CN208275377U - A kind of overflow gas-liquid allotter and its hydrogenator - Google Patents

A kind of overflow gas-liquid allotter and its hydrogenator Download PDF

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CN208275377U
CN208275377U CN201820421161.1U CN201820421161U CN208275377U CN 208275377 U CN208275377 U CN 208275377U CN 201820421161 U CN201820421161 U CN 201820421161U CN 208275377 U CN208275377 U CN 208275377U
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outer barrel
liquid
cone
gas
overflow gas
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周帅
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Dalian Ruibang Shihua Technology Co Ltd
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Dalian Ruibang Shihua Technology Co Ltd
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Abstract

The application provides a kind of overflow gas-liquid allotter and its hydrogenator, overflow gas-liquid allotter includes central tube, outer barrel, splashes cone and connecting rod, central tube is placed at outer barrel center, central tube as gas phase channel, necking down nozzle is arranged in its underpart, the purpose for improving gas velocity is realized, convenient for dispelling drop;The top of outer barrel is provided with the first tooth socket, effectively avoids the Biased flow phenomenon generated by tray level degree problem, improves the evenly distributed degree of material;The bottom end of outer barrel is provided with Taper Pipe, can produce splash fluidised form, liquid phase stream is hit scattered, provides bigger dispersion domain;Therefore, the overflow gas-liquid allotter is simple with structure, pressure drop is small, the more operating condition of mechanical admixture, metal sulfide and coke powder suitable for coal tar, pressure drop caused by can effectively eliminating because of dirt blocking generates, because of the bias current problem that tray level degree generates, the stabilization long-term operation of hydrogenator is ensured.

Description

A kind of overflow gas-liquid allotter and its hydrogenator
Technical field
The application belongs to field of chemical equipment, and in particular to a kind of overflow gas-liquid allotter and its hydrogenator.
Background technique
Since oil hydrogenation process is exothermic reaction, feedstock oil is unevenly distributed on 303 radial section of catalyst bed, It is violent to will lead to the good position extent of reaction of catalyst irrigation effect, it is more to generate heat;Catalyst local temperature is higher, reaction Rate is faster, and the superposition of the two effect will form heat spot, makes this partial catalyst performance premature inactivation, damages the property of catalyst Can, the coking, hardened of catalysing area subregion is resulted even in, material can not normally flow through, and catalyst is ineffective below, To substantially reduce the service life of catalyst and the on-stream time of device.
Coal tar is one of the liquid product that coal obtains in destructive distillation, gasification or pyrolytic process, containing a large amount of alkene, The unsaturated hydrocarbons such as polycyclic aromatic hydrocarbon and sulphur, nitrogen compound, acidity is high, gum level is high, product roadholding is poor, is unable to satisfy The requirement used as fuel oil.Coal tar is handled using hydrogenation modifying process, that is, in certain temperature, pressure and urge Under agent effect, achievable desulfurization, unsaturated hydrocarbons saturation, denitrification reaction, aromatic hydrocarbons saturation, reaching improves its stability, reduces sulphur The purpose of content and arene content, final to obtain naphtha and high-grade fuel oil, product quality can achieve gasoline, diesel oil tune And oil index.
Since coal tar acidity is high, causes equipment to be corroded, generate a large amount of oil soluble metal ions, in high temperature, high pressure, face hydrogen Metal sulfide is generated under operating condition;In addition, powdered dirt is generated under worst hot case rich in burnt matter in coal tar, it is conventional Bubble cap distributor is based on suction principle, and the dirt of deposition usually floods bubble cap distributor, the pressure drop for causing distribution plate to carry Beyond Design cooling load, distribution plate is caused to collapse.Therefore, overflow gas-liquid allotter, overflow be can choose under this working environment Gas-liquid allotter is not easy pressure drop caused by being blocked by dirt.
Existing overflow gas-liquid allotter as shown in Figure 1, generally include open at both ends and place vertically overflow pipe 101, Several slime flux mouths 102 for being set on 101 tube body of overflow pipe and the stream breaker for being set to 101 bottom end open-mouth of overflow pipe 103.When normal operation, liquid phase stream enters the overflow pipe 101 from the slime flux mouth 102, spacious from 101 bottom end of overflow pipe It is flowed out at mouthful, gaseous stream enters from the 101 top open-mouth of overflow pipe, and gas-liquid two-phase occurs in the overflow pipe 101 First time collisional mixing cocurrent is downward, and second of collisional mixing baffling occurs at the stream breaker 103 and is diffused into catalyst bed The surrounding of layer 303, realizes evenly distributing for liquid phase.
But above-mentioned overflow gas-liquid allotter is at work, is to be fixed on several above-mentioned overflow gas-liquid allotters to add On column plate in hydrogen reactor, except 101 bottom end of overflow pipe is open and stream breaker 103 is below column plate, remaining part is in column plate Top.If accumulated in the liquid level difference of the liquid phase on column plate or when column plate tilts, the week of liquid level higher position It encloses overflow gas-liquid allotter and overflow first occurs, overflow occurs after surrounding's overflow gas-liquid allotter of liquid level lower or cannot overflow Stream causes gas-liquid between overflow gas-liquid allotter to be distributed uneven, Biased flow phenomenon occurs.
Utility model content
In view of the deficiencies of the prior art, the utility model provides a kind of overflow gas-liquid allotter, by several overflow gas-liquids Distributor is fixed on tower tray, is constituted reactor distribution plate, is mounted in reactor, realizes material on reactor water plane section Evenly distribute, to solve the problem of that the distribution of existing overflow gas-liquid allotter is uneven or even bias current occurs.
A kind of overflow gas-liquid allotter, including hollow central tube and the outer barrel being sheathed on outside the central tube, Be provided with below the outer barrel and splash cone, the outer barrel with it is described splash to bore connect by connecting rod;
The central tube at least one end is set to inside the outer barrel;
The barrel top of the outer barrel is provided with the first tooth socket, and the barrel bottom end of the outer barrel is provided with Taper Pipe;
The internal diameter of the Taper Pipe is gradually reduced from the one end being connected with outer barrel to free end;
The outer diameter for splashing cone close to Taper Pipe one end to far from Taper Pipe one end from being gradually increased.
Further, the center line of the central tube is overlapped with the center line line of the outer barrel.
Further, the central tube bottom end is provided with necking down nozzle, and the necking down nozzle is located in the outer barrel, institute It states central tube top and stretches out outer barrel top.
Further, the bottom end of the Taper Pipe is provided with the second tooth socket.
Further, the slot tooth of first tooth socket is triangle, square, rectangle or semicircle, second tooth socket Slot tooth be triangle.
Further, the bus of the Taper Pipe and it is described splash element of a cone splashed described in the angle of vertex of a cone angular direction be 10 °- 90 °, the apex angle for splashing cone 203 is 90 ° -170 °.
Further, the bus of the Taper Pipe and it is described splash element of a cone splashed described in the angle of vertex of a cone angular direction be 50 °- 70 °, the apex angle for splashing cone 203 is 100 ° -150 °.
The application also provides a kind of hydrogenator, overflow gas-liquid allotter including any one of above scheme and Tower tray;
The top of the outer barrel is located at the top of the tower tray, and the bottom end of the outer barrel is located under the tower tray Side;
Multiple overflow gas-liquid allotters are fixed on tower tray and constitute distribution plate, the distribution plate is located at described plus hydrogen Top gas-liquid entrance in reactor and between catalyst bed.
Further, the overflow gas-liquid allotter is arranged in several rows, and triangular in shape, four sides on the tower tray Shape, diamond shape or circular arrangement.
Further, overflow gas-liquid allotter quincuncial arrangement on the tower tray.
As known from the above, the application provides a kind of overflow gas-liquid allotter and its hydrogenator, overflow gas-liquid allotter Including central tube, outer barrel, cone and connecting rod are splashed, central tube is placed at outer barrel center, as the central tube of gas phase channel, Necking down nozzle is arranged in lower part, the purpose for improving gas velocity is realized, convenient for dispelling drop;The first tooth is provided on the top of outer barrel Slot effectively avoids the Biased flow phenomenon generated by tray level degree problem, improves the evenly distributed degree of material;The bottom end of outer barrel is arranged There is Taper Pipe, can produce splash fluidised form, liquid phase stream is hit scattered, provides bigger dispersion domain.Therefore, the overflow gas-liquid allotter It is simple with structure, pressure drop is small, the more operating condition of the mechanical admixture, metal sulfide and coke powder suitable for coal tar, can Pressure drop caused by effectively eliminating because of dirt blocking generates, and because of the bias current problem that tray level degree generates, ensures hydrogenator Stabilization long-term operation.
Detailed description of the invention
Fig. 1, existing overflow gas-liquid allotter structural schematic diagram;
Fig. 2, the overflow gas-liquid allotter structural schematic diagram of the utility model;
Fig. 3, a kind of tooth slot structure schematic diagram of the utility model;
Fig. 4, a kind of overflow working method schematic diagram of the utility model;
Fig. 5, a kind of distribution map of the overflow gas-liquid allotter of the utility model on tower tray;
Fig. 6, a kind of hydrogenator structural schematic diagram of the utility model.
Wherein, 101- overflow pipe, 102- slime flux mouth, 103- stream breaker, 200- overflow gas-liquid allotter, 201- central tube, 2011- air inlet, 2012- necking down nozzle, 202- outer barrel, the first tooth socket of 2021-, 2022- Taper Pipe, the second tooth socket of 2023-, 203- splashes cone, 204- connecting rod, 3- hydrogenator, 301- tower tray, 302- distribution plate, 303- catalyst bed.
Specific embodiment
Below in conjunction with the attached drawing in the embodiment shown in the embodiment of the present application, to the embodiment shown in the embodiment of the present application In technical solution be clearly and completely described.
As shown in Figure 2 to Figure 3, the overflow gas-liquid allotter 200 of the application includes hollow central tube 201 and is sheathed on institute The outer barrel 202 outside central tube 201 is stated, is provided with below the outer barrel 202 and splashes cone 203, the outer barrel 202 and institute It states and splashes cone 203 and connected by connecting rod 204.
Central tube 201 is the hollow tube of upper lower open mouth, and as gas phase channel, top opening is as gaseous stream entrance Air inlet 2011, outlet of the lower open mouth as gaseous stream.When work, most gaseous streams are from 201 lower end of central tube Open-mouth spray, want to mix with the liquid phase stream in outer barrel 202, drop will be relatively large in diameter and dispel into diameter smaller droplet, And diameter smaller droplet is transported in certain range.
The barrel top of outer barrel 202 is provided with the first tooth socket 2021 on top as slime flux weir, outer barrel 202 Barrel bottom end is provided with Taper Pipe 2022, and the internal diameter of Taper Pipe 2022 is gradually subtracted from the one end being connected with outer barrel 202 to free end It is small;The outer diameter of cone 203 is splashed from being gradually increased close to 2022 one end of Taper Pipe to far from 2022 one end of Taper Pipe, and therefore, vivid sees cone The floor projection of pipe 2022 is inverted trapezoidal.At work, liquid phase material is downward along 202 inner wall of outer barrel by the first tooth socket 2021 Trickling, after flowing on Taper Pipe 2022, since 2022 upper end diameter of Taper Pipe is greater than the diameter of lower end, the reduction meeting of diameter is so that liquid Phase logistics generates splash fluidised form, continuous liquid phase stream is hit scattered, forms drop, then recycles gas that drop is delivered to four Week, so that the range of droplet distribution is wider.
At least one end of central tube 201 is located in outer barrel 202.That is, lower open mouth end is ok on central tube 201 In outer barrel, liquid phase stream flows to lower section along 202 inner wall of outer barrel, and central tube 201 is used as gaseous stream channel, center The diameter of pipe 201 is smaller than the diameter of outer barrel 202, and 201 end portion of central tube is fastened on outer barrel 202 by support frame It is interior.Using central tube 201 and 202 sleeve structure of outer barrel, realize that gas-liquid shunts, the form of liquid phase overflow can adapt to coal tar The working condition that oily metal impurities are more, coke powder is more, overflow gas-liquid allotter 200 are not easy to plug, and distribution plate 302 is avoided to generate Pressure drop.
It splashes cone 203 and 2022 lower section of Taper Pipe is fixed on by connecting rod 204, specifically, connecting rod 204 is L shape, connecting rod 204 One end be connected to the outer wall of outer barrel 202, the other end of connecting rod 204 is connected to the bottom for splashing cone 203, splashes the center of cone 203 The center line of line and Taper Pipe 2022 point-blank, be conducive to drop disperse toward surrounding it is more uniform.
A kind of overflow gas-liquid allotter 200 provided by the utility model, when work, by several above-mentioned overflow gas-liquids point Orchestration 200 is fixed on tower tray 301, is constituted reactor distribution plate 302, is mounted in reactor, realizes material in reactor water Evenly distributing on plane section, as shown in Figure 4.When liquid level is horizontal or when tower tray 301 tilts on tower tray 301, It necessarily will appear the non-uniform situation of liquid level, the liquid level in some places is high, and the liquid level in some places is low, the high place of liquid level First reach the first tooth socket 2021 on the top of outer barrel 202.If no first tooth socket 2022 in 202 top of outer barrel, then its Area of passage is bigger, and therefore, the high local flow velocity of liquid level is larger, and Biased flow phenomenon is than more serious.The outer barrel 202 of the application Top border is provided with several first tooth sockets 2021, when the high place of liquid level reaches the first tooth socket of lowest point on tower tray 301 2021, liquid phase stream starts to carry out overflow from this, since the first tooth socket 2021 reduces area of passage, on tower tray 301 Liquid level it is raised very fast, the liquid level on tower tray 301 will set up balance quickly, and reduction overflow gas-liquid allotter 200 is to tower The dependence of disk levelness, it is ensured that with the presence of liquid phase in the circumferential direction of overflow gas-liquid allotter 200, to improve the distribution of overflow gas-liquid The even macroscopic degree of device 200, avoids Biased flow phenomenon.
Preferably, the center line of central tube 201 is overlapped with the center line of outer barrel 202, so that gaseous stream uniformly sprays To 2022 bottom end of Taper Pipe, be conducive to the even macroscopic degree for improving overflow gas-liquid allotter 200.
Preferably, 201 bottom end of central tube is provided with necking down nozzle 2012, and necking down nozzle 2012 can be in central tube 201 Bottom end fix a conical nozzle;It can also be a part of central tube 201, specially 201 bottleneck upper end of central tube For hollow circular-tube, bottleneck lower end cone.Present invention take advantage of that the stronger characteristic of gas phase compressibility, to realize raising gas velocity Purpose, gaseous stream at necking down nozzle 2012 by being compressed when work, and the gaseous stream speed of ejection significantly improves, more Diameter smaller droplet is dispelled into convenient for drop will be relatively large in diameter, and delivers droplets on and is transported in biggish range, is overflow to improve The service-domain of gas-liquid allotter 200 is flowed, the pressure of distributor is effectively reduced in energy needed for distributor dispersed material is effectively reduced Power drop.More specifically, the height of necking down nozzle 2012 can just allow ejection gaseous stream cover Taper Pipe 2022 bottom end, If the height of necking down nozzle 2012 is too high, the flow velocity for being sprayed onto the gaseous stream of the bottom end of Taper Pipe 2022 will be lower, be unfavorable for by Liquid phase stream dispels into drop, if the height of necking down nozzle 2012 is too low, the gaseous stream of ejection is directly through Taper Pipe 2022 The purpose that liquid phase stream is dispelled into drop is not achieved in bottom end.
Preferably, the floor projection shape of the first tooth socket 2021 is triangle, square, rectangle or semicircle.Wherein The floor projection shape of one tooth socket 2021 is that the effect of triangle is best, and level is just considered as " V " shape.At work, using this The tooth socket of kind " V " shape, area of passage are gradually increased from the bottom up.When liquid level reaches " V " shape bottom, due to this shape First tooth socket, 2021 bottom area of passage very little is more conducive to setting up so the liquid level on tower tray 301 is raised very fast Uniform liquid level, so that the even macroscopic degree of overflow gas-liquid allotter 200 be greatly improved, hardly Biased flow phenomenon.
A kind of preferred embodiment of the utility model is, as shown in Fig. 2, the bottom end border of Taper Pipe 2022 is provided with several second Tooth socket 2023.When continuous liquid flow to the second tooth socket 2023, due to there is gap between the second adjacent tooth socket 2023, one Liquid separation body is flowed down from gap location, and a part flows down after flowing through the second tooth socket 2023, therefore the second tooth socket 2023 can make continuous liquid Phase logistics is converted into discrete fluidised form, is passed through between hole convenient for gaseous stream at this time, so as to gaseous stream and liquid phase stream Mixing, the drop for being formed liquid phase stream after splash, is conducive to the dispersion of gas-liquid.
More specifically, the floor projection shape of the second tooth socket 2023 is triangle, level is just considered as " V " shape.In work When making, using the second tooth socket 2023 of this " V " shape, it is equivalent to and is provided with a circle sawtooth in 2022 bottom end of Taper Pipe.Work as liquid flow When through the second tooth socket 2023, since " V " shape texture grooves and convex portion have corner angle, although liquid phase stream has certain Surface tension, but be easy to puncture liquid film in edges and corners, it is more easier to convert discrete fluidised form for continuous liquid phase stream, more Be conducive to the dispersion of gas-liquid.
Another preferred embodiment of the utility model is that the bus of Taper Pipe 2022 is pushed up with the bus for splashing cone 203 along cone 203 is splashed The angle of angular direction is 10 ° -90 °, and the apex angle for splashing cone 203 is 90 ° -170 °.Specifically, when drop is from the bottom end of Taper Pipe 2022 At an angle hit splashes cone 203 after ejection, after drop, which bumps against, splashes cone 203, since the speed of drop is larger, has certain Impact force, drop can further fragmentation, formed the smaller drop of partial size.In addition drop is touched at an angle with cone 203 is splashed It hits, tiny drop can not only be formed under the influence of the impact force, and the drop after collision can be to splash 203 buses of cone Normal is that center line is reflected, and having can collide between certain angle and the droplet of speed again, generate more refinement Small drop.Drop can be oriented to farther place by the corner angle for splashing cone 203, realize the more uniform of droplet distribution.
More specifically, the bus of Taper Pipe 2022 with splash the bus of cone 203 along the angle for splashing 203 apex angle directions of cone be 50 °- 70 °, the apex angle for splashing cone 203 is 100 ° -150 °.If the bus of Taper Pipe 2022 splashes 203 apex angle directions of cone with the bus edge for splashing cone 203 Angle it is too small, then angle after droplet collision, close to the bus for splashing cone 203, dispersion is closer;If Taper Pipe 2022 Bus and the bus for splashing cone 203 are excessive along the angle for splashing 203 apex angle directions of cone, although the dynamics of collision is bigger, after collision Liquid drop speed loss it is larger, be also unfavorable for being distributed to farther place, thus above range setting Taper Pipe 2022 and splash cone 203 can make the dispersion effect of drop preferable.
The application also provides a kind of hydrogenator 3, as shown in fig. 6, including overflowing in above-mentioned any one technical solution Flow gas-liquid allotter 200 and tower tray 301.As shown in Figure 4 and Figure 5, it is offered on tower tray 301 and 202 size phase of outer barrel The mounting hole matched, outer barrel 202 are passed through mounting hole, are fixed on tower tray 301 by the way of welding, wherein outer barrel 202 Top is located at the top of tower tray 301, and the bottom end of outer barrel 202 is located at the lower section of tower tray 301.By multiple overflow gas-liquid allotters 200, which are fixed on composition distribution plate 302, distribution plate 302 on tower tray 301, is located at the top gas-liquid entrance in the hydrogenator 3 Between catalyst bed 303.Overflow gas-liquid allotter 200 is arranged in several rows on the tower tray 301, and triangular in shape, Quadrangle, diamond shape or circular arrangement, so that droplet distribution is uniform.More specifically, overflow gas-liquid allotter 200 is in the tower Quincuncial arrangement on disk 301 realizes the more uniform of droplet distribution.
3 specific works situation of the application hydrogenator as shown in fig. 6, gas-liquid two-phase logistics from the top of hydrogenator 3 Entrance enter, liquid phase stream is dropped on tower tray 301 under the action of gravitational field, and forms the liquid layer of certain depth, works as liquid When layer reaches certain height, overflow is into outer barrel 202 from from the first tooth socket 2021 for liquid phase stream, and liquid phase stream is along outer barrel 202 inner wall trickles downwards, and after the second tooth socket 2023 by 2022 bottom of Taper Pipe, continuous liquid phase stream can be by the second tooth Slot 2023 punctures, therefore just has gap between liquid phase stream and form discrete fluidised form.Gaseous stream from central tube 201 upper end into Port 2011 enters and moves downward, and when passing through necking down nozzle 2012, gaseous stream is compressed, and flow velocity increases and sprays necking down Nozzle 2012.Gaseous stream blows to liquid phase stream and occurs to collide for the first time, by discrete liquid phase stream, dispels into drop state, And carrier's drop blows to and splashes cone 203, is diffused into catalyst splashing second of collisional mixing baffling of gas-liquid two-phase generation at cone 203 The surrounding of bed 303 realizes evenly distributing for liquid phase.
To sum up, the distributor of the overflow gas-liquid allotter 200 of the application is simple with structure, pressure drop is small, is suitable for coal The more operating condition of mechanical admixture, metal sulfide and coke powder in tar, pressure drop caused by can effectively eliminating because of dirt blocking It generates, because of the bias current problem that 301 levelness of tower tray generates, ensures the stabilization long-term operation of hydrogenator 3.
Those skilled in the art will readily occur to its of the application after considering specification and practicing application disclosed herein Its embodiment.This application is intended to cover any variations, uses, or adaptations of the application, these modifications, purposes or Person's adaptive change follows the general principle of the application and including the undocumented common knowledge in the art of the application Or conventional techniques.The description and examples are only to be considered as illustrative, and the true scope and spirit of the application are by following Claim is pointed out.
It should be understood that the application is not limited to the precise structure that has been described above and shown in the drawings, and And various modifications and changes may be made without departing from the scope thereof.Scope of the present application is only limited by the accompanying claims.

Claims (10)

1. a kind of overflow gas-liquid allotter, which is characterized in that including hollow central tube (201) and be sheathed on the central tube (201) external outer barrel (202) is provided with below the outer barrel (202) and splashes cone (203), the outer barrel (202) and Described splash cone (203) are connected by connecting rod (204);
It is internal that the central tube (201) at least one end is set to the outer barrel (202);
The barrel top of the outer barrel (202) is provided with the first tooth socket (2021), and the barrel bottom end of the outer barrel (202) is set It is equipped with Taper Pipe (2022);
The internal diameter of the Taper Pipe (2022) is gradually reduced from the one end being connected with outer barrel (202) to free end;
The outer diameter for splashing cone (203) close to Taper Pipe (2022) one end to far from Taper Pipe (2022) one end from being gradually increased.
2. overflow gas-liquid allotter according to claim 1, which is characterized in that the center line of the central tube (201) with The center line of the outer barrel (202) is overlapped.
3. overflow gas-liquid allotter according to claim 2, which is characterized in that central tube (201) bottom end is provided with Necking down nozzle (2012), the necking down nozzle (2012) are located in the outer barrel (202), and central tube (201) top is stretched Outer barrel (202) top out.
4. according to claim 1, overflow gas-liquid allotter described in 2,3 any one, which is characterized in that the Taper Pipe (2022) Bottom end be provided with the second tooth socket (2023).
5. overflow gas-liquid allotter according to claim 4, which is characterized in that the slot tooth of first tooth socket (2021) is Triangle, square, rectangle or semicircle, the slot tooth of second tooth socket (2023) are triangle.
6. overflow gas-liquid allotter according to claim 4, which is characterized in that the bus of the Taper Pipe (2022) with it is described It is 10 ° -90 ° that the bus for splashing cone (203), which splashes the angle in cone (203) apex angle direction described in, and the apex angle for splashing cone (203) is 90°-170°。
7. overflow gas-liquid allotter according to claim 6, which is characterized in that the bus of the Taper Pipe (2022) with it is described It is 50 ° -70 ° that the bus for splashing cone (203), which splashes the angle in cone (203) apex angle direction described in, and the apex angle for splashing cone (203) is 100°-150°。
8. a kind of hydrogenator, which is characterized in that the overflow gas-liquid allotter (200) including claim 1-7 any one And tower tray (301);
The top of the outer barrel (202) is located at the top of the tower tray (301), and the bottom end of the outer barrel (202) is located at institute State the lower section of tower tray (301);
Multiple overflow gas-liquid allotters (200) are fixed on composition distribution plate (302), the distribution plate on tower tray (301) (302) it is located between the top gas-liquid entrance and catalyst bed (303) in the hydrogenator.
9. hydrogenator according to claim 8, which is characterized in that the overflow gas-liquid allotter (200) is described Several rows, and triangular in shape, quadrangle, diamond shape or circular arrangement are arranged on tower tray (301).
10. hydrogenator according to claim 9, which is characterized in that the overflow gas-liquid allotter (200) is described Quincuncial arrangement on tower tray (301).
CN201820421161.1U 2018-03-27 2018-03-27 A kind of overflow gas-liquid allotter and its hydrogenator Active CN208275377U (en)

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CN113070002A (en) * 2021-03-03 2021-07-06 中国石油化工股份有限公司 Gas-liquid distribution equipment
CN113070001A (en) * 2021-03-03 2021-07-06 中国石油化工股份有限公司 Gas-liquid distribution device
CN113754084A (en) * 2020-06-05 2021-12-07 松江土建株式会社 Gas-liquid dissolving device
CN114570290A (en) * 2022-03-17 2022-06-03 海南贝朗生物科技有限公司 Method for prolonging operation period of hydrogenation device
CN114923118A (en) * 2022-05-19 2022-08-19 中康长和健康科技(深圳)有限公司 Metal hydride hydrogen storage tank
CN115814470A (en) * 2023-02-22 2023-03-21 森诺科技有限公司 Adjustable oil collecting device for oil removal tank or air-floating tank

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113754084A (en) * 2020-06-05 2021-12-07 松江土建株式会社 Gas-liquid dissolving device
CN113754084B (en) * 2020-06-05 2024-03-29 松江土建株式会社 Gas-liquid dissolving device
CN113070002A (en) * 2021-03-03 2021-07-06 中国石油化工股份有限公司 Gas-liquid distribution equipment
CN113070001A (en) * 2021-03-03 2021-07-06 中国石油化工股份有限公司 Gas-liquid distribution device
CN113070002B (en) * 2021-03-03 2022-10-14 中国石油化工股份有限公司 Gas-liquid distribution apparatus
CN114570290A (en) * 2022-03-17 2022-06-03 海南贝朗生物科技有限公司 Method for prolonging operation period of hydrogenation device
CN114570290B (en) * 2022-03-17 2023-10-17 上海科瑞德能源科技有限公司 Method for prolonging operation period of hydrogenation device
CN114923118A (en) * 2022-05-19 2022-08-19 中康长和健康科技(深圳)有限公司 Metal hydride hydrogen storage tank
CN115814470A (en) * 2023-02-22 2023-03-21 森诺科技有限公司 Adjustable oil collecting device for oil removal tank or air-floating tank

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