CN208626955U - Flue gas washing system - Google Patents

Flue gas washing system Download PDF

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Publication number
CN208626955U
CN208626955U CN201820761234.1U CN201820761234U CN208626955U CN 208626955 U CN208626955 U CN 208626955U CN 201820761234 U CN201820761234 U CN 201820761234U CN 208626955 U CN208626955 U CN 208626955U
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China
Prior art keywords
clean water
fluid reservoir
water
spray unit
nozzle
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CN201820761234.1U
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Inventor
宋海涛
王鹏
孙言
姜秋桥
林伟
田辉平
张久顺
达志坚
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Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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Sinopec Research Institute of Petroleum Processing
China Petroleum and Chemical Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

This disclosure relates to a kind of flue gas washing system, the system includes: scrubbing tower tower body (3), the chimney (5) being in fluid communication with the scrubbing tower tower body (3), the exhanst gas outlet (6) for being set to the smoke inlet (2) of scrubbing tower tower body (3) lower part and being set at the top of the chimney (5), absorbing liquid spray unit is provided in the scrubbing tower tower body (3), it is characterized in that, being provided with clean water spray unit above the absorbing liquid spray unit;The clean water spray unit includes cleaning (operating) water nozzle (8), clean water fluid reservoir (13) and gas-liquid contact reinforcing elements (14).The system of the disclosure can effectively eliminate wet scrubbing tower flue gas trailing phenomenon, solve blue smoke and plume subsidence problems, and do not influence the operating flexibility of scrubbing tower and upstream device, while additionally aiding and slowing down equipment corrosion.

Description

Flue gas washing system
Technical field
This disclosure relates to a kind of flue gas washing system.
Background technique
In industrial processes, especially in some production processes containing heat treatment step (dry, roasting, burning etc.) In, the exhaust gas such as the tail gas containing pollutant or flue gas can be generated.For example, part during catalytic cracking (FCC), in raw material Sulphur, nitrogen compound enter coke laydown on reclaimable catalyst in riser reaction process, and spent agent enters regenerator and burns When regeneration, sulphur, nitrogen compound oxidation in these coke generate SOx、NOxEqual flue gas pollutants.For another example, the nothings such as catalyst production In machine chemical process, whens heat resolves such as sulfate, nitrate, villaumite for containing in raw material, can be generated containing SOx、NOx、 Cl2, the pollutants and pernicious gas such as HCl tail gas.These flue gases and tail gas containing pollutant and pernicious gas need to be by purifications It could qualified discharge after processing.
Power generation, petrochemical industry, inorganization is had been widely used for by the wet scrubbing technology of core equipment of wet scrubbing tower The flue gas and tail gas clean-up of the industrial process such as work are handled.Although process flow and structure have certain difference, its basic principle is all It is that the pollutant in gas phase is absorbed into liquid phase by gas-liquid contact, achievees the purpose that purifying smoke or tail gas.United States Patent (USP) US20070189949A1 discloses a kind of wet scrubbing system for regeneration fume from catalytic cracking processing, by washing alkalinity It washs liquid and flue gas and carries out spray and contact, efficient removal SO may be implemented2While trap dust effect.
But also gradually there are some problems for discovery wet scrubbing process in industry park plan, are also easy to produce flue gas hangover and blue The problems such as plume sinks causes to seriously affect to plant area and periphery production and living environment.
Utility model content
Purpose of this disclosure is to provide a kind of flue gas washing systems, to solve the flue gas of existing and newly-built wet scrubbing system Hangover and subsidence problems reduce the adverse effect to plant area and periphery production and living environment.
To achieve the goals above, the disclosure provides a kind of flue gas washing system, the system include: scrubbing tower tower body, with The chimney of the scrubbing tower tower body fluid communication is set to the smoke inlet of scrubbing tower tower body lower part and is set to institute The exhanst gas outlet of chimney top is stated, is provided with absorbing liquid spray unit in the scrubbing tower tower body, which is characterized in that the absorption Clean water spray unit is provided with above liquid spray unit;
The clean water spray unit includes cleaning (operating) water nozzle, the clean water liquid storage below the cleaning (operating) water nozzle Tank and multiple clean water fluid reservoir flues axially through the clean water fluid reservoir, the cleaning (operating) water nozzle and Gas-liquid contact reinforcing elements are provided between clean water fluid reservoir, the cleaning (operating) water nozzle and clean water fluid reservoir pass through pipe respectively Line is connected with clean water transfer pump.
Optionally, the clean water fluid reservoir has clean water fluid reservoir overflow port, which connects It is connected to the clean water overflow line for extending to the absorbing liquid spray unit.
Optionally, the quantity of the clean water spray unit is one or more.
Optionally, the clean water spray unit is set in the chimney, the upper end tank mouth of the clean water fluid reservoir It is tightly connected with the inner wall of the chimney;And/or
The clean water spray unit is set in the scrubbing tower tower body, the upper end tank mouth of the clean water fluid reservoir with The inner wall of the scrubbing tower tower body is tightly connected.
Optionally, the quantity of the cleaning (operating) water nozzle is 1~12;When the quantity more than one of the cleaning (operating) water nozzle, The cleaning (operating) water nozzle is circumferentially and/or radial direction is equally spaced.
Optionally, the cleaning (operating) water nozzle is selected from least one of spiral nozzle, fan nozzle and nozzle ring.
Optionally, the gas-liquid contact reinforcing elements are filler and/or column plate;The filler be selected from Pall ring filler, At least one of ladder ring packing, corrugated plate packing and structured packing, the filler are preferably regular honeycomb padding.
Optionally, the salt content of clean water used in the clean water spray unit is not higher than and is collected by the exhanst gas outlet Flue gas condensing water salt content.
Optionally, the clean water is selected from least one of fresh water, middle water and waste water Jing Guo desalting processing.
Through the above technical solutions, the disclosure in the case where not changing original main structure of wet scrubbing tower, increases Clean water spray unit, the clean water for spraying out flue gas before tower out with cleaning (operating) water nozzle contact, can effectively eliminate wet process and wash Tower flue gas trailing phenomenon is washed, solves blue smoke and plume subsidence problems, and do not influence the operating flexibility of scrubbing tower and upstream device, together When additionally aid slow down equipment corrosion;It is recycled in addition, being collected by clean water fluid reservoir with the clean water after smoke contacts It utilizes, the utilization rate of clean water can also be effectively improved, while improving the spray flow of clean water;Further, it is sprayed in clean water Mouth spray lower section, which increases gas-liquid contact reinforcing elements, can strengthen the contact between flue gas and clean water, reduce water consumption, more effectively Ground solves blue smoke and plume subsidence problems.The system structure that the disclosure provides is simple, at low cost, can be used for various industrial process Flue gas or vent gas treatment, including power generation, petrochemical industry, inorganic chemical industry etc..
Other feature and advantage of the disclosure will the following detailed description will be given in the detailed implementation section.
Detailed description of the invention
Attached drawing is and to constitute part of specification for providing further understanding of the disclosure, with following tool Body embodiment is used to explain the disclosure together, but does not constitute the limitation to the disclosure.In the accompanying drawings:
Fig. 1 is a kind of structural schematic diagram of the specific embodiment for the flue gas washing system that the disclosure provides;
Fig. 2 is the schematic diagram that a kind of arrangement mode of (operating) water nozzle is cleaned in the flue gas washing system of disclosure offer;
Wherein, the arrow direction in figure refers to the direction of motion of fluid.
Description of symbols
1 replenisher entrance
2 smoke inlets
3 scrubbing tower tower bodies
4 replenisher entrances
5 chimneys
6 exhanst gas outlets
7 clean water transfer pumps
8 cleaning (operating) water nozzles
9 second absorbing liquid circulating pumps
10 second absorb nozzle for liquid
11 first absorbing liquid circulating pumps
12 efflux wastewater pipelines
13 clean water fluid reservoirs
14 gas-liquid contact reinforcing elements
15 first absorb nozzle for liquid
16 first absorbing liquid fluid reservoirs
17 second absorbing liquid fluid reservoirs
18 second fluid reservoir flues
19 clean water fluid reservoir flues
20 absorbing liquid overflow lines
21 clean water overflow lines
Specific embodiment
It is described in detail below in conjunction with specific embodiment of the attached drawing to the disclosure.It should be understood that this place is retouched The specific embodiment stated is only used for describing and explaining the disclosure, is not limited to the disclosure.
In the disclosure, in the absence of explanation to the contrary, the noun of locality used such as " upper and lower " typically refers to system reality Upper and lower when border works, " inside and outside " is for profile of structure itself.
The disclosure provides a kind of flue gas washing system, and with reference to Fig. 1, which includes: scrubbing tower tower body 3 and scrubbing tower tower The chimney 5 of the fluid communication of body 3 is set to the smoke inlet 2 of 3 lower part of scrubbing tower tower body and is set to the chimney 5 and pushes up The exhanst gas outlet 6 in portion.Absorbing liquid spray unit (also referred to as absorbing liquid spray equipment), institute are provided in the scrubbing tower tower body 3 It states and is provided with clean water spray unit (also referred to as cleaning water spray system) above absorbing liquid spray unit.
The disclosure increases clean water spray unit, cigarette in the case where not changing original main structure of wet scrubbing tower Spray of the gas before tower out Jing Guo clean water can effectively eliminate flue gas trailing phenomenon, solve blue smoke and plume subsidence problems, and The operating flexibility of scrubbing tower and upstream device is not influenced, while being additionally aided and being slowed down equipment corrosion.
According to the disclosure, the clean water spray unit may include cleaning (operating) water nozzle 8, be located at the cleaning (operating) water nozzle 8 The clean water fluid reservoir 13 of lower section and multiple clean water fluid reservoir fume pipes axially through the clean water fluid reservoir 13 Road 19.The clean water fluid reservoir flue 19 for flue gas upwardly through clean water fluid reservoir 13, shape and size without Especially limitation, can be Venturi tube, straight tube, reducer pipe or other structures.Flue gas is by clean water fluid reservoir flue 19 It rises, the clean water that cleaning (operating) water nozzle 8 sprays is met, to carry out the spray of clean water spray unit.The cleaning (operating) water nozzle 8 with it is clear Clean water fluid reservoir 13 is connected by pipeline with clean water transfer pump 7 respectively, to collect spray by clean water fluid reservoir 13 Clean water and be delivered to cleaning (operating) water nozzle 8 recycled, effectively improve the utilization rate of clean water, while improving clean water Spray flow, the flue gas hangover for the scrubbing tower that effectively disappears and plume sinkage.It will be appreciated by persons skilled in the art that can lead to The intake pipeline for crossing clean water transfer pump 16 conveys into the clean water spray unit and/or supplements clean water.
According to the disclosure, the clean water fluid reservoir 13 can have clean water fluid reservoir overflow port, the clean water liquid storage Tank overflow port is connected with the clean water overflow line 21 for extending to the absorbing liquid spray unit.The effect of overflow port is this field Known to technical staff, when the liquid level in clean water fluid reservoir 13 is excessively high and reaches the clean water fluid reservoir overflow port, cleaning Water can be entered in underlying absorbent liquid spray unit by clean water overflow line 21, in this way, excessive clean water can be used as absorption The replenisher of liquid spray unit, to reduce the absorbing liquid magnitude of recruitment of absorbing liquid spray unit.The clean water fluid reservoir overflows The position that opens up of head piece can according to need the upper end for being designed, such as can making the clean water fluid reservoir flue 19 Opening is higher than the clean water fluid reservoir overflow port, i.e. the exhanst gas outlet position of clean water fluid reservoir flue 19 is higher than cleaning Liquid level in water fluid reservoir 13, avoids that flue gas enters in clean water fluid reservoir 13 or clean water by 19 overflow of pipeline goes out fluid reservoir 13。
According to the disclosure, the quantity of the clean water spray unit can be one or more.In a kind of tool of the disclosure In body embodiment, the clean water spray unit be can be set in the chimney 5.Further, the clean water liquid storage The shape of tank 13 can be the tapered shaped can that diameter gradually decreasees from top to bottom, and the inner wall of upper end tank mouth and the chimney 5 seals Connection, in this way it can be ensured that it is real in turn to fall into clean water fluid reservoir 13 after clean water and smoke contacts that cleaning (operating) water nozzle 8 sprays Now recycle.In another specific embodiment of the disclosure, the clean water spray unit can be set to be washed in described It washs in tower tower body 3, at this moment, the tapered shaped can that the clean water fluid reservoir 13 or diameter gradually decrease from top to bottom, and on The inner wall of tank mouth and the scrubbing tower tower body 3 is held to be tightly connected.Both the above embodiment can be individually present, can also be mutual In conjunction with.Generally, the structure in chimney 5 is more simple compared in scrubbing tower tower body 3, therefore, engineered easy to implement in order to make, It is preferred that clean water spray unit is arranged in the chimney 5, as shown in Figure 1;In addition, the clean water spray unit is set to In the chimney 5, flue gas cleaned water spray before it will go out tower can be made, remove smoke trailing phenomenon to the greatest extent, solves Blue smoke and plume subsidence problems, and the operating flexibility of scrubbing tower and upstream device is not influenced, while being additionally aided and being slowed down equipment corruption Erosion.
According to the disclosure, the quantity of the cleaning (operating) water nozzle 8 of each clean water spray unit can be 1~12 It is a, preferably 4~8.When it is described cleaning (operating) water nozzle 8 quantity more than one when, the cleaning (operating) water nozzle 8 can circumferentially with/ Or radial direction is equally spaced, to improve spraying effect, wherein the circumferential direction and radial direction here and below is with scrubbing tower And/or defined on the basis of the periphery of chimney.For example, it is 4 and circumferentially arranged one kind that Fig. 2, which is clean water nozzle quantity, The schematic diagram of embodiment.When the quantity of the clean water spray unit is the clear of more than one and each clean water spray unit When the quantity more than one of clean (operating) water nozzle, the cleaning (operating) water nozzle of two neighboring clean water spray unit can be circumferential and/or radial Upper position is arranged across, to further increase spraying effect, for example, multiple cleaning (operating) water nozzles of each cleaning water unit can be with It is arranged radially evenly, that is, is formed as a row, two rows of cleaning (operating) water nozzles of two neighboring clean water spray unit can be in 90 ° Or other angles be arranged.The shape of the cleaning (operating) water nozzle 8 can include but is not limited to common spiral spray without particular/special requirement Mouth, fan nozzle, nozzle ring and various hole shapes the pressure atomized fog jet that shower water atomization may be implemented.It is described clear The material of clean (operating) water nozzle can include but is not limited to that polytetrafluoro, stainless steel etc. are various to commonly use corrosion-resistant material also without particular/special requirement.
According to the disclosure, the clean water is the liquid without detergent, and further, the salt content of the clean water is not Higher than the salt content for the flue gas condensing water collected by the exhanst gas outlet 6.Specifically, the clean water can be for selected from fresh At least one of water, middle water and waste water Jing Guo desalting processing.In addition, according to actual needs, the clean water can also contain There is additive, as long as the salt content increase of absorbing liquid used in absorbing liquid spray unit will not be made by meeting the additive, The type of the additive does not have special limitation, such as can include but is not limited to defoaming agent etc..
Gas-liquid contact reinforcing elements 14 are arranged below the cleaning (operating) water nozzle 8 can effectively strengthen clean water spray unit Gas-liquid contact, reduce water consumption, thus more effectively remove smoke hangover and plume sinkage.The gas-liquid contact is strengthened Component 14 is the Common Component that can be realized above-mentioned purpose.In a kind of specific embodiment of the disclosure, the gas-liquid contact Reinforcing elements 14 can be filler.The filler can be set in system using method well-known to those skilled in the art, By the way that packing section is arranged, it is capable of increasing the contact surface of flue gas and clean water, makes its mutually strong mixing, to reach as described above Purpose.The filler for example can be for selected from Pall ring filler, ladder ring packing, corrugated plate packing and structured packing such as honeycomb At least one of shape filler, to reduce pressure drop, more preferably regular honeycomb padding, material can include but is not limited to gather The various common corrosion-resistant materials such as tetrafluoro, stainless steel.In the above-described embodiment, the height and voidage of the filler are without spy It is different to require.In the other embodiments of the disclosure, the gas-liquid contact reinforcing elements 14 or column plate etc..
The flue gas washing system of the disclosure can also include quenching unit, for carrying out fast cooling to flue gas, along flue gas Flow direction is set to before absorbing liquid spray unit, such as can be set in scrubbing tower or outside scrubbing tower, and structure can be with To be common in existing wet flue gas washing system, the disclosure does not have special limitation and repeats no more.
According to the disclosure, the absorbing liquid spray unit can be structure common in existing wet flue gas washing system, The disclosure does not have special limitation to it.Only the specific embodiment of absorbing liquid spray unit property for example is retouched below State, those skilled in the art it should be understood that how the specific structure of absorbing liquid spray unit has no effect on the disclosure It realizes.
For example, the absorbing liquid spray unit can be multiple.The absorbing liquid spray unit may include the first absorption Liquid spray unit and the second absorbing liquid spray unit, the first absorbing liquid spray unit and the second absorbing liquid spray unit are along cigarette The setting of flow of air direction interval, i.e., flue gas first passes through the first absorbing liquid spray unit and sprays using second absorbing liquid Unit.The first absorbing liquid spray unit may include the first absorption nozzle for liquid 15 and be located under the first absorption nozzle for liquid First absorbing liquid fluid reservoir 16 of side, described first absorb nozzle for liquid 15 and the first absorbing liquid fluid reservoir 16 respectively by pipeline with First absorbing liquid circulating pump 11 is connected, and absorbing liquid used in the first absorbing liquid spray unit can be in the work of the first absorbing liquid circulating pump With lower recycling.At this moment, the smoke inlet 2 can be provided with the first absorption nozzle for liquid 15 and the first absorbing liquid liquid storage On 3 side wall of scrubbing tower tower body between tank 16, in this way, flue gas encounters upwards after entering scrubbing tower tower body 3 by the smoke inlet 2 First absorbs the absorbing liquid that nozzle for liquid 15 sprays, and starts the spray washing for carrying out the first absorbing liquid spray unit.Described first inhales The efflux wastewater pipeline 12 for efflux wastewater can also be connected with by receiving liquid circulating pump 11.
Further, the first absorbing liquid fluid reservoir 16 can be the tapered shaped can that diameter gradually decreasees from top to bottom, and The inner wall of upper end tank mouth and the scrubbing tower tower body 3 is tightly connected, so that it is guaranteed that first absorbs the absorbing liquid that nozzle for liquid 15 sprays It is recycled with falling into the first absorbing liquid fluid reservoir 16 after smoke contacts and then realizing.
Further, the described first quantity for absorbing nozzle for liquid 15 can be one or more.When first absorbing liquid When the quantity of nozzle 15 is multiple, the first absorption nozzle for liquid 15 can circumferentially and/or be evenly radially arranged, to improve Spraying effect.Described first absorbs the shape of nozzle for liquid 15 without particular/special requirement, can include but is not limited to common spiral nozzle, The pressure atomized fog jet that shower water atomization may be implemented of fan nozzle, nozzle ring and various hole shapes.The cleaning The material of (operating) water nozzle can include but is not limited to that polytetrafluoro, stainless steel etc. are various to commonly use corrosion-resistant material also without particular/special requirement.
Further, the second absorbing liquid spray unit may include the second absorption nozzle for liquid 10, be located at described second Absorb the second absorbing liquid fluid reservoir 17 of 10 lower section of nozzle for liquid and axially through the more of the second absorbing liquid fluid reservoir 17 A second fluid reservoir flue 18.The second fluid reservoir flue 18 is for accommodating flue gas upwardly through the second absorbing liquid Fluid reservoir 17, shape and size are not particularly limited, and can be Venturi tube similar with structure of column scrubber or other structures.Cigarette Gas meets the absorbing liquid of the second absorption nozzle for liquid 10 ejection upwards, to carry out the spray washing of the second absorbing liquid spray unit.It is described Second absorption nozzle for liquid 10 and the second absorbing liquid fluid reservoir 17 are connected by pipeline with the second absorbing liquid circulating pump 9 respectively, and second Absorbing liquid used in absorbing liquid spray unit can be recycled under the action of the second absorbing liquid circulating pump.
Further, the quantity of the second absorbing liquid spray unit can be one or more.Second absorbing liquid Fluid reservoir 17 can have the second fluid reservoir overflow port, and the second fluid reservoir overflow port, which is connected with, extends to the adjacent storage in lower section Absorbing liquid overflow line 20 in flow container.When the quantity of the second absorbing liquid spray unit is one, the second absorbing liquid fluid reservoir 17 the second fluid reservoir overflow port is connected with the absorbing liquid overflow line 20 for extending to the first absorbing liquid fluid reservoir 16;When the second suction When the quantity of receipts liquid spray unit is multiple, the second fluid reservoir overflow port connection for the second absorbing liquid fluid reservoir 17 being located above There are the absorbing liquid overflow line 20 for extending to the second adjacent absorbing liquid fluid reservoir 17 of lower section, the second absorbing liquid liquid storage of bottom Second fluid reservoir overflow port of tank 17 is connected with the absorbing liquid overflow line 20 for extending to the first absorbing liquid fluid reservoir 16;And At this moment, clean water overflow line 21 can be extended to the second absorbing liquid fluid reservoir 17 of the top by clean water fluid reservoir overflow port In;In this way, absorbing liquid can lead to when the liquid level in the second absorbing liquid fluid reservoir 17 is excessively high and reaches the second fluid reservoir overflow port It crosses absorbing liquid overflow line 20 to enter in the fluid reservoir of lower section, recycles the absorbing liquid in whole system rationally.Described The position that opens up of two fluid reservoir overflow ports can according to need and be designed, but need to make the second fluid reservoir flue 18 Upper end opening is higher than the second fluid reservoir overflow port, i.e. exhanst gas outlet position is higher than the liquid in the second absorbing liquid fluid reservoir 17 Position avoids flue gas from entering in the second absorbing liquid fluid reservoir 17.
Further, the second absorbing liquid fluid reservoir 17 can be the tapered shaped can that diameter gradually decreasees from top to bottom, and The inner wall of upper end tank mouth and the scrubbing tower tower body 3 is tightly connected, in this way it can be ensured that second absorbs the suction that nozzle for liquid 10 sprays The second absorbing liquid fluid reservoir 17 is fallen into after receiving liquid and smoke contacts and then realization recycles.
Further, the quantity of the second absorption nozzle for liquid 10 of each second absorbing liquid spray unit can be It is multiple, and circumferentially and/or be evenly radially arranged, to improve spraying effect.Further, the second fluid reservoir fume pipe It is consistent that the quantity in road 18 can absorb the quantity of nozzle for liquid 10 with described second, and is located at second absorbing liquid correspondingly The lower section of nozzle 10 is absorbed in this way, the flue gas overflowed by the second fluid reservoir flue 18 can directly be encountered by top second The absorbing liquid that nozzle for liquid 10 sprays most optimally realizes the washing absorption effect of absorbing liquid.Described second absorbs nozzle for liquid 10 Shape can include but is not limited to common spiral nozzle, fan nozzle, nozzle ring and various aperture shapes without particular/special requirement The pressure atomized fog jet that shower water atomization may be implemented of shape.The material of the cleaning (operating) water nozzle can wrap also without particular/special requirement Include but be not limited to that polytetrafluoro, stainless steel etc. are various commonly uses corrosion-resistant material.
According to the disclosure, absorbing liquid used in the absorbing liquid spray unit can be common in wet flue gas washing system , the disclosure does not have special limitation.For example, absorbing liquid used in the absorbing liquid spray unit can be for selected from sodium hydroxide At least one of solution, potassium hydroxide solution, sodium carbonate liquor and sodium bicarbonate solution.
According to the disclosure, can be offered on the side wall of the scrubbing tower tower body 3 for supplementing cleaning into the system The replenisher entrance Isosorbide-5-Nitrae of water and/or absorbing liquid.The replenisher entrance Isosorbide-5-Nitrae opens up position on the side wall of scrubbing tower tower body 3 It can be designed according to the structure of absorbing liquid spray unit, for example, in embodiment listed above, the replenisher entrance Open up position of the Isosorbide-5-Nitrae on the side wall of scrubbing tower 1 can be for close to the first absorbing liquid fluid reservoir 16 and/or the second absorbing liquid The upper end tank mouth of fluid reservoir 17.When the upper end tank mouth of the first absorbing liquid fluid reservoir 16 and/or the second absorbing liquid fluid reservoir 17 When being tightly connected with the inner wall of the scrubbing tower tower body 3, the replenisher entrance Isosorbide-5-Nitrae can be provided with the junction.First inhales Receive liquid fluid reservoir 16, the second absorbing liquid fluid reservoir 17 it is also optional exterior liquid mouth is respectively set, for absorbing liquid therein to be discharged, It adjusts absorbing liquid such as liquid level to facilitate, form, concentration, pH value etc..
According to the disclosure, the structure of the chimney 5 can be the common structure in existing wet flue gas washing system, this public affairs Open not special limitation.For example, the chimney 5 can be the tubular that upper and lower ends are open respectively, at this moment, flue gas can be direct Chimney 5 is entered by scrubbing tower tower body 3.In addition, the tubular of the chimney 5 or upper end opening, lower end closed, and close The periphery at cylinder bottom has flue gas to collect bent passage, and flue gas can first rise to the passway, and then downlink enters back into chimney 5, with reality The separation of existing flue gas and drop.In such cases, the clean water overflow line 21 can be with the bottom end of chimney 5 described in hermetically passing And it extends in underlying absorbent liquid fluid reservoir.
The flue gas washing system of the disclosure can be used for various industrial process, including power generation, petrochemical industry, inorganic chemical industry Deng the pollutant in handled flue gas can include but is not limited to SOx、NOx、NH3、CO、CO2、Cl2, HCl etc..Particularly, originally Disclosed system is particularly suitable for the wet scrubbing processing of catalytic cracking unit regenerated flue gas, the technique of the catalytic cracking unit Without specifically limited, regenerative operation mode can be regeneration or incomplete regen-eration completely for type, process scale, catalyst etc..
The washing side in specific embodiment using the system of the disclosure to flue gas is simply introduced below in conjunction with attached drawing 1-2 Method with the system for further illustrating the disclosure, but does not constitute the limitation to the disclosure.
By taking flue gas washing system as shown in Figure 1 is for the wet scrubbing processing of catalytic cracking unit regenerated flue gas as an example. With SO2It counts, SO in heat boiler outlet flue gasxContent can be in 50-10000mg/m3, preferably in 100-5000mg/m3;Solid Particle content can be in 10-1000mg/m3, preferably in 30-500mg/m3.Temperature into the regenerated flue gas of system can be 50-500 DEG C, preferably at 100-300 DEG C.The salt content for the efflux wastewater collected by efflux wastewater pipeline 12 is in 0.1-10 weight % is measured, preferably in 2-8 weight %.The salt content for the flue gas condensing water collected by exhanst gas outlet 6 can be 0.01-0.5 weight %.
Flue gas enters system by smoke inlet 2, successively sprays upwards through the first absorbing liquid spray unit and the second absorbing liquid The pH of absorbing liquid used in the spray washing of unit, the first absorbing liquid spray unit and the second absorbing liquid spray unit can be in 5- 10, preferably in 6.5-9.The quantity of second absorbing liquid spray unit is 1.First absorbing liquid fluid reservoir 16 and the storage of the second absorbing liquid Flow container 17 is respectively the tapered shaped can that diameter gradually decreasees from top to bottom, and the inner wall of upper end tank mouth and scrubbing tower tower body 3 seals and connects It connects.Second fluid reservoir overflow port of the second absorbing liquid fluid reservoir 17 is connected with the absorption extended in the first absorbing liquid fluid reservoir 16 Liquid overflow line 20.The upper end opening of second fluid reservoir flue 18 is higher than the second fluid reservoir overflow port.
Flue gas by continuing to rise after the spray washing of the first absorbing liquid spray unit and the second absorbing liquid spray unit, into Enter chimney 5.The quantity of clean water spray unit is 1.It cleans (operating) water nozzle 8 and uses polytetrafluoro material spiral nozzle, quantity 4 Branch is circumferentially 90 ° of arrangements by angle, as shown in Figure 2.It is high to clean filling bed between (operating) water nozzle 8 and clean water fluid reservoir 13 Degree is the filler of 0.1-1m, is preferably highly the honeycomb structured packing of 0.2-0.5m.Clean water fluid reservoir 13 is diameter by upper The tapered shaped being gradually reduced under, and the inner wall of upper end tank mouth and chimney 5 is tightly connected.That collects in clean water fluid reservoir 13 is clear Clean water can be entered in the second absorbing liquid fluid reservoir 17 by clean water fluid reservoir overflow port.Clean water fluid reservoir flue 19 Upper end opening is higher than clean water fluid reservoir overflow port.Clean water used is fresh process water, and salt content is not higher than 0.01 weight %.
The pump discharge pressure for cleaning (operating) water nozzle 8 can be 0.1-10MPa, preferably 0.1-1.0MPa.It is supplied in clean water In the case that 7 conveying clean water circulation of pump is for spraying, the spray flow of clean water can be much higher than the magnitude of recruitment of clean water, practical to spray Leaching amount depends on the efficiency of clean water transfer pump 7 and cleans the quantity and bore size of (operating) water nozzle 8.Clean water magnitude of recruitment, which is included in, is In moisturizing total amount of uniting, and convert according to evaporation capacity and outer displacement rate of water make-up (the moisturizing total amount of system of other replenisher entrances Equal to the sum of evaporation capacity and efflux wastewater amount).In the limiting case, system water supplement can be entered by cleaning (operating) water nozzle 8, total Water consumption is not significantly increased, or even flue gas hangover and subsidence problems are solved in the case where decreasing.For example, fresh clean water The ratio of magnitude of recruitment and flue gas is typically not greater than 0.15kg/Nm3, preferably 0.001-0.05kg/Nm3.With the cleaning after smoke contacts Water recycles after can collecting, and to reuse and increase spray flow, the ratio of the spray flow of clean water and flue gas can be with are as follows: 0.001-0.5kg water/Nm3Flue gas, preferably 0.01-0.2kg water/Nm3Flue gas, wherein Nm3Refer to the gas volume under the status of criterion.
Finally, the flue gas after washing, by 6 discharge system of exhanst gas outlet, observation has no that flue gas hangover, blue smoke and plume sink Phenomena such as.
The preferred embodiment of the disclosure is described in detail in conjunction with attached drawing above, still, the disclosure is not limited to above-mentioned reality The detail in mode is applied, in the range of the technology design of the disclosure, a variety of letters can be carried out to the technical solution of the disclosure Monotropic type, these simple variants belong to the protection scope of the disclosure.
It is further to note that specific technical features described in the above specific embodiments, in not lance In the case where shield, can be combined in any appropriate way, in order to avoid unnecessary repetition, the disclosure to it is various can No further explanation will be given for the combination of energy.
In addition, any combination can also be carried out between a variety of different embodiments of the disclosure, as long as it is without prejudice to originally Disclosed thought equally should be considered as disclosure disclosure of that.

Claims (9)

1. a kind of flue gas washing system, which is characterized in that the system includes: scrubbing tower tower body (3) and the scrubbing tower tower body (3) chimney (5) that is in fluid communication is set to the smoke inlet (2) of scrubbing tower tower body (3) lower part and is set to described Exhanst gas outlet (6) at the top of chimney (5), the scrubbing tower tower body (3) is interior to be provided with absorbing liquid spray unit, the absorbing liquid spray Clean water spray unit is provided with above leaching unit;
The clean water spray unit includes cleaning (operating) water nozzle (8), is located at the clean water liquid storage cleaned below (operating) water nozzle (8) Tank (13) and multiple clean water fluid reservoir flues (19) axially through the clean water fluid reservoir (13) are described It is provided with gas-liquid contact reinforcing elements (14) between cleaning (operating) water nozzle (8) and clean water fluid reservoir (13), the cleaning (operating) water nozzle (8) it is connected respectively by pipeline with clean water transfer pump (7) with clean water fluid reservoir (13).
2. system according to claim 1, which is characterized in that the clean water fluid reservoir (13) has clean water fluid reservoir Overflow port, the clean water fluid reservoir overflow port are connected with the clean water overflow line for extending to the absorbing liquid spray unit (21)。
3. system according to claim 1, which is characterized in that the quantity of the clean water spray unit is one or more It is a.
4. system according to claim 3, which is characterized in that the clean water spray unit is set to the chimney (5) Interior, the upper end tank mouth of the clean water fluid reservoir (13) and the inner wall of the chimney (5) are tightly connected;And/or
The clean water spray unit is set in the scrubbing tower tower body (3), the upper end tank of the clean water fluid reservoir (13) Mouth and the inner wall of the scrubbing tower tower body (3) are tightly connected.
5. system according to claim 1, which is characterized in that the quantity of cleaning (operating) water nozzle (8) is 1~12;When When the quantity more than one of cleaning (operating) water nozzle (8), the cleaning (operating) water nozzle (8) is circumferentially and/or radial direction is equally spaced set It sets.
6. system according to claim 1, which is characterized in that the cleaning (operating) water nozzle (8) is selected from spiral nozzle, sector At least one of nozzle and nozzle ring.
7. system according to claim 1, which is characterized in that the gas-liquid contact reinforcing elements (14) be filler and/or Column plate;The filler is selected from least one of Pall ring filler, ladder ring packing, corrugated plate packing and structured packing.
8. system according to claim 1, which is characterized in that the salt of clean water used in the clean water spray unit contains Salt content of the amount not higher than the flue gas condensing water collected by the exhanst gas outlet (6).
9. system according to claim 8, which is characterized in that the clean water is selected from fresh water, middle water and by de- At least one of waste water of salt treatment.
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CN201820761233.7U Active CN208553709U (en) 2017-11-07 2018-05-21 Flue gas washing system
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JPH0722675B2 (en) * 1986-03-26 1995-03-15 バブコツク日立株式会社 Wet flue gas desulfurization equipment
CN201871320U (en) * 2010-11-12 2011-06-22 中国石油化工股份有限公司 Catalytic cracking regeneration flue gas desulfurization dedusting device
CN103059923B (en) * 2011-10-18 2015-09-23 中国石油化工股份有限公司 A kind of Light hydrocarbon oil catalytic conversion method with heat exchange
CN104258668B (en) * 2014-10-13 2016-04-06 北京国电龙源环保工程有限公司 A kind of washing degree of depth dust arrester
CN104874255A (en) * 2015-06-08 2015-09-02 北京香源溪环保科技有限公司 Demisting system with dedusting, demisting and water recovery functions

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