CN208398490U - A kind of ice chest with n- parahydrogen transformation function - Google Patents

A kind of ice chest with n- parahydrogen transformation function Download PDF

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Publication number
CN208398490U
CN208398490U CN201820803223.5U CN201820803223U CN208398490U CN 208398490 U CN208398490 U CN 208398490U CN 201820803223 U CN201820803223 U CN 201820803223U CN 208398490 U CN208398490 U CN 208398490U
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China
Prior art keywords
heat exchanger
parahydrogen
exchanger tube
shell
hydrogen
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CN201820803223.5U
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Chinese (zh)
Inventor
倪中华
邬海强
严岩
魏蔚
况开锋
郭道峰
王秋霞
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Jiangsu Guofu Hydrogen Energy Technology Equipment Co Ltd
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Zhangjiagang Furui Hydrogen Energy Equipment Co Ltd
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Priority to CN201820803223.5U priority Critical patent/CN208398490U/en
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Abstract

The utility model discloses a kind of ice chests with n- parahydrogen transformation function, it include: shell, housing inlet port and housing outlets are provided on shell, cold source can be flowed into shell by housing inlet port, and shell can be flowed out by housing outlets, it is additionally provided with a combined type heat exchanger tube in the housing, the heat exchange tube inlet and heat transfer tube outlet of combined type heat exchanger tube stretch out shell respectively, combined type heat exchanger tube includes one section of helix-coil heat exchanger tube and one section of straight heat exchanger tube, helix-coil heat exchanger tube is located on the outside of straight heat exchanger tube, the catalyst of the hydrogen catalyzed n- parahydrogen conversion of energy is provided in straight heat exchanger tube.A kind of above-mentioned ice chest with n- parahydrogen transformation function uses more air-flow sunk type shell-and-tube heat exchanger design concepts, so that hydrogen_cooling synchronous in ice chest can be carried out with the conversion of the n- parahydrogen of hydrogen, and the heat generated in n- parahydrogen conversion process is also absorbed, solves the problems, such as that temperature maintains in n- parahydrogen conversion process.

Description

A kind of ice chest with n- parahydrogen transformation function
Technical field
The utility model relates to liquid hydrogen production equipment fields, and in particular to a kind of ice chest with n- parahydrogen transformation function.
Background technique
Liquid hydrogen is the transparency liquid of the no color or smell as made of liquefaction of hydrogen, is the mixing of parahydrogen (p-H2) and ortho-hydrogen (o-H2) Object.Ortho-hydrogen and parahydrogen are two kinds of spin isomers of molecular hydrogen, and parahydrogen is identical with the chemical property of ortho-hydrogen, and physical property Difference.In room temperature or when being higher than room temperature, just, the equilibrium composition of parahydrogen ratio be 75:25, referred to as standard hydrogen (n-H2) or normal Hydrogen.When lower than room temperature, just, the equilibrium composition of parahydrogen ratio will change, percentage shared by parahydrogen increase.Gaseous Hydrogen it is just secondary State conversion could occur in the presence of a catalyst, and liquified hydrogen then will spontaneously be sent out in the case where no catalyst Raw just secondary conversion, but conversion rate is slower.The just secondary conversion of hydrogen is an exothermic reaction, the heat released in conversion process and conversion When temperature it is related.Liquid hydrogen evaporation loss caused by heat release is converted to reduce positive parahydrogen, requires parahydrogen to contain in all liquid hydrogen products Amount requires to be substantially all ortho-hydrogen when liquefaction to be catalytically conveted to parahydrogen at least 95% or more.When preparing liquid hydrogen, need in gas Be about to begin n- parahydrogen conversion when state hydrogen.
Have now can be provided for gaseous state liquefaction of hydrogen the ice chest of cooling capacity with can for the ice chest that the n- parahydrogen of Gaseous Hydrogen converts, but It is not have the ice chest that can be provided cooling capacity simultaneously for gaseous state liquefaction of hydrogen and can convert for the n- parahydrogen of Gaseous Hydrogen now.
Utility model content
The technical problem to be solved by the utility model is to will provide a kind of for gaseous state liquefaction of hydrogen can provide cooling capacity and energy For the ice chest with n- parahydrogen transformation function of the n- parahydrogen conversion of Gaseous Hydrogen.
To solve the above-mentioned problems, the technology employed by the present utility model is a kind of have n- parahydrogen transformation function Ice chest, comprising: shell, it is characterised in that: housing inlet port and housing outlets are provided on shell, cold source can be entered by shell Mouth is flowed into shell, and can flow out shell by housing outlets, be additionally provided with a combined type heat exchanger tube, group in the housing The heat exchange tube inlet and heat transfer tube outlet of box-like heat exchanger tube stretch out shell respectively, and combined type heat exchanger tube includes that one section of helix-coil changes Heat pipe and one section of straight heat exchanger tube, helix-coil heat exchanger tube are located on the outside of straight heat exchanger tube, and being provided in straight heat exchanger tube can urge Change the catalyst of the n- parahydrogen conversion of hydrogen.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: be arranged in heat transfer tube outlet The filter that hydrogen prevents catalyst from flowing out can be filtered by having.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: filter is metal filtering core.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: the filtering accuracy of metal filtering core No more than 35~45 microns.
Further, a kind of ice chest with n- parahydrogen transformation function above-mentioned, in which: housing inlet port and housing outlets The both ends in shell side channel are respectively arranged at, combined type heat exchanger tube is arranged along shell side channel.
A kind of the advantages of the utility model are as follows: ice chest use with n- parahydrogen transformation function described in the utility model More air-flow sunk type shell-and-tube heat exchanger design concepts, so that the n- parahydrogen conversion of hydrogen_cooling and hydrogen can be synchronous in ice chest It carries out, and also absorbs the heat generated in n- parahydrogen conversion process, solve temperature in n- parahydrogen conversion process and maintain Problem.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram of the ice chest with n- parahydrogen transformation function described in the utility model.
Specific embodiment
The utility model is described in further detail with attached drawing combined with specific embodiments below.
As shown in Figure 1, a kind of ice chest with n- parahydrogen transformation function, comprising: shell 1 is provided with shell on shell 1 Body entrance 11 and housing outlets 12, cold source can be flowed into shell 1 by housing inlet port 11, and can be flowed by housing outlets 12 Shell 1 out, in the present embodiment, cold source are usually liquid nitrogen;It is additionally provided with a combined type heat exchanger tube 2, combined type within the case 1 The heat exchange tube inlet 24 and heat transfer tube outlet 25 of heat exchanger tube 2 stretch out shell 1 respectively, and combined type heat exchanger tube 2 includes one section of helical coil Bent heat exchanger tube 21 and one section of straight heat exchanger tube 22, helix-coil heat exchanger tube 21 is located on the outside of straight heat exchanger tube 22, in straight heat exchanger tube The catalyst 23 of the hydrogen catalyzed n- parahydrogen conversion of energy is provided in 22.
When work, liquid nitrogen flows into shell 1 from housing inlet port 11, then flows out shell 1 from housing outlets 12, and hydrogen is from changing Heat pipe entrance 24 flows into combined type heat exchanger tube 2, and hydrogen can carry out heat with the liquid nitrogen in shell 1 in helix-coil heat exchanger tube 21 Exchange, to provide cooling capacity for liquefaction of hydrogen, helix-coil heat exchanger tube 21 can increase the area of hydrogen Yu liquid nitrogen heat exchange, so that Hydrogen can cool down faster;Then hydrogen can carry out n- parahydrogen conversion in straight heat exchanger tube 22, while can also carry out heat with liquid nitrogen Exchange carries out so that hydrogen_cooling is synchronous with the conversion of n- parahydrogen, and also absorbs the heat generated in n- parahydrogen conversion process Amount solves the problems, such as that temperature maintains in n- parahydrogen conversion process.
In the present embodiment, the filter that hydrogen prevents catalyst 23 from flowing out can be filtered by being provided in heat transfer tube outlet 25 251.Filter 251 is metal filtering core.The filtering accuracy of metal filtering core is no more than 35~45 microns.Filtering accuracy is excessively high can be unfavorable It is flowed in hydrogen.
Housing inlet port 11 and housing outlets 12 are respectively arranged at the both ends in shell side channel, and combined type heat exchanger tube 2 is along shell side Channel arrangement.Setting can make hydrogen sufficiently exchange heat with cold source in this way.

Claims (5)

1. a kind of ice chest with n- parahydrogen transformation function, comprising: shell, it is characterised in that: be provided with shell on shell and enter Mouth and housing outlets, cold source fluid can be flowed into shell by housing inlet port, and can flow out shell by housing outlets, A combined type heat exchanger tube is additionally provided in shell, the heat exchange tube inlet and heat transfer tube outlet of combined type heat exchanger tube stretch out shell respectively Body, combined type heat exchanger tube include one section of helix-coil heat exchanger tube and one section of straight heat exchanger tube, and helix-coil heat exchanger tube, which is located on, directly to be changed The outside of heat pipe is provided with the catalyst of the hydrogen catalyzed n- parahydrogen conversion of energy in straight heat exchanger tube.
2. a kind of ice chest with n- parahydrogen transformation function according to claim 1, it is characterised in that: go out in heat exchanger tube The filter that hydrogen prevents catalyst from flowing out can be filtered by being provided on mouth.
3. a kind of ice chest with n- parahydrogen transformation function according to claim 2, it is characterised in that: filter is gold Belong to filter core.
4. a kind of ice chest with n- parahydrogen transformation function according to claim 3, it is characterised in that: metal filtering core Filtering accuracy is no more than 35~45 microns.
5. a kind of ice chest with n- parahydrogen transformation function according to claim 1 or 2 or 3 or 4, it is characterised in that: shell Body entrance and housing outlets are respectively arranged at the both ends in shell side channel, and combined type heat exchanger tube is arranged along shell side channel.
CN201820803223.5U 2018-05-28 2018-05-28 A kind of ice chest with n- parahydrogen transformation function Active CN208398490U (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201820803223.5U CN208398490U (en) 2018-05-28 2018-05-28 A kind of ice chest with n- parahydrogen transformation function

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108562112A (en) * 2018-05-28 2018-09-21 张家港富瑞氢能装备有限公司 A kind of ice chest with n- parahydrogen transformation function
CN114505014A (en) * 2022-04-19 2022-05-17 北京中科富海低温科技有限公司 Pressure container
WO2022135515A1 (en) * 2020-12-25 2022-06-30 江苏国富氢能技术装备股份有限公司 Hydrogen liquefaction system having ortho-parahydrogen conversion function

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108562112A (en) * 2018-05-28 2018-09-21 张家港富瑞氢能装备有限公司 A kind of ice chest with n- parahydrogen transformation function
WO2022135515A1 (en) * 2020-12-25 2022-06-30 江苏国富氢能技术装备股份有限公司 Hydrogen liquefaction system having ortho-parahydrogen conversion function
CN114505014A (en) * 2022-04-19 2022-05-17 北京中科富海低温科技有限公司 Pressure container
CN114505014B (en) * 2022-04-19 2022-06-28 北京中科富海低温科技有限公司 Pressure container

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CP03 Change of name, title or address
CP03 Change of name, title or address

Address after: 215600 No. 236, Guotai North Road, Zhangjiagang City, Suzhou City, Jiangsu Province

Patentee after: Jiangsu Guofu hydrogen energy technology equipment Co.,Ltd.

Address before: 215600 Fuxin (morning) road 19, Yang Shi Town, Zhangjiagang City, Suzhou, Jiangsu.

Patentee before: Jiangsu Guofu Hydrogen Energy Technology Equipment Co.,Ltd.

Address after: 215600 Fuxin (morning) road 19, Yang Shi Town, Zhangjiagang City, Suzhou, Jiangsu.

Patentee after: Jiangsu Guofu Hydrogen Energy Technology Equipment Co.,Ltd.

Address before: 215600 Fuxin (new morning) road 19, Zhangjiagang, Suzhou, Zhangjiagang, Jiangsu province Zhangjiagang Furui hydrogen energy equipment Co., Ltd.

Patentee before: ZHANGJIAGANG FURUI HYDROGEN ENERGY EQUIPMENT Co.,Ltd.