CN208612163U - A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner - Google Patents

A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner Download PDF

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Publication number
CN208612163U
CN208612163U CN201821254154.3U CN201821254154U CN208612163U CN 208612163 U CN208612163 U CN 208612163U CN 201821254154 U CN201821254154 U CN 201821254154U CN 208612163 U CN208612163 U CN 208612163U
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Prior art keywords
phosphoric acid
sawdust
absorption tower
fixed bed
exhaust gas
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CN201821254154.3U
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荀波
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NANJING ZHENGSEN ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
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NANJING ZHENGSEN ENVIRONMENTAL PROTECTION TECHNOLOGY CO LTD
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Abstract

The utility model discloses a kind of activated carbon of phosphoric acid method to activate exhaust gas cleaner, including fixed bed absorption tower, spray column and cyclone separator, the fixed bed absorb the bottom of the tower is equipped with active carbon and activates tail gas air inlet, fixed bed absorption tower top gas outlet is connected to the lower end of spray column by gas-guide tube, and spray column top is connected to cyclone separator;Sawdust feed inlet is equipped at the top of the fixed bed absorption tower, bottom is correspondingly provided with charcoal discharge gate, and active carbon activation tail gas enters in fixed bed absorption tower with sawdust antikinesis, is discharged so that the phosphoric acid drop in tail gas is adsorbed in sawdust.The exhaust gas cleaner absorbs phosphoric acid, alkali spray, whirlwind using sawdust and removes water three-level unit, flue gas containing highly concentrated phosphoric acid first passes through the absorption tower of filling sawdust, 99% phosphoric acid is absorbed by sawdust, remaining phosphoric acid is collected by alkaline spray liquid, flue gas removes steam through cyclonic separation again, and last clean gas cleans discharge.

Description

A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner
Technical field
The utility model relates to a kind of exhaust purifier, specifically a kind of activated carbon of phosphoric acid method activates exhaust gas cleaner.
Background technique
Active carbon is the most commonly used material of current application field, be related to the energy, environmental protection, military project, space flight, food, medicine, Chemical industry energy national economy various industries.China has been the first big producer of World Activated Carbon and big export country, Activated Carbon Production side Method mainly has physical method and chemical activation method.Chemical activation method mainly with phosphoric acid, zinc chloride, potassium hydroxide etc. for activator, Middle phosphoric acid activation method activity carbon yield accounts for 70% or more.Phosphoric acid forms gaseous state phosphoric acid at high temperature and is discharged with tail gas, industrialization Tail gas phosphorus acid content is more than 3000ppm in production, if not being subject to Recovery Purifying, being directly discharged into atmosphere will cause serious atmospheric dirt Dye.
Phosphoric acid method activation needs to be passed through a large amount of hot fume in activation furnace, with high temperature ring needed for maintaining reaction process Therefore border activates tens of thousands of per hour cubes of exhausted air quantity of tail gas, the devices such as conventional water spray, Bag filter and electric demisting compared with Hardly possible realizes so huge treating capacity, and operating cost is high.Meanwhile a large amount of phosphoric acid waste water that water spray and electric demisting generate are still It need to be further processed, otherwise will generate secondary liquid phase pollution.As the requirement of atmosphere environmental protection increasingly improves, it is necessary to by phosphorus in flue gas Acid is removed using the method for high efficiency, low cost, reaches the requirement of cleaning discharge, while phosphoric acid circulation utilizes, and does not generate secondary dirt Dye realizes that phosphoric acid method activates low consumption clean manufacturing mode.
Traditional purification method is the methods of washing, bag-type dust, electric demisting.Since activation exhaust gas volumn is very big, phosphoric acid Concentration is high, and washing, electric demisting can generate a large amount of highly concentrated phosphoric acid waste water, causes secondary pollution.Actual motion energy consumption is high, and equipment is thrown Money is big, and operating cost is high, promotes and applies difficult.
Utility model content
Technical problem to be solved in the utility model is in view of the deficiencies of the prior art, to provide a kind of suitable for exhaust gas volumn Greatly, phosphoric acid concentration is high, filter effect is good, the simple purification device of structure.
In order to solve the above-mentioned technical problem, the utility model discloses a kind of activated carbon of phosphoric acid method activation tail gas clean-up dresses It sets, including fixed bed absorption tower, spray column and cyclone separator, the fixed bed absorb the bottom of the tower is equipped with active carbon and activates tail gas Air inlet, fixed bed absorption tower top gas outlet are connected to the lower end of spray column, spray column top and cyclonic separation by gas-guide tube Device connection;Sawdust feed inlet is equipped at the top of the fixed bed absorption tower, bottom is correspondingly provided with charcoal discharge gate, and active carbon activates tail Gas enters in fixed bed absorption tower with sawdust antikinesis, is discharged so that the phosphoric acid drop in tail gas is adsorbed in sawdust.
Further, fixed bed absorption tower lower end is additionally provided with screw conveyor, and bottom is adsorbed with phosphoric acid drop Sawdust passes through charcoal discharge gate in time and is discharged.
Further, the sawdust for being adsorbed with phosphoric acid drop is sent into phosphoric acid method life by transporter by the charcoal discharge gate It produces in activated-carbon device, the sawdust for having adsorbed phosphoric acid can be used as the raw materials for production of active carbon, realize recycling for phosphoric acid;Its In, producing active carbon by phosphoric acid method device is this field Typical reactive charcoal process units, not as the difference of technical scheme Technical characteristic.
Preferably, using alkaline water spray in the spray column.
Further, it is additionally provided with circulation line in the spray column, sprays the alkaline water to get off and returns spray through circulation line Head is recycled.
The cyclone separator bottom, which is equipped at the top of discharge outlet, is equipped with gas discharge outlet, is removed in tail gas by cyclonic separation Moisture, and be up to cleaning emission request gas discharged.
The utility model has the advantages that
1, the utility model exhaust gas cleaner absorbs phosphoric acid, alkali spray, whirlwind water removal three-level unit using sawdust, containing height The flue gas of concentrated phosphoric acid first passes through the absorption tower of filling sawdust, and 99% phosphoric acid is absorbed by sawdust, and remaining phosphoric acid is sprayed by alkalinity Liquid is collected, and flue gas removes steam through cyclonic separation again, and last clean gas cleans discharge;
2, the utility model exhaust gas cleaner sawdust after absorbing saturation phosphoric acid, is passed through by entering at the top of absorption tower by bottom Auger discharging, the sawdust for having adsorbed phosphoric acid can be used as activation raw material, and activation furnace activation production active carbon is sent into after with phosphoric acid, real Phosphoric acid purification is showed and has recycled;
3, the utility model exhaust gas cleaner spray column can be realized the circulation of alkaline water using alkaline water spray is recycled It utilizes, can reduce operating cost, green economy.
Detailed description of the invention
The utility model is done with reference to the accompanying drawings and detailed description and is further illustrated, the utility model Above-mentioned and/or otherwise advantage will become apparent.
Fig. 1 is the overall structure diagram of activated carbon of phosphoric acid method activation exhaust gas cleaner.
Specific embodiment
According to following embodiments, the utility model may be better understood.
Structure depicted in Figure of description, ratio, size etc., only to cooperate the revealed content of specification, with Understand for those skilled in the art and read, is not intended to limit the utility model enforceable qualifications, therefore does not have skill Essential meaning in art, the modification of any structure, the change of proportionate relationship or the adjustment of size are not influencing the utility model institute Under the effect of capable of generating and the purpose that can reach, it should all still fall in what the revealed technology contents of the utility model can be covered In range.Meanwhile cited such as "upper", "lower", "front", "rear", " centre " term in this specification, it is merely convenient to chat That states is illustrated, rather than to limit the enforceable range of the utility model, relativeness is altered or modified, without substantive change Under more technology contents, when being also considered as the enforceable scope of the utility model.
As shown in Figure 1, the exhaust gas cleaner includes fixed bed absorption tower 1, spray column 2 and cyclone separator 3, fixed bed 1 bottom of absorption tower is equipped with active carbon and activates tail gas air inlet 11, and 1 top gas outlet 12 of fixed bed absorption tower is connected to by gas-guide tube The lower end of spray column 2,2 top of spray column are connected to cyclone separator 3;Sawdust feed inlet 13 is equipped at the top of fixed bed absorption tower 1, Bottom is correspondingly provided with charcoal discharge gate 14, and active carbon activation tail gas enters in fixed bed absorption tower 1 and sawdust antikinesis, thus Phosphoric acid drop in tail gas is adsorbed in sawdust and is discharged, 1 lower end of fixed bed absorption tower is additionally provided with screw conveyor, and bottom is inhaled Sawdust with phosphoric acid drop passes through the discharge of charcoal discharge gate 14 in time, and charcoal discharge gate 14 will be adsorbed with phosphorus by transporter 15 The sawdust of acid droplet is sent into producing active carbon by phosphoric acid method device as activation raw material, is realized phosphoric acid purification and is recycled.
Spray head 21 is equipped at the top of spray column 2, inside is additionally provided with circulation line, sprays the alkaline water to get off through circulation line Spray head 21 is returned to be recycled.
3 bottom of cyclone separator, which is equipped at the top of discharge outlet 31, is equipped with gas discharge outlet 32, removes tail gas by cyclonic separation In moisture, and be up to cleaning emission request gas discharged.
The activated carbon of phosphoric acid method activate exhaust gas cleaner can large scale processing gas-solid reaction fixed bed device, tail gas and Sawdust antikinesis, fixed bed interior air-flow path is short, and unit time treating capacity is big, and the sawdust amount in fixed bed is big, can relatively satisfy With absorb the phosphoric acid drop in tail gas, residual impurity is discharged through spray and whirlwind again in tail gas, reaches cleaning discharge.Whole system Equipment is few, and treating capacity is big, good purification, and the waste water of generation is few, and low energy consumption, and operating cost is low, is suitble to industrialization practical application.
The utility model provides the thinking and method of a kind of activated carbon of phosphoric acid method activation exhaust gas cleaner, specific implementation There are many method and approach of the technical solution, and the above is only the preferred embodiment of the utility model, it is noted that for For those skilled in the art, without departing from the principle of this utility model, several change can also be made Into and retouching, these improvements and modifications also should be regarded as the protection scope of the utility model.Each composition being not known in the present embodiment The available prior art in part is realized.

Claims (6)

1. a kind of activated carbon of phosphoric acid method activates exhaust gas cleaner, which is characterized in that including fixed bed absorption tower (1), spray column (2) and cyclone separator (3), fixed bed absorption tower (1) bottom are equipped with active carbon activation tail gas air inlet (11), fixed bed Absorption tower (1) top gas outlet (12) is connected to the lower end of spray column (2), spray column (2) top and cyclonic separation by gas-guide tube Device (3) connection;Sawdust feed inlet (13) are equipped at the top of the fixed bed absorption tower (1), bottom is correspondingly provided with charcoal discharge gate (14), active carbon activation tail gas enter in fixed bed absorption tower (1) with sawdust antikinesis, thus by the phosphoric acid drop in tail gas It is adsorbed in sawdust and is discharged.
2. a kind of activated carbon of phosphoric acid method according to claim 1 activates exhaust gas cleaner, which is characterized in that the fixation Bed absorption tower (1) lower end is additionally provided with screw conveyor, and the sawdust that bottom is adsorbed with phosphoric acid drop is passed through charcoal discharge gate in time (14) it is discharged.
3. a kind of activated carbon of phosphoric acid method according to claim 2 activates exhaust gas cleaner, which is characterized in that the charcoal The sawdust for being adsorbed with phosphoric acid drop is sent into producing active carbon by phosphoric acid method device by discharge gate (14) by transporter (15).
4. a kind of activated carbon of phosphoric acid method according to claim 1 activates exhaust gas cleaner, which is characterized in that the spray Using alkaline water spray in tower (2).
5. a kind of activated carbon of phosphoric acid method according to claim 4 activates exhaust gas cleaner, which is characterized in that the spray It is additionally provided with circulation line in tower (2), the alkaline water to get off is sprayed and returns spray head (21) recycling through circulation line.
6. a kind of activated carbon of phosphoric acid method according to claim 4 activates exhaust gas cleaner, which is characterized in that the whirlwind Separator (3) bottom is equipped at the top of discharge outlet (31) and is equipped with gas discharge outlet (32), removes the water in tail gas by cyclonic separation Point, and the gas for being up to cleaning emission request is discharged.
CN201821254154.3U 2018-08-03 2018-08-03 A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner Active CN208612163U (en)

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CN201821254154.3U CN208612163U (en) 2018-08-03 2018-08-03 A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner

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Application Number Priority Date Filing Date Title
CN201821254154.3U CN208612163U (en) 2018-08-03 2018-08-03 A kind of activated carbon of phosphoric acid method activation exhaust gas cleaner

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111425280A (en) * 2020-01-08 2020-07-17 江西天美生物科技有限公司 Activated carbon phosphoric acid activated tail gas purification device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111425280A (en) * 2020-01-08 2020-07-17 江西天美生物科技有限公司 Activated carbon phosphoric acid activated tail gas purification device

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