CN208170858U - Co 2 liquefaction recyclable device - Google Patents

Co 2 liquefaction recyclable device Download PDF

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Publication number
CN208170858U
CN208170858U CN201820491382.6U CN201820491382U CN208170858U CN 208170858 U CN208170858 U CN 208170858U CN 201820491382 U CN201820491382 U CN 201820491382U CN 208170858 U CN208170858 U CN 208170858U
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CN
China
Prior art keywords
flow
gas
ammonia
liquefaction
liquefied ammonia
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201820491382.6U
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Chinese (zh)
Inventor
付亦玮
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FUJIAN PROVINCIAL PETROCHEMICAL DESIGNING INSTITUTE
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FUJIAN PROVINCIAL PETROCHEMICAL DESIGNING INSTITUTE
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Priority to CN201820491382.6U priority Critical patent/CN208170858U/en
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Publication of CN208170858U publication Critical patent/CN208170858U/en
Expired - Fee Related legal-status Critical Current
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0027Oxides of carbon, e.g. CO2
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0203Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
    • F25J1/0204Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle as a single flow SCR cycle
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0228Coupling of the liquefaction unit to other units or processes, so-called integrated processes
    • F25J1/0235Heat exchange integration
    • F25J1/0237Heat exchange integration integrating refrigeration provided for liquefaction and purification/treatment of the gas to be liquefied, e.g. heavy hydrocarbon removal from natural gas
    • F25J1/0238Purification or treatment step is integrated within one refrigeration cycle only, i.e. the same or single refrigeration cycle provides feed gas cooling (if present) and overhead gas cooling
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0244Operation; Control and regulation; Instrumentation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00Processes or apparatus involving steps for the removal of impurities
    • F25J2220/80Separating impurities from carbon dioxide, e.g. H2O or water-soluble contaminants
    • F25J2220/82Separating low boiling, i.e. more volatile components, e.g. He, H2, CO, Air gases, CH4
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30Compression of the feed stream
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/90External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Separation By Low-Temperature Treatments (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)

Abstract

The utility model discloses a kind of co 2 liquefaction recyclable devices, during the recyclable device is run, flow information is simultaneously fed back to master controller by the flow of the gas of gas flow sensor real-time detection raw material gas tank outflow, master controller controls the revolving speed of frequency conversion liquid pump according to the changes in flow rate of gas, and control the flow that flow adjusts electrically-controlled valve, to adjust the conveying capacity of liquefied ammonia, to make the conveying capacity of liquefied ammonia and the flow of gas match, keep the utilization of liquefied ammonia more reasonable, reduce the absorption of the heat in liquefied ammonia external environment, to which the electric energy of subsequent re-liquefied ammonia consumption be effectively reduced, reduce the energy consumption of carbon dioxide recovering apparatus.

Description

Co 2 liquefaction recyclable device
Technical field
The utility model relates to a kind of petrochemical industry waste gas recovery equipments, more specifically, it relates to a kind of carbon dioxide Recovery device of liquefied.
Background technique
Petrochemical industry, a large amount of exhaust gas can be generated in industrial processes by smelting etc., and main ingredient is carbon dioxide, is contained Amount is generally 80% or more, these exhaust gas are directly discharged in atmosphere, can cause greatly to pollute to atmospheric environment.
Since carbon dioxide is a kind of widely used raw material of industry, by the carbon dioxide in petrochemical production process into Row, which recycles, not only can be reduced atmosphere pollution, but also can increase economic efficiency.
The mode of liquefaction separation is usually used to the recycling of carbon dioxide in the prior art, utilizes each component in unstripped gas The different boiling point of gas is made unstripped gas cooling liquid and is separated with boiling point difference using the method for cryogenic technique.But it liquefies Isolation technics is just needed using a fairly large number of refrigeration machine, since the power consumption of refrigeration machine is very big, so current liquefaction separation is returned The mode cost for receiving carbon dioxide is high, limits recycling of the people for carbon dioxide in waste gas.
Application No. is the Chinese patents of CN200920245485.5 to disclose carbon dioxide liquid in a kind of petrochemical industry tail gas Change recyclable device, successively by raw material gas tank, compressor, cooler, separator, heat exchanger, destilling tower and cryogenic vacuum storage tank Be formed by connecting by pipeline, carbon dioxide gas through compression, cooling, recompress, be segregated into one wing passage of heat exchanger, it is special Sign be further include liquid-gas phase transition device, the liquid-gas phase transition device is connected by pipeline with the evaporator on destilling tower top, steaming Hair device is connected to another wing passage of the heat exchanger, generates cooling capacity using liquefied ammonia detour phase transition process and replaces conventional titanium dioxide Refrigeration unit is set in carbon liquid separation process, cooling capacity is provided, not only saves the equipment investment of refrigeration machine, but also save for a long time Power consumed by refrigerator operation is saved, so that cryogenic liquid carbon dioxide cost obtained greatly declines.
But it is exactly that the flow of its liquefied ammonia cannot be adjusted with the flow of gas raw material that the recyclable device, which has a defect, It will appear the conveying excessive situation of ammonia in the flow-reduction of gas raw material, it is excessive other than absorbing the heat of gas raw material Liquefied ammonia can absorb the heat in environment, cause subsequent to need to consume unnecessary electric energy, therefore, this time to the re-liquefied of ammonia Receiving apparatus has much room for improvement, to reduce its energy consumption.
Utility model content
In view of the deficienciess of the prior art, the purpose of this utility model is to provide a kind of recycling of co 2 liquefaction to fill It sets, the conveying capacity of liquefied ammonia can be automatically adjusted with the flow of gas raw material, have lower energy consumption.
To achieve the above object, the utility model provides following technical solution:
A kind of co 2 liquefaction recyclable device, the raw material gas tank, the first compressor, cold including passing sequentially through pipeline connection But device, separator, heat exchanger, destilling tower and cryogenic vacuum storage tank, on the pipeline of connection raw material gas tank and the first compressor It is installed with gas flow sensor, which further includes liquid ammonia storage tank, and the outlet of the liquid ammonia storage tank is by going out ammonia pipeline The import of the evaporator on destilling tower top is connected, the outlet of the evaporator is connected with back ammonia pipeline, and described time ammonia pipeline passes through After heat exchanger connect liquid ammonia storage tank import, it is described go out ammonia pipeline on along liquefied ammonia circulation direction be successively installed with flow tune Electrically-controlled valve and frequency conversion liquid pump are saved, is installed with the second compressor on described time ammonia pipeline, which further includes master controller, institute It states flow adjusting electrically-controlled valve and frequency conversion liquid pump is all connected with and is controlled by master controller, the gas flow sensor and master controller Sampling end connection.
Preferably:The flow adjusts electrically-controlled valve using electromagnetic valve of flow control.
Preferably:The master controller includes PLC controller and the frequency converter that is electrically connected, the frequency conversion liquid Pump connects and is controlled by frequency converter, the sampling end of the gas flow sensor connection PLC controller, and the flow adjusts electromagnetism The control terminal of valve connection PLC controller.
Preferably:The gas flow sensor connects the sampling end of PLC controller by transmitter.
Preferably:Described a first compressor and a second compressor is screw compressor.
Preferably:The heat exchanger is metal plate fin type heat exchanger.
Compared with prior art, the utility model has the advantages that:During the recyclable device is run, gas flow sensing Flow information is simultaneously fed back to master controller by the flow of the gas of device real-time detection raw material gas tank outflow, and master controller is according to gas Changes in flow rate control the revolving speed of frequency conversion liquid pump, and the flow that flow adjusts electrically-controlled valve is controlled, to adjust the conveying of liquefied ammonia Amount keeps the utilization of liquefied ammonia more reasonable, reduces in liquefied ammonia external environment so that the conveying capacity of liquefied ammonia and the flow of gas be made to match The absorption of heat reduce the energy of carbon dioxide recovering apparatus so that the electric energy of subsequent re-liquefied ammonia consumption be effectively reduced Consumption.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of recyclable device;
Fig. 2 is circuit diagram.
Description of symbols:1, raw material gas tank;2, gas flow sensor;3, the first compressor;4, cooler;5, divide From device;6, heat exchanger;7, destilling tower;8, evaporator;9, cryogenic vacuum storage tank;10, frequency conversion liquid pump;11, flow is adjusted automatically controlled Valve;12, liquid ammonia storage tank;13, the second compressor.
Specific embodiment
Referring to Fig.1, a kind of co 2 liquefaction recyclable device, successively by raw material gas tank 1, the first compressor 3, cooler 4, Separator 5, heat exchanger 6, destilling tower 7 and cryogenic vacuum storage tank 9 are formed by connecting by pipeline.
It is installed with gas flow sensor 2 on the pipeline of connection raw material gas tank 1 and the first compressor 3, the recyclable device It further include liquid ammonia storage tank 12, the import that the outlet of liquid ammonia storage tank 12 connects the evaporator 8 on 7 top of destilling tower by going out ammonia pipeline, The outlet of evaporator 8 is connected with back ammonia pipeline, returns the import that ammonia pipeline connects liquid ammonia storage tank 12 after over-heat-exchanger 6, is going out Flow is successively installed with along the direction that liquefied ammonia circulates on ammonia pipeline and adjusts electrically-controlled valve 11 and frequency conversion liquid pump 10, on returning ammonia pipeline It is installed with the second compressor 13.
Referring to Fig. 2, which further includes master controller, and flow adjusts electrically-controlled valve 11 and frequency conversion liquid pump 10 is all connected with simultaneously It is controlled by master controller, gas flow sensor 2 is connect with the sampling end of master controller.
The working principle of the recyclable device is:
Unstrpped gas is flowed out from raw material gas tank 1, and carbon dioxide gas successively passes through the first compressor 3, cooler 4 and first Compressor 3, thus by compression, cooling, recompress, be segregated into 6 one wing passage of heat exchanger, the carbon dioxide through overcompression, Pressure reaches 2Mpa, and the carbon dioxide gas of high pressure subsequently enters in destilling tower 7, and frequency conversion liquid pump 10 will be in liquid ammonia storage tank 12 Liquefied ammonia is sent out, and liquefied ammonia passes through the evaporator 8 on 7 top of destilling tower, and liquefied ammonia evaporation absorbs amount of heat, enters back into heat exchanger 6 Another wing passage, by the carbon dioxide gas cooling liquid after compression separation, the carbon dioxide after liquefaction enters the progress of destilling tower 7 Separation, becomes high purity liquid carbon dioxide storage in cryogenic vacuum storage tank 9, to realize the liquefaction recycling of carbon dioxide.
Ammonia, liquefied ammonia mixture after absorbing heat then pass through the second compressor 13, and the high pressure of the second compressor 13 makes Obtain ammonia becomes liquefied ammonia again, in this way, flow back into liquid ammonia storage tank 12 is just entirely liquefied ammonia.
During recyclable device operation, the stream of the gas of 2 real-time detection raw material gas tank 1 of gas flow sensor outflow It measures and flow information is fed back into master controller, master controller controls turning for frequency conversion liquid pump 10 according to the changes in flow rate of gas Speed, and the flow that flow adjusts electrically-controlled valve 11 is controlled, so that the conveying capacity of liquefied ammonia is adjusted, to make the conveying capacity and gas of liquefied ammonia Flow match, make liquefied ammonia utilization it is more reasonable, reduce liquefied ammonia external environment in heat absorption, thus after being effectively reduced The electric energy for continuing re-liquefied ammonia consumption, reduces the energy consumption of carbon dioxide recovering apparatus.
In the present embodiment, flow adjusts electrically-controlled valve 11 using electromagnetic valve of flow control, and master controller includes PLC control Device and the frequency converter being electrically connected, frequency conversion liquid pump 10 connect and are controlled by frequency converter, and gas flow sensor 2 passes through transmitter The sampling end of PLC controller is connected, electromagnetic valve of flow control connects the control terminal of PLC controller.
In the present embodiment, the first compressor 3 and the second compressor 13 are screw compressor, and heat exchanger 6 is metal plate Fin type heat exchanger 6.
The above is only the preferred embodiment of the utility model, and the protection scope of the utility model is not limited merely to Above-described embodiment, technical solution belonging to the idea of the present invention belong to the protection scope of the utility model.It should refer to Out, for those skilled in the art, it is without departing from the principle of the utility model it is several improvement and Retouching, these improvements and modifications also should be regarded as the protection scope of the utility model.

Claims (6)

1. a kind of co 2 liquefaction recyclable device, raw material gas tank, the first compressor, cooling including passing sequentially through pipeline connection Device, separator, heat exchanger, destilling tower and cryogenic vacuum storage tank, it is characterized in that:In connection raw material gas tank and first compressor Gas flow sensor is installed on pipeline, which further includes liquid ammonia storage tank, and the outlet of the liquid ammonia storage tank is by going out Ammonia pipeline connects the import of the evaporator on destilling tower top, and the outlet of the evaporator is connected with back ammonia pipeline, described time ammonia pipe Road connects the import of liquid ammonia storage tank after over-heat-exchanger, is successively installed on the ammonia pipeline out along the direction of liquefied ammonia circulation Flow adjusts electrically-controlled valve and frequency conversion liquid pump, is installed with the second compressor on described time ammonia pipeline, which further includes master control Device processed, the flow adjusts electrically-controlled valve and frequency conversion liquid pump is all connected with and is controlled by master controller, the gas flow sensor with The sampling end of master controller connects.
2. co 2 liquefaction recyclable device according to claim 1, it is characterized in that:The flow adjusts electrically-controlled valve and uses Be electromagnetic valve of flow control.
3. co 2 liquefaction recyclable device according to claim 2, it is characterized in that:The master controller includes PLC control Device processed and the frequency converter being electrically connected, the frequency conversion liquid pump connect and are controlled by frequency converter, and the gas flow sensor connects Connect the sampling end of PLC controller, the control terminal of the electromagnetic valve of flow control connection PLC controller.
4. co 2 liquefaction recyclable device according to claim 3, it is characterized in that:The gas flow sensor passes through The sampling end of transmitter connection PLC controller.
5. co 2 liquefaction recyclable device according to claim 1, it is characterized in that:First compressor and the second pressure Contracting machine is screw compressor.
6. co 2 liquefaction recyclable device according to claim 1, it is characterized in that:The heat exchanger is metal plate fin type heat Exchanger.
CN201820491382.6U 2018-04-09 2018-04-09 Co 2 liquefaction recyclable device Expired - Fee Related CN208170858U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820491382.6U CN208170858U (en) 2018-04-09 2018-04-09 Co 2 liquefaction recyclable device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201820491382.6U CN208170858U (en) 2018-04-09 2018-04-09 Co 2 liquefaction recyclable device

Publications (1)

Publication Number Publication Date
CN208170858U true CN208170858U (en) 2018-11-30

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201820491382.6U Expired - Fee Related CN208170858U (en) 2018-04-09 2018-04-09 Co 2 liquefaction recyclable device

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110296576A (en) * 2019-06-13 2019-10-01 天津大学 A kind of industrial smoke collecting carbonic anhydride and waste heat recycle integrated system
CN111322829A (en) * 2020-03-05 2020-06-23 惠州市华达通石化有限公司 Novel carbon dioxide liquefaction device and preparation method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110296576A (en) * 2019-06-13 2019-10-01 天津大学 A kind of industrial smoke collecting carbonic anhydride and waste heat recycle integrated system
CN111322829A (en) * 2020-03-05 2020-06-23 惠州市华达通石化有限公司 Novel carbon dioxide liquefaction device and preparation method

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Granted publication date: 20181130

Termination date: 20210409