CN208093679U - Solid electrolyte for horizon battery - Google Patents
Solid electrolyte for horizon battery Download PDFInfo
- Publication number
- CN208093679U CN208093679U CN201721896007.1U CN201721896007U CN208093679U CN 208093679 U CN208093679 U CN 208093679U CN 201721896007 U CN201721896007 U CN 201721896007U CN 208093679 U CN208093679 U CN 208093679U
- Authority
- CN
- China
- Prior art keywords
- cathode
- anode
- layer
- coated
- pole cream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 12
- 239000006071 cream Substances 0.000 claims abstract description 48
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000919 ceramic Substances 0.000 claims abstract description 18
- 239000011521 glass Substances 0.000 claims abstract description 17
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 239000002131 composite material Substances 0.000 claims abstract description 16
- 239000011888 foil Substances 0.000 claims abstract description 11
- 229910001245 Sb alloy Inorganic materials 0.000 claims abstract description 10
- 239000002140 antimony alloy Substances 0.000 claims abstract description 10
- 229910006654 β-PbO2 Inorganic materials 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims 1
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 229910052787 antimony Inorganic materials 0.000 claims 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims 1
- YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000004744 fabric Substances 0.000 abstract description 8
- 230000006872 improvement Effects 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 229910021397 glassy carbon Inorganic materials 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 102000004310 Ion Channels Human genes 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Inorganic materials O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000002320 enamel (paints) Substances 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Cell Electrode Carriers And Collectors (AREA)
- Connection Of Batteries Or Terminals (AREA)
Abstract
The utility model is related to field of batteries, disclose the solid electrolyte for horizon battery, the cathode for including anode and being correspondingly arranged with anode, it further include encapsulating shell, anode is packaged in cathode inside encapsulating shell, and anode includes titanium-base layer, and one layer of conductive film is coated on titanium-base layer, on conductive film anode lug is connected with coated with positive pole cream, anode；Cathode includes glass carbon composite layer, and glass carbon composite layer is equipped with adhesion layer, is coated with cathode pole cream on lead-antimony alloy foil, cathode is connected with cathode tab；Bipolar plates are connected between anode and cathode, bipolar plates include ceramic layer, and positive pole cream and cathode pole cream are coated in ceramic layer；Anode lug and cathode tab each extend to outside encapsulating shell.When the application solves the unleaded cloth support of pole cream, easy fracture is damaged in use, the problem of influencing conductive effect.
Description
Technical field
The utility model is related to field of batteries, and in particular to be used for the solid electrolyte of horizon battery.
Background technology
Horizon battery is that have the research and development of Electrosource companies of the U.S. early 1980s, and full name is " lead cloth
Level double-clicks VRLA lead-acid accumulators ".It is the continuity product of VRLA lead-acid accumulators, uses the water of lead cloth and double polarity plate
Flat group stack structure, has many advantages, such as that battery specific energy is high, specific power reaches, punching/flash-over characteristic is good, the charging time is short, lasts a long time.
In traditional horizon battery, charge and discharge process electric current enters side plate from one end, bipolar into first through partition board
Unit, then another pole is entered by grid, electric current goes directly the other end.Positive and negative electrode cream is distinguished full-filling and grid two by horizon battery
End, makes pole plate, grid is usually lead cloth, and lead cloth complex manufacturing process, fund input is big and weight is big, increases level
The cost of manufacture and transportation cost of battery.If but easy fracture is damaged in use for the support of the unleaded cloth of pole cream, influences conduction
Effect.
Utility model content
The utility model is intended to provide the solid electrolyte for horizon battery, when being supported with solving the unleaded cloth of pole cream,
Easy fracture is damaged during use, the problem of influencing conductive effect.
In order to achieve the above objectives, the basic technology scheme of the utility model is as follows：For the solid electrolyte of horizon battery,
Include anode and with the cathode that anode is correspondingly arranged, further include encapsulating shell, anode is packaged in cathode inside encapsulating shell, sun
Pole includes titanium-base layer, and one layer of conductive film is coated on titanium-base layer, positive pole cream is coated on conductive film, anode is connected with anode
Lug；Cathode includes glass carbon composite layer, and glass carbon composite layer is equipped with adhesion layer, cathode pole is coated on lead-antimony alloy foil
Cream, cathode are connected with cathode tab；Bipolar plates are connected between anode and cathode, bipolar plates include ceramic layer, conduction pottery
The both sides of enamel coating are coated by positive pole cream and cathode pole cream；Anode lug and cathode tab each extend to outside encapsulating shell.
The principle of this programme is：When practical application, package casing plays the role of encapsulation and protects internal structure, anode,
Cathode and bipolar plates collectively form electrolyte structure, wherein titanium-base layer plays the role of the positive pole cream of support, and conductive film can increase
The adhesiveness for adding titanium-base layer makes titanium-base layer combine closely with positive pole cream, prevents falling off for positive pole cream, vitreous carbon is compound
Layer plays the role of supporting cathode pole cream, adhesion layer that can increase the adhesiveness between glass carbon composite layer and cathode pole cream, prevent
Cathode pole cream falls off, and positive pole ear and negative lug are the contact points of charging, discharging electric batteries, and positive pole cream and cathode pole cream assign titanium
Substrate layer and glass carbon composite layer polarity provide ion channel for battery current, and bipolar plates are connected to anode and cathode, wherein lead
Electroceramics layer plays the role of the positive pole cream of support and cathode pole cream.
The advantages of this programme is：
1. compared with the solid electrolyte of traditional horizon battery, base of the application using titanium-base layer as positive pole cream
Plate meets pole plate of the layer as cathode pole cream using vitreous carbon, titanium-base layer and glass carbon composite layer it is more traditional lead cloth it is light
Much, and durability is good, not only reduces the weight of battery itself, is more convenient transport, reduces transportation cost.
2. the application uses ceramic layer as the substrate of bipolar plates, intensity is high, stability is good, good conductivity and has
Preferable adhesiveness can well be adsorbed with positive pole cream and cathode pole cream, prevent falling off for pole cream, ensure that battery conductive
Stability.
Preferably, as an improvement, conductive film is β-PbO2Film.β-PbO2Film can not only increase the conduction of titanium-base layer
Effect can also increase adhesiveness, ensure the adhesiving effect of titanium-base layer and pole cream.
Preferably, as an improvement, adhesion layer is lead-antimony alloy layers of foil.It is compound that lead-antimony alloy layers of foil can increase vitreous carbon
Adhesiveness between layer and pole cream, avoids falling off and causing battery short circuit problem for pole cream.
Preferably, as an improvement, ceramic layer is equipped with multiple through-holes.Conductivity ceramics can go out in charge and discharge
The variation of existing volume, is arranged multiple logical in ceramic layer, can avoid being applied by volume change when ceramic layer
Pressure and produce fracture phenomenon.
Preferably, as an improvement, β-PbO2Finishing coat is equipped between film and titanium-base layer.Titanium-base layer is filling
It will produce TiO when electric discharge2, due to β-PbO2Film is more loose, to TiO2Restriction effect it is undesirable, and finishing coat can be prevented
Only TiO2Increase, to ensure conductive effect.
Description of the drawings
Fig. 1 is the structural schematic diagram of the utility model embodiment.
Specific implementation mode
The utility model is described in further detail below by specific implementation mode：
Reference numeral in Figure of description includes：Encapsulating shell 1, titanium-base layer 2, conductive film 3, positive pole cream 4, surface are repaiied
Adorn layer 5, anode lug 6, glass carbon composite layer 7, adhesion layer 8, cathode pole cream 9, cathode tab 10, ceramic layer 11, through-hole
12。
Embodiment is substantially as shown in Figure 1：Include anode and corresponding with anode for the solid electrolyte of horizon battery
The cathode of setting further includes encapsulating shell 1, and anode is packaged in cathode inside encapsulating shell 1, and anode includes titanium-base layer 2, titanium-base
One layer of conductive film 3 is coated on layer 2, conductive film 3 is β-PbO2Film, coated with positive pole cream 4, β-PbO on conductive film 32Film and titanium-based
Finishing coat 5 is equipped between plate layer 2, finishing coat 5 is SnO2+Sb2O3Layer, anode are connected with anode lug 6；Cathode packet
Include glass carbon composite layer 7, glass carbon composite layer 7 is equipped with adhesion layer 8, and adhesion layer 8 is lead-antimony alloy layers of foil, on lead-antimony alloy foil
Coated with cathode pole cream 9, cathode is connected with cathode tab 10；Bipolar plates are connected between anode and cathode, bipolar plates include leading
Electroceramics layer 11, ceramic layer 11 are equipped with multiple through-holes 12, positive pole cream 4 and cathode pole are coated in ceramic layer 11
Cream 9；Anode lug 6 and cathode tab 10 each extend to outside encapsulating shell 1.
In the present embodiment, when practical application, one layer of β-PbO is plated on titanium-base layer 22Positive pole cream 4 is coated to plating by film
There are β-PbO2On the titanium-base layer 2 of film, due to β-PbO2Film increases the surface adhesive of titanium-base layer 2, make titanium-base layer 2 with
Positive pole cream 4 is combined closely, and falling off for positive pole cream 4 is avoided；Titanium-base layer 2 will produce TiO in charge and discharge2, due to β-PbO2
Film is more loose, to TiO2Restriction effect it is undesirable, and finishing coat 5 can prevent TiO2Increase, to ensure conductive effect
Fruit；One layer of lead-antimony alloy layers of foil is plated on glass carbon composite layer 7, is applied on the glass carbon composite layer 7 for being coated with lead-antimony alloy layers of foil
Cathode pole cream 9 is applied, lead-antimony alloy layers of foil can increase the adhesiveness between glass carbon composite layer 7 and cathode pole cream 9, avoid pole cream
It falls off and causes battery short circuit；Apply positive pole cream 4 and cathode pole cream 9 in ceramic layer 11, and by titanium-base layer 2 and glass
Glass carbon composite layer 7 is connected to the both ends of ceramic layer 11, and multiple through-holes 12 are arranged in ceramic layer 11, can avoid working as
Ceramic layer 11 is produced fracture phenomenon by volume change pressure applied.
Above-described is only the embodiments of the present invention, the common sense such as well known concrete structure and/or characteristic in scheme
It does not describe excessively herein.It should be pointed out that for those skilled in the art, before not departing from the utility model structure
It puts, several modifications and improvements can also be made, these should also be considered as the scope of protection of the utility model, these all will not shadow
Ring effect and patent practicability that the utility model is implemented.This application claims protection domain should be in its claim
Subject to appearance, the records such as specific implementation mode in specification can be used for explaining the content of claim.
Claims (4)
- Include anode and the cathode that is correspondingly arranged with anode 1. for the solid electrolyte of horizon battery, it is characterised in that： Further include encapsulating shell, the anode is packaged in cathode inside encapsulating shell, and the anode includes titanium-base layer, the titanium-base layer On be coated with one layer of conductive film, be connected with anode lug coated with positive pole cream, the anode on the conductive film；The cathode packet Glass carbon composite layer is included, the glass carbon composite layer is equipped with adhesion layer, and the adhesion layer is lead-antimony alloy layers of foil, the lead antimony Cathode pole cream is coated in alloy layers of foil, the cathode is connected with cathode tab；It is connected between the anode and cathode bipolar Plate, the bipolar plates include ceramic layer, and the both sides of the ceramic layer are coated by positive pole cream and cathode pole cream； The anode lug and cathode tab each extend to outside the encapsulating shell.
- 2. the solid electrolyte according to claim 1 for horizon battery, it is characterised in that：The conductive film is β- PbO2 films.
- 3. the solid electrolyte according to claim 2 for horizon battery, it is characterised in that：In the ceramic layer Equipped with multiple through-holes.
- 4. the solid electrolyte according to claim 3 for horizon battery, it is characterised in that：β-PbO2 the films and titanium Finishing coat is equipped between substrate layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721896007.1U CN208093679U (en) | 2017-12-28 | 2017-12-28 | Solid electrolyte for horizon battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721896007.1U CN208093679U (en) | 2017-12-28 | 2017-12-28 | Solid electrolyte for horizon battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN208093679U true CN208093679U (en) | 2018-11-13 |
Family
ID=64065146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201721896007.1U Active CN208093679U (en) | 2017-12-28 | 2017-12-28 | Solid electrolyte for horizon battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN208093679U (en) |
-
2017
- 2017-12-28 CN CN201721896007.1U patent/CN208093679U/en active Active
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Guangzhou Zhuoyue Power Technology Co.,Ltd. Assignor: GUANGZHOU ZHUOYUE POWER NEW ENERGY Co.,Ltd. Contract record no.: X2023980048526 Denomination of utility model: Solid state electrolyte for horizontal batteries Granted publication date: 20181113 License type: Common License Record date: 20231204 Assignee: Guangzhou shunyao Energy Technology Co.,Ltd. Assignor: GUANGZHOU ZHUOYUE POWER NEW ENERGY Co.,Ltd. Contract record no.: X2023980048519 Denomination of utility model: Solid state electrolyte for horizontal batteries Granted publication date: 20181113 License type: Common License Record date: 20231204 |
|
| EE01 | Entry into force of recordation of patent licensing contract |