CN208292725U - A kind of supercritical fluid water oxygen wastewater treatment equipment - Google Patents
A kind of supercritical fluid water oxygen wastewater treatment equipment Download PDFInfo
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- CN208292725U CN208292725U CN201820446346.8U CN201820446346U CN208292725U CN 208292725 U CN208292725 U CN 208292725U CN 201820446346 U CN201820446346 U CN 201820446346U CN 208292725 U CN208292725 U CN 208292725U
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- wastewater treatment
- supercritical fluid
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- treatment equipment
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Abstract
The utility model provides a kind of supercritical fluid water oxygen wastewater treatment equipment, the supercritical fluid water oxygen wastewater treatment equipment includes waste water pump, oxidation liquid pump, pure water pump, tubular reactor, the waste water pump, oxidation liquid pump, pure water pump access the tubular reactor after connecing with preheater tube, the waste water pump, oxidation liquid pump, pure water pump delivery outlet be connected to check valve, the lower end of the tubular reactor is equipped with the cooling chamber being connected to the inner cavity of the tubular reactor.Beneficial effect, present apparatus wastewater treatment is thorough, the oxidation operation in waste water sufficiently can be reached pure state, not will cause environmental pollution after discharge.
Description
Technical field
The utility model relates to sewage treatment equipments, and in particular to a kind of supercritical fluid water oxygen wastewater treatment equipment.
Background technique
Contain a large amount of organic matter in industrial wastewater, using oxidant by the oxidation operation in waste water, it is possible to reduce useless
The ingredient of Organic substance in water.So that discharged wastewater met the national standard, reduces the pollution to environment.Existing technology needs to provide a kind of utilization
The new device of the supercritical technology processing waste water of water.
Summary of the invention
The utility model overcomes the shortcomings of that background technique provides a kind of supercritical fluid water oxygen wastewater treatment equipment, this
Device wastewater treatment is thorough, the oxidation operation in waste water sufficiently can be reached pure state, not will cause environment after discharge
Pollution.
The utility model provides following technical proposals: a kind of supercritical fluid water oxygen wastewater treatment equipment, described super
Critical fluids water oxygen wastewater treatment equipment includes waste water pump 1, oxidation liquid pump 2, pure water pump 3, tubular reactor 4, the waste water
Pump 1, oxidation liquid pump 2, pure water pump 3 access the tubular reactor 4, the waste water pump 1, oxidation solution after connecing with 5 pipe of preheater
The delivery outlet for pumping 2, pure water pump 3 is connected to check valve 6, and the lower end of the tubular reactor 4 is equipped with and the tubular reactor 4
The cooling chamber 7 of inner cavity connection, the cooling chamber 7 and the input end pipe of cooler 8 connect, and the output end pipe of the cooler 8 connects back
Gas separator 10 is accessed after pressure valve 9.
The input terminal of the preheater 5 is equipped with hand-operated valve 11.
The preheating temperature of the preheater 5 is 500 degrees Celsius.
The entrance of the tubular reactor 4 is equipped with the first thermal detector 12, and reactor upper, middle and lower portion is respectively equipped with the
The upper and lower part of two thermal detectors 13, third thermal detector 14, the 4th thermal detector 15, the cooler 8 is equipped with the 5th thermal detector respectively
16, the 6th thermal detector 17.
The tubular reactor 4 uses Split heating furnace heat temperature raising, and Split heating furnace is divided to two sections of temperature controls.
The utility model has the beneficial effects that supercritical water is fabulous solvent to organic matter and oxygen, therefore organic matter
Oxidation can be carried out in oxygen-enriched homogeneous phase, there is no the limitations that generate due to needing mutually to ask transfer for reaction.Meanwhile 400
~600 DEG C of high reaction temperature also accelerates reaction speed, can reach 99% or more within several seconds reaction time
Destructive rate.The oxidation reaction that organic matter carries out in supercritical water.The oxidation operation in waste water sufficiently can be reached pure
State not will cause environmental pollution after discharge.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model supercritical fluid water oxygen wastewater treatment equipment.
Specific embodiment
The utility model is further described below in conjunction with attached drawing and specific embodiment.
In Fig. 1: waste water pump 1, oxidation liquid pump 2, pure water pump 3, tubular reactor 4, preheater 5, check valve 6, cooling chamber 7,
Cooler 8, counterbalance valve 9, gas separator 10, hand-operated valve 11, the first thermal detector 12, the second thermal detector 13, third thermal detector 14,
4th thermal detector 15, the 5th thermal detector 16, the 6th thermal detector 17.
A kind of supercritical fluid water oxygen wastewater treatment equipment, the supercritical fluid water oxygen wastewater treatment equipment include
Waste water pump 1, oxidation liquid pump 2, pure water pump 3, tubular reactor 4, the waste water pump 1, oxidation liquid pump 2, pure water pump 3 are and preheater
5 pipes access the tubular reactor 4 after connecing, the waste water pump 1, oxidation liquid pump 2, pure water pump 3 delivery outlet be connected to check valve
6, the lower end of tubular reactor 4 is equipped with the cooling chamber 7 being connected to the inner cavity of the tubular reactor 4, cooling chamber 7 and cooler 8
Input end pipe connect, the output end pipe of cooler 8, which connects, accesses gas separator 10 after counterbalance valve 9.Organic matter in waste water is in institute
It states in tubular reactor 4 and oxidation reaction occurs under the oxidant high temperature and pressure of supercritical water, the organic matter in waste water for being
It is oxidized to gaseous state, is separated in gas separator, counterbalance valve 9 is for regulating and controlling the outlet pressure of cooling chamber.Gas passes through gas
Body separator 10 is released, and liquid is released by counterbalance valve 9.
Further, the input terminal of the preheater 5 is equipped with hand-operated valve 11.It timely can be connected and be truncated according to demand liquid
Stream.
Further, the preheating temperature of the preheater 5 is 500 degrees Celsius.Water body is got into supercriticality.The temperature of water body
Degree increases, and pressure also rises with it.
Further, the entrance of the tubular reactor 4 is equipped with the first thermal detector 12, reactor upper, middle and lower portion difference
Equipped with the second thermal detector 13, third thermal detector 14, the 4th thermal detector 15, the upper and lower part of the cooler 8 is equipped with the 5th survey respectively
Warm device 16, the 6th thermal detector 17.Different depth is observed using the second thermal detector 13, third thermal detector 14, the 4th thermal detector 15
Under, if all reach supercriticality, it is ensured that chemical reaction it is comprehensive.
Further, the tubular reactor 4 uses Split heating furnace heat temperature raising, and Split heating furnace is divided to two sections of temperature
Control.
It is so-called overcritical, refer to a kind of special state of flowing material.When the fluid increasing temperature and pressure for being in vapor-liquid equilibrium
When, thermal expansion causes fluid density to reduce, and the raising of pressure makes the phase interface of vehicle repair major disappear, and becomes homogeneous system,
Here it is critical points.It is known as when the temperature of fluid, pressure are respectively higher than critical-temperature and critical pressure in supercritical state
State.Supercritical fluid has the good fluidity of similar gas, but density is much larger than gas again, therefore has many unique reasons
Change property.
The critical point of water is 374.3 DEG C of temperature, pressure 22.064MPa, if by the temperature of water, pressure rise to critical point
More than, as supercritical water, the basic performances such as density, viscosity, conductivity, dielectric constant have very big difference with light water,
Show the property similar to nonpolar organic compound.Therefore, supercritical water can be complete with apolar substance and other organic matters
It dissolves each other entirely, and inorganic matter especially salt, the dissociation constant and solubility in supercritical water are but very low.Meanwhile supercritical water
It can dissolve each other completely with gases such as air, oxygen, nitrogen and carbon dioxide.
Since supercritical water is fabulous solvent to organic matter and oxygen, the oxidation of organic matter can be oxygen-enriched
It is carried out in homogeneous phase, there is no the limitations generated because needing mutually to ask transfer for reaction.Meanwhile 400~600 DEG C of high reaction temperature
Also accelerate reaction speed, can reach 99% or more destructive rate within several seconds reaction time.Organic matter faces super
The oxidation reaction carried out in boundary's water.
Claims (5)
1. a kind of supercritical fluid water oxygen wastewater treatment equipment, which is characterized in that at the supercritical fluid water oxidized waste water
Reason device includes waste water pump (1), oxidation liquid pump (2), pure water pump (3), tubular reactor (4), the waste water pump (1), oxidation solution
Pump (2), pure water pump (3) access the tubular reactor (4) after connecing with preheater (5) pipe, the waste water pump (1), oxidation solution
Pump (2), pure water pump (3) delivery outlet be connected to check valve (6), the lower end of the tubular reactor (4) is equipped with and the tubular type
The cooling chamber (7) of the inner cavity connection of reactor (4), the cooling chamber (7) and the input end pipe of cooler (8) connect, the cooling
The output end pipe of device (8) connects counterbalance valve (9) and accesses gas separator (10) afterwards.
2. a kind of supercritical fluid water oxygen wastewater treatment equipment according to claim 1, which is characterized in that the preheater
(5) input terminal is equipped with hand-operated valve (11).
3. a kind of supercritical fluid water oxygen wastewater treatment equipment according to claim 1, which is characterized in that the preheater
(5) preheating temperature is 500 degrees Celsius.
4. a kind of supercritical fluid water oxygen wastewater treatment equipment according to claim 1, which is characterized in that the tubular type is anti-
The entrance of device (4) is answered to be equipped with the first thermal detector (12), reactor upper, middle and lower portion is respectively equipped with the second thermal detector (13), the
The upper and lower part of three thermal detectors (14), the 4th thermal detector (15), the cooler (8) is equipped with the 5th thermal detector (16), the 6th respectively
Thermal detector (17).
5. a kind of supercritical fluid water oxygen wastewater treatment equipment according to claim 1, which is characterized in that the tubular type is anti-
Answer device (4) using Split heating furnace heat temperature raising, Split heating furnace is divided to two sections of temperature controls.
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CN201820446346.8U CN208292725U (en) | 2018-04-01 | 2018-04-01 | A kind of supercritical fluid water oxygen wastewater treatment equipment |
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CN201820446346.8U CN208292725U (en) | 2018-04-01 | 2018-04-01 | A kind of supercritical fluid water oxygen wastewater treatment equipment |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108217910A (en) * | 2018-04-01 | 2018-06-29 | 南通市华安超临界萃取有限公司 | A kind of supercritical fluid water oxygen wastewater treatment equipment |
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2018
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108217910A (en) * | 2018-04-01 | 2018-06-29 | 南通市华安超临界萃取有限公司 | A kind of supercritical fluid water oxygen wastewater treatment equipment |
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