A kind of ice chest with n- parahydrogen transformation function
Technical field
The utility model relates to liquid hydrogen production equipment fields, and in particular to a kind of ice chest with n- parahydrogen transformation function.
Background technique
Liquid hydrogen is the transparency liquid of the no color or smell as made of liquefaction of hydrogen, is the mixing of parahydrogen (p-H2) and ortho-hydrogen (o-H2)
Object.Ortho-hydrogen and parahydrogen are two kinds of spin isomers of molecular hydrogen, and parahydrogen is identical with the chemical property of ortho-hydrogen, and physical property
Difference.In room temperature or when being higher than room temperature, just, the equilibrium composition of parahydrogen ratio be 75:25, referred to as standard hydrogen (n-H2) or normal
Hydrogen.When lower than room temperature, just, the equilibrium composition of parahydrogen ratio will change, percentage shared by parahydrogen increase.Gaseous Hydrogen it is just secondary
State conversion could occur in the presence of a catalyst, and liquified hydrogen then will spontaneously be sent out in the case where no catalyst
Raw just secondary conversion, but conversion rate is slower.The just secondary conversion of hydrogen is an exothermic reaction, the heat released in conversion process and conversion
When temperature it is related.Liquid hydrogen evaporation loss caused by heat release is converted to reduce positive parahydrogen, requires parahydrogen to contain in all liquid hydrogen products
Amount requires to be substantially all ortho-hydrogen when liquefaction to be catalytically conveted to parahydrogen at least 95% or more.When preparing liquid hydrogen, need in gas
Be about to begin n- parahydrogen conversion when state hydrogen.
Have now can be provided for gaseous state liquefaction of hydrogen the ice chest of cooling capacity with can for the ice chest that the n- parahydrogen of Gaseous Hydrogen converts, but
It is not have the ice chest that can be provided cooling capacity simultaneously for gaseous state liquefaction of hydrogen and can convert for the n- parahydrogen of Gaseous Hydrogen now.
Utility model content
The technical problem to be solved by the utility model is to will provide a kind of for gaseous state liquefaction of hydrogen can provide cooling capacity and energy
For the ice chest with n- parahydrogen transformation function of the n- parahydrogen conversion of Gaseous Hydrogen.
To solve the above-mentioned problems, the technology employed by the present utility model is a kind of have n- parahydrogen transformation function
Ice chest, comprising: shell, it is characterised in that: housing inlet port and housing outlets are provided on shell, cold source can be entered by shell
Mouth is flowed into shell, and can flow out shell by housing outlets, be additionally provided with a combined type heat exchanger tube, group in the housing
The heat exchange tube inlet and heat transfer tube outlet of box-like heat exchanger tube stretch out shell respectively, and combined type heat exchanger tube includes that one section of helix-coil changes
Heat pipe and one section of straight heat exchanger tube, helix-coil heat exchanger tube are located on the outside of straight heat exchanger tube, and being provided in straight heat exchanger tube can urge
Change the catalyst of the n- parahydrogen conversion of hydrogen.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: be arranged in heat transfer tube outlet
The filter that hydrogen prevents catalyst from flowing out can be filtered by having.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: filter is metal filtering core.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: the filtering accuracy of metal filtering core
No more than 35~45 microns.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: housing inlet port and housing outlets
The both ends in shell side channel are respectively arranged at, combined type heat exchanger tube is arranged along shell side channel.
A kind of the advantages of the utility model are as follows: ice chest use with n- parahydrogen transformation function described in the utility model
More air-flow sunk type shell-and-tube heat exchanger design concepts, so that the n- parahydrogen conversion of hydrogen_cooling and hydrogen can be synchronous in ice chest
It carries out, and also absorbs the heat generated in n- parahydrogen conversion process, solve temperature in n- parahydrogen conversion process and maintain
Problem.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the ice chest with n- parahydrogen transformation function described in the utility model.
Specific embodiment
The utility model is described in further detail with attached drawing combined with specific embodiments below.
As shown in Figure 1, a kind of ice chest with n- parahydrogen transformation function, comprising: shell 1 is provided with shell on shell 1
Body entrance 11 and housing outlets 12, cold source can be flowed into shell 1 by housing inlet port 11, and can be flowed by housing outlets 12
Shell 1 out, in the present embodiment, cold source are usually liquid nitrogen;It is additionally provided with a combined type heat exchanger tube 2, combined type within the case 1
The heat exchange tube inlet 24 and heat transfer tube outlet 25 of heat exchanger tube 2 stretch out shell 1 respectively, and combined type heat exchanger tube 2 includes one section of helical coil
Bent heat exchanger tube 21 and one section of straight heat exchanger tube 22, helix-coil heat exchanger tube 21 is located on the outside of straight heat exchanger tube 22, in straight heat exchanger tube
The catalyst 23 of the hydrogen catalyzed n- parahydrogen conversion of energy is provided in 22.
When work, liquid nitrogen flows into shell 1 from housing inlet port 11, then flows out shell 1 from housing outlets 12, and hydrogen is from changing
Heat pipe entrance 24 flows into combined type heat exchanger tube 2, and hydrogen can carry out heat with the liquid nitrogen in shell 1 in helix-coil heat exchanger tube 21
Exchange, to provide cooling capacity for liquefaction of hydrogen, helix-coil heat exchanger tube 21 can increase the area of hydrogen Yu liquid nitrogen heat exchange, so that
Hydrogen can cool down faster;Then hydrogen can carry out n- parahydrogen conversion in straight heat exchanger tube 22, while can also carry out heat with liquid nitrogen
Exchange carries out so that hydrogen_cooling is synchronous with the conversion of n- parahydrogen, and also absorbs the heat generated in n- parahydrogen conversion process
Amount solves the problems, such as that temperature maintains in n- parahydrogen conversion process.
In the present embodiment, the filter that hydrogen prevents catalyst 23 from flowing out can be filtered by being provided in heat transfer tube outlet 25
251.Filter 251 is metal filtering core.The filtering accuracy of metal filtering core is no more than 35~45 microns.Filtering accuracy is excessively high can be unfavorable
It is flowed in hydrogen.
Housing inlet port 11 and housing outlets 12 are respectively arranged at the both ends in shell side channel, and combined type heat exchanger tube 2 is along shell side
Channel arrangement.Setting can make hydrogen sufficiently exchange heat with cold source in this way.