CN208506293U - A kind of stiffened plated film fog-proof lens - Google Patents
A kind of stiffened plated film fog-proof lens Download PDFInfo
- Publication number
- CN208506293U CN208506293U CN201820457057.8U CN201820457057U CN208506293U CN 208506293 U CN208506293 U CN 208506293U CN 201820457057 U CN201820457057 U CN 201820457057U CN 208506293 U CN208506293 U CN 208506293U
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- stiffened
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- 238000000576 coating method Methods 0.000 claims abstract description 35
- 239000011248 coating agent Substances 0.000 claims abstract description 34
- 230000007797 corrosion Effects 0.000 claims abstract description 24
- 238000005260 corrosion Methods 0.000 claims abstract description 24
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 238000001771 vacuum deposition Methods 0.000 claims abstract description 20
- 238000005728 strengthening Methods 0.000 claims description 8
- 230000000694 effects Effects 0.000 abstract description 9
- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- 230000035699 permeability Effects 0.000 abstract description 3
- 238000002360 preparation method Methods 0.000 abstract description 3
- 238000002310 reflectometry Methods 0.000 abstract description 3
- 230000010148 water-pollination Effects 0.000 abstract description 3
- 239000003595 mist Substances 0.000 abstract description 2
- 238000002834 transmittance Methods 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002086 nanomaterial Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- 241000446313 Lamella Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 229930013930 alkaloid Natural products 0.000 description 1
- -1 alkaloid compound Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Landscapes
- Surface Treatment Of Optical Elements (AREA)
- Eyeglasses (AREA)
Abstract
The utility model discloses a kind of stiffened plated film fog-proof lens and preparation method thereof.It includes substrate layer and the upper vacuum coating anti-fog layer being arranged in above substrate layer and the upper vacuum coating anti-fog layer being arranged in below substrate layer, stiffened coating is provided between substrate layer and upper anti-fog layer, lower stiffened coating is provided between substrate layer and lower anti-fog layer, upper stiffened coating includes upper corrosion cross-linked layer and upper corrosion cross-linked layer and upper anti-fog layer is arranged alternately the upper stiffened strengthened coat to be formed, and lower stiffened coating includes that lower corrosion cross-linked layer and lower corrosion cross-linked layer and lower anti-fog layer are arranged alternately the lower stiffened strengthened coat to be formed.The advantage is that: surface is made to generate unique physicochemical characteristics, reach hydrophily function film and reduces reflectivity, improve the permeability of eyeglass, it is therefore prevented that lens surface mist formation, to achieve the effect that the visibility for not influencing mirror image or increase the light transmittance of eyeglass.
Description
Technical field
The present invention relates to a kind of fog-proof lens, specifically a kind of stiffened plated film fog-proof lens.
Background technique
Original resin lens are particularly easy to generate fogging in the environment for have the temperature difference, and spectacle lens, which haze, to be referred in temperature difference environment
Water vapour in middle air reaches saturation state, condenses to form small droplet formation fog in lens surface, these drops one
Aspect is reflected and is scattered to light, is changed the optical property of lens surface, is affected translucency, and the impermeable of eyeglass is caused
Bright phenomenon, still further aspect can also make lens surface is different degrees of to get wet, so as to cause because of moist bring surface corrosion
Thus problem brings inconvenience to life, bring serious harm to traffic safety.
Existing fog-proof lens are typically all that anti-fog coating (immersion type anti-fog coating) and other coatings is used to be tied
The mode of processing is closed, although this mode can reach certain anti-fog effect, its structure and technique exist certain
Defect, therefore, reflecting rate are high, and comfort is excessively poor and durability is also bad.
Summary of the invention
The technical problem to be solved in the present invention is to provide one kind, not only good antifogging effect but also wearability and durability are good, saturating
The stiffened plated film fog-proof lens that light rate is high and reflecting rate is low.
In order to solve the above-mentioned technical problem, stiffened plated film fog-proof lens of the invention, including substrate layer and setting are in base
Upper vacuum coating anti-fog layer above lamella and the lower vacuum coating anti-fog layer being arranged in below substrate layer, substrate layer and upper vacuum
It is provided with stiffened coating between plated film anti-fog layer, lower stiffened coating is provided between substrate layer and lower vacuum coating anti-fog layer,
Upper stiffened coating includes upper corrosion cross-linked layer and upper corrosion cross-linked layer be arranged alternately with upper vacuum coating anti-fog layer to be formed it is upper
Stiffened strengthened coat, lower stiffened coating include that lower corrosion cross-linked layer and lower corrosion cross-linked layer replace with lower vacuum coating anti-fog layer
The lower stiffened strengthened coat formed is set.
The upper stiffened coating includes at least three layers and above corrodes cross-linked layers and at least one layer of upper stiffened strengthening layers, adds under described
Hard conating includes corrosion cross-linked layer and at least one layer of lower stiffened strengthening layer under at least three layers.
The present invention has the advantages that allowing eyeglass to pass through a kind of includes the stiffened coating for corroding cross-linked layer and stiffened strengthening layer
And the specific structure that processing makes lens surface generate anti-fog thin film, reasonable structure design are carried out by high vacuum coating unit
And the high vacuum nano material plated film carried out by the processing of special rational method, so that surface is generated unique physical chemistry special
Property, reach hydrophily function film and reduced reflectivity, improves the permeability of eyeglass, it is therefore prevented that lens surface mist formation,
To achieve the effect that the visibility for not influencing mirror image or increase the light transmittance of eyeglass.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of stiffened plated film fog-proof lens of the present invention.
Specific embodiment
Stiffened plated film fog-proof lens of the invention are described in further detail with reference to the accompanying drawings and detailed description.
As shown, the stiffened plated film fog-proof lens and preparation method thereof of the utility model, including substrate layer 1 and setting
Upper vacuum coating anti-fog layer 2 above substrate layer and the lower vacuum coating anti-fog layer 3 being arranged in below substrate layer, the substrate
Be provided with stiffened coating 4 between layer 1 and upper vacuum coating anti-fog layer 2, the substrate layer and lower vacuum coating it is antifog layer by layer it
Between be provided with lower stiffened coating 5, the upper stiffened coating 4 includes upper corrosion cross-linked layer 6 and upper corrosion cross-linked layer and upper vacuum
Plated film anti-fog layer is arranged alternately the upper stiffened strengthened coat 7 to be formed, the lower stiffened coating 5 include lower corrosion cross-linked layer 8 and
Lower corrosion cross-linked layer and lower vacuum coating anti-fog layer are arranged alternately the lower stiffened strengthened coat 9 to be formed.
Further, described upper stiffened coating 4 includes that at least three layers upper corrosion cross-linked layer and at least one layer of upper stiffened are strong
Change layer, lower stiffened coating 5 includes corrosion cross-linked layer and at least one layer of lower stiffened strengthening layer under at least three layers.
A kind of preparation method of such as above-mentioned stiffened plated film fog-proof lens, comprising the following steps:
A, immersion treatment
Corrosion cross-linked layer in the stiffened coating of substrate carries out processing using crosslinking agent and forms the eyeglass with stiffened coating,
In treatment process, allow substrate circulation immersion 1-5 minutes in the compound of corrosion crosslinking agent；Corruption in described stiffened coating
The crosslinking agent that uses of erosion cross-linked layer for strong alkaloid compound and alkaline compound, wherein strongly alkaline compound has sodium hydroxide
With potassium hydroxide two or more；Alkaline compound has sodium hydroxide, surfactant and softened water in the mixed of 2:5:3 ratio
Mixture.
B, concussion cleaning after-hardening processing
First the eyeglass merging softening ultra-pure deionized water in step A is cleaned with ultrasonic vibration 15-20 minutes；Again will
Eyeglass carries out two-sided stiffened reinforcing by impregnating coating apparatus, and stiffened strengthening layer is with a thickness of 500-3000 nanometers, described stiffened
Strengthening layer is 360 degree and impregnates coating without dead angle, and coating is the polymer containing hardness functional group (such as silica), passes through methanol
Dilution, solid content is between 20-28%；
C, solidification combines
For the curing oven regulated and controled by temperature to eyeglass isolation baking 1-3 hours in step B, temperature was 90-120 DEG C, is reached
To surface firmness, there is very good effect, hardness is also greatly enhanced；D, vacuum coating:
One of eyeglass in step C is placed in high vacuum coating unit down in better purifying space and is at the uniform velocity rotated simultaneously
It vacuumizes, until 4.5*10-5torr vacuum values；It carries out ion gun to bombard lens surface, high-purity argon gas assists 150 seconds；
Electron gun is carried out when vacuum values reach 3.5*10-5torr uniformly to bombard nano material to material melting point volatilization plating
Film (at least three or more nano material includes: silica, zirconium dioxide, titanium dioxide etc.) forms nano thin-film, thickness
Range is at 300-500 nanometers；
It reuses electron gun to volatilize to nanometer anti-fog Coating Materials, between 50-100 nanometers, described is received
Rice anti misting materials are containing hydrophilic and raising film hardness functional group (such as titanium dioxide, silica, hydroxy)；
Color needed for finally confirming plated film film layer stops plated film, allows coating machine to be filled with air filtering and reach and plated film cabin
Outer the same air pressure, automatic storehouse door opening, wherein the antifog plated film film of a face stiffened is formed lens surface, eyeglass is passed through more than
Same mode is by its other one side also vapor deposition forming.
By it was verified that the present invention by the surface of original resin lens substrate by full automatic cleaning equipment to it
Surface carries out ultrasonic wave and corrosion treatment, upsets the molecular structure on surface, is carrying out the leaching of stiffened formula using the hardening liquid modulated
It steeps coating and solidification combines, reach its surface firmness and condition that hardness all has, then list is carried out by high vacuum coating unit
Face (convex surface A concave surface B) gradation plated film, the incorporating parametric of every kind of nano material finally form hydrophilic film simultaneously in lens surface
Reflectivity is reduced, the permeability of eyeglass is improved, to realize anti-fog effect, is solved from there through special plated film mode
The anti-fog effect that lens surface hydrophily reaches does not influence to increase on the basis of its optical property antifog compared to common plated film lens
Effect；The opposite eyeglass with immersion type anti-fog coating increases on the basis of same anti-fog effect, hardness, firmness are consistent
The translucency of eyeglass, reduces reflecting rate.
Claims (2)
1. a kind of stiffened plated film fog-proof lens, it is characterised in that: including substrate layer (1) and be arranged in upper true above substrate layer
Empty plated film anti-fog layer (2) and the lower vacuum coating anti-fog layer (3) being arranged in below substrate layer, the substrate layer (1) and upper vacuum
It is provided between plated film anti-fog layer (2) stiffened coating (4), is provided with down between the substrate layer and lower vacuum coating anti-fog layer
Stiffened coating (5), the upper stiffened coating (4) include upper corrosion cross-linked layer (6) and upper corrosion cross-linked layer and upper vacuum coating
Anti-fog layer is arranged alternately the upper stiffened strengthened coat (7) to be formed, the lower stiffened coating (5) include lower corrosion cross-linked layer (8) with
And lower corrosion cross-linked layer and lower vacuum coating anti-fog layer are arranged alternately the lower stiffened strengthened coat (9) to be formed.
2. stiffened plated film fog-proof lens described in accordance with the claim 1, it is characterised in that: the upper stiffened coating (4) includes extremely
Few three layers of upper corrosion cross-linked layer and at least one layer of upper stiffened strengthening layer, the lower stiffened coating (5) include corroding under at least three layers
Cross-linked layer and at least one layer of lower stiffened strengthening layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201820457057.8U CN208506293U (en) | 2018-04-03 | 2018-04-03 | A kind of stiffened plated film fog-proof lens |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201820457057.8U CN208506293U (en) | 2018-04-03 | 2018-04-03 | A kind of stiffened plated film fog-proof lens |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN208506293U true CN208506293U (en) | 2019-02-15 |
Family
ID=65295574
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201820457057.8U Expired - Fee Related CN208506293U (en) | 2018-04-03 | 2018-04-03 | A kind of stiffened plated film fog-proof lens |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN208506293U (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108345053A (en) * | 2018-04-03 | 2018-07-31 | 江苏俊联光学眼镜科技有限公司 | A kind of stiffened plated film fog-proof lens and preparation method thereof |
| CN110187416A (en) * | 2019-07-06 | 2019-08-30 | 丹阳市宏鑫光学眼镜有限公司 | A kind of coating fog-proof lens |
| CN111323851A (en) * | 2020-04-10 | 2020-06-23 | 厦门立林科技有限公司 | Preparation process of hardened antifogging lens |
| WO2022016482A1 (en) * | 2020-07-24 | 2022-01-27 | Carl Zeiss Vision International Gmbh | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same |
-
2018
- 2018-04-03 CN CN201820457057.8U patent/CN208506293U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108345053A (en) * | 2018-04-03 | 2018-07-31 | 江苏俊联光学眼镜科技有限公司 | A kind of stiffened plated film fog-proof lens and preparation method thereof |
| CN110187416A (en) * | 2019-07-06 | 2019-08-30 | 丹阳市宏鑫光学眼镜有限公司 | A kind of coating fog-proof lens |
| CN111323851A (en) * | 2020-04-10 | 2020-06-23 | 厦门立林科技有限公司 | Preparation process of hardened antifogging lens |
| WO2022016482A1 (en) * | 2020-07-24 | 2022-01-27 | Carl Zeiss Vision International Gmbh | Spectacle lens with antibacterial and/or antiviral properties and method for manufacturing the same |
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| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190215 |