CN208271934U - A kind of package support of high photosynthetic efficiency ultraviolet LED - Google Patents

A kind of package support of high photosynthetic efficiency ultraviolet LED Download PDF

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Publication number
CN208271934U
CN208271934U CN201820481035.5U CN201820481035U CN208271934U CN 208271934 U CN208271934 U CN 208271934U CN 201820481035 U CN201820481035 U CN 201820481035U CN 208271934 U CN208271934 U CN 208271934U
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CN
China
Prior art keywords
tablet
enclosing
ultraviolet led
ceramic substrate
chip
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201820481035.5U
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Chinese (zh)
Inventor
曾祥华
何苗
郭玉国
胡建红
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Jiangsu Hongli China Ze Photoelectric Technology Co Ltd
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Jiangsu Hongli China Ze Photoelectric Technology Co Ltd
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Priority to CN201820481035.5U priority Critical patent/CN208271934U/en
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Expired - Fee Related legal-status Critical Current
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Abstract

The utility model discloses a kind of package supports of high photosynthetic efficiency ultraviolet LED, including plane ceramic substrate, and the enclosing tablet with reflector, the reflector inwall surface is vapor-deposited with fine aluminium mirror surface film and is covered with magnesium fluoride protective film;The enclosing tablet is thermoset epoxy capsulation material, which presses with ceramic substrate bonding;The chip of the ultraviolet LED is fixed on the ceramic substrate in reflector, and the chip of the LED includes positive and negative electrode, and positive and negative anodes connection is completed on ceramic substrate.The reflector plastics enclosing tablet that aluminium film is deposited by the way that surface is arranged on ceramic substrate, is remarkably improved the extracting power of UV LED chip side light, while by ceramic substrate to chip cooling, while guaranteeing the reliability of device performance.

Description

A kind of package support of high photosynthetic efficiency ultraviolet LED
Technical field
The present invention relates to ultraviolet LED encapsulation field, specifically a kind of package support of high photosynthetic efficiency ultraviolet LED.
Background technique
As LED technology continues to develop, the emission wavelength of LED is extended to deep ultraviolet band via visible light wave range, purple A branch of the outer LED as LED, it has high surface light emissions intensity, is widely applied to the neck such as hardening of resin, printing Domain, and towards market developments such as sterilization, disinfections, the application of ultraviolet LED is with the maturation of its technology and the reduction of cost, it will more Extensively,
Since there are a large amount of dislocation densities by LED chip epitaxial material ALN for deep ultraviolet (280~100nm of UVC wave-length coverage) Cause LED chip electro-optical efficiency low.Simultaneously because ultraviolet LED has high radiation energy and high calorific value, current envelope Dress form is mainly using the inorganic material such as copper ceramic substrate bracket and quartz glass are covered, although ceramic substrate has very high stabilization Property and heat-sinking capability, but its outer wall copper clad layers is very low to the short-wavelength light reflectivity of deep ultraviolet LED, causes its secondary heat absorption same When side light cannot efficiently use, as Chinese patent (application number CN201710334523) discloses a kind of encapsulation of ultraviolet LED Device, the groove that aluminium oxide ceramic substrate is equipped with have reflecting cup structure, and side wall is inclined surface, the smooth table formed with copper coating Face can effectively reflect ultraviolet light.Therefore the efficiency of light extraction and heat dissipation for improving deep ultraviolet LED encapsulation, are ultraviolet LED encapsulation fields Emphasis direction.
With advancing by leaps and bounds for semiconductor technologies, other than filling photoelectric characteristic of the part with various semiconductor materials, mirror Face metallic reflective coating also plays the part of considerable status.It can reflect back incident laser energy major part or almost all, plating The common material of metallic reflective coating processed has aluminium (A1), silver-colored (Ag), golden (Au) etc., and aluminium film is that all have from ultra-violet (UV) band to infrared region very The sole material of high reflectance, reflectivity are about 90% or so.Its advantage is that being easily worked, reflectivity is high and is not easy burn into exists Reflectivity in humid air can remain unchanged for a long period of time etc..
Since most metal films are all relatively soft, it is easily damaged, so usually add plating layer protecting film again outside metal film, this Sample can improve intensity and protect metal film not by atmospheric corrosion.But it has plated protective film back reflection rate and has had certain decline, Most common protective film is silicon monoxide, aluminium oxide etc..But as the aluminium film in ultraviolet reflectance face cannot with silicon monoxide or Aluminium oxide is as protective film, because it has significant absorption in ultra-violet (UV) band, and uses magnesium fluoride or lithium fluoride as preventing alumina Protective film, then can be very good control aluminium film reflectivity decline.
Chinese patent, application number: CN201320794398 discloses a kind of LED package support of all-metal structure, the branch The rack body (1) with spill reflector (11) is made of metal plate for frame;It is opposite two with high temperature insulation adhesive layer (2) The upper surface that independently separated sheet metal (3) is fixed on the rack body (1) forms one and has under the conditions of insulation protection The integrated all-metal LED package support of input and output electrode;LED chip (4) is fixed on the spill reflector (11) Upper surface, described two sheet metals (3) form electrical connection between the one end and LED chip (4) of LED chip (4);Or The coating being electrically connected can be done with the LED chip (4) in the upper surface Direct precipitation of the spill reflector (11);The branch The lower surface of frame ontology (1) is welded with heat dissipation metal substrate, and the heat dissipation metal substrate surface has silver, nickel, tin plated material.So And the prior art, although increasing heat dissipation effect, also brings along some potential safety problems due to using metal substrate, together When the structure LED chip light extracting power be also not very high.
Summary of the invention
The purpose of the present invention is in view of the deficienciess of the prior art, providing a kind of LED package support, which is adopted It is remarkably improved deep ultraviolet LED chip light extracting power with new structure, the invention is realized by the following technical scheme:
A kind of package support of high photosynthetic efficiency ultraviolet LED, it is characterized in that: including plane ceramic substrate 301, have reflector 102 enclosing tablet 101,102 inner wall surface of reflector are vapor-deposited with fine aluminium mirror surface film and are covered with magnesium fluoride protective film; The enclosing tablet 101 be thermoset epoxy capsulation material, 101 baseplane of enclosing tablet and ceramic substrate bonding pressing and At;The chip of the ultraviolet LED is fixed on the ceramic substrate in reflector, and the chip of the LED includes positive and negative electrode, Positive and negative anodes connection is completed on ceramic substrate.
Further, groove is arranged in 101 top of enclosing tablet, places quartz glass cover, quartz glass in groove Cover is bonded with groove, and the ultraviolet LED is formed by cutting separation of ceramic and tablet.
Further, the enclosing tablet is designed to that 40-45 degree bell mouth shape reflects cup structure, ultraviolet in favor of reflecting The light of the chip sides of LED;
Further, the enclosing tablet injection temperature 180 degree;Injection pressure 7-18MPa;Time 90-120S;
Further, the mirror metal aluminium layer of the plastics enclosing web surface vapor deposition 99.99%, is deposited cavity inner temperature About 40-50 degree, evaporation rate is greater than 40nm/s, while the pressure of vacuum chamber will maintain 1.3x10-4Pa or lower, and should be as far as possible Reduce the oxidation of aluminium;
Further, mirror surface aluminum layer thickness 1-1.5um is deposited in the enclosing tablet;
Further, the chip peak value with a thickness of ultraviolet LED of magnesium fluoride protective film on aluminium layer is deposited in the enclosing tablet The 1/2 of wavelength, generally 0.12-0.18um, evaporation rate control are 2-5nm/s;
Further, the plastics enclosing tablet adhesive surface finished, which is deposited, to be ground, to remove film plating layer, it is ensured that bonding Intensity.
Further, plastics enclosing tablet need to be bonded with ceramic substrate, and binding material is thermosetting plastics adhesive, Thickness about 20-30um is bonded, is made of following ratio: vinyl acetate resin 40-70%, zinc oxide 5-10%, stearic acid 5- 10%, dimethylbenzene 10-20%, chloroform 10-20%;
Further, plastics enclosing tablet and ceramic substrate bonding, which finish, need to carry out pressing solidification, and press equipment is using true Dead level press, curing time 10-20s.
Further, the anti-UV glue of coating in plastics enclosing tablet upper grooves, the interior quartz glass cover of placing of groove are made For the protection of LED chip.
Compared with prior art, the present invention has the positive effect that:
1, the present invention is bevel structure and its mirror by the way that reflection cup structure enclosing tablet, reflector are arranged on ceramic substrate Face aluminium coated jointly effectively reflects ultraviolet light, can be sufficiently by ultraviolet LED side compared to now plane ceramic encapsulating structure is commonly used The light reflection in face extracts.
2, enclosing tablet of the present invention uses heat cured epoxy material, and thermoset epoxy materials have very strong wetting capacity, Processability is good, and bulk density is easy to be injection moulded greatly, can avoid with LED chip binding site AM aluminum metallization reflecting layer ultraviolet LED radiation damage, while thermosetting plastics splicing easier than thermoplastic.
3, the present invention bonds ceramic substrate using resinoid, and hot setting adhesive is hot, catalyst independent Or a kind of adhesive of chemical bond is formed under synergy, it is not readily dissolved after solidifying, and has good creep-resistant property, each There is good durability in kind heat, cold environment.The bonding is the dissolution that the bond site of plastics to be bonded is micro, is made it combine Strength greatly reinforces, without bonding the problem of falling off after worrying long-time.
4, one layer of fine aluminium mirror surface film is deposited in its surface of enclosing tablet of the present invention, relative to other metal material silver (Ag), for golden (Au), metallic aluminium is all to have very high reflectance from ultra-violet (UV) band to infrared region to ultraviolet reflectivity highest Sole material, reflection and wavelength near linear linear relationship of the aluminium film to light, change rate minimum such as Fig. 6 in visible-range It is shown.
5, the present invention covers magnesium fluoride protective film in fine aluminium film surface, and magnesium fluoride coating securely can be very well as preventing The protective film of alumina can prevent aluminium film from scratching and aoxidizing.Most common protective film is silicon monoxide, but as ultraviolet reflectance face Aluminium film cannot make protective film with silicon monoxide or aluminium oxide because it has significant absorption in ultra-violet (UV) band.
6, it is substrate that the present invention, which can select aluminium nitride or aluminium oxide ceramics according to the watt level of LED chip, as ultraviolet The carrier of LED chip completes circuit connection, has good heat spreading function, avoids UV LED chip heat dissipation is bad from leading to light decay Or initial failure.
Detailed description of the invention
Fig. 1 is the schematic perspective view of the package support of high photosynthetic efficiency ultraviolet LED of the present invention;
Fig. 2, Fig. 3 are 101 plane of enclosing tablet and A-A cross-section structure in the package support of high photosynthetic efficiency ultraviolet LED of the present invention Schematic diagram;
The package support front view of Fig. 4 high photosynthetic efficiency ultraviolet LED;
The package support B-B cross-sectional view of Fig. 5 high photosynthetic efficiency ultraviolet LED;
One layer of fine aluminium mirror surface film is deposited in enclosing web surface in the package support of Fig. 6 high photosynthetic efficiency ultraviolet LED of the present invention, Reflection and wavelength linear relationship of the aluminium film to light in visible-range.
Specific embodiment
In the following with reference to the drawings and specific embodiments, the present invention is furture elucidated, and the present embodiment is with technical solution of the present invention Premised under implemented.
Embodiment:
A kind of package support of high photosynthetic efficiency ultraviolet LED, it is characterized in that: including plane ceramic substrate 301, have reflector 102 enclosing tablet 101,102 inner wall surface of reflector are vapor-deposited with fine aluminium mirror surface film and are covered with magnesium fluoride protective film; The enclosing tablet 101 be thermoset epoxy capsulation material, 101 baseplane of enclosing tablet and ceramic substrate bonding pressing and At;The chip of the ultraviolet LED is fixed on the ceramic substrate in reflector, and the chip of the LED includes positive and negative electrode, Positive and negative anodes connection is completed on ceramic substrate.
Shown in Figure 1, upper part is thermoset epoxy plastic packaging enclosing tablet 101, is equipped with reflector in enclosing tablet 102, enclosing tablet bottom is coated with hot setting adhesive 201, and enclosing tablet and plane ceramic substrate 301 pass through adhesive 201 Bonding presses.
Referring to fig. 2, shown in 3, according to device package dimension and light distribution requirements design reflector 102 and groove 107, reflector It is general to select 40-45 degree beam angle, depth about 0.7mm, upper grooves depth about 0.2mm, the chemical conversion of enclosing tablet selection Hitachi CEL-W-7005 type heat cured epoxy material is injection moulded in injector, injection temperature 180 degree;Injection pressure 7-18MPa;When Between 90-120S.Injection process makes material flow through heated machine barrel, compression removing air and heated material acquisition using a screw rod Low viscosity makes screw rod propelled at high velocity in low viscosity material press-in die with hydraulic, and die cavity pressure if being filled maintains 10-30 seconds, then mold closing mechanism is opened in subsequent release, ejects product.
Injection molding enclosing tablet is placed in vacuum coating equipment, the metallic aluminium of purity 99.99% is heated to 600-1200 degree generates metal vapors and enclosing tablet is deposited, and cavity inner temperature about 40-50 degree is deposited, and evaporation rate is greater than 40nm/s, while the pressure of vacuum chamber will maintain 1.3x10-4Pa or lower, and the oxidation of aluminium, enclosing should be reduced to the greatest extent 103 thickness control of tablet mirror surface aluminium coat is 1-1.5um.
The enclosing tablet of the complete aluminium film of above-mentioned plating is placed in vacuum coating equipment, uses magnesium fluoride as target, evaporation rate 0.12-0.18um magnesium fluoride protective film 104 is deposited in 2-5nm/s in aluminium film.
The back side 106 of enclosing tablet finished is deposited to be ground and cleared up, it is ensured that adhesive surface is peace and quiet, without greasy dirt.
Fig. 4 and Fig. 5 is the plane and B-B the schematic diagram of the section structure of ultraviolet LED package support of the present invention, in enclosing tablet 106 combine 301 position of ceramic substrate, coat the resinoid 201 of 20-30um thickness, answer uniform gluing by maxxaedium, to protect Card infiltration avoids bubble from generating, and adhesive is made of the raw material of following ratio: vinyl acetate resin 40-70%, zinc oxide 5- 10%, stearic acid 5-10%, dimethylbenzene 10-20%, chloroform 10-20%.
Adhesive is so that its glue-line is become the process of solid by chemically and physically acting on, and when solidification applies certain pressure The scattering and permeating for being conducive to adhesive, avoid generate bubble, hole and make glue-line uniformly and fixed with adherend position.Pass through glue Enclosing tablet 101 made of stick 201 bonds and plane ceramic substrate 301 are placed in vacuum laminator for enclosing tablet and ceramics Substrate pressing solidification, curing time 10-20s contact enclosing tablet with plane ceramic substrates into intimate.
It selects suitable UV LED chip 401 to be fixed on the ceramic substrate in reflector, and is completed on ceramic substrate Positive and negative anodes connect work.
Anti- UV glue is coated in enclosing tablet upper grooves 107, is placed quartz glass cover in groove and is solidified, most The uv-LED device is obtained by cutting separation of ceramic and tablet afterwards.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by the limit of above-described embodiment System, other are any without departing from the modification, combination or substitution made under the principle of the present invention, are included in protection scope of the present invention Within.

Claims (6)

1. a kind of package support of high photosynthetic efficiency ultraviolet LED, it is characterized in that: including plane ceramic substrate, the enclosing with reflector Tablet, the reflector inwall surface are vapor-deposited with fine aluminium mirror surface film and are covered with magnesium fluoride protective film;The enclosing tablet is Thermoset epoxy capsulation material, the enclosing tablet baseplane are pressed with ceramic substrate bonding;The chip of the ultraviolet LED is solid Due on the ceramic substrate in reflector, the chip of the LED includes positive and negative electrode, and positive and negative anodes are completed on ceramic substrate and are connected It connects.
2. the package support of high photosynthetic efficiency ultraviolet LED as described in claim 1, it is characterised in that: enclosing tablet top is set Groove is set, places quartz glass cover in groove, quartz glass cover is bonded with groove, and the ultraviolet LED passes through cutting Separation of ceramic and tablet form.
3. the package support of high photosynthetic efficiency ultraviolet LED as described in claim 1, it is characterised in that: the enclosing tablet is designed to 40-45 degree bell mouth shape reflects cup structure, in favor of the light of the chip sides of reflection ultraviolet LED.
4. the package support of high photosynthetic efficiency ultraviolet LED as described in claim 1, it is characterised in that: the vapor deposition of the enclosing tablet Mirror surface aluminum layer thickness 1-1.5um.
5. the package support of high photosynthetic efficiency ultraviolet LED as described in claim 1, it is characterised in that: the vapor deposition of the enclosing tablet The 1/2 of the chip peak wavelength with a thickness of ultraviolet LED of magnesium fluoride protective film on aluminium layer.
6. the package support of high photosynthetic efficiency ultraviolet LED as described in claim 1, it is characterised in that: enclosing tablet top is set Groove is set, groove depth 0.1-0.2mm, the interior setting quartz glass cover of groove is to sealed LED chip.
CN201820481035.5U 2018-04-03 2018-04-03 A kind of package support of high photosynthetic efficiency ultraviolet LED Expired - Fee Related CN208271934U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108321283A (en) * 2018-04-03 2018-07-24 江苏鸿利国泽光电科技有限公司 A kind of package support and its packaging method of specular removal ultraviolet LED
CN111370552A (en) * 2020-03-19 2020-07-03 广东格斯泰气密元件有限公司 Method for assembling plane glass optical window on SMD support
TWI701096B (en) * 2019-02-01 2020-08-11 立誠光電股份有限公司 Lds optical device and manufacturing processes thereof
CN111669888A (en) * 2019-03-06 2020-09-15 立诚光电股份有限公司 Three-dimensional circuit structure and process for optical device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108321283A (en) * 2018-04-03 2018-07-24 江苏鸿利国泽光电科技有限公司 A kind of package support and its packaging method of specular removal ultraviolet LED
TWI701096B (en) * 2019-02-01 2020-08-11 立誠光電股份有限公司 Lds optical device and manufacturing processes thereof
CN111669888A (en) * 2019-03-06 2020-09-15 立诚光电股份有限公司 Three-dimensional circuit structure and process for optical device
CN111370552A (en) * 2020-03-19 2020-07-03 广东格斯泰气密元件有限公司 Method for assembling plane glass optical window on SMD support

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Granted publication date: 20181221