CN208177249U - Novel photocatalysis equipment with sliding tube rack - Google Patents

Novel photocatalysis equipment with sliding tube rack Download PDF

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Publication number
CN208177249U
CN208177249U CN201820480397.2U CN201820480397U CN208177249U CN 208177249 U CN208177249 U CN 208177249U CN 201820480397 U CN201820480397 U CN 201820480397U CN 208177249 U CN208177249 U CN 208177249U
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China
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shell
lamp tube
sliding
rack
photocatalysis
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CN201820480397.2U
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Chinese (zh)
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罗斌
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Guangzhou Micro-Carbon Technology Co Ltd
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Guangzhou Micro-Carbon Technology Co Ltd
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Abstract

The utility model discloses a kind of novel photocatalysis equipment of the sliding tube rack of band, it includes photocatalytic oxidation device, photocatalytic oxidation device includes shell, lamp tube installation rack, ultraviolet lamp group, photochemical catalyst and microwave generator, shell is equipped with air inlet and air outlet, lamp tube installation rack is removably mounted in the photocatalysis chamber of shell, lamp tube installation rack is the hollow, rectangular structure being mutually spliced to form by two crossbeams and two vertical beams, sliding block is respectively equipped on the outside of two crossbeams of lamp tube installation rack, the sliding slot with sliding block sliding cooperation is equipped with corresponding to the position of sliding block on case inside wall, ultraviolet lamp group is mounted on lamp tube installation rack.The utility model is convenient for Job Operations such as manually installed fluorescent tube component, repair and replacement fluorescent tube component and cleaning fluorescent tube components, fluorescent tube can be taken out in batches with the disassembly of sliding detachable tube mounting bracket and be cleaned, be quickly and expediently installed, not will lead to tubes breaks down, the installation and removal of lamp tube installation rack are more convenient, and stability is good.

Description

Novel photocatalysis equipment with sliding tube rack
Technical field
The utility model relates to a kind of photocatalysis equipment, it particularly relates to which a kind of band for VOCs treatment is sliding The novel photocatalysis equipment of shifting formula tube rack.
Background technique
Organic exhaust gas be usually present it is inflammable and explosive, poisonous and harmful, be insoluble in that water, to be dissolved in organic solvent, processing difficulty big The characteristics of.Currently, photochemical catalytic oxidation decomposition technique has efficient, energy-saving and environmental protection, without two in except organic exhaust gas, deodorization engineering The advantages such as secondary pollution, therefore the application of photochemical catalytic oxidation decomposer is than wide.Photochemical catalytic oxidation decomposer generally comprises Shell, for fluorescent tube component to be fixedly mounted on the intracorporal fluorescent tube mounting bracket of shell.However, existing for installing fluorescent tube component Fluorescent tube mounting bracket be usually be arranged in shell in a manner of being fixedly connected, when carry out installation fluorescent tube component, replace When the operation such as lamp for repairing tube assembly and cleaning fluorescent tube component, due to the limit of the narrow space of photochemical catalytic oxidation decomposer shell System, not only inconvenient manually installed operation operation, but also also result in installation exercise inefficiency;Especially processing oil-containing, In the exhaust gas of dust-laden, photocatalysis equipment usually requires often to carry out periodic cleaning, could make the titanium dioxide in photocatalysis equipment Titanium Catalytic Layer and ultraviolet lamp tube keep normal working condition, and are needing to take the fluorescent tube in photochemical catalytic oxidation decomposer It when cleaning out, needs from the intracorporal fluorescent tube mounting bracket of shell to take apart fluorescent tube one by one, and to be cleaned finishes When need that the fluorescent tube after cleaning is mounted on one by one in the intracorporal fluorescent tube mounting bracket of shell again again, behaviour duplicate in this way Make not only troublesome, large labor intensity, and easily damage fluorescent tube during the installation and removal of fluorescent tube, leads to photochemical catalytic oxidation Decomposer cisco unity malfunction.
Utility model content
In view of the above shortcomings, the utility model provides a kind of convenient for manually installed fluorescent tube component, repair and replacement fluorescent tube The Job Operations such as component and cleaning fluorescent tube component, fluorescent tube can be dismantled take out with sliding detachable tube mounting bracket in batches It cleaned, be quickly and expediently installed, not will lead to the novel photocatalysis equipment with sliding tube rack of tubes breaks down, it includes Photocatalytic oxidation device, the photocatalytic oxidation device includes shell, several lamp tube installation racks, consistent with lamp tube installation rack quantity Ultraviolet lamp group, photochemical catalyst and microwave generator;The shell is equipped with air inlet and air outlet, detachable in the shell Ground is equipped with several lamp tube installation racks, and several lamp tube installation racks are mounted in parallel to each other in the photocatalysis chamber of shell, Each lamp tube installation rack is the hollow, rectangular structure being mutually spliced to form by two crossbeams and two vertical beams, and in each institute It states and is respectively equipped with sliding block on the outside of two crossbeams of lamp tube installation rack, each sliding block keeps one with the length direction of corresponding crossbeam It causes, the position of the sliding block corresponded on each lamp tube installation rack on the inner sidewall of the photocatalysis chamber of the shell is equipped with and sliding block The sliding slot of cooperation is slid, the length direction of each sliding slot is vertical with the intracorporal airflow direction of shell;The ultraviolet lamp group It is mounted on lamp tube installation rack, the ultraviolet lamp group includes several ultraviolet lamp tubes for being parallel to each other and being arranged at equal intervals, Mei Yisuo The both ends for stating ultraviolet lamp tube are respectively and fixedly installed on two vertical beams of the lamp tube installation rack, and each ultraviolet lamp tube Axial direction is vertical with the intracorporal airflow direction of shell.
In order to further realize the utility model, the ultraviolet lamp tube uses the vacuum ultraviolet fluorescent tube with water-proof function.
In order to further realize the utility model, the photocatalytic oxidation device further includes locking assembly, the locking group Part is slid in shell for limiting lamp tube installation rack, the locking assembly include lock sleeve, plug connector, grafting hole slot, Fixing piece, helical spring and guide rod, the fixing piece are fixed on the sliding slot, and the lock sleeve is movably arranged Correspond to the position of the fixing piece on the chute, the fixing piece is equipped with helical spring, and the helical spring is for forcing The plug connector is plugged in the grafting hole slot being arranged on lamp tube installation rack, and the guide rod is plugged in helical spring, institute State plug connector be equipped with the consistent guide groove of plug connector glide direction, one end of the guide rod is fixedly connected on the fixation On part, the other end of the guide rod is inserted in the guide groove.
In order to further realize the utility model, the photocatalysis equipment further includes on-line cleaning device, described online clear Cleaning device is used to carry out on-line auto-cleaning to photocatalytic oxidation device, and the on-line cleaning device includes booster water pump, water delivery Pipeline, spray piping, high pressure spray water nozzle, control valve and the control panel with control chip, the booster water pump connection are external Water source, the spray piping connect booster water pump by aqueduct, and the high pressure spray water nozzle is arranged in the shell, described High pressure spray water nozzle is connected to the spray piping, and the control valve is arranged on spray piping, the control valve and institute Booster water pump is stated to be electrically connected with the control panel with control chip.
In order to further realize the utility model, the high pressure spray water nozzle uses the wide-angle nozzle of angle adjustable.
In order to further realize the utility model, the photocatalysis equipment further includes oil gas separator, the mist of oil point From the air inlet that shell is arranged in device.
In order to further realize the utility model, the shell is interior equipped with photocatalysis chamber and microwave-excitation chamber, described Lamp tube installation rack is mounted in the photocatalysis chamber, and the microwave generator is arranged in the microwave-excitation chamber.
In order to further realize the utility model, the microwave-excitation chamber and the photocatalysis chamber pass through tubaeform company Circulation passage is interconnected, the small end opening and microwave-excitation chamber of the tubaeform communicating passage, the tubaeform connection The big end opening and photocatalysis chamber in channel.
The utility model has the beneficial effects that
1, the novel photocatalysis equipment with sliding tube rack of the utility model, photocatalytic oxidation device includes shell Body, several lamp tube installation racks and the consistent ultraviolet lamp group of lamp tube installation rack quantity, photochemical catalyst and microwave generator.Each lamp Pipe mounting rack is the hollow, rectangular structure being mutually spliced to form by two crossbeams and two vertical beams, and in each lamp tube installation rack Sliding block is respectively equipped on the outside of two crossbeams, each sliding block is consistent with the length direction of corresponding crossbeam, and the light of shell is urged The position for changing the sliding block corresponded on each lamp tube installation rack on the inner sidewall of chamber is equipped with the sliding slot cooperated with sliding block sliding, with By the Sliding Structures of sliding block and sliding slot cooperation, by several lamp tube installation racks to be similar to drawable drawer structure removably It is installed in the photocatalysis chamber of shell, convenient for manually installed fluorescent tube component, repair and replacement fluorescent tube component and cleaning light tube group The Job Operations such as part mitigate the labor intensity of operator and improve installation exercise efficiency, and can be in batches by fluorescent tube with sliding The disassembly of formula detachable tube mounting bracket, which is taken out, is cleaned, is quickly and expediently installed, not will lead to tubes breaks down, can significantly be prolonged The service life of long fluorescent tube.
2, the novel photocatalysis equipment with sliding tube rack of the utility model exists equipped with being used to limit lamp tube installation rack The locking assembly slid in shell, the setting of locking assembly not only guarantee the stabilization that lamp tube installation rack is installed in shell Property, it avoids lamp tube installation rack from damaging ultraviolet lamp tube with axial float occurs when catalytic oxidizing equipment works, improves photocatalysis The stability of oxidation unit photochemical catalytic oxidation working performance can also improve convenience when lamp tube installation rack installation.
3, the novel photocatalysis equipment with sliding tube rack of the utility model, photocatalytic oxidation device, which is equipped with, to be passed through Tubaeform communicating passage interconnected microwave-excitation chamber and photocatalysis chamber, the small end opening of tubaeform communicating passage with it is micro- The connection of wave stimulation chamber, the big end opening and photocatalysis chamber of tubaeform communicating passage, so that being located at microwave-excitation chamber The microwave that indoor microwave generator generates is urged by tubaeform communicating passage towards photocatalysis chambers uniform stray radiation to light Change each corner of chamber, so that the microwave that microwave generator generates is radiation-curable to the indoor each purple of photocatalysis chamber On outer fluorescent tube, excitation ultraviolet lamp tube generates ultraviolet light and is radiated on photocatalyst layer, and to flowing into, photocatalysis chamber is indoor organic Gas carries out photocatalysis Decomposition, can effectively improve the effect and efficiency of photochemical catalytic oxidation
Detailed description of the invention
Fig. 1 is the structural schematic diagram that the organic exhaust gas combined treatment process equipment of the utility model combines;
Fig. 2 is the spray washing system of the utility model and the structural schematic diagram of electrocatalytic oxidation system;
Fig. 3 is the decomposition texture schematic diagram of the photocatalytic oxidation device of the utility model;
Fig. 4 is the structural schematic diagram of the photocatalytic oxidation device of the utility model;
Fig. 5 is the structural schematic diagram of the photocatalytic oxidation device of the utility model;
Fig. 6 is the photocatalysis chamber inner wall of the photocatalytic oxidation device of the utility model with alternating and continuous protrusion With recess portion surface structure schematic diagram;
Fig. 7 is that the photocatalysis chamber interior air-flow of the photocatalytic oxidation device of the utility model strikes with alternately and continuous Protrusion and recess portion surface layer when structural schematic diagram;
Fig. 8 is the structural schematic diagram of the installation connection locking assembly of the lamp tube installation rack of the utility model;
Fig. 9 is the side-looking direction structural schematic diagram of the installation connection locking assembly of the lamp tube installation rack of the utility model;
Figure 10 is the structural schematic diagram of the oil gas separator of the utility model;
Figure 11 be the utility model photocatalytic oxidation device in the structural schematic diagram of on-line cleaning device is installed.
Specific embodiment
The utility model is further elaborated with reference to the accompanying drawing, wherein the direction of the utility model is mark with Fig. 1 It is quasi-.
As shown in Figure 1 to 11, the novel photocatalysis equipment with sliding tube rack of the utility model, it includes spray Water wash system 1, electrocatalytic oxidation system 2, photocatalytic oxidation device 3, oil gas separator 4, on-line cleaning device 5, ultrasonic wave Decontaminate generating device 6, flue dust coacervation device 7, high-pressure suction fan 8 and air inducing pipeline 9, in which:
Spray washing system 1 is for the dust particle and flue gas flue dust in washing filtering organic exhaust gas, spray washing system System 1 includes spray washing tower body 11, smoke dust filter 12, washing spray device 13, backwash spray equipment 14,15 and of sink Circulating water pool 16;
Hollow Cylindrical housing structure design of the spray washing tower body 11 using the state in a vertical shape of the prior art, spray It washes tower body 11 and is equipped with air inlet 111 and gas outlet 112, air inlet 111 is located in the bottom sidewall of spray washing tower body 11, The air inlet 111 of spray washing tower body 11 is connected with the passing away of organic exhaust gas, and gas outlet 112 is located at spray washing tower body 11 top of tower, sink 15 are arranged in spray washing tower body 11 and are located at the bottom of spray washing tower body 11, in sink 15 Liquid level is lower than the position of the air inlet 111 of spray washing tower body 11, and spray washing tower body 11 is arranged in circulating water pool 16 Outside corresponds to the position of sink 15, and circulating water pool 16 is connected with sink 15, follows so that the water in sink 15 can flow into Ring pond 16, and the mistake for filtering dust particle and flue gas flue dust is equipped in the communicating passage of circulating water pool 16 and sink 15 Filter-screen bag, to guarantee that the water body in circulating water pool 16 cleans.
Smoke dust filter 12 is arranged in spray washing tower body 11 and is located on the air inlet 111 of spray washing tower body 11 Side, smoke dust filter 12 includes by the multistorey strainer mesh of several layers filter screen formation stacked on top of each other, the specific layer of multistorey strainer mesh Number is designed according to the needs of actual treatment flue dust, and the mutually parallel interval of each two layers adjacent of strainer in multistorey strainer mesh Setting;Washing spray device 13 is used to spray clear water towards the multistorey strainer mesh of smoke dust filter 12, in smoke dust filter The moisture film strainer of dust particle and flue gas flue dust in adsorbable organic exhaust gas is formed on 12 multistorey strainer mesh, to filter using multilayer The moisture film formed on the net carries out just into spray washing tower body 11 containing the organic exhaust gas of dust particle and flue gas flue dust Filtration treatment is walked, flows out spray washing tower body 11 to reduce dust particle in organic exhaust gas and flue gas flue dust with air-flow;Water The lower section of the multistorey strainer mesh of smoke dust filter 12 is arranged in washing and spraying device 13, and washing spray device 13 includes several first sprays Shower pipe 131, the first water pump 132 and several first water spouts 133, several first spray tubes 131 are disposed in parallel in flue dust in multiple rows of The lower section of the multistorey strainer mesh of filter device 12, every one first spray tube 131 are connect with the first water pump 132, the setting of the first water pump 132 In circulating water pool 16.Several first water spouts 133 are evenly spaced apart to be arranged on the first spray tube 131, and every one first spray The water spraying direction of water nozzle 133 is towards the multistorey strainer mesh of smoke dust filter 12, so that pass through washing spray device 13 the The water that one water spout 133 sprays can be equably injected on the multistorey strainer mesh of smoke dust filter 12, and form good water Film, sufficiently, uniformly, efficiently absorb and filter to flue dust using the moisture film on the multistorey strainer mesh of smoke dust filter 12. The top of the multistorey strainer mesh of smoke dust filter 12 is arranged in backwash spray equipment 14, and backwash spray equipment 14 includes several Second spray tube 141, the second water pump 142 and several second water spouts 143, several second spray tubes 141 are set side by side in multiple rows of In the top of the multistorey strainer mesh of smoke dust filter 12, every one second spray tube 141 is connect with the second water pump 142, the second water pump 142 are arranged in circulating water pool 16.Several second water spouts 143 are evenly spaced apart to be arranged on the second spray tube 141, and each The water spraying direction of second water spout 143 is towards the multistorey strainer mesh of smoke dust filter 12, so that passing through recoil washing and spraying dress The water for setting 14 the second water spout 143 ejection can be equably injected on the multistorey strainer mesh of smoke dust filter 12, and be formed Good moisture film, sufficiently, uniformly, efficiently inhale to flue dust using the moisture film on the multistorey strainer mesh of smoke dust filter 12 It is attached, and matched with washing spray device 13 in the multistorey strainer mesh of smoke dust filter 12 using backwash spray equipment 14 Two sides up and down on spray water simultaneously to the multistorey strainer mesh of smoke dust filter 12, and can rinse downwards and be bonded in flue dust Dust particle and flue gas flue dust on the multistorey strainer mesh of filter device 12 realize backwashing function, avoid smoke dust filter 12 multistorey strainer mesh is caused because the dust particle that dust-contained airflow is excessive or carries and flue gas flue dust block multistorey strainer mesh mesh Airflow is unsmooth, reduces the filter effect of smoke dust filter 12.The utility model is filtered in the multilayer of smoke dust filter 12 Net is located between backwash spray equipment 14 and washing spray device 13, backwashes spray equipment 14 and washing spray device 13 divides Not Wei Yu smoke dust filter 12 multistorey strainer mesh two sides up and down, and towards the side of the multistorey strainer mesh of smoke dust filter 12 To water spray, multistorey strainer mesh is sprayed simultaneously upwards in the multistorey strainer mesh both up and down of smoke dust filter 12, is effectively improved Spray forms the success rate of moisture film on strainer, to improve the filter effect of spray.
Electrocatalytic oxidation system 2 is used to carry out first oxygen to via the organic exhaust gas after 12 washing filtering of smoke dust filter Change and decomposes.The top in spray washing tower body 11 and being located at smoke dust filter 12, electro-catalysis is arranged in electrocatalytic oxidation system 2 Oxidative system 2 include packing support flase floor 21,22, two blocks of electrically conductive graphite plates 23 of mosaic electrode packing layer, grid pressure plate 24, Spring press part 25, power supply, several third spray tubes 26, water circulating pump 27 and several third water spouts 28, packing support grid Plate 21 is fixed in spray washing tower body 11, and mosaic electrode packing layer 22 is stacked on packing support flase floor 21, particle 22 metal oxide of electrode packing layer, the metal oxide of the present embodiment preferentially use copper oxide.Two blocks of electrically conductive graphite plates 23 divide The two opposite sides of mosaic electrode packing layer 22 are not set, and keep each electrically conductive graphite plate 23 and mosaic electrode packing layer 22 Respective side comes into full contact with, and two blocks of electrically conductive graphite plates 23 are electrically connected by the positive and negative anodes of conductor wire and power supply respectively, and power supply is adopted The DC power supply for being 48V with voltage, and electric current is controlled no more than 1A.The lid of grid pressure plate 24 is located at mosaic electrode packing layer 22 On, spring press part 25 is arranged between 11 inside top face of spray washing tower body and the upper surface of grid pressure flitch 24, this reality Apply example spring press part 25 be in longitudinally disposed compression helical spring, with using compression helical spring to grid pressure flitch 24 formed towards packing support flase floor 21 direction act on thrust, to prevent because the flow velocity of off-gas flows is too fast so that Electrode filler particles in grain electrode packing layer 22 are broken up or opposite grid pressure plate 24 generates strong vibration, influence to have The catalyzing, oxidizing and purifying effect of machine exhaust gas.In addition, being set to parallel interval between packing support flase floor 21 and grid pressure flitch 24 There are two limited posts 29 in longitudinal (with horizontal plane) setting, grid pressure plate 24 corresponds to the position of each limited post 29 Equipped with slide opening up and down, the bottom end of each limited post 29 is fixed on packing support flase floor 21, each limited post 29 close to its top partially pass through mosaic electrode packing layer 22 and can be up and down with respect to being slidably slidably installed in grid pressure plate 24 In slide opening, so that grid pressure plate 24 can occur to slide towards the direction of packing support flase floor 21 along limited post 29 It moves, and is equipped with sealing ring between each limited post 29 and the slide opening of grid pressure flitch 24, fully ensured that grid pressure plate 24 exists Sliding under the action of spring press part 25 is not likely to produce beat, so that the oscilaltion sliding of grid pressure plate 24 is more Flexibly, more uniform to the lid pressure active force of mosaic electrode packing layer 22.The outside of the helical spring of spring press part 25 is arranged There is telescopic plastic film capicitor, by the tail gas containing steam in the cavity of spring press part 25 and spray washing tower body 11 Isolation avoids spring press part 25 that oxidation corrosion occurs.Several third spray tubes 26 are disposed in parallel in spray washing tower in multiple rows of Top in body 11 and positioned at grid pressure plate 24, each third spray tube 26 are connect with water circulating pump 27, and water circulating pump 27 is set It sets in circulating water pool 16.Several third water spouts 28 are evenly spaced apart to be arranged on third spray tube 26, and each third is sprayed The water spraying direction of water nozzle 28 is towards mosaic electrode packing layer 22.
Electrocatalytic oxidation system 2 under the excitation of electric energy, urge in the oxidation of mosaic electrode packing layer 22 by the oxygen for being passed through air Agent surface forms the H with the nascent state of certain oxidisability2O2: O2+2H++2e-→H2O2, the H of nascent state2O2In catalyst Under catalysis, embryonic stem-like cells then occur, generate the extremely strong hydroxyl radical free radical of oxidisability: H2O2+MxOy(or M)+H+ → OH +Mx++H2O (M is metal), used catalyst has enrichment to organic matter, and hydroxyl radical free radical is sent out with organic matter Raw reaction, can be rapidly and effectively by mineralization of organic material: OH+R → CO2+ inorganic ions (R is organic matter).
The mosaic electrode packing layer 22 of electrocatalytic oxidation system 2 after powered up to air-flow generate a large amount of hydroxyl radical free radical and Energetic ion agent active group DMF has piperidines, methylene chloride, trifluoracetic acid, dithioglycol, ether, the acetonitrile etc. in air-flow Evil pollutant and living radical therein roll into a ball chemically reacts, a large amount of noxious pollutant be broken down into carbon dioxide, water, Harmless carboxylic acid.In processing gas middle and high concentration COD, 30min treatment effeciency reaches 85~95%.Therefore, the utility model 2 electrocatalytic oxidation decomposing organic gas of electrocatalytic oxidation system is high-efficient, in addition to power consumption, water consume, does not consume other raw materials, without Carry out secondary pollution, is not necessarily to secondary treatment, and catalyst long service life.
Photocatalytic oxidation device 3 is used to carry out organic exhaust gas catalysis oxidation and decomposes to achieve the purpose that purify exhaust gas.Light Catalytic oxidizing equipment 3 includes shell 31, several lamp tube installation racks 32 and the consistent ultraviolet lamp group of 32 quantity of lamp tube installation rack, light Catalyst, microwave generator 34 and locking assembly.Photocatalysis chamber 311 and microwave-excitation chamber 312, shell are equipped in shell 31 It is equipped with air inlet 313 and air outlet 314 corresponding to the position of photocatalysis chamber 311 on 31 two opposite sides, the light of shell 31 is urged Change in chamber 311 and be removably installed several lamp tube installation racks 32, several lamp tube installation racks 32, which are parallel to each other, equally spacedly pacifies In photocatalysis chamber 311, each lamp tube installation rack 32 is mutually spliced to form by two crossbeams 321 and two vertical beams 322 Hollow, rectangular structure, and the outside of two crossbeams 321 in each lamp tube installation rack 32 is respectively equipped with sliding block, and each sliding block is equal It is consistent with the length direction of corresponding crossbeam 321, each fluorescent tube is corresponded on the inner sidewall of the photocatalysis chamber 311 of shell 31 The position of sliding block on mounting rack 32 is equipped with the sliding slot 315 with sliding block sliding cooperation, the length direction and shell of each sliding slot 315 Airflow direction in 31 is vertical;Ultraviolet lamp group is mounted on lamp tube installation rack 32, and ultraviolet lamp group includes several is parallel to each other And the ultraviolet lamp tube 33 being arranged at equal intervals, the both ends of each ultraviolet lamp tube 33 pass through connecting bracket respectively and are fixedly mounted on fluorescent tube peace It shelves on 32 two vertical beams 322, and the axial direction of each ultraviolet lamp tube 33 is vertical with the airflow direction in shell 31. The ultraviolet lamp tube 33 of the present embodiment can both use common UV ultraviolet lamp tube, can also be purple using the vacuum with water-proof function Outer fluorescent tube.
Microwave generator 34 is arranged in the microwave-excitation chamber 312 of shell 31, and microwave generator 34 is anti-using high temperature resistant Water material package, contacts with water to avoid microwave generator 34 and influences its working effect.Microwave-excitation chamber 312 and photocatalysis Chamber 311 is interconnected by tubaeform communicating passage 316, the small end opening and microwave-excitation chamber of tubaeform communicating passage 316 Room 312 is connected to, and the big end opening of tubaeform communicating passage 316 is connected to photocatalysis chamber 311, so that being located at microwave-excitation chamber The microwave that microwave generator 34 in room 312 generates uniformly is spread by tubaeform communicating passage 316 towards photocatalysis chamber 311 It is radiated each corner of photocatalysis chamber 311, so that the microwave that microwave generator 34 generates is radiation-curable to photocatalysis On each ultraviolet lamp tube 33 in chamber 311, excitation ultraviolet lamp tube 33 generates ultraviolet light, to inflow photocatalysis chamber 311 Interior organic gas carries out photocatalysis Decomposition, can effectively improve the effect and efficiency of photochemical catalytic oxidation.
Locking assembly is for limiting the sliding of lamp tube installation rack 32 to realize that ultraviolet lamp group is fixed on the photocatalysis chamber of shell 31 In room 311, guarantees the stability that lamp tube installation rack 32 is installed in shell 31, avoid lamp tube installation rack 32 as catalysis oxidation fills Axial float occurs when setting 3 work and damages ultraviolet lamp tube 33, improves 3 photochemical catalytic oxidation working performance of photocatalytic oxidation device Stability.Locking assembly includes lock sleeve 351, plug connector 352, grafting hole slot 353, fixing piece 354, helical spring 355 and leads To bar 356, fixing piece 354 is fixed at one end of sliding slot 315, and lock sleeve 351 is movably disposed on sliding slot 315 corresponding In the position of fixing piece 354, fixing piece 354 is equipped with helical spring 355, and helical spring 355 is for forcing 352 grafting of plug connector In in the grafting hole slot 353 being arranged on lamp tube installation rack 32, guide rod 356 is plugged in helical spring 355, plug connector 352 Be equipped with the consistent guide groove 357 of 352 glide direction of plug connector, one end of guide rod 356 is fixedly connected on fixing piece 354 On, the other end of guide rod 356 is inserted in the guide groove 357 of plug connector 352.
The basic installation and removal operating process of lamp tube installation rack 32: it needs replacing ultraviolet lamp group in photocatalysis equipment and adds When adding photochemical catalyst, manpower stirs plug connector and plug connector 352 is driven to slide movement in the grafting hole slot 353 of lock sleeve 351, To the middle disengaging out of grafting hole slot 353 by the grafting end of plug connector 352, to guarantee cunning of the lamp tube installation rack on shell The smoothness slided in slot 315, it is simple, convenient, and stability maintenance is good.Helical spring 355 is compressed by plug connector 352 Afterwards, guide rod 356 is plugged in guide groove and slides in guide groove 357, passes through the cooperation of guide rod 356 and guide groove 357 The setting of structure, only plug connector 352 does not provide guiding role, and can effectively avoid helical spring 355 from being produced by compression The phenomenon that raw bending, to guarantee that helical spring 355 drives plug connector 352 to slide when operator unclamps plug connector 352 Smoothness avoids plug connector 352 from generating in sliding process and swings, and supports with 353 wall of grafting hole slot of lock sleeve 351 Trigger raw inlay card phenomenon.And after replacing ultraviolet lamp group and having added photochemical catalyst, by stirring plug connector 352 with hand, drive Plug connector 352 slides movement in the grafting hole slot 353 on lock sleeve 351, thus after helical spring 355 is compressed, spliced eye The grafting end face of slot 353 contradicts on the side wall of lamp tube installation rack, and lamp tube installation rack slides in the sliding slot 315 on shell and lamp Grafting hole slot 353 on pipe mounting rack is directed at plug connector 352, and the helical spring 355 on plug connector 352 is by the elastic potential energy of storage Release, so that plug connector 352 be driven to be plugged in grafting hole slot 353.The setting of locking assembly not only guarantees lamp tube installation rack 32 The stability installed in shell 31, avoid lamp tube installation rack 32 with catalytic oxidizing equipment 3 work when occur axial float and Ultraviolet lamp tube 33 is damaged, the stability of 3 photochemical catalytic oxidation working performance of photocatalytic oxidation device is improved, also improves fluorescent tube installation Convenience when frame 32 is installed.
It is provided in the photocatalysis chamber 311 of shell 31 with alternating and continuous protrusion 317 and recess portion 318, has and hand over It replaces and continuous protrusion 317 and the surface layer of recess portion 318 is equipped with one layer of catalyst layer.The material multiplicity of photochemical catalyst at present, it is main It to be many oxides sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, the white, cadmium sulfide of titanium dioxide;Wherein, due to The oxidability of titanium dioxide is stronger, and chemical substance is stable and non-toxic, becomes most important nano-photocatalyst material, this implementation Example preferably titanium dioxide is 311 inner wall of photocatalysis chamber that photochemical catalyst is attached to shell 31 with alternating and continuous protrusion 317 and 318 surface layer of recess portion, and have alternately and continuous protrusion 317 and recess portion 318 form the microvovtex siding that zigzag rises and falls. It can be easy to shape at recess portion 318 by the blocking of protrusion 317 when organic exhaust gas flows in the photocatalysis chamber 311 of shell 31 At stream swirl, there is stirring action to reaction gas, is uniformly mixed reaction gas, so that the photocatalysis chamber 311 of shell 31 Each section component of interior reaction gas tends to be identical, ensure that the efficient progress of light-catalyzed reaction, prevents reaction gas local Unreacting gas bulk concentration is excessive, and reaction gas is caused to cannot get sufficiently catalytic oxidation reaction.And it is alternately and continuous due to having The fold zigzag fashion of protrusion 317 and recess portion 318 increases the surface area of 311 inner wall of photocatalysis chamber of shell 31, that is, increases The contact area of reaction gas and catalyst, increases 3 light-catalyzed reaction rate of photocatalytic oxidation device and reaction efficiency.
Oil gas separator 4 is for separating and remove the water mist and mist of oil that are mixed in organic exhaust gas, with to entering photocatalysis Organic exhaust gas before oxidation unit 3 removed water, oil removing, and the shell 31 of photocatalytic oxidation device 3 is arranged in oil gas separator 4 Air inlet 313 at, oil gas separator 4 using the prior art high speed centrifugation oil fume separator realize, high speed centrifugation oil smoke Separator includes high-speed centrifugal fan, mist of oil strainer and connects liquid box, and the revolving speed of high speed centrifugation oil fume separator is up to 2400r/ Min, using 304 stainless steel filtering net interception oil smokes, water mist, mist of oil separating degree are up to 95%, intercepted water mist and oil mist particles It can flow into and connect liquid box.The photocatalytic oxidation device of high speed centrifugation oil fume separator is increased, not only can solve in Combined Treatment It is easy to be influenced by water mist, the mist of oil of photocatalytic oxidation device front end in photocatalytic oxidation device in technique, fluorescent tube occurs Hardly possible starting the problem of, can also thoroughly solve because water mist, mist of oil influence due to lead to problems such as burn fluorescent tube.
On-line cleaning device 5 is used to carry out regular or irregular on-line auto-cleaning to photocatalytic oxidation device 3, Line cleaning device 5 includes booster water pump 51, aqueduct 52, spray piping 53, high pressure spray water nozzle 54, control valve and with control The control panel of chip, the external tap water of booster water pump 51 or the aqueous solution dissolved with detergent, booster water pump 51 can also be set Set in clear water reserviors or the pond for containing aqueous detergent solution in, spray piping 53 by aqueduct 52 connect pressurized water Pump 51, several high pressure spray water nozzles 54 are arranged in the photocatalysis chamber 311 of the shell 31 of photocatalytic oxidation device 3, spray tube Road 53 is equipped with high pressure spray water nozzle 54, and each high pressure spray water nozzle 54 is connected to spray piping 53 by jointing, is sprayed water with high pressure Mouth 54 is using the rotation wide-angle nozzle of angle adjustable, and control valve setting is on spray piping 53, control valve and pressurized water Pump 51 is electrically connected with the control panel with control chip.On-line cleaning device 5 is provided with Manual-cleaning and automatic cleaning two Kind mode: when using manual wash mode, the uncontrolled chip controls of the working condition of on-line cleaning device 5, user can root According to actual needs, booster pump is manually booted, equipment can be cleaned;When using automatic cleaning model, by controlling chip The cleaning frequency of on-line automatic control on-line cleaning device 5 and scavenging period, are not necessarily to manual intervention, control chip according to default journey Sequence automatically controls starting booster pump, cleans to equipment.
Ultrasonic wave decontamination generating device 6 is used to excite the ultrasonic wave for generating and resonating with clear water or cleaning solution to light The schmutzband of catalytic oxidizing equipment 3 carries out Rapid Cleaning, and ultrasonic wave decontaminates generating device 6 using the ultrasonic wave transducer of the prior art Device is realized.In the photocatalysis chamber 311 for the shell 31 that photocatalytic oxidation device 3 is arranged in ultrasonic wave decontamination generating device 6, ultrasound Wave decontaminates generating device 6 using the ultrasonic transducer of medium-high frequency acoustic signals, because ultrasonic transducer is in clear water or cleaning The cavitation bubble generated in liquid can generate powerful shock wave when vanishing, so that 3 inner wall of catalytic oxidizing equipment and ultraviolet lamp tube 33 A part of the grieshoch or grease soils layer that wrap up on outer wall is stripped, disperse, emulsifies, takes off under shock wave It falls.In addition, will form cavitation quadratic effect when ultrasonic transducer generates the bubble of cavitation phenomenon generation in cleaning solution, i.e., Gap and gap of the bubble between the schmutzband and surface layer that impact is formed are permeated, and this minute bubbles can synchronize swollen with acoustic pressure Swollen, contraction, the physical force as peeling are iteratively operating on schmutzband, and schmutzband is stripped from level to level, and bubble continues inwards Infiltration, until schmutzband is fully exfoliated.Ultrasonic wave can make in the process of cleaning cleaning solution with ultrasonic vibration to dirt into The strong impact of row, so that clear water be accelerated to reach good to the cleaning process of 3 inner wall of catalytic oxidizing equipment and ultraviolet lamp tube 33 Cleaning effect.
In organic exhaust gas before spray washing tower body 11 of the flue dust coacervation device 7 for spray washing system 1 will to be entered Dust particle and flue gas flue dust is drenched and ultrasonic coagulation makes air-flow carry particulate matter and becomes larger, to improve organic exhaust gas In dust particle and flue gas flue dust washing filtering effect.Flue dust coacervation device 7 be arranged in spray washing tower body 11 into At port 111, and it is equipped at the air inlet 111 of spray washing tower body 11 and agglomerates the little particle micronic dust in air-flow convenient for ultrasonic wave The ultrasonic coagulation section 10 to become larger, flue dust coacervation device 7 include the air compressor machine (not shown) being connected to sink, atomizer (not shown), homogenizing plate 71, supersonic generator 72 and ultrasonic oscillator 73, air compressor machine (not shown), atomization Nozzle (not shown) is arranged at the air inlet 111 of spray washing tower body 11, air compressor machine and the control with control chip Panel is electrically connected, and atomizer is connected with air compressor machine, is made water fogging by air compressor machine and atomizer to spray to entrance The dust particle and flue gas flue dust washed in the organic exhaust gas of the air inlet 111 of tower body 11 carry out drenching exacerbation, have to slow down The flow velocity that dust particle and flue gas flue dust in machine exhaust gas flow in ultrasonic coagulation section with air-flow, prevents in organic exhaust gas Dust particle and flue gas flue dust with high pressure draught it is quick on alter and reduce spray washing tower body 11 to the powder in organic exhaust gas Dirt particulate matter and flue gas flue dust washing filtering effect;Homogenizing plate 71, supersonic generator 72 and ultrasonic oscillator 73 are respectively provided with In ultrasonic coagulation section 10, homogenizing plate 71 is connected to the air inlet 111 of spray washing tower body 11, homogenizing plate 71 and ultrasonic coagulation There are gaps between the cylinder of section 10, to form the chamber of ultrasonic coagulation processing.During VOCs treatment, contain powder The air-flow of dirt particulate matter and flue gas flue dust enters ultrasonic coagulation section 10 by the air inlet 111 of spray washing tower body 11, flows Plate 71 keeps the distribution of air flow containing dust particle and flue gas flue dust entered from the air inlet 111 of spray washing tower body 11 equal Enter in the chamber that the gap between homogenizing plate 71 and ultrasonic coagulation section 10 is formed after even steady air flow, so that ultrasonic wave is sent out The ultrasonic wave that raw device 72 issues can the abundant indoor air-flow of exposure cavity, to issue ultrasonic wave using supersonic generator 72, and Emit ultrasonic wave to chamber by ultrasonic oscillator 73, the fine particle in the air-flow containing dust particle and flue gas flue dust exists It is agglomerated in chamber, gradually condenses into partial size bigger dust or soot dust granule, flow into spray washing then as air-flow Tower body 11 carries out the spray washing filtering of particulate matter.The air-flow containing dust particle and flue gas flue dust of the present embodiment is in chamber The interior residence time be at least 1 second (residence time refer to gas to be processed from enter chamber to outflow chamber time, that is, Gas to be processed receives the time of ultrasonication in chamber, and the direction of ultrasonic wave is vertical with gas flow to be processed, flows Plate 71 can be used as one of the means of control residence time), the power setting of the supersonic generator 72 of flue dust coacervation device 7 is 45W/cm3, when the ultrasonic frequency of supersonic generator 72 is 24.1KHz or more, flue dust coacervation device 7 can lead to fine particle Cross the particulate matter that ultrasonic coagulation effect bonding condenses into larger particles.About ultrasonic coagulation action principle, patent can refer to Number for 201320798548.6 Chinese patent disclosed in a kind of particle aggregation device.
High-pressure suction fan 8 in device systems for forming negative pressure, to utilize negative pressure to the organic waste in each device systems Gas is aspirated, and realizes that the organic exhaust gas in device systems uninterruptedly circulates, high-pressure suction fan 8 is realized using the prior art.It is high Pressure air-introduced machine 8 is connected by air inducing pipeline 9 with the air outlet 314 of the shell 31 of photocatalytic oxidation device 3, photocatalytic-oxidation makeup The air inlet 33 for setting 3 shell 31 passes through the gas outlet 112 of air inducing pipeline 9 and the spray washing tower body 11 of spray washing system 1 It is connected.
The basic functional principle and workflow of the utility model:
1) under the negative-pressure ward effect that high-pressure suction fan 8 is formed, discharge contains a large amount of dust particulate matter and flue gas cigarette The organic exhaust gas of dirt enters spray washing tower body 11 via the air inlet 111 of spray washing tower body 11, contains a large amount of dust The air-flow of grain object and flue gas flue dust is when by the air inlet 111 of spray washing tower body 11, the atomization that is connected with air compressor machine The atomized drop that nozzle sprays drenches exacerbation, slows down what dust particle and flue gas flue dust in organic exhaust gas were flowed with air-flow Flow velocity had both improved cohesion rate and cohesion of the dust particle and flue gas flue dust in organic exhaust gas in ultrasonic coagulation section 10 Effect, but prevent dust particle and flue gas flue dust in organic exhaust gas with high pressure draught it is quick on alter and reduce spray washing tower Body 11 is to the effect of dust particle and flue gas flue dust washing filtering in organic exhaust gas, to effectively increase in organic exhaust gas Dust particle and flue gas flue dust removal effect.
2) by atomized drop drench aggravate after the air-flow containing a large amount of dust particulate matter and flue gas flue dust flow through it is super When sonic agglomeration section 10, homogenizing plate 71 makes what is entered from the air inlet 111 of spray washing tower body 11 to contain dust particle and cigarette The distribution of air flow of gas flue dust is to enter what gap between homogenizing plate 71 and ultrasonic coagulation section 10 was formed after uniform and stable air-flow In chamber, to issue ultrasonic wave using supersonic generator 72, and ultrasonic wave is emitted to chamber by ultrasonic oscillator 73, contained Fine particle in the air-flow of dust particle and flue gas flue dust agglomerates in the chamber, gradually condenses into the bigger powder of partial size Dirt or soot dust granule flow into the spray washing filtering that spray washing tower body 11 carries out particulate matter then as air-flow.
3) air-flow containing a large amount of dust particulate matter and flue gas flue dust Jing Guo ultrasonic coagulation is being sprayed using setting Wash the moisture film strainer that the multistorey strainer mesh of the smoke dust filter 12 in tower body 11 is formed, to dust particle in organic tail gas and Flue gas flue dust is adsorbed the washing filtering to realize organic tail gas, to reduce the dust particle and flue gas cigarette in organic exhaust gas Dirt flows out spray washing tower body 11 with air-flow.
4) clean gas flow of the smoke dust particle after 12 washing filtering of smoke dust filter enters electrocatalytic oxidation system System 2, the mosaic electrode packing layer 22 of electrocatalytic oxidation system 2 generate a large amount of hydroxyl radical free radical and high energy to air-flow after powered up Ionic agent active group DMF, piperidines, methylene chloride, trifluoracetic acid, dithioglycol, ether, acetonitrile in air-flow etc. is harmful dirty Dye object and living radical therein, which are rolled into a ball, to be chemically reacted, and a large amount of noxious pollutant is broken down into carbon dioxide, water, harmless Carboxylic acid.Electrocatalytic oxidation system 2 does not consume other raw materials, does not bring secondary pollution in addition to power consumption, water consume, is not necessarily to secondary treatment, And catalyst long service life.
5) air-flow after the oxidation of 2 electrolytic oxidation of electrocatalytic oxidation system enters photocatalytic-oxidation from air inlet 313 and disguises The photocatalysis chamber 311 for setting 3, containing water mist, mist of oil air-flow by shell 31 air inlet 313 when, be arranged in photocatalysis Oil gas separator 4 at the air inlet 313 of the shell 31 of oxidation unit 3, by 95% water mist in air-flow, mist of oil intercept At the air inlet 313 of shell 31 and formed water mist and oil mist particles inflow connect liquid box, not only can solve in combined treatment process In photocatalytic oxidation device in be easy to be influenced by water mist, the mist of oil of photocatalytic oxidation device front end, there is fluorescent tube difficulty and open Dynamic problem, can also thoroughly solve because water mist, mist of oil influence due to lead to problems such as burn fluorescent tube.
6) in the photocatalysis chamber 311 of photocatalytic oxidation device 3, microwave occurs the air-flow after mist of oil separating treatment Device 34 generates microwave-excitation and the generation ultraviolet light of the ultraviolet lamp tube 33 on lamp tube installation rack 32 is arranged in, and ultraviolet lamp tube 33 generates ultraviolet The light with alternating and continuous 318 surface layer of protrusion 317 and recess portion that light is radiated at 311 inner wall of photocatalysis chamber of shell 31 is urged On agent layer, and vortex is formed, so that reaction gas is well-dispersed in photocatalysis chamber 311, avoided because of reaction gas Directed flow it is too strong and lead to reaction gas and photochemical catalyst insufficient contact, to ensure that the effective of light-catalyzed reaction It carries out, improves the conversion ratio of reaction gas.
7) when using automatic cleaning model, pass through the cleaning frequency of the on-line automatic control on-line cleaning device 5 of control chip And scavenging period, it is not necessarily to manual intervention, control chip automatically controls starting booster pump according to pre-set programs, carries out to equipment clear It washes.Using physical effects such as cavitation, radiation pressure, acoustic streaming of the ultrasonic wave in clear water transmission, cleaned photocatalytic-oxidation is disguised It sets the dirt on 3 and generates pinch spalling effect, while cleaning solution can be promoted to chemically react with dirt, reach better cleaning The purpose of pipe fitting improves cleaning effect and cleaning efficiency, high degree of automation.
The foregoing is merely the better embodiment of the utility model, the utility model is not limited to above-mentioned embodiment party Formula, there may be the structural modifications that part is small in implementation process, if various changes or modifications to the utility model are not The spirit and scope of the utility model are detached from, and are belonged within the scope of the claims and equivalents of the utility model, then originally Utility model is also intended to encompass these modification and variations.

Claims (8)

1. a kind of novel photocatalysis equipment of the sliding tube rack of band, it is characterised in that: it includes photocatalytic oxidation device, described Photocatalytic oxidation device includes shell, several lamp tube installation racks and the consistent ultraviolet lamp group of lamp tube installation rack quantity, photochemical catalyst And microwave generator;The shell is equipped with air inlet and air outlet, and several fluorescent tube peaces have been removably installed in the shell It shelves, several lamp tube installation racks are mounted in parallel to each other in the photocatalysis chamber of shell, each lamp tube installation rack It is the hollow, rectangular structure being mutually spliced to form by two crossbeams and two vertical beams, and at two of each lamp tube installation rack Sliding block is respectively equipped on the outside of crossbeam, each sliding block is consistent with the length direction of corresponding crossbeam, and the light of the shell is urged The position for changing the sliding block corresponded on each lamp tube installation rack on the inner sidewall of chamber is equipped with the sliding slot cooperated with sliding block sliding, often The length direction of one sliding slot is vertical with the intracorporal airflow direction of shell;The ultraviolet lamp group is mounted on lamp tube installation rack On, the ultraviolet lamp group includes several ultraviolet lamp tubes for being parallel to each other and being arranged at equal intervals, the both ends of each ultraviolet lamp tube It is respectively and fixedly installed on two vertical beams of the lamp tube installation rack, and in the axial direction and shell of each ultraviolet lamp tube Airflow direction it is vertical.
2. the novel photocatalysis equipment of the sliding tube rack of band according to claim 1, it is characterised in that: the ultraviolet lamp Pipe uses the vacuum ultraviolet fluorescent tube with water-proof function.
3. the novel photocatalysis equipment of the sliding tube rack of band according to claim 1, it is characterised in that: the photocatalysis Oxidation unit further includes locking assembly, and the locking assembly slides in shell for limiting lamp tube installation rack, the lock Tight component includes lock sleeve, plug connector, grafting hole slot, fixing piece, helical spring and guide rod, and the fixing piece is fixed at On the sliding slot, the lock sleeve is movably disposed in the position for corresponding to the fixing piece on sliding slot, on the fixing piece Equipped with helical spring, the helical spring is for forcing the plug connector to be plugged in the grafting hole slot being arranged on lamp tube installation rack Interior, the guide rod is plugged in helical spring, and the plug connector is equipped with and the consistent guide groove of plug connector glide direction, institute The one end for stating guide rod is fixedly connected on the fixing piece, and the other end of the guide rod is inserted in the guide groove.
4. the novel photocatalysis equipment of the sliding tube rack of band according to claim 3, it is characterised in that: the photocatalysis Equipment further includes on-line cleaning device, and the on-line cleaning device is used to carry out on-line auto-cleaning to photocatalytic oxidation device, The on-line cleaning device include booster water pump, aqueduct, spray piping, high pressure spray water nozzle, control valve and with control core The control panel of piece, the booster water pump connect external water source, and the spray piping connects booster water pump, institute by aqueduct It states high pressure spray water nozzle to be arranged in the shell, the high pressure spray water nozzle is connected to the spray piping, the control valve It is arranged on spray piping, the control valve and the booster water pump are electrically connected with the control panel with control chip.
5. the novel photocatalysis equipment of the sliding tube rack of band according to claim 4, it is characterised in that: the high pressure spray Water nozzle uses the wide-angle nozzle of angle adjustable.
6. the novel photocatalysis equipment of the sliding tube rack of band according to claim 3, it is characterised in that: the photocatalysis Equipment further includes oil gas separator, and the air inlet of shell is arranged in the oil gas separator.
7. the novel photocatalysis equipment of the sliding tube rack of band according to claim 1, it is characterised in that: in the shell Equipped with photocatalysis chamber and microwave-excitation chamber, the lamp tube installation rack is mounted in the photocatalysis chamber, the microwave hair Raw device is arranged in the microwave-excitation chamber.
8. the novel photocatalysis equipment of the sliding tube rack of band according to claim 1, it is characterised in that: the microwave swashs It sends out chamber and the photocatalysis chamber to be interconnected by tubaeform communicating passage, the small end opening of the tubaeform communicating passage With microwave-excitation chamber, the big end opening and photocatalysis chamber of the tubaeform communicating passage.
CN201820480397.2U 2018-04-04 2018-04-04 Novel photocatalysis equipment with sliding tube rack Active CN208177249U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820480397.2U CN208177249U (en) 2018-04-04 2018-04-04 Novel photocatalysis equipment with sliding tube rack

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201820480397.2U CN208177249U (en) 2018-04-04 2018-04-04 Novel photocatalysis equipment with sliding tube rack

Publications (1)

Publication Number Publication Date
CN208177249U true CN208177249U (en) 2018-12-04

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201820480397.2U Active CN208177249U (en) 2018-04-04 2018-04-04 Novel photocatalysis equipment with sliding tube rack

Country Status (1)

Country Link
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