CN208327656U - A kind of desulfurization wastewater resource utilization process system - Google Patents

A kind of desulfurization wastewater resource utilization process system Download PDF

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CN208327656U
CN208327656U CN201820285620.8U CN201820285620U CN208327656U CN 208327656 U CN208327656 U CN 208327656U CN 201820285620 U CN201820285620 U CN 201820285620U CN 208327656 U CN208327656 U CN 208327656U
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chemicals dosing
dosing plant
clarifier
water
pipeline
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CN201820285620.8U
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陈�峰
张博
卢瑞珍
李会杰
马全胜
李雨蔓
仙琨
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Guoneng Water Environmental Protection Co.,Ltd.
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Beijing Lucency Enviro Tech Co Ltd
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Abstract

The utility model discloses desulfurization wastewater resource utilization process system, this system mainly includes waste water tank, waste-water vortex device, high-efficiency clarifier, clarifier, pre-concentration device, ceramic membrane, HIRO, electrolysis unit, clear water reserviors, vacuum belt machine, flocculation aid chemicals dosing plant, sodium hydroxide chemicals dosing plant, composite flocculation agent chemicals dosing plant, carbon dioxide chemicals dosing plant, soda ash chemicals dosing plant;This system can be realized desulfurization wastewater resource utilization, generate sodium hypochlorite products, solve the problems such as evaporative crystallization energy consumption is high;Shorten system flow, each byproduct recycles and reuses, saves the advantages that effluent part investment and operation processing cost, solves the problems, such as that current high-salinity wastewater zero-emission encounters.

Description

A kind of desulfurization wastewater resource utilization process system
Technical field
The present invention relates to desulfurization wastewater technical field of resource comprehensive utilization, and in particular to a kind of desulfurization wastewater resource utilization Process system.
Background technique
The current processing means of desulfurization wastewater are limited, and by evaporative crystallization recycle-water, salt carries out landfill disposal, causes resource Waste.
Present patent application integrally considers a kind of desulfurization wastewater resource utilization process system, is entirely by desulfurization wastewater System comprehensively considers, optimization system technique, its product is finally carried out resource utilization, generates sodium hypochlorite products, can be to sewage It is sterilized.
It is more than embrane method+evaporative crystallization and flue gas that current common desulfurization wastewater resource utilization, which was explored with the experimental stage, Two kinds of thermal evaporation, embrane method has positive infiltration and high pressure reverse osmosis, and flue residue heat evaporation is divided into before deduster sprays after spray and deduster Leaching.It is carnallite that fume afterheat, which steams generation, and possible next stage can be influenced by environmental protection policy, and embrane method+evaporative crystallization, soft It is excessively high to change reagent cost, runs and overhauls and is more demanding.
Summary of the invention
The present invention overcomes the deficiencies in the prior art, provide a kind of desulfurization wastewater resource utilization process system.
In view of the above problem of the prior art, according to an aspect of the present invention, in order to solve the above technical problems, this Invention use a kind of desulfurization wastewater resource utilization process system, this system mainly include waste water tank, waste-water vortex device, efficiently it is clear Clear device, clarifier, pre-concentration device, ceramic membrane, HIRO, electrolysis unit, clear water reserviors, vacuum belt machine, flocculation aid chemicals dosing plant, Sodium hydroxide chemicals dosing plant, composite flocculation agent chemicals dosing plant, carbon dioxide chemicals dosing plant, soda ash chemicals dosing plant, to guarantee this work The operation steady in a long-term of process system further includes that related matched cleaning device, chemicals dosing plant, electrical system and instrument control, It is characterized in that:
(1) flocculation aid chemicals dosing plant accesses waste water tank by pipeline, and waste water tank is equipped with blender, after adding medicine stirring, leads to It crosses pump and pipeline is connected to waste-water vortex device, dosage is 0.5 ~ 1ppm, and waste water carries out flocculation in waste water tank and generates larger Grain carries out mud-water separation through eddy flow gravity in waste-water vortex device, so that it is discharged solid content less than 1%;
(2) it is set before high-efficiency clarifier there are two quick agitator tank, mixing speed is 200rpm or more, is equipped with and leads in agitator tank Flowing plate and guide shell, sodium hydroxide chemicals dosing plant are connected to the first quick agitator tank, and sodium hydroxide is added, and the residence time is 30min makes the pH value of water be maintained at 11 ~ 12, and composite flocculation agent chemicals dosing plant is connected to second quick agitator tank, is added compound Flocculant, residence time 10min, after waste water sequentially enters the first, second quick agitator tank, subsequently into high-efficiency clarifier, Guide shell, rotating flow guidance plate are set in high-efficiency clarifier, waste water produces the high-strength centrifugal rotation of water in high-efficiency clarifier, increases floccule body grain Diameter and density realize speed separation, and clear water enters next stage clarifier by pipeline, its key reaction formula are as follows:
Mg2++2OH+─→Mg(OH)2
(HCO3)+2OH+─→(CO3)2-+H2O
(3) carbon dioxide chemicals dosing plant is connected by pipeline with the perforated pipe of bottom of clarifier, opening diameter 5mm, instead The residence time is 30min in Ying Chi, and surface loading is 1 ~ 3m/h, and 5 ~ 6m of the depth of water makes the pH value of water be maintained at 9.5 or more, it Key reaction formula are as follows:
Ca2++CO3 2-─→CaCO3
(4) clarifier is connected to pre-concentration by pipeline, pump, valve and pre-concentration device, ceramic membrane, soda ash chemicals dosing plant Device, it is secondary except hard, so that hardness is remained 1mol/L hereinafter, pre-concentration device sludge concentration is kept within 4%, is equipped with densimeter, When reaching 4%, it is back to high-efficiency clarifier, ceramic membrane material uses ceramic sintering, and water inlet pH value is 1 ~ 14, influent turbidity 5000,10 ~ 80 degree of inflow temperature, water SDI is produced less than 1, turbidity is its key reaction formula of 0.2NUT are as follows:
Ca2++CO3 2-─→CaCO3
(5) HIRO uses rolled film, and runner is 0.8 ~ 4mm, can be used vertical using vertical encapsulation with specific reference to water quality Series connection, maximum are no more than 7, and it is 6.5 ~ 7.5 that water inlet PH, which is adjusted, while setting electronic anti-scaling agent, ultraviolet sterilizer, electronics Antisludging agent forms electron beam, is formed and is fettered to hardness ions, fouling tendency is effectively reduced;
(6) HIRO produces water and enters clear water reserviors, and concentrated water enters electrolysis unit by pipeline, is electrolysed as NACLO, wherein concentrated water NACL content is 10000 ~ 30000mg/L;
(7) spoil disposal of high-efficiency clarifier and clarifier enters the front end of vacuum belt machine, the feed liquor point with gypsum cyclone It opens, since the molecular diameter in spoil disposal is smaller, is easy dirty stifled vacuum belt machine, is arranged in after gypsum cyclone underflow, It can prevent dirty stifled;
Compared with prior art, of the invention to be advantageous in that:
(1) by desulfurization wastewater resource utilization, sodium hypochlorite products are generated, solve the problems such as evaporative crystallization energy consumption is high;
(2) the HIRO film for using large area reduces investment operating cost;
(3) high-efficiency clarifier substitutes original three header and clarifier, and land occupation is smaller, invests relatively small;
(4) flocculation aid is added in waste water tank, is conducive to fine particle and forms larger particles, while divides in waste-water vortex device From;
(5) concentrated water that HIRO device generates enters electrolysis unit, and the byproduct generated is comprehensively utilized;
(6) each unit can independent operating, regulating power is stronger;
(7) process flow is relatively short, reduces investment outlay and operating cost.
Detailed description of the invention
Illustrate present specification embodiment or technical solution in the prior art in order to clearer, it below will be to embodiment Or attached drawing needed in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only It is the reference to embodiments some in present specification, for those skilled in the art, what is do not made the creative labor In the case of, other attached drawings can also be obtained according to these attached drawings, used after can also being adjusted to certain a part therein.
Fig. 1 shows the structural representation of desulfurization wastewater resource utilization process system according to an embodiment of the invention Figure.In figure, (101) waste water tank, (102) waste-water vortex device, (103) high-efficiency clarifier, (104) clarifier, (105) pre-concentration dress Set, (106) ceramic membrane, (107) HIRO, (108) electrolysis unit, (109) clear water reserviors, (110) vacuum belt machine, (111) help it is solidifying Agent chemicals dosing plant, (112) sodium hydroxide chemicals dosing plant, (113) composite flocculation agent chemicals dosing plant, (114) carbon dioxide dosing dress It sets, (115) soda ash chemicals dosing plant.
Specific embodiment
The present invention is described in further detail below with reference to embodiment, embodiments of the present invention are not limited thereto.
Fig. 1 shows desulfurization wastewater resource utilization process system according to an embodiment of the invention, including (101) give up Water tank, (102) waste-water vortex device, (103) high-efficiency clarifier, (104) clarifier, (105) pre-concentration device, (106) ceramic membrane, (107) HIRO, (108) electrolysis unit, (109) clear water reserviors, (110) vacuum belt machine, (111) flocculation aid chemicals dosing plant, (112) Sodium hydroxide chemicals dosing plant, (113) composite flocculation agent chemicals dosing plant, (114) carbon dioxide chemicals dosing plant, (115) soda ash dosing Device.
In order to realize zero discharge of industrial waste water with high salt, this desulfurization wastewater resource utilization process system is broadly divided into five A step is realized, each device in pipeline and pump attachment system is passed through.
Step 1: desulfurization wastewater enters (101) waste water tank after gypsum cyclone, and (111) flocculation aid chemicals dosing plant passes through Pipeline is connect with (101) waste water tank, and dosage is 0.5 ~ 1ppm, and (101) waste water tank is equipped with blender, mixes by stirring Flocculation is carried out in (101) waste water tank with, waste water and generates larger particles, and (102) waste-water vortex device is entered through eddy flow weight by pump Power carries out mud-water separation, so that it is discharged solid content less than 1%;
Step 2: setting before (103) high-efficiency clarifier there are two quick agitator tank, and mixing speed is 200rpm or more, stirring Deflector and guide shell are equipped in case, (112) sodium hydroxide chemicals dosing plant is connected to the first quick agitator tank, and hydroxide is added Sodium, residence time 30min make the pH value of water be maintained at 11 ~ 12, and (113) composite flocculation agent chemicals dosing plant is connected to second Quick agitator tank, addition composite flocculation agent, residence time 10min, after waste water sequentially enters the first, second quick agitator tank, Subsequently into (103) high-efficiency clarifier, guide shell is set in (103) high-efficiency clarifier, rotating flow guidance plate, waste water is efficient in (103) Clarifier produces the high-strength centrifugal rotation of water, increases floccule body partial size and density, realizes speed separation, and clear water enters next stage by pipeline (104) clarifier, its key reaction formula are as follows:
Mg2++2OH+─→Mg(OH)2
(HCO3)+2OH+─→(CO3)2-+H2O
Step 3: (114) carbon dioxide chemicals dosing plant is connected by pipeline with the perforated pipe of (104) bottom of clarifier, is opened Bore dia is 5mm, and the residence time is 30min in reaction tank, and surface loading is 1 ~ 3m/h, 5 ~ 6m of the depth of water, keeps the pH value of water 9.5 or more, its key reaction formula are as follows:
Ca2++CO3 2-─→CaCO3
Step 4: (104) clarifier passes through pipeline, pump, valve and (105) pre-concentration device, (106) ceramic membrane, (115) The connection of soda ash chemicals dosing plant, it is secondary to remove firmly, so that hardness is remained 1mol/L hereinafter, (105) pre-concentration device sludge concentration is kept Within 4%, it is equipped with densimeter, when reaching 4%, is back to (104) high-efficiency clarifier, (106) ceramics membrane material is burnt using ceramics System, water inlet pH value be 1 ~ 14, influent turbidity 5000,10 ~ 80 degree of inflow temperature, produce water SDI less than 1, turbidity for 0.2NUT it Key reaction formula are as follows:
Ca2++CO3 2-─→CaCO3
Step 5: (107) HIRO uses rolled film, and runner is 0.8 ~ 4mm, can with specific reference to water quality using vertical encapsulation Using vertical series connection, maximum is no more than 7, and it is 6.5 ~ 7.5 that water inlet PH, which is adjusted, at the same set electronic anti-scaling agent, ultraviolet light kills Bacterium device, electronic anti-scaling dosage form form hardness ions and fetter, fouling tendency is effectively reduced at electron beam;
Step 6: (107) HIRO produces water and enters (109) clear water reserviors, and concentrated water enters (108) electrolysis unit by pipeline, Electrolysis unit reacts, and is electrolysed as NACLO, and wherein concentrated water NACL content is 10000 ~ 30000mg/L;
Step 7: the spoil disposal of (103) high-efficiency clarifier and (104) clarifier enters the front end of (110) vacuum belt machine, with The feed liquor of gypsum cyclone separates, and since the molecular diameter in spoil disposal is smaller, dirty stifled (110) vacuum belt machine is easy, by its cloth It is placed in after gypsum cyclone underflow, can prevent dirty stifled.
For the operation steady in a long-term for guaranteeing this process system, realizes complete zero-emission, while product is utilized, further include Related matched cleaning device, chemicals dosing plant, electrical system and instrument control participate in a kind of this high-salt wastewater treatment process system Operation.
" one embodiment " and " embodiment " for being spoken of in the present specification etc. refers to combining embodiment description Specific features, structure or feature are included at least one embodiment generally described herein.It is multiple in the description It is not centainly to refer to the same embodiment that statement of the same race, which occurs, in place.Furthermore, it is understood that describing one in conjunction with any embodiment Specific features, structure perhaps feature when to be advocated is that this feature, structure or feature are realized in conjunction with other embodiments Also it falls within the scope of the present invention.
Although reference be made herein to invention has been described for multiple explanatory embodiments of the invention, however, it is to be understood that Those skilled in the art can be designed that a lot of other modification and implementations, these modifications and implementations will fall in this Shen It please be within disclosed scope and spirit.More specifically, disclose in the application, drawings and claims in the range of, can With the building block and/or a variety of variations and modifications of layout progress to theme combination layout.In addition to building block and/or layout Outside the variations and modifications of progress, to those skilled in the art, other purposes also be will be apparent.

Claims (1)

1. a kind of desulfurization wastewater resource utilization process system, this system mainly includes waste water tank, waste-water vortex device, efficiently clarification Device, clarifier, pre-concentration device, ceramic membrane, HIRO, electrolysis unit, clear water reserviors, vacuum belt machine, flocculation aid chemicals dosing plant, hydrogen Sodium oxide molybdena chemicals dosing plant, composite flocculation agent chemicals dosing plant, carbon dioxide chemicals dosing plant, soda ash chemicals dosing plant, to guarantee this technique The operation steady in a long-term of system further includes related matched cleaning device, chemicals dosing plant, electrical system and instrument control, spy Sign is:
(1) flocculation aid chemicals dosing plant accesses waste water tank by pipeline, and waste water tank is equipped with blender, is connected to by pump and pipeline useless Water cyclone;
(2) it is set before high-efficiency clarifier there are two quick agitator tank, agitator tank is interior to be equipped with deflector and guide shell, sodium hydroxide dosing Device is connected to the first quick agitator tank, and composite flocculation agent chemicals dosing plant is connected to second quick agitator tank, and waste water successively connects After connecing the first, second quick agitator tank, subsequently into high-efficiency clarifier, guide shell is set in high-efficiency clarifier, rotating flow guidance plate, two Carbonoxide chemicals dosing plant is connected by pipeline with the perforated pipe of bottom of clarifier;
(3) clarifier passes through pipeline, pump, valve and pre-concentration device, ceramic membrane, the connection of soda ash chemicals dosing plant;
(4) HIRO uses rolled film, and vertical series connection can be used with specific reference to water quality using vertical encapsulation, and maximum is no more than 7, Electronic anti-scaling agent, ultraviolet sterilizer are set simultaneously;
(5) HIRO production water enters clear water reserviors, and concentrated water connects electrolysis unit by pipeline;
(6) spoil disposal of high-efficiency clarifier and clarifier connects vacuum belt machine, separates, is arranged with the feed liquor of gypsum cyclone After gypsum cyclone underflow.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110217919A (en) * 2019-07-09 2019-09-10 北京朗新明环保科技有限公司 A kind of desulfurization wastewater low cost resource utilization system and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110217919A (en) * 2019-07-09 2019-09-10 北京朗新明环保科技有限公司 A kind of desulfurization wastewater low cost resource utilization system and method

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Address after: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee after: Guoneng Lang Xinming Environmental Protection Technology Co.,Ltd.

Address before: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee before: BEIJING LUCENCY ENVIRO-TECH Co.,Ltd.

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Address after: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee after: Guoneng Water Environmental Protection Co.,Ltd.

Country or region after: China

Address before: 100039 6th floor, building 1, yard 16, West Fourth Ring Middle Road, Haidian District, Beijing

Patentee before: Guoneng Lang Xinming Environmental Protection Technology Co.,Ltd.

Country or region before: China