CN208413940U - A kind of device handling industrial circulating cooling water - Google Patents

A kind of device handling industrial circulating cooling water Download PDF

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Publication number
CN208413940U
CN208413940U CN201820831477.8U CN201820831477U CN208413940U CN 208413940 U CN208413940 U CN 208413940U CN 201820831477 U CN201820831477 U CN 201820831477U CN 208413940 U CN208413940 U CN 208413940U
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China
Prior art keywords
cooling water
electrode
circulating cooling
target
industrial circulating
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CN201820831477.8U
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Chinese (zh)
Inventor
陈雪明
金华长
於洋
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Zhejiang University ZJU
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Zhejiang University ZJU
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Abstract

The utility model discloses a kind of devices for handling industrial circulating cooling water.Electrochemical reactor be a top be cuboid, bottom be funnel shaped container, the positive lower part of cuboid is provided with water inlet, and funnel bottom is mud discharging mouth, and the top at the cuboid back side is provided with overflow seam, overflow seam is connected to external catch basin, and catch basin lower part is provided with water outlet;Water fender is equipped in the electrochemical reactor of face water inlet;In the slot for the front and back that two lateral electrodes and target equidistant vertical are embedded in electrochemical reactor.The mode of connection between the electrode and power supply of the device, which obtains, significantly to be simplified, and electric current declines to a great extent, and power supply cost reduces;Electrode applies insulating layer or electrode places insulating barrier up and down significantly improves current efficiency, and energy consumption declines to a great extent;Cathode detergency is easy to operate, and detergency is high-efficient.It is suitable for electric power, petroleum, and the processing of the industries industrial circulating cooling water such as metallurgy while softening to industrial circulating cooling water, plays the role of sterilization algae removal.

Description

A kind of device handling industrial circulating cooling water
Technical field
The utility model relates to the devices of water process, more particularly, to a kind of device for handling industrial circulating cooling water.
Background technique
The industries such as electric power, petrochemical industry, metallurgy need to often use a large amount of recirculated cooling water.Fouling, mitigation are rotten in order to prevent Lose and suppress growth of microorganism breeding, it is necessary to be effectively treated to recirculated cooling water.For a long time, it mostly uses greatly both at home and abroad The method for adding the chemical agents such as antisludging agent, corrosion inhibiter and Biocidal algae-killing agent handles recirculated cooling water.Although chemical drugs Agent adds the problems such as method can preferably solve fouling, corrosion and microbial growth, but operating cost is high, and easily causes secondary Pollution.
In recent years, electrochemical process in circulating water treatment using increasing.Compared with chemical agent adds method, electrification Method has outstanding advantages of environmental-friendly, treatment effeciency is high, applied widely and easy to operate, has a extensive future.But it is existing There are still some defects for some electrochemical treatment device of circulating cooling water.Firstly, all anode needs link together, Suo Youyin Pole is also required to link together, and is then connected respectively with the positive and negative electrode of DC power supply again, electrochemical appliance is comparatively multiple It is miscellaneous, and usually require to be equipped with high-current dc power supply, cost of investment is relatively high;Secondly, cathode surface detergency method exists The problems such as cumbersome, detergency low efficiency.
Utility model content
In order to solve the problems, such as background technology field, the purpose of this utility model is to provide a kind of processing industry The device of recirculated cooling water, it is that a kind of structure is simple, easy detergency, and the electrochemical appliance of energy efficient process recirculated cooling water.
The technical solution adopted in the utility model is:
The electrochemical reactor of the utility model be a top be cuboid, bottom be funnel shaped container, cuboid Positive lower part is provided with water inlet, and funnel bottom is mud discharging mouth, and the top at the cuboid back side is provided with overflow seam, overflow seam with it is external Catch basin connection, catch basin lower part is provided with water outlet;Water fender is equipped in the electrochemical reactor of face water inlet;Two sides In the slot for the front and back that electrode and target equidistant vertical are embedded in electrochemical reactor.
The spacing of the adjacent electrode of two lateral electrode and target is 2~10 mm, is the DSA electrode of plate.
Two lateral electrode and target by recess-mounted that depth is 3~10 mm in electrochemical reactor just In the slot at face and the back side.
Insulating layer is coated within the scope of 10~50 mm of upper and lower part of two lateral electrode and target.
The upper and lower part of two lateral electrode and target is equipped with insulating barrier.
Two lateral electrode upper end all has protrusion part, and protrusion part is drilled with aperture, connects with wiring by the way that screw is fixed It connecing, wiring is connected with the positive and negative electrode of power supply respectively again, and the target does not have a wiring connection, in galvanization, target One side be anode, the another side of target is cathode.
The utility model has the beneficial effect that
1) mode of connection between the electrode and power supply of the utility model obtain it is significant simplify, electric current declines to a great extent, power supply at This reduction;
2) electrode, which applies insulating layer or electrode and places insulating barrier up and down, significantly improves current efficiency, and energy consumption is therefore substantially Decline.
3) cathode detergency is easy to operate, and detergency is high-efficient.
The utility model is suitable for electric power, petroleum, the processing of the industries industrial circulating cooling water such as metallurgy, to industrial cycle While cooling water is softened, play the role of sterilization algae removal.
Detailed description of the invention
Fig. 1 is the utility model structure principle chart.
Fig. 2 is the A-A cross-sectional view of Fig. 1.
Fig. 3 is the B-B cross-sectional view of Fig. 1.
In figure: 1, electrochemical reactor, 2, two lateral electrodes, 3, target, 4, insulating barrier, 5, water outlet, 6, overflow Seam, 7, water inlet, 8, water fender, 9, mud discharging mouth, 10, catch basin.
Specific embodiment
The following is a further explanation of the present invention with reference to the accompanying drawings and embodiments
As shown in Figure 1, Figure 2, Figure 3 shows, electrochemical reactor 1 be a top be cuboid, bottom be funnel shaped container, The positive lower part of cuboid is provided with water inlet 7, and funnel bottom is mud discharging mouth 9, and the top at the cuboid back side is provided with overflow seam 6, overflows Stream seam 6 is connected to external catch basin 10, and 10 lower part of catch basin is provided with water outlet 5;Electrochemical reactor at face water inlet 7 Water fender 8 is equipped in 1;Two lateral electrodes 2 and 3 equidistant vertical of target are embedded in the front and back of electrochemical reactor 1 In slot.
The spacing of the adjacent electrode of two lateral electrode 2 and target 3 is 2~10 mm, is the DSA electricity of plate Pole.
Two lateral electrode 2 and target 3 are by recess-mounted that depth is 3~10 mm in electrochemical reactor 1 In the slot of front and back.
It is coated with insulating layer within the scope of 10~50 mm of upper and lower part of two lateral electrode 2 and target 3, or
The upper and lower part of two lateral electrode 2 and target 3 is equipped with insulating barrier 4 (as shown in Figure 1 and Figure 2), with Prevent when handling high conductivity raw water electric current from 3 surrounding of target across causing current efficiency to be remarkably decreased.
Two lateral electrodes, 2 upper end all has protrusion part, and protrusion part is drilled with aperture, connects with wiring by the way that screw is fixed It connecing, wiring is connected with the positive and negative electrode of power supply respectively again, and the target 3 is connected without wiring, in galvanization, intermediate electricity The one side of pole 3 is anode, and the another side of target 3 is cathode.
The dirty layer that cathode surface deposits in the electrochemical reactor is removed by the way of pole.
The working principle of the utility model is as follows:
1) when carrying out industrial circulating cooling water processing:
Mud discharging mouth valve is closed, water inlet valve is opened and outlet valve, recirculated cooling water inputs electrification from water inlet 7 Reactor 1 is learned, carries out water distribution uniformity using water fender 8, water flow passes through electrochemical reactor 1 from bottom to top;The DSA electrode of two sides It is connected respectively with the positive and negative electrode of DC power supply by wiring, intermediate DSA electrode is connected not over wiring;Open direct current Source applies direct current to electrochemical reactor 1, is 10-300 A/m using current density2Direct current promote water electrolysis, it is intermediate DSA electrode be on one side anode, another side is cathode;Using the hypochlorous acid generated on electrolytic process Anodic to recirculated cooling water Carry out sterilization algae removal;Utilize the high concentration OH generated on cathode?, with the HCO in recirculated cooling water3 ?、Ca2+ And Mg2+Reaction point It Sheng Cheng not CaCO3 With Mg (OH)2And it is deposited on cathode surface, the hardness ions in water are removed;Treated water is through overflow seam 6 Catch basin 10 is flowed into, then is discharged by water outlet 5;In treatment process, the gas that two electrodes generate relies on natural buoyancy from electrification It learns and is discharged at the top of reactor 1.
When handling high conductivity raw water, coated on insulating layer or electrode if not descending within the scope of 10~50 mm on the electrode Lower placement insulating barrier 4, then since about 3 resistance per square of target is small, electric current is easily crossed over from about 3 target and causes electric current Efficiency is remarkably decreased;And insulating layer or electrode placement insulating barrier 4 up and down are coated within the scope of lower 10~50 mm on the electrode Afterwards, due to elongated across path, resistance increases, and electric current is not easy to cross over from about 3 target, and current efficiency significantly improves.
2) when carrying out cathode detergency processing:
When dirty layer gradually covered cathode surface, the problem of cathode performance fails will lead to, it is therefore desirable to periodically to cathode Surface carries out detergency processing.Allow electrode to be totally submerged in solution, using controller or manually control exchange two sides DSA electrode Polarity, the original cathode plane of target will become anode surface, and original anode surface will become cathode plane;Open direct current Source applies direct current to electrochemical reactor 1, is 100~300 A/m using current density2Direct current promote water electrolysis, it is former The cathode plane for being first covered with dirty layer will generate high concentration H as anode+, H+With the CaCO inside dirty layer3 With Mg (OH)2Reaction makes it Dissolution, facilitates falling off for dirty layer, the sediment of removing is transferred to water phase from cathode surface;During detergency, two electrodes are generated Gas be discharged at the top of electrochemical reactor 1 by natural buoyancy;After detergency, DC power supply is closed, opens mud discharging mouth The sediment of removing is discharged valve from mud discharging mouth 9.
Embodiment:
Hardness is about 950 mg/L, and conductivity is 3482 μ S/cm, and inhibitor concentration is about the industrial circulating water of 2 mg/L It is handled using utility model device.The device includes six pieces of DSA plate electrodes, and the size of electrode is 100 mm × 100 The mm of mm × 2, the clear spacing between two electrodes are 10 mm.Depth of groove is 5 mm, and insulating barrier width is 10 mm.
Operating condition is as follows: processing stage current density is 75 A/m2, 25 L/h of water velocity lasts 12 h;Cathode is de- Dirty 100 A/m of stage current density2, 5 min of detergency time.When electrode upper and lower part installation insulating barrier, total hardness of water out For 808 mg/L.In contrast, when electrode upper and lower part do not install insulating barrier, total hardness of water is 847 mg/L out.
When not installing insulating barrier, hardness removal amount is the mg/L of 950mg/L-847 mg/L=103;Insulating barrier is installed Afterwards, hardness removal amount is the mg/L of 950mg/L-808 mg/L=142, therefore hardness removal amount increases after installation insulating barrier (142-103)/103=37.9%.Softening efficiency when installing insulating barrier increases 37.9% when not installing insulating barrier.

Claims (6)

1. a kind of device for handling industrial circulating cooling water, it is characterised in that: electrochemical reactor (1) is that a top is rectangular Body, bottom are funnel shaped container, and the positive lower part of cuboid is provided with water inlet (7), and funnel bottom is mud discharging mouth (9), rectangular The top at the body back side is provided with overflow seam (6), and overflow seam (6) is connected to external catch basin (10), and catch basin (10) lower part is provided with Water outlet (5);Water fender (8) are equipped in electrochemical reactor (1) at face water inlet (7);Two lateral electrodes (2) and centre electricity In the slot for the front and back that pole (3) equidistant vertical is embedded in electrochemical reactor (1).
2. a kind of device for handling industrial circulating cooling water according to claim 1, it is characterised in that: two lateral electrode (2) and the spacing of the adjacent electrode of target (3) is 2~10 mm, is the DSA electrode of plate.
3. a kind of device for handling industrial circulating cooling water according to claim 1, it is characterised in that: two lateral electrode (2) and target (3) by depth be 3~10 mm recess-mounted in electrochemical reactor (1) front and back slot It is interior.
4. a kind of device for handling industrial circulating cooling water according to claim 1, it is characterised in that: two lateral electrode (2) and within the scope of 10~50 mm of upper and lower part of target (3) it is coated with insulating layer.
5. a kind of device for handling industrial circulating cooling water according to claim 1, it is characterised in that: two lateral electrode (2) and the upper and lower part of target (3) is equipped with insulating barrier (4).
6. a kind of device for handling industrial circulating cooling water according to claim 1 or 2, it is characterised in that: the two sides Electrode (2) upper end all has protrusion part, and protrusion part is drilled with aperture, is fixedly connected with wiring by screw, wiring is distinguished again It is connected with the positive and negative electrode of power supply, the target (3) connects without wiring, in galvanization, the one side of target (3) For anode, the another side of target (3) is cathode.
CN201820831477.8U 2018-05-31 2018-05-31 A kind of device handling industrial circulating cooling water Withdrawn - After Issue CN208413940U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820831477.8U CN208413940U (en) 2018-05-31 2018-05-31 A kind of device handling industrial circulating cooling water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201820831477.8U CN208413940U (en) 2018-05-31 2018-05-31 A kind of device handling industrial circulating cooling water

Publications (1)

Publication Number Publication Date
CN208413940U true CN208413940U (en) 2019-01-22

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Country Status (1)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108483589A (en) * 2018-05-31 2018-09-04 浙江大学 Handle the device of industrial circulating cooling water

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108483589A (en) * 2018-05-31 2018-09-04 浙江大学 Handle the device of industrial circulating cooling water
CN108483589B (en) * 2018-05-31 2021-11-30 浙江大学 Device for treating industrial circulating cooling water

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