-10-10 | A kind of online desulfurizing device of lead-acid accumulator based on chaos |
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CN201721298201.XU CN208690433U (en) | 2017-10-10 | 2017-10-10 | A kind of online desulfurizing device of lead-acid accumulator based on chaos |
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CN201721298201.XU Expired - Fee Related CN208690433U (en) | 2017-10-10 | 2017-10-10 | A kind of online desulfurizing device of lead-acid accumulator based on chaos |
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2017
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